HomeMy WebLinkAboutResolution - 6261 - Admendment To Contract Of Sale - LCCIC & LCU - 04_08_1999Resolution No. 6261
Item No. 38
April 8, 1999
RESOLUTION
BE IT RESOLVED BY THE CITY COUNCIL OF THE CITY OF LUBBOCK:
THAT the Mayor of the City of Lubbock BE and is hereby authorized and
directed to execute for and on behalf of the City of Lubbock an Amendment and
Modification of Contract of Sale by and between the City of Lubbock and Lubbock
Christian College Investment Corporation and Lubbock Christian University, attached
hereto, which shall be spread upon the minutes of the Council and as spread upon the
minutes of this Council shall constitute and be a part of this Resolution as if fully copied
herein in detail.
Passed by the City Council this 8th day of April , 1999.
ATTEST:
�.J
Ka a arnell, City Secretary
APPROVED AS TO CONTENT:
Te6—my011erbr6ok, Managing Director of
Water Utilities
APPROVED AS TO F RM:
Richard . Ca ner, Natural Re'sowces Attorney
da/ccdocsfLCU-AraendCOS.res
April 8, 1999
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Resolution No. 6261
Item No. 38
April 8, 1999
AMENDMENT AND MODIFICATION OF CONTRACT OF SALE
STATE OF TEXAS §
COUNTY OF LUBBOCK §
C WHEREAS, effective January 14, 1999, Lubbock Christian University
Investment Corporation ("LCUIC"), Lubbock Christian University ("LCU") and the City
I' of Lubbock, Texas, a Home Rule Municipal Corporation of Lubbock County, Texas
("Buyer"), entered into that certain Contract of Sale ("Contract") contemplating the
purchase of lands located in Lubbock and Lynn Counties of Texas, as more particularly
r' described in Exhibit "A" and Exhibit "B" attached to the Contract; and
WHEREAS, the Contract provides that the Seller of the lands described therein is
LCUIC; however, further investigation has revealed that LCUIC does not exist as a legal
entity and that the owner of the lands described in the Contract is Lubbock Christian
College Investment Corporation, a Texas Non -Profit Corporation (referred to herein as
"Seller"); and
WHEREAS, it has come to the attention of Seller, LCU and Buyer that certain
other provisions of the Contract are in need of modification and amendment; and
WHEREAS, Seller, LCU and Buyer now desire to amend and modify the
Contract as to certain terms and provisions.
NOW, THEREFORE, for good and valuable consideration, the receipt and
f sufficiency of which is hereby acknowledged, Seller, LCU and Buyer hereby amend and
C modify the Contract as follows:
1. The first paragraph of the Contract is deleted in its entirety and the following
paragraph substituted therefore:
This Contract of Sale (the "Contract") is made by and between
Lubbock Christian College Investment Corporation, a Texas Non -Profit
Corporation (referred to herein as "Seller"), Lubbock Christian University
(referred to herein as "LCU") and the City of Lubbock, Texas, a Home Rule
Municipal Corporation of Lubbock County, Texas (referred to herein as
"Buyer").
2. Article 1 of the Contract is deleted in its entirety and the following Article I
substituted therefore:
ARTICLE I
SALE OF PROPERTY
For the consideration hereinafter set forth, and upon the terms,
conditions and provisions herein contained, Seller agrees to sell and convey
to Buyer and Buyer agrees to purchase from Seller (i) by general warranty
and reserving the oil, gas and other minerals, as set forth in Exhibit "A"
attached to this Amendment and Modification of Contract of Sale and the
Contract, as amended, and with surface protection covenants, as set forth in
the General Warranty Deed attached to this Amendment and Modification of
Contract of Sale and the Contract, as amended, as Exhibit "C", the Property,
less and except the ROW's; and (ii) by quitclaim conveyance, the ROW's.
3. Section 5.01(c) of the Contract is deleted in its entirety and the following
paragraph substituted therefore:
(c) The Seller has good and marketable fee simple title to the Property,
less and except the ROW's, subject only to the Permitted Exceptions.
4. Section 5.01(o) of the Contract is deleted in its entirety and the following
paragraph substituted therefore:
(o) All Leases, as defined in Section 5.02(a), shall have expired or
otherwise terminated on or before Closing.
5. Section 5.02(c) of the Contract is deleted in its entirety and the following
paragraph substituted therefore:
(c) Seller and LCU shall, for the consideration stated herein, quitclaim to
Buyer and cause Lubbock Christian University Institute of Water Research
("LCUIWR") to quitclaim to Buyer, on the form attached to this
Amendment and Modification of Contract of Sale and the Contract, as
"E",
amended, as Exhibit the ROW's. Further, LCU and LCUIWR shall
°
convey and assign the personal property described in the Bill of Sale, made a
part of this Amendment and Modification of Contract of Sale and the
Contract, as amended, as Exhibit "D", to Buyer. LCU expressly stipulates
that LCUIWR will benefit, in the same manner as LCU as set forth in
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Section 5.04, from the transactions contemplated hereby and that LCU
possesses the requisite control over LCUIWR to cause LCUIWR to execute
and deliver said quitclaim conveyance and Bill of Sale.
6. Section 5.02(e), set forth below, is added to the Contract, as amended:
(e) LCU and J. E. Hancock shall, for the consideration stated herein,
convey by Deed Without Warranty, to Buyer, on the form attached to this
Amendment and Modification of Contract of Sale and the Contract, as
Amendment and Modification of Contract of Sale
„Page 2 of 6
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amended, as Exhibit "G", the lands described on Exhibit "H" to this
Amendment and Modification of Contract of Sale and the Contract, as
amended. LCU expressly stipulates that J. E. Hancock will benefit, in the
same manner as LCU as set forth in Section 5.04, from the transactions
contemplated hereby and that LCU possesses the requisite control over J. E.
�^ Hancock to cause J. E. Hancock to execute and deliver said Deed Without
6 Warranty.
7. Section 5.03(g) of the Contract is deleted in its entirety, and the following
paragraph substituted therefore:
(g) Environmental Claims or Environmental Cleanup Liability which
arise directly or indirectly from or are related to the use, operation,
maintenance, occupation, ownership or abandonment of the Property before
the Effective Date shall be deemed to be limited to the Environmental Claims
or Environmental Cleanup Liability arising directly or indirectly from or are
related to those matters set forth in the Environmental Assessment attached
to and made a part of this Amendment and Modification of Contract of Sale
and the Contract, as amended, for all intents and purposes, as Exhibit "F".
Section 5.03(h) of the Contract is deleted in its entirety.
9. Section 5.05 of the Contract is deleted in its entirety, and the following Section
5.05 substituted therefore:
5.05 Survival Beyond Closing. The representations, warranties, covenants
and agreements of Seller and LCU as set forth in this Article V of this
Amendment and Modification of Contract of Sale and the Contract, as
amended, shall survive the Closing.
10. Section 6.05 of the Contract is deleted in its entirety.
11. Section 7.01 of the Contract is deleted in its entirety, and the following Section
7.01 substituted therefore:
7.01 Date and Place of Closing. The Closing shall take place in the offices of
the Title Company and shall be accomplished through an escrow to be
established with the Title Company, as escrowee. The Closing Date (herein
sometimes called), shall be on the later to occur of (i) the date upon which
Seller cures, or Buyer waives, Buyer's Objections, as set forth in Article III
of the Contract, as amended; or (ii) as mutually agreed on by Seller and
Buyer.
12. Section 7.02(a)(v) of the Contract is deleted in its entirety, and the following
paragraph substituted therefore:
Amendment and Modification of Contract of Sale
Page 3 of 6
G.
(v) The Quitclaim Conveyance, substantially in the form as attached to
this Amendment and Modification of Contract of Sale and the Contract, as
�^ amended, as Exhibit "E", duly executed by Seller, and acknowledged.
13. Section 7.02(b)(ii) of the Contract is deleted in its entirety, and the following
paragraph substituted therefore:
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(ii) The Deed Without Warranty, substantially in the form as attached to
7 this Amendment and Modification of Contract of Sale and the Contract, as
c amended, as Exhibit "G", duly executed by LCU and J. E. Hancock, and
acknowledged.
14. Section 7.04 of the Contract is deleted in its entirety, and the following Section
7.04 substituted therefore:
7.04 Possession at Closing. Possession of the Property shall be delivered to
Buyer by Seller on the Closing Date (the f°Date of Possession"), in its present
condition, subject only to ordinary wear and tear.
15. Exhibit "A" of the Contract is deleted in its entirety and Exhibit "A" attached to
this Amendment and Modification of Contract of Sale and the Contract, as amended,
substituted therefore.
16. Exhibit "C" of this Contract is deleted in its entirety and Exhibit "C" attached to
r this Amendment and Modification of Contract of Sale and the Contract, as amended,
substituted therefore.
17. Exhibit "D" of this Contract is deleted in its entirety and Exhibit "D" attached to
this Amendment and Modification of Contract of Sale and the Contract, as amended,
substituted therefore.
.- 18. Exhibit "E" of this Contract is deleted in its entirety and Exhibit "E" attached to
this Amendment and Modification of Contract of Sale and the Contract, as amended,
substituted therefore.
19. Exhibits "F" through "H" to this Amendment and Modification of Contract of
Sale, are added to this Amendment and Modification of Contract of Sale and the
Contract, as amended.
To the extent any of the terms or provisions of this Amendment and Modification
of Contract of Sale shall conflict with any terms or provisions of the Contract, the terms
and provisions of this Amendment and Modification of Contract of Sale shall control and
prevail. All terms and provisions of the Contract shall be and remain in full force and
effect as therein written, except as otherwise expressly amended and/or modified herein.
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Amendment and Modification of Contract of Sale
Page 4 of 6
This Amendment and Modification of Contract of Sale is executed on the dates
set forth below, but effective as of the Effective Date, as defined in the Contract, as
�• amended.
SELLER:
LUBBOCK CHRISTIAN COLLEGE
INVESTMENT CORPORATION
By:
HARVIE M. R ITT
Chairman of the Board
Executed by Seller on the day of .1999.
LCU:
LUBBOCK CHRISTIAN UNIVERSITY
v
By: p A A --f 0 A 4 -4 -'ej,
JERgYyb. HA
ChairVan of the Board
Executed by LCU on the day of , 1999.
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Amendment and Modification of Contract of Sale
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BUYER:
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WIYD If
Executed by Buyer the gkk day I
on of
ATTEST:
/6AL
Ka �cairrlell, City Secretary
AS CONTENT:
APPROVED TO
1
Terry Ellerbro6k,
Managing Director of Water Utilities
APPROVED AS TO FORM:
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Flo
, /!:
-6— --..�
Richard K. Casner,
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Natural Resources Attorney
cityatt/richard/LCU-ContractAmendment.doc
April 7, 1999
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Amendment and Modification of Contract of Sale
Page 6 of 6
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, Mayor
1999.
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Exhibit "A' To Amendment and
Modification of Contract of Sale
and Contract of Sale, as Amended
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FEXHIBIT "A"
To Amendment and Modification of Contract of Sale
and Contract of Sale, as Amended
The following described tracts or parcels of land lying and being situated in Lynn
County, Texas, to -wit:
All of Tracts 2, 3, 4, 5, 6 and 8, in League One, and Tract 7 of League
Two, according to the map or plat of Wm. D. Green's Subdivision of a
part of Leagues 1, 2, 3 and 4, Wilson County School Lands, Lynn County,
Texas, which map or plat is of record in Book 57, Page 38, of the Deed
Records of Lynn County, Texas, containing 1214.52 acres.
All of Tracts 1, 7, 9 and 10 in League 1; Tracts 1, 2, 6, 8, 11, 12, 13 and 14
in League 2; Tract 3 in League 3; and Tracts 1, 2, 3 and 4 in League 4,
according to the Map or Plat of William D. Green Subdivision of a part of
Leagues 1, 2, 3 and 4, Wilson County School Lands, Lynn County, Texas,
which Map or Plat is of record in Book 57, Page 38, of the Deed Records
of Lynn County, Texas.
LESS and EXCEPT the following described lands located in Lynn
County, Texas, to -wit:
METES AND BOUNDS DESCRIPTION OF A 41.977 ACRE TRACT
OF LAND IN THE WILSON COUNTY SCHOOL LAND, LYNN
COUNTY, TEXAS BEING A PORTION OF TRACT 4 LEAGUE 4 OF
THE WM. D. GREEN'S SUBDIVISION AS SHOWN ON THE MAP OR
PLAT THEREOF RECORDED IN VOLUME 57 PAGE 38 OF THE
DEED RECORDS OF LYNN COUNTY, TEXAS AND BEING A
PORTION OF THAT TRACT DESCRIBED IN VOLUME 291 PAGE
935 OF SAID RECORDS AND FURTHER DESCRIBED AS
FOLLOWS:
BEGINNING AT A'/z" IRON ROD WITH CAP FOUND IN THE
SOUTH LINE OF SAID TRACT 4 AND THE NORTHWEST RIGHT
OF WAY LINE OF F.M. HIGHWAY 400 AS DESCRIBED IN
VOLUME 104 PAGE 306 OF SAID RECORDS FROM WHENCE A %"
IRON ROD FOUND AT THE SOUTHWEST CORNER OF SAID
TRACT 4 BEARS S 89053'00" W A DISTANCE OF 2673.79 FEET;
THENCE S 89°53'00" W, ALONG THE SOUTH LINE OF SAID
TRACT 4, A DISTANCE OF 996.19 FEET TO A %" IRON ROD WITH
CAP SET FOR A CORNER OF THIS TRACT;
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THENCE N 0000'00" E A DISTANCE OF 3 81.3 9 FEET TO A %" IRON
ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE S 89053'00" W A DISTANCE OF 1605.04 FEET TO A'/z"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 0000'00" E A DISTANCE OF 1145.30 FEET TO A'/s"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 90000'00" E A DISTANCE OF 100.00 FEET TO A'/z"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE S 0000'00" W A DISTANCE OF 1045.10 FEET TO A %"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 89053'00" E A DISTANCE OF 1075.06 FEET TO A %"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 0000'00" E A DISTANCE OF 173.89 FEET TO A %s" IRON
ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 90000'00" E A DISTANCE OF 100.00 FEET TO A %Z"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE S 0000'00" W A DISTANCE OF 173.69 FEET TO A'/z" IRON
ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 89053'00" E A DISTANCE OF 455.22 FEET TO A'/s"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 0000'00" E A DISTANCE OF 1065.86 FEET TO A'/2"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 89053'00" E A DISTANCE OF 963.27 FEET TO A %s"
IRON ROD WITH CAP SET IN THE EAST LINE OF SAID TRACT 4
AND A GRADED COUNTY ROAD FOR A CORNER OF THIS
TRACT;
THENCE S 0000'06" E, ALONG SAID EAST LINE AND SAID
COUNTY ROAD, A DISTANCE OF 1447.62 FEET TO A'/z" IRON
ROD FOUND IN SAID NORTHWEST RIGHT OF WAY FOR A
CORNER OF THIS TRACT;
THENCE S 42046'51" W, ALONG SAID RIGHT OF WAY LINE, A
DISTANCE OF 136.0 FEET TO THE PLACE OF BEGINNING.
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SAVE AND EXCEPT, all oil, gas and other minerals in, on and under and that may be
produced from the Land are hereby reserved unto Seller and Seller's successors and
assigns. As used herein, the term "minerals" shall exclude (i) all substances (except oil
C
and gas) that any reasonable extraction, mining or other exploration and/or production
method, operation, process or procedure would consume, deplete or destroy the surface
of the Land; and (ii) all substances (except oil and gas) which are at or near the surface of
the Land. The intent of the parties hereto is that the meaning of the term "minerals" as
utilized herein, shall be in accordance with that set forth in Reed v. Wylie, 597 S.W.2d
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743 (Tex. 1980).
cityatt\richardlexhA-amendCOS.doc
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Exhibit "C" To Amendment and
Modification of Contract of Sale
and Contract of Sale, as Amended —
General Warranty Deed
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EXHIBIT "C"
To Amendment and Modification of Contract of Sale
and Contract of Sale, as Amended
GENERAL WARRANTY DEED
STATE OF TEXAS §
COUNTY OF LYNN §
KNOW ALL MEN BY THESE PRESENTS:
That LUBBOCK CHRISTIAN COLLEGE INVESTMENT CORPORATION, a Texas
Non -Profit Corporation (herein called "Grantor"), for and in consideration of the sum of TEN
AND NO/100 DOLLARS ($10.00), and other good and valuable consideration to Grantor in hand
paid by the CITY OF LUBBOCK, a Texas Home Rule Municipal Corporation (herein called
"Grantee"), P.O. Box 2000, Lubbock, Texas 79457, the receipt and sufficiency of which are
hereby acknowledged and confessed, subject to the reservations set further below, has
GRANTED, SOLD and CONVEYED, and by these presents does GRANT, SELL and
CONVEY, unto Grantee all the real property in Lynn County, Texas described on Exhibit "A"
attached hereto, together with all fixtures and improvements attached thereto (the "Lands").
PROVIDED HOWEVER, the Lands are hereby conveyed subject to all valid, existing
mineral reservations and conveyances, and easements and rights -of -way, if any, affecting said
premises and of record in the Offices of the County Clerk of Lynn County, Texas.
Grantor, subject to the restrictions set forth below, expressly reserves to itself, its
successors and assigns, all oil, gas and other minerals lying in, on, under and that may be
produced from the Lands. As used herein, the term "minerals" shall exclude (i) all substances
(except oil and gas) that any reasonable extraction, mining or other exploration and/or production
method, operation, process or procedure would consume, deplete or destroy the surface of the
Lands; and (ii) all substances (except oil and gas) which are at or near the surface of the Lands.
GENERAL WARRANTY DEED
Page 1 of 6
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FThe intent of the parties hereto is that the meaning of the term "mineral" as utilized herein, shall
be in accordance with that set forth in Reed v. Wylie, 597 S.W.2d 743 (Tex. 1980).
For the protection of the surface estate of the Lands, and as a covenant running with said
lands and binding upon the Grantor herein and the Grantor's successors and assigns, it is agreed
that any person, company or other entity conducting operations in connection with the interest in
the oil, gas and other minerals in, on, under and that may be produced from said Lands which is
now owned by Grantor, under the authority of the Grantor, its successors and assigns, granted
after the date hereof, shall comply with the following provisions and requirements for the
protection of the surface estate of said Lands, and any oil, gas and mineral lease hereafter
executed by the Grantor, its successors and assigns, shall contain such provisions, it being
understood and agreed, however, that such provisions will be binding upon the person,
company or other entity conducting such mineral operations (in such provisions referred
to as Lessee) as covenants running with the land and whether or not such provisions are
included in such lease or leases hereafter executed, said provisions being as follows:
(a) Lessee, its successors and assigns, (as used in paragraphs (a) through (k),
the term "Lessee" shall include Grantor if Grantor is the party conducting
the oil, gas and other mineral exploration and/or production activities) shall
pay to the owner of the surface estate of the Lands (the "Surface Owner") a
reasonable amount for all damages of any type or kind caused or related to
mineral exploration and/or production activities upon the Lands.
(b) Lessee shall conduct all of its mineral exploration and/or production
activities upon the Lands in such a manner so as to interfere as little as
reasonably possible with the use and operation of the Lands of the Surface
Owner. No surface drilling location, storage facility, roadway or facility of
any kind located on or above the surface shall be located within or under a
pivot irrigation system without the prior consent of the Surface Owner,
which consent shall not be unreasonably withheld.
(c) It is further understood and agreed that any and all roads established by the
Lessee hereunder shall be located as nearly as practical as agreed upon by
and between Lessee and the Surface Owner.
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k GENERAL WARRANTY DEED
Page 2 of 6
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(d) All pipelines, flowlines, electric transmission lines, telephone lines or other
lines necessary or related to mineral exploration and/or production activities
on the Lands shall be buried no less than thirty-six (36) inches below the
I surface of the ground, except at the actual drilling or storage facility site.
(e) Upon completion of any mineral exploration and/or production activities,
including exploration activities that result in the completion of an oil or gas
well(s) or abandonment of any drill site(s), pit area(s), well location(s), tank
battery location(s), roadway(s) or other surface disturbance(s), Lessee shall
as soon as reasonably practicable (i) remove all rock, gravel, caliche, or
other materials foreign to the natural condition of the Lands; (ii) level and
fill with topsoil all pits, ruts, or other surface disturbances in such a manner
as to restore same to the natural contour of the Lands; (iii) clean the area to
the end that all objects, materials and structures not reasonably necessary to
the production of oil and/or gas are removed and eliminated; (iv) reseed the
affected area with native grass; and (v) otherwise restore the surface of the
Lands to its original condition as nearly as reasonably possible.
(f) Any saltwater produced from wells drilled on the Lands shall be disposed of off
the Lands, or shall be reinjected into a subsurface strata at a depth sufficient to
protect all sources and supplies of fresh and potable water. No saltwater shall be
disposed on the Lands, as set forth herein, except that produced from the Lands.
(g) Lessee agrees to protect the potable water, in, on and under the Lands, from
contamination from mineral exploration and/or production activities, and upon the
abandonment of any oil or gas well. Lessee shall plug the same in compliance
with the applicable laws, rules and regulations of the Railroad Commission of
Texas, and/or any other governmental authority having jurisdiction over such
matters.
(h) Lessee, if requested by Surface Owner, shall construct and maintain fences around
each site of surface facilities related to mineral pumping units, tank batteries and
pits sufficient to keep all livestock out of such sites.
(i) Lessee shall not, and shall not permit any of its employees, contractors, agents, or
other third parties acting on behalf of such parties entering upon the Lands, to
bring upon the Lands any alcoholic beverages or illegal drugs, to hunt on any
portion of the Lands or to take or carry any firearms thereon for any purpose
whatsoever.
(j) All mineral exploration and/or production operations on the Lands shall be
conducted in a reasonably prudent manner and in compliance with the laws, rules
GENERAL WARRANTY DEED
Page 3 of 6
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and regulations pertaining to oil, gas and mineral operations within the State of
Texas.
(k) No potable water, or water suitable for livestock consumption, irrigation or land
application purposes, may be taken or used, in any way, manner or form, from the
Lands for or related to any mineral exploration and/or production activities of any
kind or type.
Notwithstanding any of the above language to the contrary, Grantor shall have no
personal liability to the owner of the surface estate in connection with the mineral
operations conducted thereon by other parties.
TO HAVE AND TO HOLD the Lands, together with all and singular the rights and
appurtenances thereto in anywise belonging unto Grantee and Grantee's successors and assigns
forever; and Grantor does hereby bind Grantor and Grantor's successors and assigns to
WARRANT AND FOREVER DEFEND all and singular the Lands unto Grantee and Grantee's
successors and assigns, against every person whomsoever lawfully claiming or to claim the same
or any part thereof.
EXECUTED this day of April, 1999.
LUBBOCK CHRISTIAN COLLEGE
INVESTMENT CORPORATION
L80
Harvie M. Pruitt, Chairman
GENERAL WARRANTY DEED
Page 4 of 6
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STATE OF TEXAS §
COUNTY OF §
p This instrument was acknowledged before me on the day of April, 1999, by Harvie
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�., M. Pruitt, Chairman of the Board of Directors of Lubbock Christian College Investment
4
Corporation, a Texas non-profit corporation, on behalf of said corporation.
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Notary Public, State of Texas
GNRLWARR.rkc
March 29. 1999
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GENERAL WARRANTY DEED
Page 5 of 6
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EXHIBIT "A"
To General Warranty Deed
The following described tracts or parcels of land lying and being situated in Lynn County,
Texas, to -wit:
All of Tracts 2, 3, 4, 5, 6 and 8, in League One, and Tract 7 of League Two,
according to the map or plat of Wm. D Green's Subdivision of a part of
Leagues 1, 2, 3 and 4, Wilson County School Lands, Lynn County, Texas,
which map or plat is of record in Book 57, Page 38, of the Deed Records of
Lynn County, Texas, containing 1214.52 acres.
All of Tracts 1, 7, 9 and 10 in League 1; Tracts 1, 2, 6, 8, 11, 12, 13 and 14 in
League 2; Tract 3 in League 3; and Tracts 1, 2, 3 and 4 in League 4, according
to the Map or Plat of William D. Green Subdivision of a part of Leagues 1, 2, 3
and 4, Wilson County School Lands, Lynn County, Texas, which Map or Plat is
of record in Book 57, Page 38, of the Deed Records of Lynn County, Texas.
LESS and EXCEPT the following described lands located in Lynn County,
Texas, to -wit:
METES AND BOUNDS DESCRIPTION OF A 41.977 ACRE TRACT OF
LAND IN THE WILSON COUNTY SCHOOL LAND, LYNN COUNTY,
TEXAS BEING A PORTION OF TRACT 4 LEAGUE 4 OF THE WM. D.
GREEN'S SUBDIVISION AS SHOWN ON THE MAP OR PLAT THEREOF
RECORDED IN VOLUME 57 PAGE 38 OF THE DEED RECORDS OF LYNN
COUNTY, TEXAS AND BEING A PORTION OF THAT TRACT DESCRIBED
IN VOLUME 291 PAGE 935 OF SAID RECORDS AND FURTHER
DESCRIBED AS FOLLOWS:
BEGINNING AT A V2" IRON ROD WITH CAP FOUND IN THE SOUTH LINE
OF SAID TRACT 4 AND THE NORTHWEST RIGHT OF WAY LINE OF F.M.
HIGHWAY 400 AS DESCRIBED IN VOLUME 104 PAGE 306 OF SAID
RECORDS FROM WHENCE A V2" IRON ROD FOUND AT THE
SOUTHWEST CORNER OF SAID TRACT 4 BEARS S 89053'00" W A
DISTANCE OF 2673.79 FEET;
THENCE S 89053'00" W, ALONG THE SOUTH LINE OF SAID TRACT 4, A
DISTANCE OF 996.19 FEET TO A'/z" IRON ROD WITH CAP SET FOR A
CORNER OF THIS TRACT;
GENERAL WARRANTY DEED
Page 6 of 7
Exhibit "D" To Amendment and
Modification of Contract of Sale
and Contract of Sale, as Amended —
Bill of Sale
EXHIBIT "D"
To Amendment and Modification of Contract of Sale
and Contract of Sale, as Amended
BILL OF SALE
STATE OF TEXAS §
KNOW ALL MEN BY THESE PRESENTS
COUNTY OF LUBBOCK §
The undersigned, LUBBOCK CHRISTIAN UNIVERSITY, successor by name
change to LUBBOCK CHRISTIAN COLLEGE, LUBBOCK CHRISTIAN COLLEGE
INVESTMENT CORPORATION, a Texas Non -Profit Corporation and LUBBOCK
CHRISTIAN UNIVERSITY INSTITUTE OF WATER RESEARCH (collectively, the
"Grantor"), for and in consideration of the sum of TEN AND N0/100 DOLLARS
($10.00) and other good and valuable consideration to Grantor in hand paid by the CITY
OF LUBBOCK, a Texas Home Rule Municipal Corporation ("the Grantee"), the receipt
and sufficiency of which are hereby acknowledged and confessed, has BARGAINED,
SOLD and CONVEYED and by these presents, does BARGAIN, SELL and CONVEY
unto Grantee, all of Grantor's right, title, and interest to the personal property located in
or on or utilized in connection with or related to the real property described on Exhibit
"A" and Exhibit "B" attached hereto, including without limitation, the personal property
described on Exhibit "C", attached hereto (the "Property").
TO HAVE AND TO HOLD all of the Grantor's right, title and interest in and to
the Property unto said Grantee and Grantee's successors and assigns forever, so that
neither Grantor nor Grantor's successors and assigns shall have, claim or demand any
right or title to the Property.
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Executed and effective this
day of April, 1999.
GRANTOR:
LUBBOCK CHRISTIAN UNIVERSITY
Jerry D. Harris
Chairman of the Board
GRANTOR:
LUBBOCK CHRISTIAN COLLEGE
INVESTMENT CORPORATION
Harvie M. Pruitt
Chairman of the Board
GRANTOR:
LUBBOCK CHRISTIAN UNIVERSITY
INSTITUTE OF WATER RESEARCH
By: _
Name:
Title:
F EXHIBIT "A"
To Bill of Sale
The following described tracts or parcels of land lying and being situated in Lynn
County, Texas, to -wit:
Tract One
All of Tracts 2, 3, 4, 5, 6 and 8, in League One, and Tract 7 of League
Two, according to the map or plat of Wm. D. Green's Subdivision of a
part of Leagues 1, 2, 3 and 4, Wilson County School Lands, Lynn County,
Texas, which map or plat is of record in Book 57, Page 38, of the Deed
Records of Lynn County, Texas, containing 1214.52 acres.
Tract Two
All of Tracts 1, 7, 9 and 10 in League 1; Tracts 1, 2, 6, 8, 11, 12, 13 and 14
in Leauge 2; Tract 3 in League 3; and Tracts 1, 2, 3 and 4 in League 4,
according to the Map or Plat of William D. Green Subdivision of a part of
Leagues 1, 2, 3 and 4, Wilson County School Lands, Lynn County, Texas,
which Map or Plat is of record in Book 57, Page 38, of the Deed Records
of Lynn County, Texas.
Tract Three
Three (3) tracts of land, being: (a) 31.39 acre tract, more or less, in the
form of a triangle, said triangle being bounded on the N by the S line of
Tracts 3 and 4, League 4, Wilson County School Land; on the SE by the
Panhandle and South Plains Railroad right-of-way; and on the SW by Kerr
Avenue of the Town of Wilson, Texas; (b) 31.50 acres, more or less, said
tract being bounded on the N by the S line of Tracts 3 and 4, League 4,
Wilson County School Land; on the NE by Culpepper Avenue of the
Town of Wilson, Texas; on the SE by 16`h Street of the Town of Wilson,
Texas; on the SW by Green Avenue of the Town of Wilson, Texas; and on
the W by the W line of League 4, Wilson County School Land, SAVE &
EXCEPT Lots 1, 2, 3, 10, 11 and 12, Block 171, Lots 1, 2, 3, 7, 8, 9, 10,
11 & 12, Block 172, all of Block 178, 160' x 175' tract sold to Dan Cook
(being all of Lots 11 and 12, Block 182 and all of the Street lying South of
said lots); (c) a 14.25 acre tract, more or less, being all of Blocks 173, 175,
176, 177, 183, 185, 186, 187, 188 and 189, as shown of record in Volume
15, Page 102-103, Deed Records of Lynn County, Texas, SAVE &
EXCEPT those portions of the aforementioned blocks deeded to Henry
Dreyer, Jr., by deed recorded in Volume 62, Page 418-419, Deed Records
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of Lynn County, Texas, and EXCEPTING all of Block 174 dedicated as a
public park.
Tract Four
All of Block 169, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-
12 of Block 170, Old Town Wilson, Wilson, Lynn County, Texas; Lots 4-
9 of Block 171, Old Town Wilson, Wilson, Lynn County, Texas; Lots 4-6
�.. of Block 172, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-12
of Block 179, Old Town Wilson, Wilson, Lynn County, Texas; All of
Block 180, Old Town Wilson, Wilson, Lynn County, Texas; All of Block
r. 181, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-6 of Block
182, Old Town Wilson, Wilson, Lynn County, Texas; Lots 5-12 of Block
184, Old Town Wilson, Wilson, Lynn County, Texas.
LESS and EXCEPT the following described lands located in Lynn
County, Texas, to -wit:
METES AND BOUNDS DESCRIPTION OF A 41.977 ACRE TRACT
OF LAND IN THE WILSON COUNTY SCHOOL LAND, LYNN
COUNTY, TEXAS BEING A PORTION OF TRACT 4 LEAGUE 4 OF
THE WM. D. GREEN'S SUBDIVISION AS SHOWN ON THE MAP OR
PLAT THEREOF RECORDED IN VOLUME 57 PAGE 38 OF THE
DEED RECORDS OF LYNN COUNTY, TEXAS AND BEING A
PORTION OF THAT TRACT DESCRIBED IN VOLUME 291 PAGE
935 OF SAID RECORDS AND FURTHER DESCRIBED AS
FOLLOWS:
BEGINNING AT A'/z" IRON ROD WITH CAP FOUND IN THE
SOUTH LINE OF SAID TRACT 4 AND THE NORTHWEST RIGHT
OF WAY LINE OF F.M. HIGHWAY 400 AS DESCRIBED IN
VOLUME 104 PAGE 306 OF SAID RECORDS FROM WHENCE A %"
IRON ROD FOUND AT THE SOUTHWEST CORNER OF SAID
TRACT 4 BEARS S 89053'00" W A DISTANCE OF 2673.79 FEET;
THENCE S 89053'00" W, ALONG THE SOUTH LINE OF SAID
TRACT 4, A DISTANCE OF 996.19 FEET TO A %" IRON ROD WITH
CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 0000'00" E A DISTANCE OF 381.39 FEET TO A %" IRON
ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE S 89053'00" W A DISTANCE OF 1605.04 FEET TO A'/2"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
1 � THENCE N 0000'00" E A DISTANCE OF 1145.30 FEET TO A %"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
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THENCE N 90000'00" E A DISTANCE OF 100.00 FEET TO A'/2"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE S 0000'00" W A DISTANCE OF 1045.10 FEET TO A t/z"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 89053'00" E A DISTANCE OF 1075.06 FEET TO A'/2"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 0000'00" E A DISTANCE OF 173.89 FEET TO A'/2" IRON
ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 90000'00" E A DISTANCE OF 100.00 FEET TO A'/2"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE S 0000'00" W A DISTANCE OF 173.69 FEET TO A'/z" IRON
ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 89053'00" E A DISTANCE OF 455.22 FEET TO A'/2"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 0000'00" E A DISTANCE OF 1065.86 FEET TO A t/s"
IRON ROD WITH CAP SET FOR A CORNER OF THIS TRACT;
THENCE N 89053'00" E A DISTANCE OF 963.27 FEET TO A'/2"
IRON ROD WITH CAP SET IN THE EAST LINE OF SAID TRACT 4
AND A GRADED COUNTY ROAD FOR A CORNER OF THIS
TRACT;
THENCE S 0000'06" E, ALONG SAID EAST LINE AND SAID
COUNTY ROAD, A DISTANCE OF 1447.62 FEET TO A %Z" IRON
ROD FOUND IN SAID NORTHWEST RIGHT OF WAY FOR A
CORNER OF THIS TRACT;
THENCE S 42046'51" W, ALONG SAID RIGHT OF WAY LINE, A
DISTANCE OF 136.0 FEET TO THE PLACE OF BEGINNING.
cityatttrichard/LCU-ToBillof5ale.exttA
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EXHIBIT "B"
To Bill of Sale
All easements, rights -of way or any other ways of access and all rights in and to pipelines
and appurtenant property or facilities owned by Grantor in Sections 1 and 4, Block B;
i Sections 1, 2, 4, 11,12, 13,16, 25, 26, 27, 28, 55, 56, 57, 58, 59 and 60, Block S, GC &
SF R.R. Co. Survey, and Sections 40, 35, 30, 31, 32 and 34, Block 24, HE & VAT R.R.
Co. Survey, Lubbock County, Texas and Sections 2 and 3, Block M, EL & RR R.R. Co.
Survey, Lynn County, Texas, including without limitation, the following:
Description of the approximate location of a 2T force main leading from the
Southeast Water Reclamation Plant to the LCC Institute of Water Research
Lubbock Land Treatment System Research and Demonstration Project at the
Wilson farm in Lynn Co., also referred to as the Wilson Line, contained in
Lubbock and Lynn Counties of the State of Texas:
Beginning at Station 0+00 said point being the connection to the discharge header
at the Southeast Reclamation Plant;
Thence S 11. 15' E a distance of 139' to station 1+38;
Thence S 33" 45' E a distance of 400' to station 5+38;
Thence S 2r 30' E a distance of 256 to station 7+94;
Thence S 67* 30' W a distance of 402' to station 11+96;
Thence south a distance of 223' to station 14+ 19;
FThence S 67* 39 W a distance of 710' to station 21+29;
Thence in a southerly direction, 18' east of and parallel to the ccnterline of Guava_
Avenue, a distance of 3110' to station 52+39, said point being the end of a curve
to the right having a radius of 833', and arch distance of 64' and a delta angle of 4°
24' 07";
Vence along said curve to the right a distance of 64' to station 53+03, said point
being in the end of a curve to the right and the beginning of a curve to the left
having a radius of 1106', arch distance of 149', and a delta angle of 71 43' 08";
Thence along said curve a distance of 149 to station 54+52 said point falling in
the right-of-way of FM 835 at the approximate highway centerline station 8+44 as
referred to in State Department of Highways and Public Transportation Approval
r Form 1023, control 4933, Section 1, dated November 28, 1979;
l Thence in a southeasterly direction a distance of 73' to station 55+25;
Thence in a southwesterly direction a distance of 51' to station 55+76 said point
being 15' west of the centerline of Burlington Railway Spur Track #261;
Thence in a southeasterly direction, 15' west of and parallel to Burlington Spur
Track #261 a distance of 786' to station 63+62
Thence in a southwesterly direction, 194' to station 65+46 said point being 25'
east of the centerline of Spur 331 and highway station 185+52.5 as referred to in
State Department of Highways and Public Transportation Approval Form 1023,
Control 53, Section 1, Highway # Spur 331 and Control 3273, Section 1,
Highway #FM 3020 dated December 5, 1979;
l . Thence parallel to and 6 east of the east right-of-way line a distance of 1208' to
station 115+64 said point being the beginning of a transition from 6' east of the
east right-of-way line to 25' east of the centerline of Spur 331;
Thence parallel to and 25' east of the centerline of Spur 331 a distance of 3171' to
r station 147+35 said point being the beginning of a transition back to 25' east of
i the centerline to 3T east of the centerline;
Thence parallel to and 37' east of the centerline of Spur 331 a distance of 326' to
station 150+61 said point being the beginning of a transition back to 25' east of
the centerline;
Thence 28T to station 153+48 said point being 25' east of the centerline of Spur
331;
Thence parallel to and 25' east of the centerline a distance of 3216' to station
185+64 said point being the beginning of a transition back from 25' east of the
centerline to 3' west and parallel to the east right-of-way line of Spur 331;
Thence 3' west and parallel to east right-of-way line a distance of 1336 to station
199+00 said point being the beginning of a transition from 3' west of the east
right-of-way of Spur 331 to 10' west of and parallel to the east right-of-way line of
Spur 331;
Thence in a southeasterly direction a distance of approximately 100' to station
200+00 said point being 10' west of the east right-of-way line of Spur 331;
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Thence 10' west of and parallel to the east right-of-way lien a distance of 2099' to
station 220+99 said point being at the end of Spur 331 and where the control for
U.S. 84 begins;
Thence continuing in a southeasterly direction 10' south of the northern right-of-
way line of U.S. 84 and parallel to U.S. 84 a distance of 14,666' to station 367+65
said point being station 486+88 on U.S. 84 Highway Station, as noted in State
Department of Highways and Public Transportation approval form 1023, Control
53, Section 1 dated November 28, 1979;
Thence in a southwesterly direction at a right angle to Highway 84, across U.S. 84
a distance of 238' to station 370+03 said point falling 7' east of the west right-of-
way line of Co. Rd. 30 as referred to in the Commissioner's Court Records Book
24, Page 563, dated November 28, 1979;
Thence in a southerly direction T east of and parallel to the west right-of-way line
of Co. Rd. 30 a distance of 21,262 to station 582+65;
Thence in a westerly direction 7' south of the north right-of-way of Co. Rd. 30 a
distance of 591' to station 588+56;
Thence in a southerly direction 7' east of and parallel to the west right-of-way line
of Co. Rd. 30 a distance of 889' t to station 597+45 said point being the
beginning of a transition from 13' west of the centerline of Co. Rd. 30 to 30' west
of the centerline of F.M. 41;
Thence in a southerly direction 105' to station 598+50;
Thence in a southerly direction 30' west of and parallel to the centerline of F.M.
41 a distance of 4927' to station 647+77;
Thence in a southeasterly direction across F.M. 41 a distance of 81' to a point that
falls 9.5' east of the west right-of-way of Co. Rd. 30 to station 648+58;
Thence in a southerly direction 9.5' east of and parallel to the west right-of-way
line of Co. Rd. 30 a distance of 4912' t to a transition point from 9.5' east of the
west right-of-way line of Co. Rd. 30 to station 697+70;
Thence in a southerly direction at 7' east of the west right-of-way line of Co. Rd.
30 a distance of 5365' to station 751+35;
Thence in an easterly direction at 7' north of the south right-of-way line of a Co.
Rd. a distance of 1833' to station 769+68;
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Thence in a southerly direction at T east of the west right-of-way line of Co. Rd.
30 a distance of 5152' to station 821+20 and the end of this project.
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EXHIBIT "C"
To Bill of Sale
PERSONAL PROPERTY
WILSON LAND APPLICATION SITE
21 Zimmatic Center Pivot Systems complete with Panel Boxes,
Booster Pumps and Electrical Disconnects
All pipelines, pumps and valves
All existing groundwater wells, pumps and related equipment.
Existing Barbed wire fences around lakes
1 Trailer House
2 Large hay barns
3 Houses (habitable)
2 Houses (inhabitable)
1 Large shop and equipment storage
1 Smaller shop and equipment storage
Miscellaneous pivot parts
Micro switches
Used nozzles
1 14.9x24 pivot tire and wheel
rolled drop hoses
rolled drag hoses
used motor and pump
miscellaneous fittings
end caps for pivots
stand pipes for pivots
1 durst gearbox
u joints
capacitors
Gaskets
clamps
Opening valves far row water
End pivot irrigation pipe
Used pump motor from lake 3
Computer house on lake 1
Computerized controls for variable on take 1
2 pumps and motors on lake I
1 pump and motor on lake 2
2 pumps and motors on lake 3
Wscellaheous used pivot wheels
Fences and"cattle guards on take 1 and 3
Pump and motor on Dube playa lake
SAVE AND EXCEPT, there is hereby reserved and not
included in this conveyance, the following property,
whether or not such property constitutes fixtures to the
Lands, to -wit:
(a) 3 sheds, 1 stock water pump, and all fencing (except
barbed wire fencing around ponds) belonging to Keith Wied
and David Wied;
(b) 2 stock water pumps and all gravel belonging to Todd
Lockaby; and
(c) 2 wood -frame seed houses belonging to B&TP Farms or
Bill Phillips.
Provided however, the above described personal property is
conveyed and purchased "as is" in its present condition, and
without any warranty of suitability, fitness for a particular
purpose and without any warranty of any kind, except for warranty
of title.
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Exhibit "E" To Amendment and
Modification of Contract of Sale
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and Contract of Sale, as Amended —
F Quitclaim Conveyance
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EXHIBIT "E"
To Amendment and Modification of Contract of Sale
and Contract of Sale, as Amended
QUITCLAIM CONVEYANCE
STATE OF TEXAS §
COUNTIES OF LUBBOCK AND LYNN §
That LUBBOCK CHRISTIAN UNIVERSITY, successor by name change to
LUBBOCK CHRISTIAN COLLEGE, LUBBOCK CHRISTIAN COLLEGE
INVESTMENT CORPORATION, a Texas Non -Profit Corporation and LUBBOCK
CHRISTIAN UNIVERSITY INSTITUTE OF WATER RESEARCH (collectively, the
"Grantor"), for and in consideration of the sum of TEN AND NO/100 DOLLARS
($10.00) and other good and valuable consideration, the receipt and sufficiency of which
is herein acknowledged, have QUITCLAIMED, and by this instrument do QUITCLAIM
to the City of Lubbock, a Texas Home Rule Municipal Corporation ("Grantee"), P.O.
Box 2000, Lubbock, Texas 79457, all of its right, title and interest in and to that certain
real property (the "Property"), lying and being situated in Lubbock County and Lynn
County, Texas, being described on Exhibit "A" attached hereto.
TO HAVE AND TO HOLD all of the right, title and interest in and to these
premises, together with all and singular the rights, privileges, and appurtenances to the
premises in any manner belonging to the Grantee, its successors and assigns forever, so
that neither the Grantor, nor any of the Grantor's successors, assigns, legal
representatives, nor any persons claiming under the Grantor shall any time in the future
have, claim or demand any right or title to the property described above.
w.
Executed this
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day of April, 1999.
LUBBOCK CHRISTIAN UNIVERSITY
Jerry D. Harris, Chairman of the Board
LUBBOCK CHRISTIAN COLLEGE
INVESTMENT CORPORATION
Harvie M. Pruitt, Chairman of the Board
LUBBOCK CHRISTIAN UNIVERSITY
INSTITUTE OF WATER RESEARCH
Name:
Title:
rb STATE OF TEXAS §
COUNTY OF LUBBOCK §
This instrument was acknowledged before me on , by Jerry
D. Harris, Chairman of the Board of Lubbock Christian University, a ,
on behalf of said
Notary Public in and for the State of Texas
My Commission Expires:
STATE OF TEXAS §
COUNTY OF LUBBOCK §
This instrument was acknowledged before me on , by
Harvie M. Pruitt, Chairman of the Board of Lubbock Christian College Investment
Corporation, a Texas non-profit corporation, on behalf of said corporation.
Notary Public in and for the State of Texas
My Commission Expires:
STATE OF TEXAS §
COUNTY OF LUBBOCK §
This instrument was acknowledged before me on , by
, of Lubbock Christian
University Institute of Water Research, a , on behalf of said
Notary Public in and for the State of Texas
My Commission Expires:
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EXHIBIT "A"
To Quitclaim Conveyance
All easements, rights -of --way or any other ways of access and all rights in and to pipelines
and appurtenant property or facilities owned by Grantor in Sections 1 and 4, Block B;
Sections 1, 2, 4,11,12,13, 16, 25, 26, 27, 28, 55, 56, 57, 58, 59 and 60, Block S, GC &
SF R.R. Co. Surrey; and Sections 40, 35, 30, 31, 32 and 34, Block 24,11E & WT R.R.
Co. Survey, Lubbock County, Texas and Sections 2 and 3, Block M, EL & RR R.R. Co.
Survey, Lynn County, Texas, including without limitation, the following:
Description of the approximate location of a 27' force main leading ham the
Southeast Water Reclamation Plant to the LCC Institute of water Research
Lubbock Land Treatment System Research and Demonstration Project at the
Wilson farm in Lynn Co., also referred to as the Wilson Line, contained in
Lubbock and Lynn Counties of the State of Texas:
Beginning at Station 0+00 said point being the connection to the discharge header
at the Southeast Reclamation Plant;
Thence S 110 15' E a distance of 139' to station 1+38;
Thence S 33° 45' E a distance of 400' to station 5+38;
Thence S 220 30' E a distance of 256' to station 7+94;
Thence S 67° NY W a distance of 402, to station 11+96;
Thence south a distance of 223' to station 14+19;
Thence S 67° 30' W a distance of 710' to station 21+29;
Thence in a southerly direction, IS' cast of and parallel to the centerline of Guava
" Avenue, a distance of 3110' to station 52+39, said point being the end of a curve
i to the right having a radius of 833', and arch distance of 64' and a delta angle of 4°
24' 07% .
Thence along said curve to the right a distance of 64' to station 53+03, said point
being in the end of a curve to the right and the beginning of a curve to the left
having a radius of 1106', arch distance of 149', and a delta angle of 7° 43' 08";
Thence along said curve a distance of 149' to station 54+52 said point falling in
the right-of-way of FM 835 at the approximate highway centerline station 8+44 as
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referred to in State Department of Highways and Public Transportation Approval
Form 1023, control 9933, Section 1, dated November 28, 1979;
Thence in a southeasterly direction a distance of 73' to station 55+25;
Thence in a southwesterly direction a distance of 51' to station 55+76 said point
being 15' west of the centerline of Burlington Railway Spur Track #261;
Thence in a southeasterly direction, 15' west of and parallel to Burlington Spur
Track #261 a distance of 786' to station 63+62
Thence in a southwesterly direction, 184' to station 65+46 said point being 25'
east of the centerline of Spur 331 and highway station 185+52.5 as referred to in
State Department of Highways and Public Transportation Approval Form 1023,
Control 53, Section 1, Highway # Spur 331 and Control 3273, Section 1,
Highway #FM 3020 dated December 5, 1979;
Thence parallel to and 6' east of the east right -of --way line a distance of 1208' to
station 115+64 said point being the beginning of a transition from 6' east of the
east right -of --way line to 25' east of the centerline of Spur 331;
Thence parallel to and 25' east of the centerline of Spur 331 a distance of 3171' to
station 147+35 said point being the beginning of a transition back to 25' east of
the centerline to 37' east of the centerline;
Thence parallel to and 37' east of the centerline of Spur 331 a distance of 326' to
station 150+61 said point being the beginning of a transition back to 25' east of
the centerline;
Thence 28T to station 153+48 said point being 25' east of the centerline of Spur
331;
�. Thence parallel to and 25' east of the centerline a distance of 3216' to station
185+64 said point being the beginning of a transition back from 25' east of the
' centerline to 3' west and parallel to the east right-of-way line of Spur 331;
Thence 3' west and parallel to cast right -of --way line a distance of 1336 to station
199+00 said point being the beginning of a transition from 3' west of the east
right-of-way of Spur 331 to 10' west of and parallel to the east right-of-way line of
Spur 331;
Thence in a southeasterly direction a distance of approximately 100' to station
200+00 said point being 10' west of the cast right-of-way line of Spur 33 l;
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Thence 10' west of and parallel to the cast right-of-way lien a distance of 2099' to
station 220+99 said point being at the end of Spur 331 and where the control for
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U.S. 84 begins;
Thence continuing in a southeasterly direction 10' south of the northern right-of-
way line of U.S. 84 and parallel to U.S. 84 a distance of 14,666' to station 367+65
k'
said point being station 486+88 on U.S. 84 Highway Station, as noted in State
�.
Department of Highways and Public Transportation approval form 1023, Control
53, Section 1 dated November 28, 1979;
Thence in a southwesterly direction at a right angle to Highway 84, across U.S. 84
a distance of 238' to station 370+03 said point failing T cast of the west right-of-
way line of Co. Rd. 30 as referred to in the Commissioner's Court Records Book
r 24, Page 563, dated November 28, 1979;
Thence in a southerly direction T east of and parallel to the west right-of-way line
of Co. Rd. 30 a distance of 21,262 to station 582+65;
Thence in a westerly direction 7' south of the north right -of --way of Co. Rd. 30 a
distance of 591' to station 588+56;
Thence in a southerly direction 7' east of and parallel to the west right-of-way line
of Co. Rd. 30 a distance of 889' t to station 597+45 said point being the
beginning of a transition from 13' west of the centerline of Co. Rd. 30 to 30' west
of the centerline of F.M. 41;
Thence in a southerly direction 105' to station 598+50;
{ Thence in a southerly direction 30' west of and parallel to the centerline of F.M.
41 a distance of 4927' to station 647+77;
Thence in a southeasterly direction across F.M. 41 a distance of 81' to a point that
falls 9.5' east of the west right-of-way of Co. Rd. 30 to station 648+58;
Thence in a southerly direction 9.5' east of and parallel to the west right-of-way
line of Co. Rd. 30 a distance of 4912' t to a transition point from 9.5' east of the
west right-of-way line of Co. Rd. 30 to station 697+70;
Thence in a southerly direction at T east of the west right-of-way line of Co. Rd.
30 a distance of 5365' to station 751+35;
Thence in an easterly direction at 7' north of the south right-of-way line of a Co.
Rd. a distance of 1833' to station 769+68;
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l hence in a southerly direction at � cast of the west right-of-way line of Co. Rd.
30 a distance of S 152' to station 921 +20 and the end of this project.
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Exhibit "F" To Amendment and
Modification of Contract of Sale and
Contract of Sale, as Amended —
Environmental Assessment
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C
Baseline Assessment
(Current Baseline Report)
Wilson Land Application Site
(Municipal Wastewater Land Application Site)
3,943 Acres
North of Wilson, Texas
Lynn County, Texas
Project Number: EN-1761
Prepared for:
C4 of Lubbock, Lubbock, Texas
EN FORMOTEC
Englhee*V aoftiftm wBh a New for fCrnorrow
6310 Genoa Avenue, Suite E, Lut bock, Taal
(806) 794-1100
March 1999
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Baseline Assessment
(Current Baseline Report)
Wilson Land Application Site
(Municipal Wastewater Land Application Site)
3,943 Acres
North of Wilson, Texas
Lynn County, Texas
Project Number: EN-1761
Prepared for:
City of Lubbock, Lubbock, Texas
Prepared by:
Sample Analysis Certes Environmental Laboratories
R
Trace Analysis Inc.
Data Compilation Mark A. Schneider c
Report Preparation Mark A. Schneider
Review Aubrey A. Spear, P.E. aZZV�_e e��'
7Report
�'
ESV PRC�►TEc
EnCrneedng soJvdons with a view for tOn O=w
Pm
6310 Genoa Avenue. Suite E, Lubbock, Texas
1
(806)794-1100
March 1999
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Table of Contents
Tableof Contents...............................................................................................................1
ExecutiveSummary ...........................................................................................................5
ProjectSummary ......................................................................................................................................5
GroundwaterFindings..............................................................................................................................6
Detection in Groundwater....................................................................................................................6
DrinkingWater MCLs...........................................................................................................................7
Irrigation Restrictions and Phytotoxicity..............................................................................................8
Typical Wastewater Concentrations: ..................................................................................................
9
SoilFindings............................................................................................................................................10
Detectionin Soil Samples..................................................................................................................10
Soil Concentrations for Groundwater Protection..............................................................................11
Soil Concentrations for Ingestion......................................................................................................12
SludgeFindings......................................................................................................................................13
Detection in Sludge Samples............................................................................................................13
SubjectProperty Summary .............................................................................................14
EnvironmentalSetting.....................................................................................................17
Physiography, Relief, and Drainage......................................................................................................17
Climate/ Weather..................................................................................................:................................17
Regional Geology /Hydrology...............................................................................................................18
Site Geology / Hydrology ................................... ..20
GroundwaterSampling....................................................................................................22
Groundwater Sampling Techniques......................................................................................................22
4
Initial Groundwater Sampling and Analysis...........................................................................................22
Subsequent Groundwater Sampling......................................................................................................24
rGroundwater
Analysis............................................................................................................................25
Groundwater Constituents / Parameters Detected...............................................................................27
Alkalinity as Carbonate and Bicarbonate
..........................................................................................27
Ammonia(NH3)..............................................................................................................I...........:.......28
Boron..................................................................................................................................................28
r..
Calcium..........................................................................................................................................29
Chloride..............................................................................................................................................
29
Chromium...........................................................................................................................................
30
Coliform - Total and Fecal ...........................................
30
Copper................................................................................................................................................
31
aldehyde.................................................................................................................................31
rEndrin
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Lead.................................................................................................................................................... 31
Magnesium......................................................................................................................................... 32
Nitrites/ Nitrates.................................................................................................................................32
Phenol................................................................................................................................................. 33
Potassium........................................................................................................................................... 33
Selenium.............................................................................................................................................34
Sodium................................................................................................................................................ 34
Sodium Adsorption Ratio (SAR) and Conductivity (EC)..................................................................34
Sulfate.................................................................................................................................................35
Total Kjeldahl Nitrogen(fKN)............................................................................................................35
Total Petroleum Hydrocarbons(fPH)...............................................................................................36
Zinc.....................................................................................................................................................37
SoilSampling....................................................................................................................38
SoilSampling Techniques......................................................................................................................38
Initial Soil Sampling and Analysis..........................................................................................................38
SubsequentSoil Sampling.....................................................................................................................41
SoilAnalysis............................................................................................................................................42
Soil Contaminants and Parameters.......................................................................................................44
4,4-DDE..............................................................................................................................................44
Alkalinity as Carbonate and Bicarbonate..........................................................................................44
Ammonia(NH3)..................................................................................................................................45
Arsenic................................................................................................................................................ 45
Boron..................................................................................................................................................45
Cadmium............................................................................................................................................46
Calcium.:...........................................................................................
.................................................. 46
Chloride..............................................................................................................................................46
Chromium...........................................................................................................................................47
Coliform- Total...................................................................................................................................47
Copper............................................................................................................................................... 48
HeptachlorEpoxide............................................................................................................................48
Lead.................................................................................................................................................... 48
Magnesium........................................................................................................................................49
Mercury............................................................................................................................................... 49
Molybdenum.............................................................................................................................:.........49
Nickel.................................................................................................................................................. 50
........ Nitrites / Nitrates.........................................................................................................................50
Potassium........................................................................................................................................... 51
Selenium............................................................................................................................................. 51
Sodium................................................................................................................................................ 51
Sodium Adsorption Ratio (SAR)........................................................................................................52
Sulfate.................................................................................................................................................52
Total Kjeldahl Nitrogen(TKN)............................................................................................................52
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Total Petroleum Hydrocarbons(fPH)...............................................................................................53
Zinc.....................................................................................................................................................54
SludgeSampling..............................................................................................................55
5
iSludge
Sampling Techniques................................................................................................................55
SludgeSampling and Analysis..............................................................................................................55
Sludge Contaminants and Parameters..................................................................................................57
Alkalinity as Carbonate and Bicarbonate..........................................................................................57
Ammonia(NH3)..................................................................................................................................58
Boron..................................................................................................................................................58
Cadmium............................................................................................................................................58
Calcium...............................................................................................................................................
58
Chloride..............................................................................................................................................59
Chromium...........................................................................................................................................59
Copper................................................................................................................................................
59
Lead....................................................................................................................................................60
Magnesium.........................................................................................................................................60
rMercury
................................................................................................................................................61
Molybdenum.......................................................................................................................................61
Nickel..................................................................................................................................................61
�.
Potassium...........................................................................................................................................62
Sodium................................................................................................................................................62
Sulfate.................................................................................................................................................
62
Total Kjeldahl Nitrogen(TKN)............................................................................................................63
Total Petroleum Hydrocarbons(fPH)...............................................................................................63
Zinc.....................................................................................................................................................64
Contaminants and Parameters.......................................................................................65
Alkalinity as Carbonate and Bicarbonate..............................................................................................65
Ammonia(NH3).......................................................................................................................................65
Arsenic....................................................................................................................................................65
Boron....................................................................................................................................................... 66
Cadmium.................................................................................................................................................66
Calcium...................................................................................................................................................67
Chloride................................................................................................................................................... 67
Chromium................................................................................................................................................ 67
Coliform— Total and Fecal.....................................................................................................................67
Copper..................................................................................................................................................... 68
Lead......................................................................................................................................................... 68
Magnesium.............................................................................................................................................. 68
Mercury................................................................................................................................................... 68
Molybdenum...........................................................................................................................................69
Nickel....................................................................................................................................................... 69
Nitrites/ Nitrates.....................................................................................................................................70
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Pesticides! Herbicides ! Fungicides......................................................................................................70
4,4-DDE..............................................................................................................................................
71
EndrinAldehyde.................................................................................................................................71
HeptachlorEpoxide............................................................................................................................71
PolychlorinatedBiphenyls (PCBs).........................................................................................................72
Potassium...............................................................................................................................................72
Selenium.................................................................................................................................................73
Semi-Volatiles.........................................................................................................................................73
Phenol.................................................................................................................................................
74
Sodium....................................................................................................................................................74
SodiumAdsorption Ratio (SAR)............................................................................................................74
Sulfate.....................................................................................................................................................74
TotalKjeldahl Nitrogen(TKN)................................................................................................................75
Total Petroleum Hydrocarbons (TPH)...................................................................................................75
Zinc..........................................................................................................................................................75
Appendix A Maps and Figures
Appendix B
Appendix C
Groundwater Sample Results
Soil Sample Results
Appendix D Sludge Sample Results
Appendix E Lab Reports and Chains -Of -Custody
(Included under separate cover)
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Executive Summary
Project Summary
On January 15, 1999, Mr. Dan T. Dennison, Environmental Compliance Manager for the City of
Lubbock, Texas; contracted with Enprotec Inc. to have a Contamination Baseline Assessment
(investigation or assessment) conducted. The property investigated (subject property or Site)
is a tract of land located north of the City of Wilson in Lynn County, Texas and encompasses
approximately 3,943 acres of land. Property boundaries are illustrated by the Site Map in
Appendix A.
The subject property was once part of an EPA sponsored and funded study (EPA Study)
regarding the effects of applying municipal wastewater to cropland. As such, the Site has received
t treated municipal wastewater from the City of Lubbock's Southeast Water Reclamation Plant since
1981. This wastewater is pumped to three storage reservoirs located on -site and is then applied to
i cultivated land via center pivot irrigation systems. This investigation was conducted to confirm the
existence or absence of specific chemical constituents that may have resulted due to the Site's
eighteen -year history of receiving municipal wastewater. In addition, the reported concentrations
of detected chemical constituents will be used to demonstrate due diligence and to establish a
baseline against which future municipal wastewater impacts could be compared.
To determine the chemical contaminants most likely to be present, site -specific sampling records
and EPA guidance documents regarding the impacts of municipal wastewater land application
were researched. Based on this information, a decision was made to collect groundwater and soil
samples having the highest potential for contamination and analyze these initial samples (along
with composite sludge samples from each reservoir bottom) for a full -spectrum of contaminants. In
addition to analyzing for chemical contamination, analysis was also conducted to determine other
baseline information (i.e. sodium adsorption ratio, total nitrogen, ammonia) pertinent to wastewater
operations.
Based on the initial sampling results, a decision was made regarding -the laboratory analysis
necessary to effectively determine a baseline. Subsequent groundwater samples (from all
accessible water and monitor wells), reservoir water samples (from each reservoir), and composite
soil samples (from under each center pivot and from a flood irrigation area) were analyzed using
this baseline protocol.
Findings resulting from groundwater, soil, and sludge analysis follow:
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Groundwater Findincis
Note: The following data and comparisons are based on the highest concentrations detected and
the average concentrations calculated during this baseline assessment These baseline averages
are provided for comparison purposes only and reflect the total of the concentrations detected
divided by the number of samples analyzed. If concentrations / parameters were equal throughout
the Site, this average would be representative. Each groundwater sample, however, is unique and
cannot be assumed to contain the average value reported.
Detection in Groundwater
The following constituents were not detected in any of the groundwater samples analyzed (except
as noted):
Fecal coliform Carbonate
Mercury
Arsenic Cadmium Nickel
Molybdenum PCBs
Pesticides I herbicides I fungicides (except endrin aldehyde)
Semi-volatiles (except phenol)
r' The following constituents / parameters were detected in almost every groundwater sample
analyzed. The percentage of samples in which these constituents / parameters appear is shown:
Bicarbonate (100%) Boron (100%) Calcium (95%)
Chloride (100%) Magnesium (100%) Nitrates (90%)
Potassium (100%) Sodium (100%) Sodium adsorption (100%)
Sulfate (100%) TKN (100%)
The following constituents were detected in a large percentage of the groundwater samples
analyzed. The percentage of samples in which these constituents / parameters appear is shown:
Ammonia (50%) TPH (40%)
The following constituents were detected in very few of the groundwater samples analyzed. The
percentage of samples in which these constituents / parameters appear is shown:
Chromium (5% -1 of 20 samples)
Copper (30% - 6 of 20 samples)
Lead (10% - 2 of 20 samples)
Phenol (10% - 2 of 20 samples)
Zinc (5% -1 of 20 samples)
Total Colifonm (33% - 2 of 6 samples)
Endrin Aldehyde (5% -1 of 20 samples)
Nitrites (10% - 2 of 20 samples)
Selenium (10% - 2 of 20 samples)
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site. Wilson. Texas Page 6
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Drinking Water MCLs
EPA drinking water maximum concentration levels (MCLs) are derived from 40 CFR 141 and are
legally enforceable standards applied to public water systems. Values with a indicator are
derived from National Secondary Drinking Water Regulations (secondary standards). Secondary
standards are non -enforceable guidelines regulating contaminants that may cause cosmetic
effects (i.e. skin or tooth discoloration) or aesthetic effects (i.e. taste, odor, and color) in drinking
water.
In this section, the highest (hi) and average (avg) concentrations returned by this baseline are
compared to drinking water MCLs and secondary standards. The reader is reminded that, for the
most part, on -site groundwater is not used for human consumption, although contaminants may
migrate to impact off -site water wells.
No drinking water standards were published for the following detected constituents I parameters:
Ammonia Bicarbonate Boron
Calcium Magnesium Potassium
TPH Total Kjeldahl Nitrogen Sodium adsorption ratio
Sodium
The concentrations detected for the following constituents / parameters meet drinking water
standards:
Chromium Copper Enddn Aldehyde
Lead (avg)* Nitrites Nitrates (avg)
Phenol Selenium (avg) Sulfate, (avg)
Zinc•
The action level for lead in drinking water is 0.015 mg/L. Average on -site lead levels are only 0.0016 mg/L
The concentrations detected for the following constituents / parameters exceed drinking water
standards. The percentage by which these standards are exceeded is shown:
Nitrates (hi) — 99% Selenium (hi) — 28% Sulfate, (hi) —130%
Chloride, (hi) — 900% Coliform (hi) —100%' Lead (hi) —100%'
Chlorides (avg) — 83% Coliform (avg) —100%* Lead (avg) —100%*
Drinking water MCLs for total coliform and lead is zero (no detection). Any coliform counts or lead exceeds the MCL by 100%.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas
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Irrigation Restrictions and Phytotoxicity
Irrigation Water Quality Restrictions are derived from Irrigation Water Quality Criteria (Westcot
and Ayers —1985 and National Academy of Sciences-1973). This document lists irrigation water
quality parameters that dictate whether the groundwater can be used without restriction, with only
moderate restrictions, or with severe restrictions. These restrictions do not indicate that the water
is unsuitable for irrigation, but its use may call for limited application, resistant crops, specific soil
conditions, or the implementation of special management practices).
Irrigation Water Phytotoxicity levels are derived from Recommended Maximum Concentrations
of Trace Elements In Irrigation Water (Pettygrove & Asano—1984). Like irrigation water quality
restrictions, these irrigation water phytotoxicity concentrations do not indicate that the water is
unsuitable for irrigation. Exceeding these recommended concentrations, however, can result in
negative plant responses (phytotoxicity) in certain plant species.
In this section, the highest (hi) and average (avg) concentrations reported by this baseline are
compared to irrigation water restrictions and phytotoxicity levels. The reader is reminded that, for
the most part, on -site groundwater is not used for irrigation purposes.
No irrigation water quality restriction or phytotoxicity criteria were published for the following
detected constituents / parameters:
Total coliform
Fecal coliform
TPH
Ammonia
Nitrite
Nitrate
Sulfate
Potassium
Calcium
Magnesium
Endrin aldehyde
Phenol
The concentrations detected for the following constituents / parameters meet irrigation water
quality criteria for unrestricted use:
Boron (avg)
Lead (hi)
Zinc
Chromium (hi)
Selenium (avg)
Copper (avg)
TKN (hi)
The concentrations detected for the following constituents I parameters occur at irrigation water
quality criteria levels that call for moderate restrictions:
Bicarbonate (avg) Boron (hi)
Sodium adsorption ratio
Sodium
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The concentrations detected for the following constituents / parameters occur at irrigation water
quality criteria levels that call for severe restrictions or may result in phytotoxicity. The percentage
by which these levels are exceeded is shown:
Bicarbonate (hi) -130%
Chloride (hi) — 614%
Chloride (avg) — 31 %
Copper (hi) — 241 % Selenium (hi) — 220%
ypical Wastewater Concentrations:
Typical Wastewater Concentrations are derived from the Composition of Secondary Treated
Municipal Wastewater Effluents and Irrigation Water (Asano et al. -1984 and Treweek —1985)
which lists the typical concentrations found in secondary wastewater effluents across the U.S.A.
In this section, the highest (hi) and average (avg) concentrations reported by this baseline are
compared to the typical range found in wastewater effluents to determine if the detected
constituents / parameters may have originated from wastewater application operations. The
reader is reminded that these figures are provided for comparison purposes only, and groundwater
samples - not wastewater effluent - were analyzed.
No typical wastewater concentrations were published for the following detected constituents /
parameters:
Total coliform Fecal coliform TPH
Nitrite Sulfate Sodium adsorption ratio
Bicarbonate Selenium Phenol
The concentrations detected for the following constituents / parameters are lower than typical
wastewater concentrations by the percentage shown:
Ammonia (hi) - 94.4%
Lead (avg) — 68%
Zinc (avg) — 92.3%
Chromium (hi) — 900%
Nitrates (avg) — 25%
Endrin Aldehyde (hi) —99%
TKN (hi) — 95%
The concentrations detected for the following constituents / parameters exceed typical wastewater
concentrations by the percentage shown:
1
Lead (hi) — 240%
Nitrates (hi) —149%
Zinc (hi) — 55%
Boron (hi) - 74%
Calcium (hi) —152%
Chloride (hi) — 3,2-33%
k
Boron (avg) — I A%
Calcium (avg) — 53%
Chloride (avg) — 511 %
Copper (hi) — 3,410%
Magnesium (hi) — 590%
Potassium (hi) —162%
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas
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Copper (avg) — 275% Magnesium (avg) — 79% Potassium (avg) — 38%
Sodium (hi) — 276%
Sodium (avg) — 77%
Soil Findings
Note: The following data and comparisons are based on the highest concentrations detected and
the average concentrations calculated during this baseline assessment These baseline averages
are provided for comparison purposes only and reflect the total of the concentrations detected
divided by the number of samples analyzed. If constituent concentrations or parameters were
equal throughout the Site, this average would be representative. Each soil sample, however, is
unique and cannot be assumed to contain the average value reported.
Detection in Soil Samples
The following constituents were not detected in any of the soil samples analyzed (except as
noted):
PCBs
Semi-volatiles
Pesticides I herbicides I fungicides (except 4,4-DDE and Heptachlor Epoxide)
The following constituents I parameters were detected in almost every soil sample analyzed. The
percentage of samples in which these constituents I parameters appear is shown:
Bicarbonate — 96%
Arsenic — 92%
Calcium —100%
Chloride — 92%
Copper —100%
Lead —100%
Nickel —100%
Nitrates — 92%
Sodium —100%
TKN — 96%
Zinc —100%
Boron —100%
Chromium —100%
Magnesium —100%
Potassium —100%
Sodium Adsorption-100%
The following constituents were detected in a large percentage of the soil samples analyzed. The
percentage of samples in which these constituents I parameters appear is shown:
Carbonate — 69% Cadmium — 88% Total Coliform — 50%
Mercury — 79% Sulfate — 79% TPH — 70%
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 10
The following constituents were detected in very few of the soil samples analyzed. The
percentage of samples in which these constituents / parameters appear is shown:
4,4-DDE -11% (3 of 27 samples) Ammonia —12.5% (6 of 48 samples)
Heptachlor epoxide — 3% (1 of 27 samples) Molybdenum— 8% (4 of 48 samples)
Nitrites —17% (8 of 48 samples) Selenium — 2% (1 of 48 samples)
Soil Concentrations for Groundwater Protection
Maximum soil concentrations to ensure groundwater protection are published by the TNRCC in 30
TAC 335.568 Appendix 11. These values are used in risk reduction computations and represent
the maximum concentrations in industrial soil assumed protective of groundwater when cross -
media contamination of the groundwater from contaminated soil is considered. These values
provide guidance and are not enforced except in some clean-up operations.
In this section, the highest (hi) and average (avg) concentrations reported by this baseline are
compared to TNRCC groundwater protection industrial soil values. The reader is reminded that,
these values are provided for comparison purposes only since the subject property is not an
industrial property.
No groundwater protection industrial soil values were published for the following detected
constituents / parameters:
Total Coliform TPH TKN
Ammonia Chloride Sulfate
Sodium Adsorption Ratio Bicarbonate Carbonate
Zinc Copper Molybdenum
Potassium Sodium Calcium
Magnesium Boron
r, The concentrations detected for the following constituents / parameters are below groundwater
protection industrial soil values by the percentage indicated:
4,4-DDE (hi) — 96% Arsenlc (avg) — 7% Heptachlor epoxide — 91 %
Mercury (hi) — 85% Nickel (avg) —1 % Nitrites (hi) — 98.3%
Nitrates (hi) — 95.5% Selenium (hi) —14%
The concentrations detected for the following constituents / parameters exceed groundwater
protection industrial soil values. The percentage by which these standards are exceeded is
shown:
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site. Wilson. Texas Page 11
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Arsenic (hi) — 36% Nickel (hi) — 33% Cadmium (hi) — 354%
Cadmium (avg) — 216%
Chromium (hi) — 72% Lead (hi) — 2,573%
Chromium (avg) — 21 % Lead (avg) — 807%
Soil Concentrations for Ingestion
TNRCC maximum soil concentrations for industrial soil exposures are published in 30 TAC
335.568 Appendix ll. These figures provide industrial site soil parameters to be used in risk
reduction computations and represent the maximum concentrations in industrial soil when cross -
media contamination of air and the human ingestion / inhalation pathways is considered.
In this section, the highest (hi) and average (avg) concentrations reported by this baseline are
compared to TNRCC industrial soil ingestion levels.
No industrial soil ingestion values were published for the following detected constituents I
parameters:
Total Coliform
TPH
TKN
Ammonia
Nitrates
Chloride
Sulfate
Boron
Bicarbonate
Carbonate
Zinc
Copper
Molybdenum
Potassium
Sodium
Calcium
Magnesium
Sodium Adsorption Ratio
The concentrations detected for the following constituents / parameters are below industrial soil
ingestion criteria by the percentages indicated:
4,4-DDE — 99.98% Cadmium (hi) — 99.8% Heptachlor epoxide — 99.7%
�- Chromium (hi) — 99.7% Lead (hi) — 96.0% Mercury (hi) — 99.99%
t
Nickel (hi) — 99.93% Nitrites (hi) — 99.99% Selenium (hi) — 99.96%
The concentrations detected for the following constituents / parameters exceed industrial soil
ingestion criteria. The percentage by which these values are exceeded is shown:
Arsenic (hi) —108%
Arsenic (avg) — 43%
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Sludge Findings
National averages for the concentrations of some constituents / parameters typically found in
sewer sludges (NSSS National Average) and EPA ceiling concentrations for regulating the land
application of sewer sludges were used to compare our analytical results. Sludges from the on -
site reservoirs did not remotely approach the NSSS national averages or EPA ceiling
concentrations.
Detection in Sludge Samples
The following constituents were not detected in any of the sludge samples analyzed:
Nitrites Nitrates Carbonate
Arsenic Selenium PCBs
Semi-volatiles Pesticides I Fungicides Herbicides
The following constituents 1 parameters were detected in every sludge sample analyzed (only
three composite samples were collected).
TKN
Ammonia
Chloride
Sulfate
Bicarbonate
Mercury
Chromium
Zinc
Copper
Nickel
Lead
Molybdenum
Potassium
Sodium
Calcium
Magnesium
The following constituents were detected in only one or two of the three sludge samples analyzed:
TPH (2 samples) Cadmium (2 samples) Boron (1 sample)
Basefine Assessment (Current Baserine Report) — Wilson Land Application Site, Wilson, Texas Page 13
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Subject Property Summa
Except for a relatively small oilfield operation, the subject property is primarily used for agricultural
purposes. Crops grown on the subject property are irrigated with treated municipal wastewater
pumped from the City of Lubbock's Southeast Water Reclamation Plant to three on -site storage
reservoirs and then applied via center pivot irrigation systems.
Site improvements include: municipal wastewater reservoirs, pumping stations, aboveground and
underground irrigation piping, center -pivot irrigation systems, farmsteads (including houses and
outbuildings), hay barns, drinking water wells, environmental monitoring wells, stock tanks, oilfield
pumpjacks, oilfield saltwater injection wells, and oilfield tank batteries. Improvements range from
good to severely deteriorated in condition. Many of the farmsteads are abandoned or vacant
The Site is currently owned by Lubbock Christian University under several different entity names
r, including Lubbock Christian College Investment Corporation, Lubbock Christian College, and
r Lubbock Christian University Endowment Trust Historically, the subject property was pioneered
r " by the Green family since before the 1940's, purchased by Mr. J.E. Hancock around 1981, and
FW bequeathed to Lubbock Christian University around 1989.
Except for the City of Wilson, all adjacent properties are being used for agricultural or oilfield
purposes. All bounding and abutting properties are paved roads, unpaved roads, or cultivated
farmlands. There is no evidence that the subject property or neighboring properties were ever
used for large-scale industrial, commercial, or manufacturing purposes.
Three large municipal wastewater reservoirs are located on the subject property:
e East Reservoir
This reservoir has a 15.5-foot high water level and has a 387,877,776-gallon (1,188.64
acre feet) capacity.
r' a Middle Reservoir
} This reservoir has a 20.0-foot high water level and has a 195,227,136-gallon (599.04
acre feet) capacity.
r-
e West Reservoir
This reservoir has a 17.0-foot high water level and has a 196,302,606-gallon (602.34
,�.. acre feet) capacity.
These reservoirs were constructed over natural playa lake basins. Large pieces of broken
concrete and asphalt (from road demolition) were used as riprap along the banks. As part of the
reservoir construction project, the Randall clay native to the playa bottoms was partially excavated
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Baseline Assessment (Current Baserne Report) —Wilson Land Apprication Site, Wilson, Texas Page 14
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and then used to build up the reservoir sides. In addition, moats were constructed around each
reservoir.
Twenty-one center pivot irrigation systems are installed to dispense municipal wastewater to the
Site grounds in a controlled fashion. Another large center pivot installation has been removed from
the southwest corner of the Site. Together, these center pivots irrigate most of the subject
property. Irrigation risers allow for row irrigation of those areas not exposed to center pivot
irrigation. Municipal wastewater is pumped from the Site reservoirs to the center pivots via
underground pipelines. In places, valves servicing these pipelines have leaked continuously,
creating a bog of municipal wastewater. It is conceivable that minor contaminants in the
wastewater would accumulate and concentrate in such bogs since they would not be dispersed by
plant uptake and evaporation. It is possible that leaks in the underground wastewater pipelines
also exist and could create areas of subsurface saturation.
Numerous water wells and irrigation wells have been drilled, capped, and / or abandoned on -site.
Many of the water wells observed on -site are improperly capped, improperly abandoned, open to
surface discharges, and / or poorly sealed. Vermin have burrowed around many of the well
casings.
Mounds of cotton burrs and cotton gin trash (sticks, weeds, bolls, etc.) are lined up in windrows at
several points on -site. These cotton burrs and wastes are applied to the grounds as a soil additive
to provide organic matter. A concern was expressed that arsenic -based defoliants might have
contaminated the cotton wastes and could potentially leach into surrounding soils and reservoirs.
On -site farmers do not concur with this concern since arsenic -based defoliants were banned
several years ago and the cotton wastes have been on -site since no earlier than 1997. Arsenic -
based defoliants have not been used on -site for seven to ten years. Plains Cotton Growers states
that the use of arsenic -acid based defoliants has been banned for the last five to seven years and
groundwater / soil contamination resulting from the long-term storage of cotton wastes at other
sites has not been reported.
A "dead pif is located along the northeast side of Pivot #3. This shallow caliche pit is primarily
used for the disposal of sheep carcasses, but a small portion of the pit shows signs of dumping
and incineration. The dumped debris is primarily lumber and brush.
Several empty herbicide drums and numerous empty 5-gallon agricultural chemical containers
were noted on -site. In addition, large accumulations of used tires, scrap metal, abandoned
vehicles, out -of -service farm machinery, and steel pipe can be found at several points on -site and
scattered in smaller quantities throughout the Site.
Four aboveground storage tanks (ASTs) are installed on -site and used for fuel (gasoline and
diesel) storage. These tanks are not diked and are cradled over native earth that shows signs of
minor spillage and ground staining. A single underground storage tank (UST) is also installed on -
site and was assumably used for waste oil storage. Significant ground staining around the fill area
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 15
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1 of this UST is indicative of previous spills. Five large ASTs support on -site oilfield operations and
contain oil and brine. These tanks are installed over native earth and are protected by an earthen
berm. Significant ground staining from both oil and saltwater is evident around these tanks. Tanks
such as these have been known extensively contaminate subsurface soils (and even groundwater)
due to leakage from pitting and corrosion of the tank bottoms. Environmental damage resulting
from bulk container spillage and leakage can often be severe and can result in significant cleanup
expenses.
On -site oilfield exploration / operations have continued since 1951 and have been largely confined
to the southeast corner of the Site. Currently, four producing oil wells and two saltwater injection
wells are located on the southeast corner of the Site along with a tank battery, heater treater,
separator, flare, and pumpjacks. Another off site oilfield installation is located immediately east
and across County Road Z from the on -site installation. An investigation of this area revealed:
• Ground staining and salt deposits (indicative of the release of both petroleum products
and saltwater) were noted around most pieces of oilfield equipment and are most
t
extensive around the tank battery and injection wells.
• In the tank battery, a cut -down 55-gallon drum is being used as a catch basin under
one of the tank outlet valves. This drum is partially full of crude oil and is exposed to
stormwater, posing a "material threat of release'.
1
. Chemical products found at the various oilfield installations are primarily contained in
• '
55-gallon drums and 5-gallon pails. Many of these containers are unlabeled, so their
,y
contents are unknown. These containers are not sheltered, labeled, or palletized.
k Phase I Assessment guidance documents make it clear that
• Current and historical oilfield operations can result in extensive and far-reaching
surface soil, subsurface soil, and groundwater contamination from a myriad of sources
including:
— Contaminant migration along well casings and down boreholes
— Improperly closed mud pits and wells
— Use of drilling fluids and other oilfield chemicals
— Leaking underground pipelines and storage tanks
— Communication between groundwater and oil -producing formations
— Communication between saltwater and freshwater sources
• The migratory potential of both surface and sub -surface contaminants from oil and gas
operations could have a negative impact on a property's environmental conditions
from distances of up to one mile away.
Baseline Assessment (Current Baseline Report) — Wilson land Application Site, Wiilson, Texas Page 16
7
` Environmental Setting
Physiography, Relief, and Drainage
Lynn County is part of the southern High Plains of Texas known locally as the South Plains. The
South Plains are separated by the valley of the Canadian River from the main part of the High
Plains, which form a vast plateau extending north and west of Texas. Regionally, elevations range
from 3,000 to 3,300 feet.
Topographically, the county appears to be nearly level. However, there is a general slope to the
I ; southeast of 10 to 15 feet per mile. The smooth surface is pitted with many shallow lakes, or
playas (10 to 30 feet deep and 3 to 40 acres in size) generally surrounded by gently slopes. The
playas are dry except during wet years or rainy seasons. Several intermittent salt lakes, from 15 to
F 750 acres in size and 20 to 50 feet deep, occur in the county. The floors of these salt lakes are
near the water table.
If proper agriculture and conservation practices are followed, most rainfall is absorbed by the
smooth, deep, crumbly soils. Only a small amount of runoff water collects in the playa lakes and
salt lakes. The capacity of the soils to store water and to supply it to plants is good, but there is
little precipitation.
Surface elevations of the Site range from approximately 3,100 feet to 3,125 feet above mean sea
level. While essentially level, a natural high ridge transects the Site and creates a surface gradient
that flows towards the north on tracts located north of the Site's reservoirs and towards the south
on tracts located south of the reservoirs.
Climate 1 Weather
` The climate of Lynn County is subhumid. It is characterized by low annual precipitation, a very
high rate of evaporation, high average wind velocity, hot summer days followed by cool nights, and
moderate winter temperatures punctuated by severe cold spells.
Average summer temperatures are 78,,F and average winter temperatures are 410F. Annual
precipitation varies greatly, but averages less than 19 inches per year with a recorded low of 8.73
inches and high of 40.55 inches (from 1918 to 1955). Almost 70% of the average annual
r- precipitation falls during the growing season, from May through September. Average annual
snowfall is only 7.4 inches. Occasional summer hailstorms may severely damage crops, but these
storms are rarely widespread. The average annual evaporation from an open -water surface is
about 73 inches.
C-
.a
Baseline Assessment (Current Baseline Report) —Wilson Land Application Site, Wilson, Texas Page 17
r 4
F
7
The period from January to May is characterized by strong prevailing winds usually from the west
and southwest. These winds quickly evaporate surface moisture, damage crops with blowing
soils, and cover young plants with sand. Cold masses of air from the north sweep across the area
during the winter. The average length of the frost -free season is 201 days. November 1d is the
average date of the first killing frost in the fall, and April 14th, the average date of the last killing frost
in the spring.
i
1
Regional Geology 1 Hydrology
At one time in geological history, the land surface of Lynn County was several hundred feet below
the present-day land surface. The older land surface (Triassic) was later covered by marine
deposits (Cretaceous) and then finally by the Ogallala Formation, which for all practical purposes,
serves as the current land surface. The Triassic and Cretaceous geological deposits play an
important role in the occurrence and recovery of water from the Ogallala Aquifer that underlies
much of Lynn County.
The Triassic deposit consists principally of very fine-grained clays, which allow little or no
movement of water through its thick beds. As such, the Triassic deposit serves as the base for the
Ogallala Aquifer and is often referred to as the `red beds'. The Triassic and Cretaceous deposits
experienced a great deal of erosion before the Ogallala was deposited, and much of the
Cretaceous deposit was eroded away to leave only thin beds of multi -colored shales or clays.
r Occasionally, thin beds of sand and gravel are found with these multi -colored clays.
Another Cretaceous deposit found in the area is limestone. The beds of limestone are generally
only a few feet thick but can exceed 100 feet in thickness in some areas. If the limestone was not
eroded away before the Ogallala Formation was deposited, it serves an important role in
transmitting water to wells and from one limestone deposit to another. The limestone sometimes
has solution channels, cavities; cracks, and fissures that are generally small and, consequently,
provide very limited storage space for water. If the water level in the Ogallala declines below the
porous section of the limestone transmitting water to a particular well, that well's water supply is cut
off and water in the limestone's fractures and fissures will be quickly depleted.
The Ogallala Formation was deposited over an uneven landmass that featured numerous small
hills, valleys, streams, and a few rivers. Additionally, during this period in geological history, the
former land surface (Triassic and Cretaceous) experienced a great deal of erosion. Due to
extensive erosion and the nature of the overlain landscape, the depth of the Ogallala aquifer can
vary extensively in this area. Where hills were present, the Ogallala Formation is thinner and has
less water storage than thicker Ogallala sections where deep wide valleys were present In Lynn
County, the saturated thickness of the Ogallala can vary from less than 20 feet to more than 300
feet
r
Baseline Assessment (Current Baseline Report) —Wilson Lend Application Site, Wilson, Texas Page 18
r
The Ogallala Formation consists of clay, silt, fine -to -coarse grained sands, gravel, and caliche.
The layering of these materials is very erratic and will vary within short distances, both vertically
r, and horizontally. Most of the Ogallala Formation is loosely arranged (unconsolidated); however,
near the top and locally within the formation, some of the sediments have been cemented by
calcium carbonate to form beds of caliche. The caliche occurs in single or multiple layers in the
uppermost part of the formation. Because caliche is resistant to erosion, it forms the 'caprock' of
the escarpment
Water is stored in the pore space of the clay, silt, sand, and gravel that make up the Ogallala
Formation. The water in the Ogallala Formation is not confined under layers of clay or rock and is
therefore affected by conditions that influence the water -table level. That is, the water level in a
well drilled into the saturated portion of the formation will not rise above the static water level of the
aquifer. The lateral movement of the water in the Ogallala Formation is very slow, ranging from
about two to five inches per day (60 to 150 feet per year). The rate of lateral movement is
controlled by the gradient of the watertable and the permeability of the material in the zone of
saturation.
Natural recharge to the Ogallala aquifer is believed to be less than one inch per year. The
principal source of recharge is precipitation. A small portion of the water pumped from the Ogallala
aquifer for irrigation purposes may percolate back, but does not constitute an additional supply of
water, only a reduction in the net discharge. Annual measurements reveal an average annual
decline of 1.25 feet over a five-year period in the Lynn County area (although some areas
experienced a 5.80-foot increase).
The quality of the water in the Ogallala Formation is acceptable for most uses (domestic,
municipal, industrial, irrigation, and livestock). Due to the presence of certain salts, the water is
considered 'hard", although the total dissolved solids are generally less than 1,000 milligrams per
liter in Lynn County.
The soils of Lynn County developed from thick beds of porous, friable, unconsolidated, loamy
materials that are rich in lime and plant nutrients. The native soils are characterized as having
sandier surface soils and less compact, less blocky, and more permeable subsoils than the soils
that comprise the 'hardlands' to the north.
The porosity and structure of the soils of Lynn County are favorable for agriculture. The total pore
space between soil aggregates is large in nearly all of the soils, but the size of the pores varies
greatly. A large amount of pore space increases permeability to air, water, and roots and
Flo increases the soil's water -holding capacity and permeability.
7,
Baseline Assessment (Current Baseline Report) —Wilson Land Application Site, Wilson, Texas Page 19
Site Geology / Hydrology
A Soil Survey Map illustrating the types of soils found on the subject property is included in
r' Appendix A.
The native soils making up the subject property are:
• Amarillo Fine Sandy Loam (0 —1 % Slopes)
These soils make up only a small portion of the soils found in the northwest corner of
the Site and are associated with moderate wind erosion, moderate water erosion (on
slopes), excellent water -holding capacity, moderate permeability, rapid water
absorption, and slow surface drainage.
• Amarillo Fine Sandy Loam (1— 3% Slopes)
These soils make up only a small portion of the subject property and are found
scattered throughout the Site, but largely in the northwest corner. These soils largely
occur on low ridges, knolls, and gentle slopes around playa lakes and are associated
with moderate wind erosion, moderate water erosion (on slopes), excellent water -
holding capacity, moderate permeability, rapid water absorption, and slow surface
drainage.
• Amarillo Loam (0 —1 % Slopes)
The subject property is largely comprised of these soils which are associated with
slight to moderate wind erosion, slight to moderate water erosion (on >1% slopes),
good to very good water -holding capacity, moderate permeability, rapid water
absorption, and slow surface drainage.
• Amarillo Loam (0 — 3% Slopes)
These soils are found scattered throughout the Site and concentrated around the
Site's playas. These soils are associated with slight to moderate wind erosion, slight
to moderate water erosion (on >1% slopes), good to very good water -holding
capacity, moderate permeability, rapid water absorption, and slow surface drainage.
i Church Clay Loam (0 — 0.5% Slopes)
These soils are found in a very small portion of the Site's northwest corner on the floor
7 of a playa. These soils are associated with flooding, moderate to severe wind erosion
(when frozen), virtually no water erosion, fair water holding capacity, slow
permeability, good fertility, and no surface runoff.
* Portales Fine Sandy Loam (0 —1 % Slopes)
These soils are found in a very small plot located in the north central portion of the
r Site. These soils are associated with high fertility, moderate wind erosion, moderate
water erosion (on >2% slopes), very good water -holding capacity, moderate
permeability, rapid water absorption, and slow surface drainage. Principal
r' management problems are loss of water by runoff.
r
Baseline Assessment (Current Baseline Report) — Wilson Lard Application Site, Wilson, Texas Page 20
Portales Fine Sandy Loam (1— 3 % Slopes)
These soils are found in a very small corner of a playa located in the southwest corner
of the Site. These soils are associated with high fertility, moderate wind erosion,
moderate water erosion (on >2% slopes), very good water -holding capacity, moderate
permeability, rapid water absorption, and slow surface drainage. Principal
management problems are loss of water by runoff.
• Portales Loam (0 —1 % Slopes)
These soils are found, along with Randall Clay, making up the bottom of the Site's
west reservoir. These soils are associated with slight to moderate wind erosion,
moderate water erosion (on >2% slopes), very good water -holding capacity, moderate
permeability, and slow surface drainage. Principal management problems involve
holding rainwater on the soil until it can be absorbed.
• Portales Loam (1— 3% Slopes)
These soils are found, along with Randall Clay, making up the bottoms of the Site's
reservoirs and playas. These soils are associated with slight to moderate wind
erosion, moderate water erosion (on >2% slopes), very good water -holding capacity,
� moderate permeability, and slow surface drainage.
l • Randall Clay
These soils are found, along with Portales Loams, making up the bottoms of the Site's
reservoirs and playas. These soils occur throughout Lynn County on the floors of
playa lakes and range in thickness from 2 to 30 feet Since they are found in
depressions, these soils are associated with flooding, slight wind erosion (moderate if
frozen), no water erosion, poor water holding capacity, and very slow permeability.
• Zita Fine Sandy Loam, (0.1% Slopes)
A small plot of this soil is located in the northwester corner of the Site. These soils are
associated with moderate wind erosion, slight water erosion, good water holding
capacity, moderate permeability, and good drainage. It is corrosive to uncoated steel
and has low strength.
Zita Loam (0 —1 % Slopes)
A small plot of this soil is located in the southwest corner of the subject property.
These moderately deep fertile soils are associated with slight to moderate wind
erosion, slight water erosion, good water holding capacity, moderate permeability, and
very slow surface drainage.
Groundwater in the vicinity of the Site is ranges from approximately 38 to 112 feet deep. The
groundwater gradient of the Site is illustrated in the Water Level Contours Map included in
Appendix A As shown on the map, the groundwater gradient is towards the north on tracts
located north of the reservoirs and towards the south on tracts located south of the reservoirs.
r
F Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 21
F
i
Groundwater Sampling
Groundwater Sampling Techniques
The wells sampled for this baseline assessment are Illustrated by the Site Map Included in
Appendix A. With the exception of Well T, all of the wells designated with an alpha -character (A
through U) on the map were measured and sampled. Well T could not be sampled because the
pump servicing the well was inoperable.
Groundwater elevation measurements were obtained by using an electronic measuring device that
indicates when a probe is in contact with the water in the well. Measurements are obtained by
lowering the probe into the well until it indicates that the water surface has been encountered and
by measuring the distance from the top of the riser pipe to the probe. Measurements to the
nearest 0.01-foot were recorded. Groundwater elevations were used to determine the quantity of
water to be purged from each well before sample collection.
Immediately before collecting a sample of the groundwater, the well was purged to assure that a
representative sample was collected. Purging was accomplished by pumping. A minimum of three
well casing volumes of water was removed during purging. Since significant contamination was
not expected, the purge water was not contained. Samples were collected at the outfall of the
�. purge pump. Water remaining in the sample pump lines was allowed to flow back into the well
after purge and sample operations were completed.
The water samples were collected in the appropriate laboratory and method approved containers
I for each analytical suite. Disposable protective gloves were used In collecting each sample. In
order to retain volatile constituents; samples were collected to minimize sample agitation and
exposure to the atmosphere. The samples were labeled, logged, cooled, and transported to
Certes Environmental Laboratories L.L.C. (Certes) under chain -of -custody procedures for analysis
in accordance with standard procedures.
Initial Groundwater Sampling and Analysis
p� Three groundwater samples were collected from the monitor wells located closest to each
k municipal wastewater reservoir (Wells L, M, and Q). Due to the potential for impact from irrigation
waters, stormwater runoff, and reservoir seepage; these monitor wells were thought to have the
highest potential for contamination. The initial groundwater samples were analyzed using the
€ following protocols:
r. • SM 9222B —Total coliform.
• EPA 418.1—Total petroleum hydrocarbons (TPH).
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site. Wilson. Texas Page 22
s
EPA 351 A —Total Kjeldahl Nitrogen (TKN).
SM4500NH3.D—Ammonia.
EPA 354.1- Nitrite.
EPA 353.3 — Nitrate.
SM 4500CLB — Chloride.
• EPA 375.4 — Sulfate.
• 3.2.191— Sodium adsorption ratio (SAR).
SM2320B — Alkalinity.
EPA 7470A — Mercury.
EPA 6010B — Arsenic, cadmium, chromium, zinc, copper, nickel, lead, selenium,
molybdenum, potassium, sodium, calcium, magnesium, and boron.
EPA 8081A and EPA 8WA — Specific pesticides, herbicides, fungicides, and their
byproducts.
EPA 8082 — Polychlorinated biphenyls (PCBs).
EPA 8270C — Semi -volatile chemical compounds associated with fuels, solvents,
pesticide byproducts, and other commercial / industrial processes.
The following Initial Groundwater Samples - Analytical Results table compiles the analytical
results received and shows those parameters or constituents for which a value was detected. A
table showing all of the constituents / parameters detected for each groundwater sample is
provided in Appendix B. Laboratory reports and Chains -of -Custody for all groundwater samples
are included in Appendix E (a separately bound appendix to this report). Laboratory reports list all
of the constituents / parameters for which analysis was performed.
Basefine Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 23
OR_>„ :::::. tn�tal GraundwatQr:Sampl�s;...:Anaf ..'caL.Resulis.:.
> }
Constituent / Parameter
Units
Welk
Well-M
Well-Q
Total Coliform
col/100ml
ND
ND
2
T. tal[:IP.etraierttniri.,.>
�1D ...,.
.....:NA .....:;::
Total K'eldahl Nitrogen
m
0.30
0.54
0.47
Nitrite
m
0.01
0.04
ND
Nitrate
m
3.57
ND
ND
Iohs
Chloride
mgA-
400.
5W
550
Sulfate
mgA-
368
173
168
Sodhum AdsoqLbon Ratio
ratio
5.91
6.18
3.97
Alkalinity as Bicarbonate
m
400
670
580
Mt;rdu `: ......:}.... :.
Me.....
Zinc
mg/L
0.062
ND
ND
Copper
mg/L
0.027
ND
0.010
Potassium
mgA-
27.4
22.1
39.3
Sodum
m
320
376
263
Calcium
m
97.1
98.9
105
Magnesium
m
75.9
112
138
Boron
m
0.545
0.389
0.869
Pe tic]d.aX.- ` '' .::,} '} #{
_.:;
...:....ND.::,:
Pesticides 1 tierbtci`de s < $>
3
ND
)ND
ND
P..otyg1glnated;.B..rphe�lrl :(P..CBsj::.:.:.
#:.:::.........:.........ND:°.:.:ND=..::::...
Semi Vo(atlles `:.:<ND;.:...
f
......... 3 :.......
Phenol
ug1L
18.000
ND - Not Detected
Subsequent Groundwater Sampling
Based on the initial groundwater sampling results, a decision was made to test subsequent
groundwater samples as follows:
• Ions ! Cations ! Alkalinity:
All subsequent groundwater samples were analyzed for potassium, sodium, calcium,
magnesium, chloride, sulfate, bicarbonate, carbonate, and boron. These constituents
were listed by EPA guidance documents as concerns in wastewater application
operations.
• Nitrite ! Nitrate ! Ammonia:
All subsequent groundwater samples were analyzed for nitrites, nitrates, and
ammonia. Appreciably increased levels of nitrates were detected during the EPA
Study.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson. Texas Page 24
• Metals I Trace Elements:
All subsequent groundwater samples were analyzed for arsenic, cadmium, chromium,
mercury, zinc, copper, nickel, lead, selenium, and molybdenum. Many of these metals
are RCRA-controlled contaminants and are regulated by the EPA in wastewater
sludges.
• Pesticides / Herbicides I Fungicides:
All subsequent groundwater samples
fungicides, and their byproducts.
were analyzed for pesticides, herbicides,
• Coliform —Total and Fecal:
Groundwater from wells located near occupied farmsteads and the City of Wilson was
tested for total and fecal coliform.
• Total Petroleum Hydrocarbons (TPH):
Groundwater from selected representative wells was tested for TPH. These wells
were located on the perimeter or middle of the subject property. In addition, after TPH
was detected in some soil samples, water samples from the reservoirs were collected
and submitted to Trace Analysis Inc. (Trace), an environmental laboratory for TPH
testing.
• Semi-Volatiles:
Wells located on the perimeter of the subject property were analyzed for semi-
volatiles.
f., . Total Kjeldahl Nitrogen (TKN):
g TKN analysis was conducted on three additional water wells.
Groundwater Analysis
A table showing all of the constituents / parameters detected for each groundwater sample is
provided in Appendix B. Laboratory reports and Chains -of -Custody for all groundwater samples
are included in Appendix E (a separately bound appendix to this report). Laboratory reports list all
of the constituents / parameters for which analysis was performed.
The following All Groundwater Samples -Analytical Results & Guidelines table compiles the
analytical results received and shows those parameters or constituents for which a value was
detected. The lowest, highest, and average values for each detected constituent are listed along
with water quality guidelines (when available) for comparative values.
Baseline Assessment (Current Baseline Report)—Wiilson Lend Application Site, Wilson, Texas Page 25
AII,.Groundwate.r,.Samples -14na1 ...cal
Y,.
Results
&;Gutdel.nies :...,
Constituent
Units
Current
Baseline'
73
.73
= g
$
a `
I
Ie
Y
E _
Irrigation Water
Quality
Restrictions?
Average
Wastewater
Ranges
Low
High
Avg.
None
Mod. Isevere
Low
High I
Typ.
CoUfornt
Fecal Coliform
/100ml
ND
ND
ND
ND
Total Coliform
/100ml
ND
16
3.00
ND
TPH
mg/L
ND
3.0
0.07
NitrogenaNlfrate .::.......:.
....
...... :.
..... ...
`... ...............
::
.....:;.
Total Kieidahl Nitrogen
mg/L
0.30
1.00
0.662
<30
<5
<30
>30
10.0
30.0
20.6
Ammonia
mg/l.
ND
0.56
0.15
0.1
25.0
10.0
Nitrite
mg/L
ND
0.04
0.0025
1.00
1.0D
Nitrate
mgA.
ND
19.90
6.03
10.00
10.00
1.0
20.0
8.0
................:..>,.:.... .
tooc�:Catforrst.:Alkallntty,2.,::.
Chloride
mg&
34
2,500
458.3
250s
3WI
<100
>100
>3501
50
500
75
Sulfate
mg1L
66
574
245
250,
Sodium Adsorption Ratio
(ratio)
3.97
6.18
5.35
4.0
<9.0
>9.0
Conductivity
u mhos/
1,810
1,810
1,810
Alkalinity as Bicarbonate
mg/L
216
1,150
421
<90
<500
>500
. ...............
ND:,
ND.::..
NQ ...;:
:.
;.
>
.....
tdetals.f )nMrgap.q: .
Chromium
mgA.
ND
0.010
0.0005
0.10
0.10
OADI
0.10
<0.001
0.10
0.001
Inc
mg/l.
ND
0.062
0.0031
5.0,
2.001
2.00
0.01
0.40
0.04
Copper
mg/L
NDI
0.682
0.07511
1.30
0.201
0.20
0.005
0.05
0.02
Lead
mg1L
NDI
0.017
0.00161
Zerol
0.015
5.001
5.00
0.001
0.20
0.005
Selenium
mg/L
NDI
0.064
0.0060
0.05
0.05
0.02
Potassium
mgA.
10.41
39.3
20.65
10
30
15
Sodium
mgA.
82.61
376.0
176,8
<70
>70
50
400
100
Calcium
mgA.
NDI
126.0
76.7
25
1001
50
Magnesium
mg&
18.41
138.0
35.8
10
501
20
Boron
mgA_
0.3611
0.869
0.507
<0.7
4.0
4.0
0.3
2.51
0.5
] .:..
77
....... i..,.
...
Endrin aldehyde
ug/L
NDI
0.071
0.004
0.2
2.0
0.3
20
PesUctdes :iierblc de' : >}:}]$$:
...... t..........
2xti.:Pi�:::F
:2•.•: D]Fss
] •
•..,
:::$]2••.: ]:;
:2n
• : •}::....]]}].
•:t2v
$]]F:
:•,,,......
...2
: •$:
$>
.........:: }t$F$F ir.,:.. ii:..:.:: rr..:. A]:}:•}v
ii
i,. }
]..
..%�,,:
].
Qir:
.: 2 }
ss F .::::...
..v..,..
......:::
ii
.::i.....
i$`t.:
r;}$}
>>..$
:t:,i 5 .}j:
SemlYolaUte; } Y } i.
$
k F F i2
$ }
Phenol
ugA.
ND
18.00
3.8751
300
2190
nt Not Tested
ND Not Detected
Spaces Not Detected or Not Applicable
1. Current Baseline - This portion of the table lists the lowest concentration detected, highest concentration detected, and the
average concentration detected during this baseline assessment. The baseline averages reported on this table are provided for
comparison purposes only and reflect the total of the concentrations detected divided by the number of samples analyzed. If
constituent concentrations or wastewater parameters were equal throughout the Site, this average would be representative.
Each groundwater sample, however, is unique and cannot be assumed to contain the average value reported.
Baseline Assessment (Current Baseline Report) - Wilson Land Application Site, Wilson, Texas Page 26
4. Drinking Water MCLs — This portion of the table lists EPA drinking water maximum concentration levels (MCLs) as
published in 40 CFR 141. Drinking water MCLs are legally enforceable standards applied to public water systems. Values
with a v indicator are derived from National Secondary Drinking Water Regulations (secondary standards). Secondary
standards are non -enforceable guidelines regulating contaminants that may cause cosmetic effects (.e. skin or tooth
discoloration) or aesthetic effects (.e. taste, odor, color) in drinking water. These values are provided for comparison
purposes only since Site water is not being used for drinking purposes.
5. Residential Groundwater — This portion of the We fists TNRCC maximum groundwater concentrations for residential
exposure conditions as published in 30 TAC 335568Appendlz11.
6. Irrigation Water — Phytotoxicity - This portion of the table is derived from Recommended Maximum Concentrations of
Trace Elements In Irdgatlon Waters (Petlygrove 6 Asano — 1984). Exceeding these concentrations can result in negative
plant responses (phytotoxicity) in certain plant species.
7. Irrigation Restrictions — Irrigation Water Quality Restrictions are derived from Irrigation Water Quality Criteria (Westoot
and Ayers — 1985 and National Academy of Sciences - 1973). This document lists irrigation water qua!ity parameters that
dictate whether the groundwater can be used without restriction, with only moderate restrictions, or with severe restrictions.
These restrictions do not indicate that the water is unsuitable for irrigation, but its use may call for limited application, resistant
crops, specific soil conditions, or the implementation of special management practices).
8. Typical Wastewater Range . This portion of the table is derived from Compasltlon of Secondary Treated Municipal
r^" Wastewater Effluents and Irrigation Water (Asano et at. - 1984 and Treweek — 1985) and fists the concentration ranges
normally found in secondary wastewater effluents across the U.S.A. These figures are provided for comparison purposes
only, since groundwater, not wastewater effluent, samples were enabled.
I Groundwater Constituents I Parameters Detected
No polychlorinated biphenyls (PCBs) were detected in groundwater samples. The contaminants,
chemical constituents, and wastewater parameters detected in groundwater are listed below. A
description of these items is provided in the Contaminants and Parameters section of this report
Alkalinity Carbonate and Bicarbonate Carbonate and Bicarbonate
All groundwater samples were tested for alkalinity as carbonate and bicarbonate. Alkalinity as
bicarbonate was detected in every groundwater sample. Alkalinity as carbonate was not detected
in any groundwater sample. Alkalinity as bicarbonate concentrations ranged from 216 to 1,150
mg/L. For this baseline:
Alkalini�as Bicarbonate Bicarbonate
Lowest Level:
Highest Level:
Average (20 samples):
Irrigation Restrictions:
216 mg/L
1,150 mg/L
421 mg/L
<90 mg/L — unrestricted use
90 — 500 mg/L — moderate restrictions
>500 mg/L — severe restrictions
On -site groundwater concentrations of bicarbonate exceed recommended irrigation water levels
for unrestricted use.
Baseline Assessment (Current Baseline Report) —Wilson Land Application Site, Wilson, Texas Page 27
7
i
Ammonia (NH3)
Ammonia was detected in ten of the twenty groundwater samples analyzed and concentrations
ranged from ND to 0.56 mg/L. For this baseline:
Ammonia
Lowest Level: ND
Highest Level: 0.56 mg/L
Average (20 samples): 0.15 mg/L
Typical Wastewater: 10.0 mg/L
Ammonia is not environmentally persistent and is rapidly taken up by plants and microorganisms.
Regulatory guidelines for allowable levels of ammonia in water are not published and the health
effects resulting from human exposures to water containing specific levels of ammonia are not
known. At 1.0 mg/L in water, ammonia has been demonstrated to produce only a minimal risk
level based on animal studies.
On -site groundwater ammonia concentrations are far below the typical ammonia levels found in
wastewater effluent and should not pose human health problems.
Boron
Boron was detected in every water sample and ranged from 0.361 to 0.869 mg/L. For this
baseline:
Boron
Lowest Level:
Highest Level:
Average (20 samples):
Irrigation Restrictions:
Typical Wastewater:
0.361 mg/L
0.869 mg/L
0.507 mg/L
<0.7 mg/L — unrestricted use
0.7 — 3.0 mg/L — moderate restrictions
>3.0 mg/L — severe restrictions
0.5 mg/L
Allowable levels for boron in drinking water are not published. The occurrence of boron in toxic
concentrations in certain irrigation waters, however, makes it necessary to consider this element
when assessing agricultural water quality. To certain crops and under certain conditions, boron
can be toxic in concentrations as low as 0.33 mg/L.
Average on -site groundwater boron levels slightly exceed the typical boron concentrations found in
wastewater effluents, but allow the water to be used for irrigation without restrictions.
Baseline Assessment (Current Baseline Report) — Wilson Lend Application Site, Wilson, Texas Page 28
t-
4
Calcium
Calcium was detected in all but one water sample and ranged from ND to 126 mg/L. For this
baseline:
Calcium
Lowest Level: ND
Highest Level: 126.0 mg/L
Average (20 samples): 76.7 mg/L
Typical Wastewater: 50 mg/L
In some wells, groundwater calcium levels exceed the typical calcium concentrations found in
wastewater effluents.
Chloride
Chloride was detected in every water sample and ranged from 34 to 2,500 mg/L. For this baseline:
Chloride
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCLs:
Phytotoxicity: .
Irrigation Restrictions:
Typical Wastewater:
34 mg/L
2,500 mg/L
458.3 mg/L
250 mg/L (unenforceable standard)
350 mg/L
<100 mg/L — No restrictions on use
100 - 350 mg/L — Moderate restrictions
>350 mg/L — Severe restrictions
75 mg/L
Average on -site groundwater chloride levels significantly exceed drinking water secondary
standards, phytotoxicity levels, and the chloride levels typically found in municipal wastewater
effluent. Severe restrictions in the use of this groundwater for irrigation are called for. These
restrictions do not indicate that the water is unsuitable for irrigation, but its use may call for limited
application, resistant crops, specific soil conditions, or the implementation of special management
practices.
r
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson. Texas Page 29
7
r
I.
Chromium
Chromium was detected in only one of twenty groundwater samples with a concentration of 0.01
mg/L. For this baseline:
Chromium
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCLs:
Residential Groundwater:
Phytotoxicity:
Irrigation Restrictions:
Typical Wastewater:
ND
0.01 mg/L
0.0005 mg/L
0.1 mg/L
0.1 mg/L
0.1 mg/L
>0.1 mg/L —severe restrictions
0.001 mg/L
Chromium was detected in only one on -site well in concentrations well under drinking water
standards.
Colifonm - Total and Fecal
Initial groundwater sampling demonstrated that trash and vermin in and around the monitor wells
could potentially contribute to coliform counts. For this reason, subsequent samples were
analyzed for both total coliform and fecal coliform. Since only a single, small "hit" for coliform was
detected in the initial groundwater samples, additional coliform testing was performed only on Well
A, E, and U (wells located closest to occupied farmsteads and the City of Wilson). A single "hit" for
total coliform of 16 col/100ml was detected in Well E and no fecal coliform were detected. For this
baseline:
Coliform
Lowest Level:
Highest Level:
Average (6 samples):
Drinking Water MCLs:
Fecal Total
ND
ND
ND
16 col/100ml
ND
3 co11100ml
ND
ND
Relatively low counts of total coliform were detected and exceed drinking water MCLs.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 30
t
I
7
Pw
e
Copper
Copper was detected in six of twenty groundwater samples with concentrations ranging from ND to
0.682 mg/L. For this baseline:
Copper
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCLs:
Phytotoxicity:
Irrigation Restrictions:
Typical Wastewater:
ND
0.682 mg/L
0.075 mg/L
1.3 mg/L
0.20 mg/L
>0.20 mg/L — Severe restrictions
0.02 mg/L
The highest detected levels of copper meet drinking water standards, but could impose restrictions
on the use of the groundwater for irrigation purposes.
Endrin aldehyde
Endrin aldehyde, a decomposition product of the banned pesticide Endrin, was detected in only
one groundwater sample at concentrations of 0.071 ug/L (ppb). For this baseline:
Endrin aldehyde
Lowest Level: ND
Highest Level: 0.071 ug/L (ppb)
Average (20 samples): 0.004 ug/L (ppb)
Drinking Water MCLs: 0.2 ug/L (ppb)
Residential Groundwater: 2.0 ug/L (ppb)
Typical Wastewater: 0.3 to 20.0 ug/L (ppb)
The pesticide byproduct, endrin aldehyde, is present in only one water well and at levels meeting
drinking water standards.
Lead
Lead was detected in only two of twenty samples with concentrations of 0.015 and 0.017 mg/L. For
this baseline:
Lead
Baseline Assessment (Current Baseline Report) — Wilson land Application Site, Wilson, Texas Page 31
i
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCL:
Residential Groundwater:
Phytotoxicity:
Irrigation Restrictions:
Typical Wastewater:
ND
0.017 mg/L
0.0016 mg/L
ND (0.015 mg/L Action Level)
0.015 mg/L
5.00 mg/L
>5.00 mg/L — severe restrictions
0.005 mg/L
Drinking water MCLs for lead are set at zero mg/L. If lead is detected in drinking water at the
action level of 0.015 mg/L or above, the water system must continue to monitor for lead twice a
year.
On -site groundwater lead levels are well below phytotoxicity levels and, out of two `hits', only one
well had lead levels slightly exceeding the drinking water action level.
Magnesium
Magnesium was detected in every groundwater sample in concentrations ranging from 18.4 to
138.0 mg/L. For this baseline:
Magnesium
Lowest Level:
18.4 mg/L
Highest Level:
Average
138.0 mg/L
35.8
(20 samples):
mg/L
Typical Wastewater:
20.0 mg/L
In some wells, groundwater magnesium concentrations exceed the magnesium levels typically
found in wastewater effluents.
Nitrites I Nitrates
Out of twenty groundwater samples, nitrite was detected in only two samples and nitrate was
detected in eighteen samples. Nitrites ranged from ND to 0.04 mg/L and nitrates ranged from ND
to 19.9 mg/L. For this baseline:
Nitrites Nitrates
Baseline Assessment (Current Baseline Report) —Wilson Land Application Site, Wilson, Texas Page 32
f"
i
I_
r
Lowest Level: ND ND
Highest Level: 0.04 mg/L 19.9 mg/L
Average (20 samples): 0.0025 mg/L 6.03 mg/L
Drinking Water MCLs: 1.0 mg/L 10.0 mg/L
Typical Wastewater: 8.0 mg/L
Nitrite concentrations in groundwater meet drinking water standards. On -site groundwater
concentrations of nitrates in some wells exceed drinking water standards (but average nitrate
levels are within drinking water standards).
Phenol
Phenol was detected in two of the twenty groundwater samples in concentrations of 13.0 to 18.0
ug/L (ppb). For this baseline:
Phenol
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCLs:
Residential Groundwater:
ND
18.0 ug/L (ppb)
3.875 ug/L (ppb)
300.0 ug/L (ppb)
2,190 ug/L (ppb)
Phenol was detected in two water wells at concentrations that meet drinking water standards.
Potassium
Potassium was detected in every water sample in concentrations ranging from 10.4 to 39.3 mg/L.
For this baseline:
Potassium
Lowest Level: 10.4 mg/L
Highest Level: 39.3 mg/L
Average (20 samples): 20.7 mg/L
} Typical Wastewater: 15 mg/L
In some wells, groundwater potassium levels exceed those typically found in wastewater effluent
F
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 33
{k
Selenium
Selenium was detected in only two of twenty samples with concentrations of 0.056 and 0.064 mg/L.
For this baseline:
Selenium
Lowest Level:
ND
Highest Level:
0.064 mg/L
Average (20 samples):
0.0060 mg/L
Drinking Water MCL:
0.05 mg/L
Residential Groundwater:
0.05 mg/L
Phytotoxicity:
0.02 mg/L
Selenium was detected in only two water wells at concentrations that pose phytotoxicity concerns
and slightly exceed drinking water standards.
Sodium
Sodium was detected in every water sample and ranged from 82.6 to 376.0 mg/L. For this
baseline:
Sodium
Lowest Level:
Highest Level:
Average (20 samples):
Irrigation Water Quality:
Typical Wastewater:
82.6 mg/L
376.0 mg/L
176.8 mg/L
< 70 mg/L — No restrictions on use
> 70 mg/L — Moderate restrictions
100 mg/L
On -site groundwater sodium concentrations exceed irrigation water quality criteria for unrestricted
use.
Sodium Adsorption Ratio (SAR) and Conductivity(EC)
Only the initial groundwater samples were tested for SAR and results ranged from 3.97 to 6.18. In
addition, conductivity tests were run on water samples from Well J and Well U and showed to be
1810.0 umhoskrn2 for both wells. SAR and conductivity results combine to indicate a low to
moderate sodium (alkali) hazard. Low sodium water can be used for irrigation on almost all soils
with little danger of developing harmful levels of exchangeable sodium. For this baseline:
Baseline Assessment (Current Baseline Report) —Wilson Land Apprication Site, Wilson, Texas Page 34
SAR
Lowest Level:
Highest Level:
Average (3 samples):
Irrigation Water Quality:
3.97
6.18
5.35
<3.0 — No restrictions on use
3.9 — 9.0 — Moderate restrictions
>9.0 — Severe restrictions
Sulfate
Sulfates were detected in every water sample and ranged from 66 to 574 mg/L. For this baseline:
Sulfate
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCLs:
66 mg/L
574 mg/L
245 mg/L
250 mg/L (Secondary standard)
On -site groundwater sulfate concentrations in some wells exceed drinking water secondary
standards.
Total Kieldahl Nitrooen (TKN
In total, groundwater samples from wells I, L, M, N, and Q were analyzed for TKN. The selected
wells are either located in the middle. or on the periphery of the subject property or by the
reservoirs. TKN was detected in every well tested and ranged from 0.30 to 1.00 mg/L. For this
baseline:
TKN
Lowest Level:
Highest Level:
Average (5 samples):
Phytotoxicity:
Irrigation Water Quality:
Typical Wastewater:
0.30 mg/L
1.00 mg/L
0.662 mg/L
< 30 mg/L
< 5.0 mg/L — unrestricted use
5 - 30 mg/L — moderate restrictions
> 30 mg/L — severe restrictions
20 mg/L
Baserine Assessment (Current Baseline Report) — Wilson Land AWiication Site, Wilson, Tams Page 35
f
On -site groundwater TKN levels for total nitrogen permit the unrestricted use of groundwater for
irrigation purposes.
Total Petroleum Hydrocarbons (TPH)
Although no TPH was detected in the initial groundwater samples, it was considered prudent to
spot check other wells for TPH to demonstrate due diligence. In total, groundwater samples from
wells A, B, D, H, I, K, L, K Q, and U were analyzed for TPH. The selected wells are either located
in the middle of the property, on the periphery of the property, or by the reservoirs. TPH was
detected in low levels (1 to 3 mg/Q in four of the ten wells tested. For this baseline:
TPH
Lowest Level: ND
Highest Level: 3 mg1L
Average (10 samples): 0.7 mg1L
Allowable Levels: None Published
TPH is indicative of contamination by petroleum -based products, but regulatory guidelines for
allowable levels of TPH in water are not published. The presence of TPH generally prompts for
rL further sample analysis to characterize the `hit" (i.e. BTEX, MTBE, VOCs, and semi-volatiles).
Once characterized, regulatory guidance for the specific contaminant(s) is often available. The
relatively low levels of TPH detected in the Site's groundwater should not prompt further testing if
�» the water is not used for drinking purposes.
Note: TPH In relatively high concentrations was discovered In several of the baseline assessment's
soll samples. To characterize the detected TPH, every soll sample having a TPH concentration
greater than 200 mg/Kg was tested using TX 1005 methods (total of four samples). In every case,
contaminants In the range of Cs to C2e were not detected. The TX 1005 results suggest that the
petroleum -based contaminants exist in carbon ranges greater than Cm.
The soli sample having the highest TPH concentration was further analyzed for seml-volatile
compounds (using EPA 8270C methods capable of detected many of the :oCn compounds). No semb
voladles were detected In this sample suggesting that the TPH contaminant may exist In ranges
greater than Ca Products In the :oC=a range Include heavy hydrocarbon substances such as fuel oil,
transformer oil, lubricating oil, asphalt; pitch, and wax. Generally, these heavier and more viscous
substances are not highly mobile and have a tendency to bind to sediments. As such, :oCn
compounds do not typically pose an environmental threat
Wastewater collected from the reservoirs was analyzed to determine If It was the source of TPH
contamination, but no TPH was detected using the EPA 418.1 method. Samples from the reservoirs,
however, were only grab samples and a sample representative of the wastewater column was not
collected Heavy contaminants may stratify In the lower depths of the reservoir waters.
TPH was reported In two of the three reservoir sludge samples, but no seml-voladles were detected.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 36
r
Zinc
Zinc was detected in only one of twenty samples with a concentration of 0.062 mg/L. For this
baseline:
Zinc
Lowest Level:
Highest Level:
Average (20 samples):
Drinking Water MCLs:
Phytotoxicity:
Irrigation Restrictions:
Typical Wastewater:
ND
0.062 mg/L
0.0031 mg/L
5.0 mg/L (Secondary standard)
2.0 mg/L
>2.0 mg/L — severe restrictions
0.04 mg/L
Zinc was detected in only one well, but was at concentrations that meet drinking water secondary
standards and do not pose phytotoxicity concerns.
Baseline Assessment (Current Baseline Report) — Wilson Land Apprication Site, Wilson, Texas Page 37
(i
C
Soil Sampling
Soil Sampling Technlpues
Soil samples were collected from under each center pivot irrigation system, from a flood irrigation
area located west of the East Reservoir, and from a cotton burr storage area located northwest of
the East Reservoir. In total, 414 grab samples were collected and composited into 24 `shallow'
samples (representative of "shallow" soil conditions — 0 to 6 inches deep) and 24 'deep* samples
(representative of `deep" soil conditions —18 to 24 inches deep). The locations of soils sampled
for this baseline assessment are illustrated by the Pivot Soil Sample Location Map included in
Appendix A.
Most soil samples were collected from the plots irrigated by center pivot systems. For each center
pivot with a working arc greater than 180 degrees, eighteen grab samples were collected and then
composited into two samples (one for shallow soils and one for deep soils). The grab sample
collection points were determined by extending three imaginary rays from the center pivot to the
I periphery of the plot Three sample locations were plotted along each imaginary ray, and both
shallow and deep soil samples were collected from each location (six grab samples per ray). At
each sample location, a portion of the soils from 0 to 6 inches was placed in a clean plastic
container until all grab sample locations under the current pivot were collected. Likewise, a portion
�;. of the soils from 18 to 24 inches was placed in a separate container until all grab samples were
collected. Representative portions of the composited samples were then collected and submitted
to the laboratory for analysis.
Soil samples were collected using a portable, gasoline engine driven 4-inch diameter `post hole
digger'. The spoils resulting from the soil boring activities was used to backfill the hole. The soil
samples were collected in the appropriate laboratory and method approved containers for the
analytical suite. Disposable protective gloves were used in collecting each sample. The samples
were labeled, logged, cooled, and transported to Certes Environmental Laboratories L.L.C.
(Certes) under chain -of -custody procedures for analysis in accordance with standard procedures.
Initial Soil Sampling and Analysis
Initially, four composite soil samples (three shallow and three deep) were collected from Pivot #2
and Pivot#3. In addition, two composite soil samples (one shallow and one deep) were collected
from the Cotton Burr Area. (Mounds of cotton buns and cotton gin trash are stored in windrows at
several points on -site for use as a soil additive. Due to an expressed concern that arsenic -based
defoliants might have contaminated the cotton wastes and could then potentially leach into
surrounding soils and reservoirs, a decision was made to test soils in the storage area located
closest to a reservoir).
Baseline Assessment (Current Baseline Report) — Wilson Lend Application Site, Wilson. Texas Page 38
..
These initial soil samples were analyzed using the following analytical protocols:
• SM 9222E — Total coliform.
• EPA 418.1—Total petroleum hydrocarbons (TPH).
• EPA 351 AM — Total Kjeldahl Nitrogen (TKN).
• EPA 350.31VI — Ammonia.
• EPA 354.11M - Nitrite.
• EPA 353.3 — Nitrate.
• EPA 9253 — Chloride.
EPA 9038 — Sulfate.
P
• 3.2.191 —Sodium adsorption ratio (SAR).
F
• SM2320B—Alkalinity.
• EPA 7471A — Mercury.
EPA 6010E — Arsenic, cadmium, chromium, zinc, copper, nickel, lead, selenium,
molybdenum, potassium, sodium, calcium, magnesium, and boron.
0 EPA 8081A and EPA 8151A — Specific pesticides, herbicides, fungicides, and their
byproducts.
�. • EPA 8082 — Polychlorinated biphenyls (PCBs).
• EPA 8270C — Semi -volatile chemical compounds associated with fuels, solvents,
pesticide byproducts, and other commercial 1 industrial processes.
The following Initial Soil Samples - Analytical Results table compiles the analytical results
received and shows those parameters or constituents for which a value was detected. A table
showing all of the constituents 1 parameters detected for each soil sample is provided in Appendix
C. In addition, tables showing detected constituents 1 parameters in shallow samples alone and in
deep samples alone are included in Appendix C. Laboratory reports and Chains -of -Custody for all
soil samples are included in Appendix E (a separately bound appendix to this report). Laboratory
reports list all of the constituents 1 parameters for which analysis was performed.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 39
P
40"
.... ......... ...... ......
........ . ... ..........
. .. . ......
Constituent
Units
Pivot 92
Shallow
Pivot/2
Deep
Plvot*3
Shallow
Pivot#3
Deep
Cotton Burns
Shallow
Cotton Burrs
Deep
..................
. ..........
* ..
4
%,
Total Cofifim
covorarn
7
1
3
ND
ND
ND
......... .
iPH
mogg
NO
NO
NO
NO
27
NO
R
75-
Total Kieldahl Nitrogen
mg/Kg
631
444
493
498
1,560
410
Ammonia
mgA(g
36.2
191
42.11
38.9
23.9
24.7
Nitrite
mg/Kg
12
1.1
1.5
1.7
1.5
1.4
Nitrate
mgfKg
11.7
16.2
12.1
14.2
45.4
12.5
...
.........
Chloride
mg/Kg
NO
500
NO
NO
NO
60
Sodium Absorption Ratio
0.008
0.008
0.0091
0.012
0.004
0.004
Alkalinity as Bicarbonate
Mg/L
110
sm
84
98
84
30
...........
Mercury
mgrKg
0.02
NO
0.03
0.02
0.03
0.02
hlels oir
HV'
Arsenic
mg/Kg
1 4.3
3.1
NO,
6.5
4.7
NO
Chromium
mg/Kg
11.20
11.80
11.90
15.30
15.40
14.40
Zinc
mg/Kg
26.7
28.0
29.5
38.4
42.2
33.8
Copper
mg/Kg
5.68
6.04
6.37
8.47
9.93
6.75
Nickel
mg/Kg
8.7
9.8
8.7
11.7
12.0
4,8
Lead
mg/Kg
5.7
12.4
14.31
16.4
18.6
7.3
Selenium
mgA(g
4.3
ND
NO
J ND
NO,
N
Molybdenum
mgA(g
NO
1.2
NO
1.1
1.1
1.1
Potassium
mg/Kg
2.950
3,030
3,300
3.630
5,030
3,920
Sodium
mgA(g
587
757
616
929
259
171
Calcium
mg/Kg
1 14.300
58.800
2.200
12.100
6.840
4.550
Magnesium
mg1Kg
3,190
3,460
2,430
3,460
4,060
300
Boron
mg/Kg
8.41
5.99
7.77
6.07
9.15
5.48
I-P
...........
'N
U. .
. . .......
..... ..
...............
... d-P
-7-71
NO - Not Detected
Baseline Assessment (Current Baseline Report) - Wilson Land Application Site, Wilson, Texas pap 40
PM
Subsequent Soil Sampling
Based on the initial soil sampling results, a decision was made to test subsequent soil samples as
follows:
• Ions I Cations I Alkalinity:
All subsequent soil samples were analyzed for potassium, sodium, calcium,
magnesium, chloride, sulfate, bicarbonate, carbonate, and boron. These constituents
were listed by EPA guidance documents as concerns in wastewater application
operations.
ti
. Nitrite 1 Nitrate I Ammonia:
e
All subsequent soil samples were analyzed for nitrites, nitrates, and ammonia.
• Metals I Trace Elements:
All subsequent soil samples were analyzed for arsenic, cadmium, chromium, mercury,
,1
zinc, copper, nickel, lead, selenium, and molybdenum. Many of these metals are
RCRA-controlled contaminants and are regulated by the EPA in wastewater sludges.
• Pesticides 1 Herbicides 1 Fungicides:
All shallow subsequent soil samples were analyzed for pesticides, herbicides,
fungicides, and their byproducts.
Coliform — Total and Fecal:
No subsequent soil samples were tested for coliform.
• Total Petroleum Hydrocarbons (TPH):
All shallow subsequent soil samples were analyzed for TPH. As results from these
samples were received, further TPH analysis was ordered on the deep samples
corresponding to every shallow soil sample having a TPH level of >200 mg/Kg. TX
1005 and EPA 8270C analysis was also ordered for the most contaminated soil
samples. In addition, thinking that wastewater from the reservoirs might be a source
�.,
for TPH, samples from the reservoirs were collected and submitted to Trace Analysis
Inc. (Trace), an environmental laboratory for TPH testing.
• Semi-Volatiles:
r"
Semi -volatile analysis was conducted on shallow samples collected from five center
-
pivot plots largely located on the comers of the Site boundaries.
• Total Kjeldahl Nitrogen (TKN):
TKN analysis was conducted on all subsequent soil samples.
• Sodium Adsorption Ratio (SAR):
SAR analysis was conducted on all subsequent soil samples.
Baseline Assessment (Current Baseline Report) — Wilson Lend Application Site, Wilson, Texas Page 41
Soil Analysis
The following All Soil Samples • Analytical Results table compiles the analytical results received
and shows those parameters or constituents for which a value was detected. The lowest, highest,
and average values for each detected constituent are listed along with comparative values when
available. A table showing all of the constituents / parameters detected for each soil sample is
provided in Appendix C. In addition, tables showing detected constituents / parameters in shallow
samples alone and in deep samples alone are included in Appendix C. Laboratory reports and
Chains -of -Custody for all soil samples are included in Appendix E (a separately bound appendix to
this report). Laboratory reports list all of the constituents / parameters for which analysis was
performed.
Constituent
Current
Baseline'
Units Low I High A
TNRCC Guidelines
Groundwater Soil
Protection2 Ingestii
(Total Coliform I /gram I NDI 71 1.831 1 1
Total Kjeldahl Nitrogen
mg/Kg
NDI
1560.0
497.6
Ammonia
mg/Kg
ND
42.1
3.86
Nitrite
mg/Kg
ND
1.7
0.18
100
204K
Nitrate
mg/Kg
ND
45.4
6.15
1,000
Chloride
mg/Kg
NDI
1,100
294
Sulfate
mg/Kg
NDI
1
606
197
Sodium Adsorption Ratio
(ratio)
0.004
6.200
2.307
Alkalinity as Bicarbonate
mg/Kg
ND
1,480
409.71
Alkalinity as Carbonate
mg/Kg
ND
1.040
205.24
Mercury
mg/Kg
NDI
0.03
0.01311
0.2
613
<
> x
Arsenic
mg/Kg
ND
6.8
4.66
5.00
3.27
Cadmium
mg/Kg
ND
2.27
1.58
0.50
1,020
Chromium
mg/K91
8.481
17.201
12.131
10.01
5,110
Baseline Assessment (Current Baseline Report) — Wilson Land Apprication Site, Wilson, Texas Page 42
71
..r
t
............::....
.:. ..........:. m .Les..
:. :..:•};..};;,..:::••:: is ]}.:;.,. .. ...........]::}::}:}:::::::: }:•:,:'•:::::::::::::•:•
.. ... .. ....
Constituent
Units
Current
Baseline'
TNRCC Guidelines
Groundwater
Protection2
Soil
Ingestionli
Low
High
Avg.
Zinc
mg/Kg
24.2
44.6
34.0
Copper
mg/Kg
5.68
72.90
14.56
Nickel
mg/Kg
4.81
13.3
9.89
10
20,400
Lead
mg/Kg
5.71
40.1
13.61
1.5
1,000
Selenium
mg/Kg
NDJ
4.3
0.09
5
10,200
Molybdenum
mg/Kg
ND
1.2
0.09
Potassium
mg/Kg
987
5,030
2,473
Sodium
mg/Kg
171
1,530
959
Calcium
mg/Kg
1,370
58,800
8,774
Magnesium
mg/Kg
1,2301
4,080
2,162
Boron
mg/Kg
5.48
34.00
19.66
4,4'-DDE
ug/Kg
ND
3.49
0.34
84.1
16,800
Heptachlor epoxide
ug/Kg
ND
1,88
0.07
20.0
629
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nt Not Tested
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Spaces Not Detected or Not Applicable
1. Previous Sampling -Soil sampling for specific constituents and parameters was conducted from 1992 to 1996 and reported in the
Lubbock Cbrfstfan College Investment Corporation -Soli Analysts Report for the year ending 913Q11998. The lowest, highest,
and average concentrations detected by these sampling events - for shallow and deep samples - are fisted. The previous sampling
averages are provided for comparison purposes only and reflect the total of the concentrations detected divided by the number of
samples analyzed. If constituent concentrations or parameters were equal throughout the Site, this average would be
representative. Each soil sample, however, is unique and cannot be assumed to contain the average value reported.
2. Groundwater Protection OndustdaQ - This portion of the We lists TNRCC maximum soil concentrations to ensure groundwater
protection at industrial sites as published in 30 TAC 331568 Appendix A. These figures provide industrial site sod parameters to
be used in risk reduction computations and represent the maximum concentrations in ndrstrial soil assumed protective of
groundwater considering cross -media contamination of groundwater from contaminated sal.
3. Soil Ingestion (IndustriaQ - This portion of the We fists TNRCC maximum soil concentrations for industrial sal exposures as
published in 30 TAC 335.568 Appendix It. These figures provide industrial site soil parameters to be used in risk reduction
computations and represent the maximum concentrations in industrial soil considering cross -media contamination of air and the
human ingestion I inhalation pathways.
Baseline Assessment (Current Baseline Report) -Wilson Lend Application Site, Wilson, Texas Page 43
Ow
i
Soil Contaminants and Parameters
PCBs and semi -volatile compounds were not detected in any of the forty-eight soil samples
analyzed. The contaminants, chemical constituents, and wastewater parameters that were
detected are listed below. A description of these items is provided in the Contaminants and
Parameters section of this report
4.4-DDE
DDE was detected in three of twenty-seven soil samples analyzed and concentrations ranged from
ND to 3.49 ug/Kg. For this baseline:
DDE
Lowest Level:
ND
Highest Level:
3.49 ug/Kg
Average (27 samples):
0.34 ug/Kg
Groundwater Protection:
84.1 ug/Kg
Soil Ingestion:
16,800 ug/Kg
On -site soil concentrations of DDE do not approach those levels set by the TNRCC for
groundwater protection or soil ingestion.
} Alkalinity as Carbonate and Bicarbonate
Alkalinityb bicarbonate was detected in forty-six of the forty-eight soil samples and
Y P
concentrations ranged from ND to 1,480 mg/Kg. Alkalinity by carbonate was detected in twenty-
nine of the forty-two soil samples (Initial samples were not tested) and concentrations ranged from
ND to 1,040 mg/Kg. For this baseline:
r-
r7.
t
Alkalinity
Lowest Level:
Highest Level:
Average (48 & 42 samples):
Allowable Levels:
Bicarbonate
ND
1,480 mg/Kg
409.7 mg/Kg
None Published
Carbonate
ND
1,040 mg/Kg
205.2 mg/Kg
None Published
Ammonia (NHA
Ammonia was detected in six of the forty-eight soil samples analyzed and concentrations ranged
from ND to 42.1 mg/Kg. For this baseline:
Ammonia
Lowest Level: ND
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 44
E
t
k
Highest Level:
Average (48 samples):
Allowable Levels:
42.1 mg/Kg
3.86 mg/Kg
None Published
Ammonia is not environmentally persistent and is rapidly taken up by plants and microorganisms.
Arsenic
Arsenic was detected in forty-four of forty-eight soil samples with concentrations ranging from ND
to 6.8 mg/Kg. For this baseline:
Arsenic
Lowest Level: ND
r- Highest Level: 6.80 mg/Kg
. Average (48 samples): 4.66 mg/Kg
Groundwater Protection: 5.00 mg/Kg
j Soil Ingestion: 3.27 mg/Kg
'r -
Arsenic soil levels recommended by the TNRCC to protect groundwater at industrial sites is 5.00
mg/Kg. In the event of soil ingestion, arsenic soil levels recommended by the TNRCC to protect
human health at industrial sites is 3.27 mg/Kg. This baseline assessment shows that arsenic
levels exceed these TNRCC and EPA recommendations.
Boron
Boron was detected in every soil sample and ranged from 5.48 to 34.0 mg/Kg. For this baseline:
Boron
Lowest Level: 5.48 mg/Kg
Highest Level: 34.0 mg/Kg
Average (48 samples): 19.7 mg/Kg
Allowable Levels: Not published
Allowable levels for boron in soils are not published. The occurrence of boron in toxic
concentrations in certain irrigation waters, however, makes it necessary to consider this element
when assessing agricultural water quality. To certain crops and under certain conditions, boron
can be toxic in concentrations as low as 0.33 mg/Kg. All soil boron levels exceed this level of
`toxicity'.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 45
Cadmium
Cadmium was detected in forty-two of forty-eight soil samples with concentrations ranging from ND
to 2.27 mg/Kg. For this baseline:
Cadmium
Lowest Level: ND
Highest Level: 2.27 mg/Kg
Average (48 samples): 1.58 mg/Kg
Groundwater Protection: 0.50 mg/Kg
Soil Ingestion: 1,020.0 mg/Kg
Cadmium soil levels recommended by the TNRCC to protect groundwater at industrial sites are
0.50mg1Kg. In the event of soil ingestion, cadmium soil levels recommended by the TNRCC to
protect human health at industrial sites are 1,020mg/Kg. This baseline assessment shows that
cadmium levels exceed TNRCC groundwater protection recommendations.
Calcium
Calcium was, detected in all forty-eight soil samples and ranged from 1,370 to 58,800 mg/Kg. For
this baseline:
Calcium
Lowest Level: 1,370 mg/Kg
Highest Level: 58,800 mg/Kg
Average (48 samples): 8,774 mg/Kg
Allowable Levels: Not published
Chloride
Chloride was detected in forty-four of the forty-eight soil samples and concentrations ranged from
ND to 1,100 mg/Kg. For this baseline:
r- Chloride
i
i ..y Lowest Level:
Highest Level:
Average (48 samples):
Allowable Levels:
i
i;
ND
1,100 mg/Kg
294 mg/Kg
Not published
Baseline Assessment (Current Baserne Report) —Wilson Land Application Site, Wilson. Texas Page 46
j�
1
Chromium
Chromium was detected in all forty-eight soil samples with concentrations ranging from 8.48 to
17.20 mg/Kg. For this baseline:
Chromium
Lowest Level:
8.48 mg/Kg
Highest Level:
17.20 mg/Kg
Average (48 samples):
12.13 mg/Kg
GW Protection:
10.0 mg/Kg
Soil Ingestion:
5,110 mg/Kg
Chromium soil levels recommended by the TNRCC to protect groundwater at industrial sites is
10.0 mg/Kg. In the event of soil ingestion, chromium soil levels recommended by the TNRCC to
protect human health at industrial sites are 5,110 mg/Kg. This baseline assessment shows that
some chromium levels exceed TNRCC groundwater protection recommendations.
Coliform - Total
Total coliform was detected in three of the six initial soil samples in concentrations ranging from
ND to 7.0 col/gram. Since only small `hits" for coliform were detected, soil coliform testing was not
conducted on subsequent samples. For this baseline:
Total Coliform
Lowest Level:
ND
Highest Level:
7.0 col/gram
Average (6 samples):
1.83 col/gram
Allowable Levels:
None published
Copper
Copper was detected in all forty-eight soil samples with concentrations ranging from 5.68 to 72.90
mg/Kg. For this baseline:
Copper
Lowest Level: 5.68 mg/Kg
Highest Level: 72.90 mg/Kg
Average (48 samples): 14.56 mg/Kg
r ,
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site. Wilson, Texas Page 47
F
Allowable Levels: None published
Heptachlor Epoxide
w Heptachlor epoxide was detected in only one of twenty-seven soil samples analyzed and
concentrations ranged from ND to 1.88 ug/Kg. For this baseline:
Heptachlor Epoxide
Lowest Level:
ND
Highest Level:
1.88 ug/Kg
Average (27 samples):
0.07 ug/Kg
GW Protection:
20.0 ug/Kg
Soil Ingestion:
629.0 ug/Kg
On -site levels of heptachlor epoxide do not exceed TNRCC guidelines for groundwater protection
or soil ingestion.
Lead
Lead was detected in all forty-eight of the soil samples at concentrations ranging from 5.7 to 40.1
j mg/Kg. For this baseline:
Lead
Lowest Level:
5.7 mg/Kg
Highest Level:
40.1 mg/Kg
Average (48 samples):
13.61 mg/Kg
GW Protection:
1.5 mg/Kg
Soil Ingestion:
1,000 mg/Kg
Lead soil levels recommended by the TNRCC to protect groundwater at industrial sites are 1.5
mg/Kg. In the event of soil ingestion, lead soil levels recommended by the TNRCC to protect
human health at industrial sites are 1,000 mg/Kg. This baseline assessment shows that average
lead levels exceed TNRCC groundwater protection recommendations.
Magnesium
Magnesium was detected in all forty-eight soil samples and ranged from 1,230 to 4,080 mg/Kg.
For this baseline:
Magnesium
Lowest Level: 1,230 mg/Kg
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site. Wilson. Texas Page 48
71%
Highest Level: 4,080 mg/Kg
Average (20 samples): 2,162 mg/Kg
Allowable Levels: Not published
Mercury
Mercury was detected in thirty-eight of forty-eight soil samples with concentrations ranging from
ND to 0.03 mg/Kg. For this baseline:
Mercu
Lowest Level:
ND
Highest Level:
0.0300 mg/Kg
Average (48 samples):
0.0131 mg/Kg
Groundwater Protection:
0.200 mg/Kg
Soil Ingestion:
613.0 mg/Kg
Mercury soil levels recommended by the TNRCC to protect groundwater at industrial sites is 0.20
mg/Kg. In the event of soil ingestion, mercury soil levels recommended by the TNRCC to protect
human health at industrial sites are 613.0 mg/Kg. The EPA estimates that for an adult of average
weight, exposure to 0.021 mg of mercury in food or water will probably not result in any harm. This
baseline assessment shows that mercury levels do not even approach these TNRCC and EPA
recommendations.
' Molybdenum
Molybdenum was detected in only four of the forty-eight soil samples with concentrations ranging
from ND to 1.20 mg/Kg. For this baseline:
Molybdenum
' Lowest Level: ND
Highest Level: 1.20 mg/Kg
` Average (48 samples): 0.09 mg/Kg
Irrigation Water Quality: 5 mg/L
Irrigation water having 5.0 mg/L or less molybdenum can be continuously used on all soils. In
addition, the natural occurrence of molybdenum in soils ranges between 0.2 and 5.0 mg/Kg.
Nickel
Nickel was detected in all forty-eight soil samples with concentrations ranging from 4.80 to 13.30
mg/Kg. For this baseline:
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 49
Nickel
Lowest Level:
4.80 mg/Kg
Highest Level:
13.30 mg/Kg
Average (48 samples):
9.89 mg/Kg
GW Protection:
10.0 mg/Kg
Soil Ingestion:
20,400 mg/Kg
This baseline assessment shows that average nickel levels meet TNRCC groundwater protection
and soil ingestion recommendations.
Nitrites I Nitrates
Out of forty-eight samples, nitrite was detected in only eight samples and nitrate was detected in
forty-four samples. Nitrites ranged from ND to 1.7 mg/Kg and nitrates ranged from ND to 45.4
mg/Kg. For this baseline:
Nitrites Nitrates
,— Lowest Level: ND ND
I Highest Level: 1.70 mg/Kg 45.4 mg/Kg
Average (48 samples): 0.18 mg/Kg 6.15 mg/Kg
Groundwater Protection: 100.0 mg/Kg 1,000.0 mg/Kg
Soil Ingestion: 204,000 mg/Kg
Soil levels recommended by the TNRCC to protect groundwater at industrial sites is 100 mg/Kg
(nitrites) and 1,000 mg/Kg (nitrates). Nitrite I nitrate levels do not exceed the TNRCC's
groundwater protection recommendation.
Potassium
' Potassium was detected in every soil sample and ranged from 987 to 5030 mg/Kg. For this
F
baseline:
Potassium
Lowest Level:
987 mg/Kg
Highest Level:
5,030 mg/Kg
Average (48 samples):
2,473 mg/Kg
Allowable Levels:
Not published
.� Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 50
4
A.
Selenium
Selenium was detected in only one of forty-eight soil samples with a concentration of 4.3 mg/Kg.
For this baseline:
Selenium
Lowest Level:
ND
Highest Level:
4.30 mg/Kg
Average (48 samples):
0.09 mg/Kg
GW Protection:
5.00 mg/Kg
Soil Ingestion:,
10,200 mg/Kg
This baseline assessment shows that selenium levels are under TNRCC groundwater protection
and soil ingestion levels.
Sodium
Sodium was detected in every soil sample and ranged from 171 to 1,530 mg/Kg. For this baseline:
Sodium
Lowest Level: 171 mg/Kg
Highest Level: 1,530 mg/Kg
Average (48 samples): 959 mg/Kg
Allowable Levels: Not published
Sodium Adsorption Ratio (SAR)
All soil samples were tested for SAR and results ranged from 0.004 to 6.20. Soils in this SAR
range are presumed to pose a relatively low sodium (alkali) hazard, but other parameters (i.e.
conductivity) must also be considered. For this baseline:
SAR
Lowest Level:
Highest Level:
Average (48 samples):
Allowable Levels:
7
0.004
6.20
2.31
None Published
rBaseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 51
I
I
t
` Sulfate
Sulfates were detected in thirty-eight of the forty-eight soil samples and concentrations ranged
from ND to 606 mg/Kg. For this baseline:
4
c
Sulfate
Lowest Level: ND
Highest Level: 606 mg/Kg
Average (48 samples): 197 mg/Kg
Allowable Levels: Not published
Total Kieldahl Nitrogen (TKN)
TKN was detected in forty-six of the forty-eight soil samples analyzed and concentrations ranged
from ND to 1560 mg/Kg. For this baseline:
TKN
Lowest Level: ND
Highest Level: 1,560 mg/Kg
Average (48 samples): 498 mg/Kg
Allowable Levels: None Published
Treated municipal wastewaters typically contain from 10 to 40 mg/Kg of nitrogen — or 0.001 % to
' 0.004% nitrogen. (In comparison, commercial fertilizers typically range from 11% to 82%
nitrogen). Regulatory guidelines for allowable levels of TKN in soil are not published.
` Total Petroleum Hydrocarbons (TPH)
Initially, TPH in concentrations of 27 mg/Kg was detected in the Cotton Burrs Area shallow sample,
but was not detected in any other initial soil samples. Despite this single low 'hit" for TPH, it was
considered prudent to test subsequent shallow soil samples for TPH to demonstrate due diligence.
TPH is indicative of contamination by petroleum -based products, but regulatory guidelines for
allowable levels of TPH in soil are not published. The presence of TPH generally prompts for
further sample analysis to characterize the 'hit" (i.e. BTEX, MTBE, VOCs, PAH, and semi-
volatiles). Once characterized, regulatory guidance for the specific contaminant(s) is often
available.
TPH was unexpectedly detected in eighteen of the twenty-four shallow soil samples and appeared
in concentrations ranging from ND to 292 mg/Kg. To determine the migratory extent of TPH
contamination, four deep samples corresponding to the four most contaminated shallow soil
samples were analyzed for TPH. TPH concentrations of 11 mg/Kg were detected in only two of the
F
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson. Texas Page 52
F
four deep samples tested (the other two samples were ND). This suggests that TPH is
concentrated in surface soils and is not significantly migrating to deeper soils.
To characterize the detected TPH, every soil sample having TPH concentrations greater than 200
mg/Kg was tested using TX 1005 methods (four samples). In every case, contaminants in the
range of C6 to C2e were not detected. These TX 1005 results suggest that the petroleum -based
contaminants exist in carbon ranges greater than Ca.
The soil sample having the highest TPH concentration was further analyzed for semi -volatile
compounds (using EPA 8270C methods capable of detected many of the >C2ecompounds). No
semi-volatiles were detected in this sample suggesting that the TPH contaminant may exist in
ranges greater than Cis. Products in the >C2e range include heavy hydrocarbon substances such
as fuel oil, transformer oil, lubricating oil, asphalt, pitch, and wax. Generally, these heavier and
more viscous substances are not highly mobile and have a tendency to bind to sediments: As
such, >C2e compounds do not typically pose an environmental threat.
Wastewater collected from the reservoirs was analyzed to determine if it was the source of TPH
contamination, but no TPH was detected using the EPA 418.1 method. Samples from the
reservoirs, however, were only grab samples and a sample representative of the wastewater
column was not collected. Heavy contaminants may stratify in the lower depths of the reservoir
waters.
TPH was reported in two of the three reservoir sludge samples, but no semi-volatiles were
detected.
In total, TPH was detected in twenty-one of the thirty soil samples tested. For this baseline:
TPH
Lowest Level: ND
Highest Level: 292 mg/Kg
Average (28 samples): 52.4 mg/Kg
PST Guidance: < 10 & < 200 mg/Kg
In TNRCC Petroleum Storage Tank (PST) regulations, soils having TPH levels of < 10 mg/Kg can
be used as backfill and soils having TPH levels of < 200 mg/Kg can be used as uncovered
roadbase material (providing they have < 0.5 mg/Kg of BTEX).
Zinc
Zinc was detected in all of the forty-eight soil samples with concentrations ranging from 24.2 to
44.6 mg/Kg. For this baseline:
7 Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 53
F
F
Zinc
Lowest Level: 24.2 mg/Kg
Highest Level: 44.6 mg/Kg
Average (48 samples): 34.0 mg/Kg
Allowable Levels: None published
Baseline Assessment (Current Baseline Report) —Wilson Lend Application Site, Wilson, Texas
Page 54
F
Sludge Sampling
Sludge Sampling Techniques
Composited sludge samples were collected from each of the wastewater reservoirs. Random grab
sample locations were established and a number grab samples were collected from the bottom of
each reservoir. The grab samples were collected using a weighted dredging device operated from
a small battery powered boat. The grab samples were placed in a clean plastic container until an
adequate volume was collected. Representative portions of the composited sample were then
containerized and submitted to the laboratory for analysis.
The sludge samples were collected in the appropriate laboratory and method approved containers for
the analytical suite. Disposable protective gloves were used in collecting each sample. The samples
were labeled, logged, cooled, and transported to Certes under chain -of -custody procedures for analysis
in accordance with standard procedures.
Sludge Sampling and Analysis
Three composite sludge samples were collected (one from each reservoir) and submitted for a full -
spectrum analysis using the following protocols:
• EPA 418.1—Total petroleum hydrocarbons (TPH).
• EPA WAM—Total Kjeldahl Nitrogen (TKN).
• EPA 350.3M — Ammonia.
• EPA 354.1 M - Nitrite.
• EPA 353.3 — Nitrate.
• EPA 9253 — Chloride.
• EPA 9038 — Sulfate.
• SM2320B —Alkalinity.
• EPA 7471 A — Mercury.
• EPA 6010B — Arsenic, cadmium, chromium, zinc, copper, nickel, lead, selenium,
molybdenum, potassium, sodium, calcium, magnesium, and boron.
• EPA 8081A and EPA 8151A — Specific pesticides, herbicides, fungicides, and their
byproducts.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 55
EPA 8082 - Polychlorinated biphenyls (PCBs).
• EPA 8270C - Semi -volatile chemical compounds associated with fuels, solvents,
pesticide byproducts, and other commercial / industrial processes.
The following Sludge Samples - Analytical Results table compiles the analytical results received
and shows those parameters or constituents for which a value was detected. The lowest, highest,
and average values for each detected constituent are listed along with comparative values when
available. A table showing all of the constituents / parameters detected for each sludge sample is
provided in Appendix D. Laboratory reports and Chains -of -Custody for all sludge samples are
included in Appendix E (a separately bound appendix to this report). Laboratory reports list all of
the constituents / parameters for which analysis was performed.
,51u�g
Samples Analytical
Rsults °
Constituent I Parameter
Unit
Reservoir Sludge
Current Basetine'
NSSS
Sludge
East
Middle
West
Low
High
Avg.
Avg?
Ceiling3
IPH.,.:...
f
TPH
mg/Kg
97
ND
49
ND
97
49
TPH (Reservoir Water)
mg/Kg
ND
ND
ND
NDI
ND
NO
Nitrogen i Ni%raEes :.::...:. ...:..
.
Total Kjeldahl Nitrogen
mg/Kg
1,630
1.490
1,460
1460
1630
1527
Ammonia
mg/Kg
20.6
26.3
20.6
20.6
26.3
22.5
Lon51 I'Mal nliy
Chloride
mg/Kg
400
390
240
240
400
343
Sulfate
mg/Kg
2,050
2,870
1,360
1360
2870
2093
Alkalinity as Bicarbonate
mg/L
1,280
720
720
720
1280
907
Mercury
{
r a
i s
AR
Mercury
mg/Kg
0.35
017
016
016
0.35
0.23
41
57
Metals f lhorg ahicsM.
i
Cadmium
mg/Kg
0.84
0.64
ND
0.64
0.49
85
Chromium
mg/Kg
14.001
7.28
10.80
7.28
14.00
10.691
258.0
3000
Zinc
mg/Kg
66.31
43.9
61.1
43.9
66.3
57.11
1693.0
75M
Copper
mg/Kg
26.41
15.8
21.7
15.8
26.4
21.3
665.0
4300
Nickel
mg/Kg
9.41
4.4
8.3
4.4
9.4
7.4
77.0
420
Lead
mg/Kg
15.81
9.1
14.7
9.11
15.8
13.2
195.0
840
Molybdenum
mg/Kg
3.51
2.1
3.4
2.1
3.5
3.0
13.1
75
Potassium
mg/Kg
1,7801
1,130
1,170
1130
1780
1360
Sodum
mg/Kg
672
628
513
513
672
604
Calcium
mg/Kg
13,400
12,000
6,130
6130
13400
10510
Magnesium
mg/Kg
1.430
1, 1201
1,0701
10701
14301
1207
Baseline Assessment (Current Baseline Report) - Wilson land Application Site, Wilson, Texas Page 56
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Constituent / Parameter
Unit
Reservoir Sludge
Current
Baseline'
NSSS
Sludge
East
Middle
West
Low
High
Avg.
Avg?
Ceilings
Boron
mg/Kg
11.0
ND
11
3.7
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Spaces Not Detected or Not Applicable
1. Current Baseline — This portion of the table fists the lowest concentration detected, highest concentration detected, and the average
concentration detected during this baseline assessment. The baseline averages reported on this table are provided for comparison
purposes only and reflect the total of the concentrations detected divided by the number of samples analyzed. If constituent
concentrations or parameters were equal throughout the reservoirs, this average would be representative, Each sludge sample, however,
is unique and cannot be assumed to contain the average value reported.
2. NSSS National Average - This portion of the table is derived from Summary of Results for Regulated lnorganlc Pollutants from the
!
EPA 1990 National Sewage Sludge Survey (NSSS) (Kuchendther and Carr — 1991) and fists the national average concentrations of
inorganic pollutants found in wastewater sludges.
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3. Sludge Ceiling Limits — This portion of the table is derived from Celling Concentrations, Pollutant Concentrations, and Annual
Pollutant Loading Rates (Regulations Governing Agricultural Use of Municipal Wastewater and Sludge — EPA — 1998) and rats EPA
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maximum sludge concentrations for land apprication of sewage sludges. Sludges exceeding these ceilings may not be applied to cropland.
These figures are provided for comparison purposes only since reservoir sludges are not applied to the subject property.
F
7
Sludge Contaminants and Parameters
No pesticides, herbicides, fungicides, PCBs, or semi-volatiles were detected in the sludge
samples. Sludge samples were not tested for coliform. The contaminants, chemical constituents,
and wastewater parameters detected in sludge are listed below. A description of these items is
provided in the Contaminants and Parameters section of this report
Alkalinity as Carbonate and Bicarbonate
Alkalinity by bicarbonate was detected in all three of the sludge samples and concentrations
ranged from 720 to 1280 mg/Kg. Alkalinity by carbonate was not detected in the sludge samples.
For this baseline:
Alkalini
Bicarbonate
Carbonate
Lowest Level:
720 mg/Kg
ND
Highest Level:
1,280 mg/Kg
ND
Average (3 samples):
907 mg/Kg
ND
Allowable Levels:
None Published
None Published
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 57
a
Ammonia (NH31
Ammonia was detected in all three sludge samples and concentrations ranged from 20.6 to 26.3
mg/Kg. For this baseline:
Ammonia
Lowest Level:
20.6 mg/Kg
Highest Level:
26.3 mg/Kg
Average (3 samples):
22.5 mg/Kg
Allowable Levels:
None Published
Boron
Boron was detected in only one sludge sample at a concentration of 11.0 mg/Kg. For this baseline:
Boron
Lowest Level:
ND
Highest Level:
11.0 mg/Kg
Average (3 samples):
3.67 mg/Kg
Allowable Levels:
Not published
Cadmium
Cadmium was detected in two of the three sludge samples with concentrations ranging from ND to
0.84 mg/Kg. For this baseline:
Cadmium
Lowest Level: ND
Highest Level: 0.84 mg/Kg
Average (3 samples): 0.49 mg/Kg
Sludge Ceiling Limit: 85.0 mg/Kg
two Cadmium sludge levels do not approach EPA Sludge Ceiling Limits. ,
I_
Calcium
Calcium was detected in all three sludge samples and ranged from 6,130 to 13,400 mg/Kg. For
this baseline:
Baseline Assessment (Current Baseline Report) —Wilson Land Application Site, Wilson, Texas Page 58
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Calcium
Lowest Level:
6,130 mg/Kg
Highest Level:
13,400 mg/Kg
Average (3 samples):
10,510 mg/Kg
Allowable Levels:
Not published
Chloride
Chloride was detected in all three sludge samples and concentrations ranged ftom 240 to 400
mg/Kg. For this baseline:
Chloride
Lowest Level: 240 mg/Kg
Highest Level: 400 mg/Kg
Average (3 samples): 343 mg/Kg
Allowable Levels: Not published
Chromium
Chromium was detected in all three sludge samples with concentrations ranging from 7.28 to 14.0
mg/Kg. For this baseline:
Chromium
Lowest Level:
7.28 mg/Kg
Highest Level:
14.0 mglKg
Average (3 samples):
10.69 mg/Kg
NSSS National Average:
258 mg/Kg
Sludge Ceiling Limit: "
3,000 mg/Kg
Chromium sludge levels do not approach NSSS national averages or EPA Sludge Ceiling Limits.
Copper
Copper was detected in all three sludge samples with concentrations ranging from 15.8 to 26.4
mg/Kg. For this baseline:
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas
Page 59
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Copper
Lowest Level:
15.8 mg/Kg
Highest Level:
26.4 mg/Kg
Average (3 samples):
21.3 mg/Kg
NSSS National Average:
665 mg/Kg
Sludge Ceiling Limit:
4,300 mg/Kg
Copper sludge levels do not approach NSSS national averages or EPA Sludge Ceiling Limits.
Lead
Lead was detected in all three of the sludge samples at concentrations ranging from 9.1 to 15.8
mg/Kg. For this baseline:
Lead
Lowest Level:
9.1 mg/Kg
Highest Level:
15.8 mg/Kg
Average (3 samples):
13.2 mg/Kg
NSSS National Average:
195 mg/Kg
Sludge Ceiling Limit:
840 mg/Kg
Lead sludge levels do not approach NSSS
national averages or EPA Sludge Ceiling Limits.
Magnesium
Magnesium was detected in all three sludge samples and ranged from 1,070 to 1,430 mg/Kg. For
this baseline:
Magnesium
Lowest Level: 1,070 mg/Kg
Highest Level: 1,430 mg/Kg
Average (3 samples): 1206.7 mg/Kg
Allowable Levels: Not published
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas
Page 60
Mercu
Mercury was detected in all three sludge samples with concentrations ranging from 0.16 to 0.35
mg/Kg. For this baseline:
Mercu
Lowest Level:
0.16 mg/Kg
Highest Level:
0.35 mg/Kg
Average (3 samples):
0.23 mglKg
NSSS National Average:
4.1 mg/Kg
Sludge Ceiling Limit:
57 mg/Kg
Mercury sludge levels do not approach NSSS national averages or EPA Sludge Ceiling Limits.
Molybdenum
Molybdenum was detected in all three sludge samples with concentrations ranging from 2.1 to 3.5
mg/Kg. For this baseline:
Molybdenum
Lowest Level:
2.1 mg/Kg
Highest Level:
3.5 mg/Kg
Average (3 samples):
3.0 mg/Kg
NSSS National Average:
13.1 mg/Kg
Sludge Ceiling Limit:
75 mg/Kg
Molybdenum sludge levels do not approach NSSS national averages or EPA Sludge Ceiling Limits.
Nickel
Nickel was detected in all three sludge samples with concentrations ranging from 4.4 to 9.4 mg/Kg-
For this baseline:
Nickel
Lowest Level:
4.4 mg/Kg
Highest Level:
9.4 mglKg
Average (3 samples):
7.37 mg/Kg
NSSS National Average:
77.0 mg/Kg
Sludge Ceiling Limit:
420 mg/Kg
Baseline Assessment (Current Basefne Report) — Wilson Land Application Site, Wilson, Texas
Page 61
Nickel sludge levels do not approach NSSS national averages or EPA Sludge Ceiling Limits.
Potassium
Potassium was detected in all three sludge samples and ranged from 1,130 to 1,780 mg/Kg. For
this baseline:
Potassium
Lowest Level: 1,130 mg/Kg
Highest Level: 1,780 mg/Kg
Average (20 samples): 1,360 mg/Kg
Allowable Levels: Not published
Sodium
Sodium was detected in all three sludge samples and ranged from 513 to 672 mg/Kg. For this
baseline:
Sodium
Lowest Level: 513 mg/Kg
Highest Level: 672 mg/Kg
Average (3 samples): 604.3 mg/Kg
Allowable Levels: Not published
Sulfate
Sulfates were detected in all three sludge samples and concentrations ranged from 1,360 to 2,870
mg/Kg. For this baseline:
Sulfate
Lowest Level: 1,360 mg/Kg
Highest Level: 2,870 mg/Kg
Average (3 samples): 2,093 mg/Kg
Allowable Levels: Not published
Baseline Assessment (Current Baseline Report) — Wilson Lend Application Site, Wilson, Texas Page 62
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Total Kieldshl Nitrogen (TKN)
TKN was detected in all three sludge samples and ranged from 1,460 to 1,630 mg/Kg. For this
baseline:
TKN
Lowest Level:
Highest Level:
Average (3 samples):
Allowable Levels:
1,460 mg/Kg
1,630 mg/Kg
1,527 mg/Kg
None Published
Total Petroleum Hydrocarbons (TPH)
TPH was detected in two of the three sludge samples and concentrations ranged from ND to 97
mg/Kg. For this baseline:
TPH
Lowest Level:
Highest Level:
Average (3 samples):
Allowable Levels:
ND
97 mg/Kg
49 mg/Kg
None published
TPH is indicative of contamination by petroleum -based products, but regulatory guidelines for
allowable levels of TPH in sludges are not published. The presence of TPH generally prompts for
further sample analysis to characterize the `hit" (i.e. BTEX, MTBE, VOCs, and semi-volatiles).
Once characterized, regulatory guidance for the specific contaminants) is often available.
Note: TPH In relatively high concentrations was discovered In several of the baseline assessment's
soil samples. To characterize the detected TPH, every soil sample having a TPH concentration
greater Man 200 mg/Kg was tested using 7X 1005 methods (total of four samples). In every case,
contaminants In the range of Cr to Crs were not detected. The 7X 1005 results suggest Mat the
petroleum -based contaminants exist In carbon ranges greater than Cu.
The soil sample having the highest TPH concentration was further analyzed for seml-volatile
compounds (using EPA 8270C methods capable of detected many of the >Cn compounds). No seml-
volati/es were detected In this sample suggesting Mat the TPH contaminant may exist In ranges
greater than Ca Products In the >Cn range Include heavy hydrocarbon substances such as fuel oil,
transformer oil, lubricating oil, asphalt, pitch, and wax Generally, these heavier and more viscous
substances are not highly mobile and have a tendency to bind to sediments. As such, >C2e
compounds do not typically pose an environmental threat
Wastewater collected from the reservoirs was analyzed to determine If It was the source of TPH
contamination, but no TPH was defected using the EPA 418.1 method. Samples from the reservoirs,
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 63
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however, were only grab samples and a sample representative of the wastewater column was not
collected. Heavy contaminants may stratify In the lower depths of the reservoir waters.
TPH was reported In two of the three reservoir sludge samples, but no semi-volatiles were detected.
Zinc
Zinc was detected in all three of the sludge samples with concentrations ranging from 43.9 to 66.3
mg/Kg. For this baseline:
Zinc
Lowest Level:
43.9 mg/Kg
Highest Level:
66.3 mg/Kg
Average (3 samples):
57.1 mg/Kg
NSSS National Average:
1,693 mg/Kg
Sludge Ceiling Limit:
7,500 mg/Kg
Zinc sludge levels do not approach
NSSS national averages or EPA Sludge Ceiling Limits.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 64
Contaminants and Parameters
The contaminants, chemical constituents, and wastewater parameters detected by groundwater,
soil, and sludge analysis are listed below with a brief description:
1
' Alkalinity as Carbonate and Bicarbonate
While carbonate and bicarbonates can be naturally occurring, EPA guidance documents list
elevated levels of these constituents as possible problems resulting from municipal wastewater
.oil land application operations. High concentrations of bicarbonate ions may result in precipitation of
calcium and magnesium bicarbonates from the soil solution causing an increase in the relative
proportions of sodium and, thus, a sodium hazard.
Ammonia (NH3)
Ammonia is not environmentally persistent and is rapidly taken up by plants and microorganisms.
The health effects resulting from human exposures to water containing specific levels of ammonia
1 are not known. At 1.0 mg/L in water, ammonia has been demonstrated to produce only a minimal
risk level based on animal studies.
Arsenic
Among other uses, arsenic is used in semiconductor manufacturing, petroleum refining, wood
preservatives, animal feed additives and herbicides. Arsenic is an element that occurs in the
earth's crust, so accordingly, there are natural sources of exposure. These include weathering of
r" rocks, erosion deposits to water bodies, and uptake of the metal by animals and plants.
Consumption food and water are the major sources of arsenic exposure for the majority of U.S.
citizens.
Arsenic can combine with other elements to form inorganic and organic arsenicals. In general,
inorganic derivatives are more toxic than the organic forms. While food contains both inorganic
and organic arsenicals, primarily inorganic forms are present in water.
The limited plant uptake of arsenic can lead to environmental accumulations, but arsenic poses
more of a concern in wastewater sludges than in wastewater. Arsenic is among ten inorganic
chemicals regulated in wastewater sludges . When released to land, arsenic compounds bind to
soil and are not likely to migrate to groundwater.
Arsenic is a human carcinogen, specifically linked to skin cancer, and suspected in liver, kidney,
lung, and bladder cancers. In addition, it has been reported to affect the vascular system and has
been associated with the development of diabetes.
Baseline Assessment (Current Baselne Report) — Wilson Land Application Site, Wilson, Texas Page 65
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Boron
While boron is naturally occurring, EPA guidance documents list elevated levels of boron as
possible problems resulting from municipal wastewater land application operations. Boron will be
absorbed by plants to some degree, but its relatively low affinity for water causes it to be leached
by drainage water and concentrate in low-lying areas.
Boron is often found combined with other substances to form compounds called borates. Common
borate compounds include boric acid, salts of borates, and boron oxide. Borates are used in glass
production, fire retardants, leather tanning, soaps and cleaners, and some insecticides (cockroach
control). The environmental persistence of boron is unknown.
Ingesting large amounts of boron over short periods of time can harm the stomach, intestines,
livers, kidneys, and brain. Birth defects were observed in the offspring of animals exposed during
pregnancy.
The occurrence of boron in toxic concentrations in certain irrigation waters makes it necessary to
consider this element when assessing agricultural water quality. To certain crops and under
certain conditions, boron can be toxic in concentrations as low as 0.33 mg/L.
Cadmium
Cadmium is a metal found in natural deposits of ores containing other elements. The greatest use
of cadmium is in metal plating and coating operations, enamels, photography, and pigments.
Cadmium found in municipal wastewater is usually due to the corrosion of some galvanized
plumbing and water main pipe materials, leaching of landfills, industrial discharges, runoff from
waste batteries and paints, and erosion of natural deposits. The limited plant uptake of cadmium
can lead to environmental accumulations, but cadmium poses more of a concern in wastewater
sludges than in wastewater. Cadmium is among ten inorganic chemicals regulated in wastewater
sludges .
Cadmium compounds are able to leach through soils to groundwater. When cadmium compounds
bind to the sediments in water, they can be more easily bioaccumulated or re -dissolved when the
sediments are disturbed. Cadmium's tendency to accumulate in aquatic life is great in some
species, but low in others.
r
Short-term cadmium exposures have resulted in nausea, vomiting, diarrhea, muscle cramps,
excessive salivation, sensory disturbances, liver injury, convulsions, shock, and renal failure.
' Long-term exposures have been linked to kidney, liver, bone, and blood damage.
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�^ Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 66
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Calcium
While calcium is naturally occurring, EPA guidance documents list elevated levels of calcium as
possible problems resulting from municipal wastewater land application operations. Most calcium
Will be absorbed by plants, but it may also be leached by drainage water and concentrate in low-
lying areas. Calcium, in the form of naturally occurring caliche, is widely dispersed throughout the
Site.
i
Chloride
While chloride salts are naturally occurring, EPA guidance documents list elevated levels of salts,
including chlorides, as possible problems resulting from municipal wastewater land application
I operations.
Chromium
Among other uses, chromium is used in the production of stainless steel, protective metallic
coatings, metal alloys, and pigments for paints. Although chromium occurs in nature mostly as
chrome iron ore and is widely found in soils and plants, it is rarely detected in natural waters. The
limited plant uptake of chromium can lead to environmental accumulations, but chromium poses
more of a concern in wastewater sludges than in wastewater. Chromium is among ten inorganic
chemicals regulated in wastewater sludges.
When released to land, chromium compounds bind to soil and are not likely to migrate to
groundwater. Water soluble forms of chromium are chromates and dichromates which are very
environmentally persistent in water as sediments. There is a high potential for chromium
accumulation in aquatic life.
Short-term chromium exposures have resulted in skin irritation and ulceration. Long-term
exposures have been linked to allergic dermatitis and damage to the liver, kidneys, circulatory
tissues, and nervous tissues.
Coliform —Total and Fecal
Total coliform counts are an indicator of potentially harmful aerobic bacteria and possible fecal
•- contamination. Fecal coliform counts quantify the number of fecal coliform present in 100ml of a
sampled medium. Coliform contamination and control is a concern in all wastewater treatment
operations.
Baseline Assessment (Current Baseline Report) —Wilson Land Application Site, Wilson. Texas Page 67
Copper
Among other uses, copper is widely found in household plumbing. Although copper occurs in
nature, it is rarely detected in natural waters. Copper in municipal wastewater is usually due to the
a corrosion of copper plumbing, erosion of natural deposits, and leaching from wood preservatives.
The limited plant uptake of copper can lead to environmental accumulations, but copper poses
more of a concern in wastewater sludges than in wastewater. Copper is among ten inorganic
chemicals regulated in wastewater sludges.
Exposures to copper above published action levels have resulted in gastrointestinal distress, liver
and kidney damage, and anemia.
Lead
Although lead occurs in natural ore deposits, it is rarely detected in natural waters. Most of the
lead in soil comes from particles falling out of the air. Lead found in municipal wastewater is
i usually due to the corrosion of lead plumbing fixtures and erosion of natural deposits. The limited
plant uptake of lead can lead to environmental accumulations, but lead poses more of a concern in
wastewater sludges than in wastewater. Lead is among ten inorganic chemicals regulated in
wastewater sludges.
When released to land, lead binds to soil and does not migrate to groundwater. In water, lead is
very environmentally persistent since it binds to sediments. There is a high potential for lead
accumulation in shellfish, but not in fish.
Short-term lead exposures have resulted in red blood cell chemistry interferences, delayed mental
and physical development of children, deficits in attention span, hearing and learning disabilities in
children, and increased blood pressure in some adults. Long-term exposures have been linked to
stroke, kidney disease, and cancer.
Magnesium
While magnesium is naturally occurring, EPA guidance documents list elevated levels of
magnesium as possible problems resulting from municipal wastewater land application operations.
Most magnesium will be absorbed by plants, but it may also be leached by drainage water and
concentrate in low-lying areas.
Mercury
Mercury is a chemical element that occurs naturally in the environment in several forms. In its pure
form, mercury is often referred to as `metallic mercuy. Mercury can also combine with other
chemicals (i.e. chlorine, carbon, or oxygen) to form either 'organic' or inorganic' mercury
compounds. Under certain conditions and in the presence of soil, water, and microorganisms;
mercury can change between organic and inorganic forms.
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i Baseline Assessment (Current Baseline Report) — Wason Land Application Site, Wilson, Texas Page 68
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Oak
Mercury is rarely detected in natural waters at concentrations above 25 parts per trillion. It is,
however, found in municipal wastewater due to combustion of fossil fuels, cement manufacturing,
discharges from refineries and factories, the erosion of natural deposits, and runoff from landfills
and cropland.
Mercury poses more of a concern in wastewater sludges since it is readily removed from
wastewater by activated sludge treatment Mercury is among ten inorganic chemicals regulated in
wastewater sludges.
Mercury is very environmentally persistent, and if it is present in applied wastewater, it will be
sequestered in soils and is not likely to seep into groundwater. Mercury may remain in soils for
years after wastewater application has been terminated. In water, mercury will bind to sediments.
Exposures to mercury can result in tremors, memory loss, and temporarily or permanently damage
the brain, kidneys, and developing fetuses.
Molybdenum
Molybdenum is a naturally occurring metal that is found as a trace element in plants and animals in
concentrations of a few parts per million. It is essential for plant growth because of its involvement
in the processes of nitrogen fixation and nitrate reduction. Molybdenum poses more of a concern
in wastewater sludges and is among ten inorganic chemicals regulated in wastewater sludges
Exposure of animals and human beings to trace levels of molybdenum is unlikely to be harmful and
no harmful effects from industrial exposure to molybdenum have been reported. Acute
molybdenum poisoning is extremely unlikely due to the massive dose required. In humans,
molybdenum is adsorbed and excreted rapidly and so is not likely to be a cumulative poison.
Nickel
Nickel is a metal found in natural deposits of ores containing other elements. The greatest use of
nickel is in making stainless steel and other alloys. Nickel in wastewater effluent is often due to
runoff from steelworks, coal gasification, protein rendering, and petroleum refining operations.
Nickel poses more of a concern in wastewater sludges and is among ten inorganic chemicals
regulated in wastewater sludges
Nickel is one of the most mobile of the heavy metals when released to water (particularly to
wastewater or polluted water) where organic material will keep nickel soluble. Nickel released to
soil may leach into groundwater or be washed into surface water. Though nickel does accumulate
in aquatic life, it does not become magnified along food chains.
Baseline Assessment (Current Baseline Report) — Wilson Land Appricalion Site, Wilson, Teas Page 69
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Short-term exposures to nickel are not known to cause any human health problems. Long-term
exposures to nickel have to potential to result in decreased body weight, heart and liver damage,
and skin irritation.
t
Nitrites / Nitrates
The single largest commercial use of nitrates is as fertilizer and primary sources of organic nitrates
include human sewage (municipal wastewater). All sources of nitrogen, particularly organic
nitrogen and ammonia, should be considered as potential nitrate sources. Groundwater
contamination with nitrites and nitrates usually results from impacts by sewage, feedlot operations,
runoff from fertilizer applications, and erosion of natural deposits.
While nitrites / nitrates are absorbed by plants to some degree, EPA guidance documents list
elevated levels of nitrites / nitrates as possible problems resulting from municipal wastewater land
application operations. Due to their high solubility and weak soil retention, these contaminants are
very mobile in soil and will move at the same rate as water in their migration to groundwater.
Nitrates and nitrites are likely to remain in water until they are consumed by plants or other
organisms.
Water contaminated with nitrites and nitrates has resulted in the potentially fatal `blue baby
syndrome" (in infants under six months of age), diureses, and hemorrhaging of the spleen.
Pesticides / Herbicides / Fungicides
Selected soil, groundwater, and sludge samples were tested for pesticides, herbicides, fungicides,
and their byproducts using EPA 8081A and 8151A test methods. These methods detect and
quantify the following compounds:
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC
alpha -Chlordane
gamma -Chlordane
Dieldrin
Endosulfan I
2,4-DB
Endosulfan 11
2,4,5-T
Endosulfan sulfate
2,4,5-TP (Silvex)
Endrin
Dalapon
Endrin keytone
Dicamba
Endrin aldehyde
Dichloroprop
Heptachlor
Dinoseb
Heptachlor epoxide
MCPA
Methoxychlor
MCCP
Toxaphene
2,4-D
Of these compounds, the following were detected:
Baseline Assessment (Current Baseline Report) — Wilson Lend Application Site, Wilson, Texas Page 70
k 4,4-DDE
DDT was a chemical widely used to control insects on agricultural crops until it was banned in the
United States because it endangered wildlife and human health. DDT chemical products were
t often contaminated by two similar chemical compounds including 4,4-DDE and DDD. By itself,
DDE has no commercial value.
DDT does not dissolve easily in water and sticks strongly to soil particles. DDT, therefore, does
not move quickly to groundwater and will last a very long time in the soil (half life of 2 to 15 years).
In the presence of sunlight and microorganisms, DDT in soil will usually break down to form DDE
or DDD.
DDT affects the human nervous system and in large amounts has caused excitability, tremors, and
seizures. Reversible changes in the levels of liver enzymes were detected in people with long-
term exposures. The EPA has determined that DDT, DDD, and DDE are possible human
carcinogens and may be reproductive toxins.
Endrin Aldehyde
Endrin aldehyde is an impurity and breakdown product of endrin, a pesticide once used to control
insects, rodents, and birds until it was banned in the United States in 1986. The amount of endrin
broken down to endrin aldehyde is very small.
Little is known about the properties of endrin aldehyde once it is released to the environment,
however, it is not expected to leach in most soil types. If released to water, adsorption to
sediments and bioaccumulation appear to be important fate processes. No data are present to
predict the biodegradability of endrin aldehyde.
The parent product, endrin, does not dissolve very well in water and; therefore, has only been
found in low levels in groundwater and surface water. It is more likely to bind to the sediments in
water. The persistence of endrin in the environment depends on local conditions, temperatures,
and exposure to sunlight. Some estimates indicate that endrin can stay in soil for over 10 years.
Exposures to endrin have resulted in headaches, dizziness, nervousness, confusion, nausea,
vomiting, convulsions, and death. Endrin targets the nervous system in humans and birth defects
(abnormal bone formation) have been reported in some animal studies.
Heptachlor Epoxide
Heptachlor is a manufactured chemical that was banned (except for licensed fire ant control) in
1988. Before 1988, heptachlor was used extensively for killing termites and controlling insects on
food crops (especially corn). Heptachlor epoxide is a byproduct of the breakdown of heptachlor
and is more likely to be found in the environment than heptachlor.
Baseline Assessment (Current Baseline Report) — Wilson land Application Site, Wilson, Texas Page 71
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Both heptachlor and heptachlor epoxide bind to soil particles and evaporate slowly to air. While
heptachlor does not readily dissolve in water, heptachlor epoxide will dissolve more easily.
Heptachlor epoxide can stay in the soil and water for many years. Plants can take up heptachlor
from the soil and bioaccumulation in the tissues of fish and cattle has been demonstrated.
Heptachlor and heptachlor epoxide are clearly toxic to humans and animals and can damage the
nervous system. In high concentrations, they have produced serious liver problems, adrenal gland
problems, and tremors. Evidence of reproductive interference and teratogenicy has also been
reported.
Polychlorinated Biphenyls (PCBs
Selected soil, groundwater, and sludge samples were tested for PCBs using EPA 8082 test
methods. These methods detect and quantify the following PCBs:
Aroclor-1016 Aroclor-1242 Aroclor-1254
Aroclor-1221 Aroclor-1248 Aroclor-1260
Aroclor-1232
PCBs are mixture of individual chemicals that are no longer produced in the United States, but are
still found in the environment PCBs are either oily liquids are solids and do not occur naturally.
t They have been widely used as coolants and lubricants in transformers, capacitors, and other
electrical equipment
Before they were banned in 1977, PCBs entered the environment during their manufacture and
use. Today, PCBs are released in the environment from landfill leaching, illegal or improper PCB
disposal, and leaks from non -retrofitted transformers. In water, a small amount of PCBs may
remain dissolved, but most binds to organic sediments and particles. PCBs in water build up in
fish and marine mammals and can reach levels thousands of times higher than the levels in water.
PCBs can cause irritation of the nose and throat, acne, and rashes. They have been shown to
cause cancer in animal studies.
Potassium
While potassium is naturally occurring, EPA guidance documents list elevated levels of potassium,
as possible problems resulting from municipal wastewater land application operations. While most
potassium will be absorbed by plants, it may also be leached by drainage water and concentrate in
low-lying areas.
Baseline Assessment (Current Baseline Report) — Wilson Land Application Site, Wilson, Texas Page 72
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Selenium
Selenium occurs in natural ore deposits and is used commercially in electronic components, glass,
pigments, rubber, metal alloys, textiles, petroleum, and photographic products. In wastewater
effluent, selenium is usually the result of discharges from petroleum refineries, erosion of natural
deposits, and discharges from mines. Selenium poses more of a concern in wastewater sludges
than in wastewater. Selenium is among ten inorganic chemicals regulated in wastewater sludges.
The toxicity of selenium depends on whether it is in the biologically active oxidized form, which
occurs in alkaline soils. These conditions can cause plant uptake of the metal to be increased. It
is known that selenium accumulates in living tissues. Although selenium is an essential nutrient at
low levels, short-term exposures at higher concentrations have resulted in hair and fingernail
changes, damage to the peripheral nervous system, numbness of the extremities, fatigue, and
irritability. Long-term exposures have been linked to hair and fingernail loss, dental caries,
jaundice, skin eruptions, chronic arthritis, subcutaneous edema, and damage to the kidneys, liver,
nervous system, and circulatory system.
Semi-Volatiles
Selected soil, groundwater, and sludge samples were tested for semi -volatile compounds using
EPA 8270C test methods. These methods detect and quantify the following compounds:
Benzoic acid
4-Chloro-3-methylphenol
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2-Methylphenol
4-Methylphenol
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenol
2,4,5-Tdchlorophenol
2,4,6 Tdchlorophenol
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(g,h,l)perylene
Benzo(k)fluoranthene
Benzyl alcohol
bis-(2-chloroethyl)ether
bis-(2-chloroethoxy)methane
bis-(2-chloroisopropyl)ether
bix-2-ethylhexyl)phthalate
4-Bromophenyl-phenylether
Butylbenzylphthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl-phenylether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
Baseline Assessment (Current Baseline Report) —Wilson Lend Application Site, Wilson. Texas
2,6-Dinitrotoluene (2,6-DNT)
DI-n-octylphthalate
Azobenzene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitoaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene (NB)
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
N-Nitrosodipropylamine
Phenanthrene
Page 73
7
r
r
Benzo(b)fluoranthene Di-n-butylphthalate Pyrene
1,2,4-Trichlorobenzene
The following semi -volatile compounds were detected:
Phenol
Phenol is primarily a man-made chemical, but it is found in nature in animal wastes and organic
materials. It is primarily used to make plastics and is used as a slimicide (a chemical that kills
bacteria and fungi found in watery slimes).
Small releases of phenol do not stay in the soil for long periods (usually completely gone in 2-5
days), but can remain in water for longer than 9 days. Continuous releases from industrial
wastestreams and landfill leaching have resulted in more persistent phenol contamination. Phenol
is usually found in the environment in concentrations below 100 ppb, but much higher levels have
been reported. One ppb has been found in relatively unpolluted surface and ground waters.
Repeated exposures to low levels of phenol in drinking water has been linked to diarrhea and
mouth sores. Large exposures can result in muscle tremors, loss of coordination, and death.
Sodium
While sodium is naturally occurring, EPA guidance documents list elevated levels of sodium, as
possible problems resulting from municipal wastewater land application operations. Most sodium
will be absorbed by plants, but may also be leached by drainage water and concentrate in low-
lying areas.
Sodium Adsorption Ratio (SAR)
SAR analysis was included at the request of the City of Lubbock. Municipal wastewaters can
potentially have high concentrations of salts capable of negatively affecting plant growth and soil
condition. SAR is the ratio of the sample's sodium concentration to other soluble salt
concentrations and expresses the sample's sodium hazard. Irrigation waters are classified using
SAR results (along with conductivity analysis) to predict the effect of exchangeable sodium on the
physical condition of the soil.
Sulfate
Sulfate is a substance that
r, elevated levels of sulfates
t application operations.
r
occurs naturally in drinking water. EPA guidance documents list
as possible problems resulting from municipal wastewater land
Humans will experience a laxative effect when they experience an abrupt change from drinking
water with low sulfate concentrations to drinking water with high sulfate concentrations.
Baseline Assessment (Current Baseline Report) —Wilson Land Apprication Site, Wilson, Texas Page 74
Total Kjeldahl Nitrogen (TKN)
r„ The TKN test quantifies both organically -bound nitrogen and nitrogen present in the form of
nitrates, nitrites, and ammonia and provides a sum of all these nitrogen forms. TKN is indicative of
total nitrogen content, and too much or too little nitrogen can affect crop growth.
Treated municipal wastewaters typically contain from 10 to 40 mglL of nitrogen — or 0.001% to
0.004% nitrogen. (In comparison, commercial fertilizers typically range from 11% to 82%
nitrogen).
Total Petroleum Hydrocarbons (TPH)
TPH is indicative of contamination by petroleum -based products. The presence of TPH generally
prompts for further sample analysis to characterize the `hit" (i.e. BTEX, MTBE, VOCs, and semi-
volatiles). Once characterized, regulatory guidance for the specific contaminant(s) is often
available.
Note: TPH In relatively high concentrations was discovered In several of the baseline assessment's
soil samples. To characterize the detected TPH, every so/1 sample having a TPH concentration
greater than 200 mg/Kg was tested using TX f005 methods (total of four samples). In every case,
contaminants In the range of Cc to Cgs were not detected. The TX 1005 results suggest that the
petroleum -based contaminants exist In carbon ranges greater than Cu.
The soil sample having the highest TPH concentration was further analyzed for semi -volatile
compounds (using EPA 8270C methods capable of detected many of the >Cze compounds). No semb
voladles were detected In this sample suggesting that the TPH contaminant may exist In ranges
greater than Cu Products In Me >Cu range Include heavy hydrocarbon substances such as fuel oil,
transformer oil, lubricating oil, aspha/4 pitch, and wax. Generally, these heavier and more viscous
substances are not highly mobile and have a tendency to bind to sediments. As such, oC2e
compounds do not typically pose an environmental threat
Wastewater collected from the reservoirs was analyzed to determine If It was the source of TPH
contamination, but no TPH was detected using the EPA V8.1 method. Samples from the reservoirs,
however, were only grab samples and a sample representative of the wastewater column was not
collected. Heavy contaminants may stratify In the lower depths of the reservoir waters.
TPH was reported In two of the three reservoir sludge samples, but no semi-voladles were detected
Zinc
Zinc is a naturally occurring metallic chemical element often used to in metal alloys, galvanized
steel, and as electrodes in batteries. The limited plant uptake of zinc can lead to environmental
accumulations, but zinc actually poses more of a concern in wastewater sludges than in
wastewater. Zinc is among ten inorganic chemicals regulated in wastewater sludges.
Baseline Assessment (Current Baseline Report) —Wilson land Application Site, Wilson, Texas Page 75
i
r
r
r
Appendix A
r
r
Maps and Figures
7
Site Map (Well Locations)
�-
Pivot Soil Sample Location Map
r
Soil Survey Map
Water Level Contours Map
r
r
r
r
No Text
' •' A �, Sa�mplc location
0 �pp0 Samy
s Flood Icsigaticn Areas
JUNf61
am Pit oi[ Sample Location MapENPRO7EC tiic voS
MLm L„ d AWleaCon sloe
a]f0 G.nw Awnw swr.! cb.cw br. �!, Sel�ne/dn O.b: Fsbrr ry 10➢D Wilson Land Application Site
W reelef 7942e Wilson (Lynn County), Twos
I�.N—! lilr nhYWi.,e ldTi1111Mla'Yrw14xWWibe�LwGr1! .KD
Cc Eza gar,loam 0� Os"x elope
Pa Portages fbre sandy loom 0 • t% alope
Pb Portalea Me sandy loam s - S% elope
Pe Portalss loam 0 • M slops
0 Pd Portales loam s • 0% slope
Re Randall day
k` Za Zlta Me candy loam 0 • flG pope
Zc Lu Loam 0 -s% slope
a�Daaasr bbauaNr. 1fN-1760
ENpROTEc �M st`eamK soil sul,�cy Map
or btp►rNltpa,afavrmrvw�.laaam,uw. J Ctlmmw nwa,t�dApphreat7onsrr.
aJfO G.no. Arms. swr. E u'W b7r• Af. Sc7mNder wr. Feh.+aq-!f'Dr Wilson Land A,,,,QQPlication SLHo
Lubb l 7D411o0121 Wilson �l.)'nn l.dnnti'�� TC*ne
la ) Fi. Nam.: IDe anwrtf nkiWlaa MtVtfi176fJ'a�raEawlnoWi4m d.nbwN�.KA
a '
0 3000 Conloilrinfervol. Ifccl
r-� ENPROTEC ,,,� �„,,,, F71.L GroundwaterContourMap
Fi„ovedyj vfa "MaIft�.wwnnc.: oHdwdder
W,r,.mraa,a,lppua.rr.esir. Dcccmbcr1981
9710 6.nm Awn. bWM E ch"m4b% H o.r. /rey� /pyD Wilson Land Application Site
tosar.:.� isu4ry Wilson (Lynn County). Tesps
(!OB)7Df4f00 FM Nam.• /tlr o6.mnm M371M7614rdw.B&w eW4-1 1.eAq!VM ` y
I
Appendix B
Groundwater Results
Detected Constituents l Parameters — All Samples
F
EN-1761 - Wilson Land Application Site - Contamination Baseline
Groundwater - Detected Constituents / Parameters
EN-1761
Wilson Land Application Site
Contamination Baseline - Groundwater
Lab Sample if
99-0432-008
99-0432-007
99-0488-006
99-0488-005
99-0488-007
99-M2-005
99-0432-006
Sample Date
02115199
02115199
2/16.99
02116199
02M6199
02115/99
02/15/99
Field Sam le ID
Wen A
Well B
Well C
Wen D
Wen E
Wen F
Wen G
Test
Method
Constituent
Detection
Limit
Units
I Well -A
Well-B
Well-C
Well-D
Well-E
Wen-F
Well-G
RI
P01if a
IN,
•
.......... t ........ ..
R..
SM 9222D
Fecal Colftm
1.0
MOWN
ND
SM 9222B
Total Coliform
1.0
Comm
16
TPH
1.0
IT XYL
3
M"&R,
:111-
111-
. $El -
EPA 351 AM
Total Kieldahl Nitrogen
0.2
-m9fL
nt
nt
nt
nt
nt
nt
nt
EPA 350.3M
Anvwla
0.2
M91L
0.14
0.24
0.51
0.35.
0.20
EPA 354.1
WItIffe
0.01
ff WYL
EPA 353.3
Nitrate
1.0
mg&
2.30
11.40
6.80
4.35
5.52
19.90
2.35
xN
SM 4500CLB
Chloride
50.0
Mgt
52
34
150
160
190
240
140
EPA 375A
Sulfate
50.0
Mg/L
76
66
130
182
266
286
101
32-191
Socrhn ftorption RaOo
calculated
I ratio
nt
n(
nt
nt
nt
nt
nt
EPA 120.1
Con&xtMty
1.0
umlitis/crW
1 nt
- nt
nt
nt
nt
nt
nt
_
SM4500NH3.D
Ablinity as Bicarbonate
5.0
MOL
302
314
290
240
370
218
272
E00 I
Z",
11,575"
PM
=10m:
"JIM
OWNIMM
ME
x.N
lidlit.1111) t
N
CNMIUM
0.005
zinc
0.05
nyl-
COPM
0.01
M!YL
Lead
0.015
MA
0.015
0.017
Selenium
0.04
M21
Potassium
1.0
mgfl.
12.7
13.4
16.1
15.2
17.6
22A
15.8
sodIffn
1.0-
mg&
82.6
121.0
99.2
104.0
142.0
125.0
125.0
Calcium
1.0
MYL
45.5
38.2
67.9
60.0
62.0
85.3
Mapeskm
0.01
M91L
20.5
18A
22A
22.2
22.5
24.1
20.1
8"
0.01
M91L
0.5811
OA96
0.399
0.409
OA96
0.535
0.463
ROPM
Oftio"ON
NIONNION
SIR-
Endrin aide"
0.05
U91L
-
MRai R.,
O."O."'M
400."M "MI,
Pot hloritlhfad.E.R.00,
. ..
.......
N
s'. M
. . . . . . . . . . . . ;
3 it
............ ........
1"
mom"
ORM.-
MISIDEM
Phenol 1
10
1.101.
13.0
Page 1 of 4
EN-1761 - Wilson Land Application Site - Contamination Baseline
Groundwater - Detected Constituents / Parameters
EN-1761
Wilson Land Application Site
Contamination Baseline - Groundwater
Lab Sam le 9
99-0492-003
99-0488-008
99-0432-001
99-0492-004
99-0307-003
99-0307-002
99.0488-004
Sample Date
02/12/99
02/16/99
02/10199
02/12199
02/01/99
02/01/99
02/16/99
Field Sam le ID
Well H
Well 1
10842
Well K
21152-1530
10932-1500
Well N
Test
Method
constituent
Detection
limit
Units
Well-H
We114
Well-J
Weil-K
Welk
Well-M
Well-N
:..:....:.
:.�: .:::.•:.
SM.92228 ...
ri,J .v}:h .w nx.•rrerwfx}rx+.v::w ...v..
:n..-:x :{'•nt$•viCv$r »:n• :m: :x::. ..
:: /..:.....:r:..: x$.,x�3.`•$::... .'Y:r. ..
::;i .. t;:..... •r ...$}+ . ,.::::5..:.. :s;
Co1it.4rmi ..... ......
m. ....
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::}: r..r $:. :y«c::�`:
SM 9222D
Fecal Coliform
1.0
coV100m1
nt
nt
SM 9222B
Total Coriifonn
1.0
c011100m)
ND
ND
r.rn
,: .v,:{)w.vr..
..:.: ... f...:........
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-
=:. ..�«$$:...
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..�:$<
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1.0
M91L
2
1
1
v.Jwv$:csAx:
; . •-.a:a-xx.. w.}•xw- }}:.•.�
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7.: S:i4','-•::w.`.`ii:;"::':
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Total Kjeldahl Kftgen
0.2
m2l
nt
1.00
nt
nt
0.30
0.54
1.00
EPA 350.3M
Ammonia
0.2
myl
0.39
EPA 354.1
Nitrite
0.01
moll.
0.01
0.04
EPA 353.3
Nitrate
1.0
M91L
2.88
1.29
3.30
4.58
3.57
3.58
vR,•}W}50.::..: .•:.. nrv.
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:;i X•:
SM 4500CI.B
Chloride
50.0
MA
500
500
440
350
400
530
640
EPA 375.4
Sulfate
50.0
197
262
197
406
368
173
368
3.2.191
Sodwn Admptlon Ratio
caWated
ratio
nt
nt
nt
nt
5.91
6.18
nt
EPA 120.1
Condtntivity
1.0
umhos/cm2
nt
nt
1,810
nt
ntl
nt
nt
SM4500NH3.D
Alkalinity as Bicarbonate
5.0
mgfL
480
390
314
260
400
670
352
.:. r.,w-,.
,:.,w?xr..rxA n..:nvrrv}a;.:x.xv. .;.}-.v..
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.. !i'$i2vriw}'.i.}:^-
::::: mv:
it r:$$'m
:.:�
.'•}w,.:xn
Chromium
0.005
m -
0.010
Zinc
0.06
M21
0.062
Copper
0.01
MCYL
0.097
0.027
Lead
0.015
MYL
Selenium
0.04
m
Potassium
1.0
MgIL
29.3
27A
13.9
26.5
27.4
22.1
28.3
Sodium
1.0
mgL
185.0
211.0
198.0
187.0
320.0
376.0
270.2
Calcium
1.0
MA
105
45.1
77.2
93.2
97.1
98.9
103
Magneskirn
0.01
m
24.7
24.6
23.4
23.9
75.9
112.0
24.2
Boron
0.01
m
0.396
0.387
0.625
0.620
0.545
0.389
0.693
.,. , r..,:::::.
.rrr:.:.
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j
i$$nx.[
n:�:N6
;.}::}:::i
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0.05
U91L
0.071
EPA�.13 A�,rN,,.:.esti
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deg: 0ides :.,,r::�::...
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$}}}S::G2 }f/.h x..
:}.$>}}$} $i}S:;i•-'S
rr.<:<:NC�':• :.......::::::ND.........a,.a':AID.�%vN$:v..:,:rt.:r.:.}:.NtTt.>:,�::.}
•} }:v'li}.�C':iv.'$�
ti:�;
i`.$:'v.':
i$
r}.
<.
• rl. .ii
. .1f27 x:
��.....�
h}r$$•.::.::r: xr::n.x.:x.:;'.c: - .::..::...,1.
wwrw.}r...JY}yrrxx.:...
t ,w.y...:.vvm.
n!nrS$}'/r'rJi�'.v" v..n
.�i i` lati �'r^�!:xwrx:n:,-::x. •: r::::::r:r:.v:::�.:x.
em.:Vn fi.................:....:.:h....:.................,..........:.:::::::.:.:......:........�..vh<r.:�..:,.�:rit..«n:.�.:.,,;at<fintY
;:.:: •:: < ., ..w .
r.. r.h}:.. }..
: w,.: r:,•
b. 9^.::::.:.:Yr':::.:-rsa&-:}.•::,,n,c�.:;
tt:: ::::::.: .::. :...
..:A:::. xk:ri Fr.:...work♦
:va" :^t: vv..:.
..• .hynJ::r�rY.:
..}x...rr :S'
:;:..;.:wr. a: :r.:
.::•:.}:$}};.
.,.. :$$hhavr:.�rv}.;.:;;f
,.:. .::...
;.,:... " r: hrN+O,...
t:M:: v'•}}
Y..}:....
-:.. t;:+.w.;. .:..:
•rx}}n!:iii ::rNJ}:4}
::
ix: �:.. ntN:,>:;A
J%"rrr r' . Trx:r: ::
�p:: ...$:.
"
�' ^:::.
.ri:'G 'ti?:;�.
t��'::.
: 1;i.:.. ..l•...
'
;:fir '�i ::
�>nt$�, $:.
Phenol
10
UgIL
Page 2 of 4
EN-1761 - Wilson Land Application Site - Contamination Baseline
Groundwater - Detected Constituents I Parameters
EN4761
Wilson Land Application Site
Contamination Baseline - Groundwater
Lab Sample #
99-0492-001
99-0432-003
99-0307-001
99-0492-002
99-0432-004
99-0432-002
Sample Date
02112199
02/11199
02/01/99
02/12M
02111/99
02111199
Field Sample ID
wen 0
Well P
10932-1400
Well R
Well S
Well U
Test
Method
Constituent
Detection
Limit
Units
Well-0
Well-P
Well-0
Well.R
Well-$
Well-U
PR
ORW
�00_
NIM
SM 9222D
Fecal Corftm
1.0
ODVIOOMI
nt
SM 9222B
Total Cordbrm
1.0
covioOd
2
RP
TPH
1.0
MOL
"i RMFIFFMF
EPA 351AM
Total Kjekhld Mtrogen
0.2
MgOL
nt
nt
ON
nt
nt
nt
EPA 350.3M
Ammonia
0.2
MtYL
0.56
0.18
0.35
0.170
EPA 354.1
Kffift
0.01
m9tL
EPA 353.3
Nitrate
1.0
M!Y-L
825
12.00
9.25
10.80
8.56
.0��
111-77T.
7Z-.
SM 4500C1.8
Chbft
50.0
M91L
21500
650
550
500
310
430
EPA 375.4
StIfate
50.0
ff KA
264
574
168
270
244
301
3.2.191
Sodium Adsorption Ratio
calculated
ratio
nt
nt
3.97
nt
nt
nt
EPA 120.1
CMAXNly
1.0
umhoslem'
nt
nt
nt
nt
nt
1,810
SM4500NH3.0
Alkarmity as Bicarbonate
5.0
m9fl.
290
248
580
1,060
1.150
216
W
0
eta=o
, N
V
Chmkffn
0.005
mg&
Zinc
0.05
Mgt
Co"
0.01
M91L
0.614
0.010
0.072
0.682
Lead
0.015
mq&
Selenium
0.04
Mgt
0.056
0.0641
Potassium
1.0
mg&
21.9
14.2
39.3
27.2
IOA
11.8
Sod!=
1.0
Mo.
1011.0
149.0
263.0
162.0
135.0
180.0
Calcium
1.0
mqIL
76.5
126.0
105
100
69.5
77.8
MaTiesium
0.01
M9tL
23.6
24.3
138.0
24.5
23.0
23.3
Boron
0.01
mg/L
OA54
0.539
0.869
0.361
OA20
OA53
f""
..'53
IiN N-Rit-
Enckin aldehyda
0.05
tKVL
.. . .......
.10
: . . . . . . . . . . . ........... .....
.
0
0
......
. . . . . . . . . . .
Phenol
10
ug/L
. . . . . . . . . . .
18.0
Page 3 of 4
EN-1761 - Wilson Land Application Site - Contamination Baseline
Groundwater - Detected Constituents I Parameters
EN-1761
Wilson Land Application Site
Contamination Baseline - Groundwater
Lab Sample
Current Baseline
Sample Date
Range and Average
This Assessment
19" 1
-
Field Sam le ID
Test
Method
Constituent
Detection
Limit
Units
Low
High
Avg.
SM 9222D
Fecal Coliform
1.0
coV100ml
ND
ND
ND
SM 9222B
Total coriform
1.0
cDV100ml
ND
16
3.00
T'o1 I.petral W"ft*9f"ffi9
Ems
M=
TPH
1.0
mqIL
ND
3.0
0.07
it
EPA 351 AM
Total Kieklahl Nihgen
0.2
IT VJL
0.30
1.00
0.662
EPA 350.3M
Ammonia
0.2
m!YL
ND
0.56
0.15
EPA 354.1
Write
0.01
M91L
ND
0.04
0.0025
EPA 353.3
Nitrate
1.0
mcYL
ND
I 19.90
6.03
.10
16 tr�- i
SM 4500CI.B
Chloride
50.0
mg&
34
2,500
458.3
EPA 375.4
Sulfate
50.0
M91L
66
574
245
3.2.191
So&= Adsorption Ratio
caWated
ratio
3.97
6.18
5.35
EPA 120.1
jConftNty
1.0
umwcrr?,
1,810.
1,810
1,810
SM4500NH3.D
Alkalinity as Bicarbonate
5.0
M91L
216
1,150
421
chmmkffn
0.005
M91L
ND
0.010
0.0005
Zinc
0.05
mg1l.
ND
0.062
0.0031
Copper
0.01
mgIL
ND
0.6821
0.0751
Lead
0.015
mg&
ND
0.0171
0.0016
Selenium
0.04
m(ft
ND
0.0641
0.0060
Potassium
1.0
mq/L
IOA
39.31
20.65
Sodium
1.0
mg/L
82.6
376.01
176.8
Calcium
1.0
mgIL
NO
126.01
76.7
Magnesium
0.01
mA
18.4
138.01
35.8
Boron
0.01
ff KYL
0.361
0.869
0.507
eti
..... . . . . . . . . . .
LEE
am
Endin al&*&
0.05
u
ND
0.071
0.004
..........
.,
Ej!A`08
...
.. . ..
....
.................. .........
. . . . . . . . . . . . . . . . . .
Phenol
10
WA
ND
18.00
3.875
Page 4 of 4
Appendix C
Soil Sample Results
Detected Constituents ! Parameters- All Samples
Detected Constituents 1 Parameters- Shallow Samples
Detected Constituents l Parameters- Deep Samples
Soil — All Samples
i
Detected Constituents I Parameters
7-
r
7-11
..: _ _.. /■ ■T" ... _ ' it �.. _- .■1�` -
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
All Soils - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Soils
Lab Semple R
99-0406-026
99-0331-003
99-0331-004
99-0331-001
99-0331-002
99-0406-009
99-0406-010
Semple Date
02ION9
02M2199
02MW9
02102199
02/02199
02104/99
02M4199
Lab File No.
99-0406
99-0331
99-0331
99-0331
99-0331
99-0406
.99-0406
Test
Method
Constituent
Detection
Limit
Units
Pivot 01
Deep
Pivot 02
Shallow
Pivot 112
Deep
Pivot 93
Shallow
PIM 93
Deep
Pivot 94
Shallow
Pivot 94
Deep
.6 y2.°�"
: v:• .. •� }• 'vrc
� ^'•�`�: �0ta1;C01dolYitrF
rr .:N:r.v:::::: , :r:.�:.....•r::-. •'•
M w
9."rRs}>x'..
-..+"i.':i:
s.'f"'; ...tS
.:: rKA:::ii>j`•'ri:'v::•'•:
.,,c,...,.. 3a.
.:...
r.«;:?:eti.#,+:J�:+•.r"a:G�.
``:.,y�?�{�::,�;;L is
-
;� ..'��SSS�St.
wr .... M`
.:),::.,,..�J..
.r r:c }.�..}:.••,....
Total Coldorm
1.00
covgMn
nt
7
1
3
NO
nt
nt
_
4
EPA 1�1
..... ....�
:.:5}O:i:
'
:r..,« via lbffitk
J. v..•$...•.. :'.S:i
n
i„w`G:G:=>St'y:::•.`
. «';.',"1r5:::'.:;:5:}:
i
•ry + >
TPH
10.0
M
AL
nt
NO
NO
NO
NO
292
11
r:.,::.....«n:::.
.X.::.t,.: +�:�:<«�y{' +o�i!��
.... «:;::: :�- ??2•.....�
..... ................
s«,..wrr
'x. ... .w,,;.:.r
.xn.::.w..
,x,�«;r?...........::!..
.•:':'.'�:...«n.
6^.•c::7Y�:: r�!?.;..:
.:....:.......... r.....
•: •#a:;•
:n •..rn.:J..:}::::.,-:
:Jn:.,:.
.,v:.:,-::::::: r::: n,v:
:5�Y.'^}':r:=i•:9. 'yh.G',.:;;:i;:::,
w.\�: h•
�:.+:r. :`vr-h"• .
.. `J ...
:+„V.:.. � it�::
;">.•.^,;dr:c1.+
S
,,,,G:+;'�:;;'66;£•i:
•i'ri}h^-.vx
EPA 351AM
Total Mjelidahl
1500.0
631.0
444.0
493.0
498.0
470.0
490.0
EPA350.3M
Ammorda
1.0
36.2
19.7
42.1
38.9
EPA354AM
M"a
0.10
mqIKq
1.2
1.1
1.5
1.7
EPA 353.3
MWe
1.0
Wg
3A
11.7
16.2
12.1
14.2
3.6
3A
..rx:rxr:r
<?<.:
EPA 9253
�yii
A::: nJriV11 %Catlorii- Alitatlnoffigm
t.hl Ma
::.}a:}}N:rr}::>;::.;:.;�•::.;:.':..r:.:
50
Wg
r}h,;:.;;
?:<.,:.:
,::•�:.:
1 240
::;•:v:r.:............,
.�.:::::rr?¢v>
...........................
500
,
...u.r
Vie:$::
470
230
EPA 9038
Strllate
50
nxYKg
147
353
32-191
Sodim Admption Ratio
calculated
ratio
2.200
0.008
0.008
0.009
0.012
3.100
1.600
SM 23208
AWnffy as Bicarbonate
50
mqfKg
440
110
820
84
98
120
240
SM 2320B
Mmfinfty es Carbonate
50
Mft
320
nt
nt
nt
nt
240
240
+- �
>t:8A..47.. A,
4:n.•.wrr.,• xrxr: r:
'•:-}g.{::.v.+wv.:+':d:}n'+i::::: yr>rv:::..r.r.
:}r:-:. ::Mercu ::�;;
M
J:..:.r x+w.,,:
�;;s:: •Jw}w�:
0.01
,v:.x::: xx.
f>«
WoNg
:-}:v 'J}; }:•'r.•:: •••••.
:;.}�;;>:J.r:;�;;:.:
0.02
•••..•--•
•: rv.::..: x::r,::;
.Y;•.
0.02
.•.••.••..•••••.....
; ..
:i5}:'ty
:};ii}}}}ti'l:}ii}'
..}::;;
0.03
:tip;; ':G;4}}'riv
••>�:.
0.02
i'l'S:u.}i'iri' -:
::iFr::
0.02
JY.-i;-Wii4•••
N#<�::;# :.�:
0.02
EPA 1 �;
::rt::ti}�St;',
� rro �%
Arsenic
::�'.
2.5
:::.J.,�:
MgrKg
<:z�::
5.0
:;6}"• . z=.
4.3
�:::::
3.1
:,:�;} :ti2�C
x>s:�;N . y..�.::}rk�.#>�•:
5.5
`:z�}�r:::
3A
:,fixc •s'N::u:
Cadmium
0.5
2.07
1.89
1.92
Chromium
0.5
mgtKg
1 11.60
11.20
11.80
11.90
15.30
12.40
12.30
Zinc
5.0
mglKg
1 34.5
26J
28.0
29.5
38.4
32.9
34.0
CTIM
0.5
wqtKg
11.20
5.68
6.04
6.37
8.47
8.71
15.40
Mdel
-1.0
10.5
V
9.8
8.7
11.7
9.9
11.0
Lead
1.5
14.6
5.7
12.4
14.3
16.4
11.2
14.9
Selenium
2.0
Mog
4.3
Molybdenum
1.0
nwyKg
1.2
1.1
Potassium
50
Mog 1
1,360
2,950
3,030
3,300
3,630
2,490
Z630
Sodium
50
mgfKq
817
587
757
6161
929
1,360
1,310
Calcium
50
moo
9,710
14.300
58,800
Z2001
12100
10,800
26.200
M
0.5
mqfKQ
1,510
3,190
3,460
2,4301
3,460
2,900
2,980
Boron
1.0
mgfKa
24.00
8.41
5.99
7.771
6.07
20.00
20.00
EP.... $.......
:,..<:•<..,}.,:<..:,.hN.
.:
....<•}.;::::•:
D.. ::xA„>:.
(}::�•.:;..<:NDfiN::N....NQ.,::;•.},:::r.•::x..;.
4,4'-DDE
1.67
Mor
1.61
ugfKU
: ..., ...
EPA`815i
EPA$0. .::.::P..a
:::. .. .. .. y. .. ::• •. :. •:.. ;;..........:::':J:ky;J
n.w}rr}ri.�:,•f:.::
e�kJd'�s:1:Hefb%lFdrls::rµv::>:.:::r-r:<-�
:. }}:
"tiidtlireteSl "ati l# a .v:n.
+xr '.,w..,..:::
.s�.;;:: «•v;�.;;fir:'
"":`.'•.:4}•:'•.;}:<..
,:#:.}<.: r::
............
«:x�:}:,• ..:.J.
;.:wtd'^.:...:
:::�x.,.r.:M.:::.i,t.x.,,.>::
:ti$�i:: r}}....J,........
...:?:x?...•
;::}R:3^.
riY:i`/:.3::. •;.}Y}:Aj::
.
i::>S�:
•,�<<NCi;' :
>}r:;,y,•,.y-..: ::•.
:: fi:
x >::r:Nti: r::::.r
yy<: }:::
::>;.h } D:>::.:r•
r .::;:SF
e;,�Na:.,� .:.:
:}•:}+: i:" 6::rµ:•''
:: D�<�,h#:::..::
.,v�JD.^.e'V.:z
:h+.:
rx:.:NO's;;�:Ns�:`:•�rt;nry��:::
" lldfrr.'.}:
. `?::....::.:.
rn:
.. ....
EPA:82T.00?.:
. ..: •J>y,;}}x........;;:.?; .....: s:;: ••} x
,.: - ell:•r`:"'•Ki"Sr.r.:{: S;:i.:.3a,�.L:.:
Strril.Yblttgel.:..,...�}.:s....�z:x�"�:4•,•:::.x:::.,•
o::aJCJ}}�}s::ah
:.
: :x}s..x:Nsr.,,.:r:.,,...>r:.
:....:y ;� .•,•.
.y,<y-.d}b::f.::r
............. ..:: .......
�:fi.::ni•xz•::»>
}......n. - .'V...--.
;.<z;a;;:ND..:: x::
:.
S:.r,:i�.:..-r
xs«c:.::ND:::::rsr:
>r.•r.:;:::->}+xJ::
::}:r::.
,.r..�ssN[i:.:.:::
' {�
':Sim;:<;`
•. D>::sc>•'s:
+;:.kJ:: ..r}rr::r::
•«• r:.. `•srrM+3..r
r;J:;J:J:....
:.:::0 ;t^�°<<<
Page 1 of 7
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
Ail Soils - Constituents and Parameters Detected
EN-1761
Vinson Land Application Site
Contamination Baseline - Soils
Lab Sample 6
99-0406-037
99-0406-038
99-0406-040
99-0406-039
99-0406-005
99-0406.006
99-0406-007
99-0406-008
Sample Date
02/09199
02/09199
02/09199
02/09199
02104/99
02/04199
02104/99
02/04/99
Lab File No.
99-0406
99-0406
99-0406
99-0406
99-0406
99-0405
99-0406
99-0406
Test
Method
Constituent
Detection
Limit
Units
Pivot 05
I Shallow
Pivot #5
Deep
Pivot #6
Shallow
Pivot #6
Deep
Pivot #7
Shallow
Pivot ill
Deep
Pivot 08
Shallow
Pivot 98
I Deep
..
.... .. ......
................................:.R
....: n......:::::::.:
r:.:.:...::.:,,.:.
..,,,-.::.,:...,............:..
.w:.::n rc...,r:.. r..
..:... r:. r.:::. rcr:....
Total Catiform
1.00
calf
M
M
nt
nt
nt
nt
nt
nt
��pp ,,/��:y
. �:7JN.i::.,..
(� �•. qq�,�,.7�� y�� �,y •:{o:
:i�. t�!•lFN.V Ilk. .5�1.�!1!71 ..k
`:=ir4'S!S.'•' „r
&�:
:`r':::2......:''
::v,:S:�-': ti.:ir.,..n-
:i SSS{k3$
:.^w.v
• :}d.:n:'vSi'';'i,•::.?
..; :.,,..::: •r{cam..:
�`:;xti;,:::3.',u;::z=':
TPH
10.0
1 mgfKg
ND
nti
ND
nt
236
111
220
ND
$ M'
EPA351AM
:{{C #":S'•' .'A.^.
Total K' daM NhW
vv.A..'F.v
mgfKg
n..3»}.:
:'�:'. :':.:::
43.0
}$:}r}
r:.}}3iv$:f$$:::r:
14.0
:J}$`4 lfr:
r13.0
'}::r}:•}r}}::}F:.: }}}A '
~ J 480.0
:$jY :::{•::w
C.:vroir:.nr>,b:vii
^ 370.0
`$i.0:- $hri'/:i':'m`i$.
rc 380.0
-:
iii\U'i$}'$SkriL:
460.0
EPA 350.3M
Amnania
1.0
mgfKg
EPA354AM
N"a
0.10
0.1
EPA 353.3
Nitrate
1.0
mgfKg
5.1
1.4
4.1
4.1
11.0
2.2
11.2
10.0
rrr^y,rcn.:•n:
EPA 9253
,. :•- ...
Aif�lt n,rn?kS0
Chloride
s : .r.•...,,•..,,..�.:..n
50
...:{.v{.,.{-::r..,:y::
,:;.5.:�:.aV.
mgfKg
,,: rrrk -:
•: }.. •4i,FKi.:-}'R
410
:.�}..,.
,CS.•}:•. }r,,,,�rr�...... r:::.Y:rr'F,S
340
..:n x:}:.
::'-:S}x...n
x:\. $:w:.,v.,..
330
.w':•w,+.:M::•ii
310
`-.x�fit.-.^.=•:SSi �.',•a':v:,}::,...v.
350
x r.
n..,'fS,c..
-.,ii:ih.":: :
220
«'.«:i�riY .•.: ...•
�A�:
280
.^'.•:YiSk�}':::SSfiw.
�$�rcxrv:.m:xv:: -.v.
350
EPA 9038
SoVe
50
254
131
140
119
384
342
316
393
3.2.191
Sodium Adsorption Ratio
Calculated
ratio
2.600
2.600
1300
1.900
2.900
2.000
2.300
3.100
SM 23208
OdWly as Bicarbonate
50
mq1Kg
480
1,480
720
1 300
200
240
240
SM 2320B
as Carbonate
50
240
400
1,040
160
160
:.. X.
.....r.:,:.........r}�.,^.,
.: ..v :.. v. ...r }. wrxm.x nvw:
14er�r�r. .:.v^.:... rn.v rn nv.
... ............
rr+r+u•rx:+vArr....
.n.rc^,v::...
r..x:.:+.•}: ....:::
r. e.}x.,vx.• •...::
v :{... ....:.}::.gym{ry;::ow:
:: ..
•::.}}:::.
..
}',r.J`
'vm.. .: ......
:i2?{$$`r
M MY
0.01
1 nmYKg
0.01
0.02
0.01
0.01
0.02
0.02
�:601 t3.x
A 0
r:.#tetara:i. a ic#..r
rtt
Arsenic
?::
2.5
MAX9
6.1
6A
3.0
5.4
3.3
4.2
4.6
Cadmium
0.5
1.66
2.09
2.10
2.26
1.72
1.42
1.44
1.71
Chrvrf m"
0.5
Tgg
13.30
16.10
15.30
17.10
9.76
9.87
9.15
10.80
Zinc
5.0
mgtKg
34.0
40.4
41.8
44.6
27.5
25.1
27.2
31.4
0.5
mog
8.34
9.98
9.73
10.70
51.101
7.34
11.40
9.15
Mckel
1.0
mgfKg
10.4
12.2
11.8
13.3
8.7
7.5
8.3
9.1
Lead
1.5
nuffig
14.2
17.4
18.0
13.1
10.4
9.4
7.7
11.2
Selenium
2.0
g
Molybdenum
1.0
mgfKg
Pot"Sh n
50
mgtKg
3,390
3,760
3,"0
4,290
1,850
2,1101
2,310
2,380
Sodium
50
mog
903
1.280
1,040
1,120
1,470
1,090
1,070
1,180
Calcium
50
5,720
16,300
2,830
4.470
14,700
5,940
10,500
5,970
M
0.5
m
1,730
1,760
1,770
1.760
Z390
2,260
2,430
2,770
Boron
1.0
M99
22.00
29.00
28.00
34.00
17.00
13.00
13.00
16.00
-
G-PA�800i�4. .
.,. .....,. •. A.v.}r....YS:Gv�r:..
...r :.:rm
'!rvn:<}Y Mr•}SXR.tC.ravrrrr:r
Pe'itTc �ii :�{.}}.,.
id ..,..
...::.': n.ii::` ...r:rn.:::{..:::
:.,{.N•i: n•
".'v}:r^
r{::n v:r•r
n .::xw
:r 3�kRS^: "^'
v.Sv.r {r... { ..::n
:.$$.
mr$.r,�xxv }..'F:;.}4•
^.n•{ . ,{:,
.rki ..}•::kc
:rain.
4
:v ..?. ` ..•ran
`;}.:
;>.}:.>}:,r.�:$
iS:k:
-��N - ::�^`,...
ntrc,�;::k:
:•
� 'i�-v D..
::N
4.,V-DDE
1.67
3.49
Heptada
1.67
UWxg
1.88
. 51
EeA i91 A
•::.#:
:60
EP,A.. 82:;:$::P.O
P stkldty::.H rblctd is <}..:,•
�
^:GS:.::
ate' : o � rc
. hl�fih . diir ..'ti'h li:� .,.
:::^,v:.,•:,: r:n.
:.$n ..
.....
rS4.}.,,r}}ix-,
r::::.,.:}.::rn
Q� ,:::::.,
`•
:kix:hNt%{v::}$:,:.:::::.n1nt.::�'-:}::.:<;<::w.NU..rcr.x.
...... .
.:: ::ri`�}>}
{ '{}}
}<:;.}}:.�:ND:}::.::::.:}�}n�
5}Si:' •.: :i$$SS;:}
:.�..;:}:rcr$:: ' ;}}SSS}:5}}fic'.:..
...#r ::r$%ss;>.:::.::
r N
t ••.
..?r$.
EPA827 Cn.:
... .......
� Y6�r n.:^,' wm`k,-.,,. .vn}.$•'.r•:'v.`•; $r..»
S mt.Y.alattlet:..,.::::.: ,:::::�.:rm�rr$::.w:::..:•::::::::n,:::::.:.::::$,n.,wr.
_ .......x{.....................
Fim.. rkvx .:...
.................
i"?-:r ::.r ,.
..............
:::
... rrFJ.:. -tc;,' •r arc.
rc,.rcn.:.n;vwr
........... ...........:«a«{{.tit,,;{r:>::::5:<,.:...rvD.:=~».n
rSrYrt.-:., :'.L'
.'n:
'r•4:.:.•
{ ... f:
!mS�s..n:" :,;..:.,•.
`.,`{'.,ntfi`{,�a.:{
tX??N
•, r}»s?fit.:n:.{..{�l�ts$:r.�`.'S:'.''r;;r.,:.
:ri-Yn....;
Paige 2 of 7
EN-1760 -Wilson Land Application Site - Contamination Baseline Analysis
All Soils - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Solis
Lab Semple 0
99-0406-035
99-0406-036
99-0406-017
99-0406.018
99-0406419
99-0406-020
99-0406-003
99-0406404
Simple Date
02/09/99
02109M
02105199
02/05/99
02/05199
02/05/99
02/04/99
02/04/99
Lab File No.
99-0406
99-0405
99-0406
99-0406
99-0405
99.0406
99-0406
99-0406
Test
Method
Constituent
Detection
Limit
Units
Pivot #f9
I Shallow
Pivot tt9
Deep
Pivot #10
Shallow
Pivot f10
Deep
MOM
I Shallow
Pivot 011
Deep
Pivot #12
Shallow
Pivot #12
Deep
. .-:•..:-.
.:.^':�..
_fir,
M>�7228.....
- - ••••• F. -. : .. :••Fo"--
"ac°'r{NaC >>
...F
,st Tii1a1• Iff Rrr
.�+.� ?:,..aN :�`.
;Fti •,•-Yr.. .:
x.�:."-..-., trfil.-
��%•::
wvtx.•-,.iv'Wi:-
...:•,
att:';.::>•.w•s:.
i,:.F:.,-:5::•:•:F:a:•FF}x
a.-tf:.•,\+.v. •r.,:t{,.r
:; r}S;a;:,rvc„a:t::r::;,
. {.{{:
nM
.:'"..F:�C�:53��.,:
r: .. r±----'-l+
Sb:,�..c: - 7"Gr-
N
t:Jr.--- - r
. ::;r:5."-�.r•.o.-:.
rio6ccbr...
/,d
.::wiei:i•}::
Tote) Col form
1.00
!oJ
nt
nt
nt
nt
nt
M
M
i8r xx::.
`•:55:- ttiF:
• cta :: efiror . ro _arbonx
__
itt55:::z
555,:
ii"/.'T`r.'f:
:5.,
:.�' r�..n
5.7::4'{t•:ti�:
'S! '
:�.t.�::::G:;::::'.'
x� :;
� .,#'a:'•5:`'.•'S ::r>it55:..t:•:riRa:.
,.. x:24
:ii^:•i:i:•
:::Si •''•:55<•::
:. .....
TPH
10.0...r
21.:
nr
19
nt
nt
110
nt
<:•:t: •.FF::•
a•Y :F�tt.n
{::::.::......
................
i' }'
:.w:,�,,,,..:.v::.,:x:::::.::::::::::55:i:i:555>$r:fi<<::::
EPA 351.4M
Total Kiedshl Iftogen
mgtKg
17.0
309.0
380.0
299.0
530.0
548.0
450.0
EPA 350.3M
Ammonia
1.0
m
EPA354.1M
" to
0.10
mgffg
EPA 353.3
Nitrate
1.0
3.7
2.1
2.0
5.8
3.1
3.8
5.5
EPA 9253
r, kx
..Ibh Catlo s . xxts. n
f
ChImMe
50
...................;
300
::..:�kFF}}}:;r}i�:.:i;
300
::�.N:r}}i»>r;'•:.Frrr;
270
;>rir};rrrr}rr...Fkm
550
Room
320
:<n.
360
470
560
EPA 9038
St"a
50
252
254
250
373
221
232
491
606
32.191
Sodom Adsorpfion Ratio
cdcd99ated
ratio
3.000
3.800
3.300
4.300
2.400
2.800
5.300
5.100
SM 2320E
A kd ' as Bicarbonate
50
mg1Kg
880
1,320
200
200
120
200
460
300
SM 2320E
AAA ' es Carbonate
50
Mog
560
480
160
160
240
240
... ..
r .. n
.EPA;.47114.
..: .., ...: v:-i'4w:, v•.:::.::::...::.::::.:.....................:a}}}}}•;.:.....:�::
.,:nix.:........r..fi, ..:......:.,w:r.,.rr:.,
:}:� v:J.n
x:J.....r...x:x:... e�cu w.wrnxx:r..i�:
M
rx... ,M.
"•:tr:}}. }:v
N. ii5tx
0.01
nFFrF-:; .-:
:. ::rYv::: :. �.
nVAg
:..... ::: ;'F•}}F:}fFF:;
•}::.;:i:,• :::::::
':S:J55
0.01
.• .:.:::i:ir;:aF:...: ...
}'ii::: :.,i.'-.^vF.S::
x:::::
0.02
:4xv'••l.}Y.LF:F:.;
:
N.::a-,�xx:::::::
0.01
•«:Fw:.;FiF:.:i.........}:-i:•r:,+:�.
-:: is i 5::555}
0.02
'•;�'r'I.FW:::}}'?;.FF':Fi%i?YJF:'•F'�'::•
.:. :iF'm'Yvri45ii>"
0.02
,.. f::.n•:::r::...5>5,
ems.
0.01
........:. i,...........:•;:::F.::::::
.:
":Sh?t55555t
F:{•::::-
0.02
r�..w�.-xr....xn
EPA b0:i 8.:
.. i..
::.tiletahr7. Icdr r:��� ..x,-3�,r:
htb >aME
Arsenic
2.5
mWXg
F.•aw.x
4.8
:O'Sr
k�'
5.4
.x
5.8
6.4
YS•rv:
4.5
;ir•:>tri, a-.q::,
.r.Sr.
r t
5.3
3.9
6.7
Cadmium
0.5
Wg
2.14
2.07
1.64
2.03
2.09
2.27
1.71
1.76
Clxomirxn
0.5
mgtKg
15.00
15.20
11.10
12.60
11.90
13.90
9.47
12.50
Zinc
5.0
Wo
40.7
41.3
31.7
35.8
36.0
40.9
30.8
34.6
copper
0.5
10.70
9.75
28.60
15.80
17.30
21.00
8.66
10.70
Nickel
1.0
11.9
11.7
9.0
10.4
10.5
12.1
8.8
11.4
Lead
1.5
mgMg
13.8
10.4
14.7
23.1
14.0
14.7
11.7
12.2
Selenium
2.0
m g
MdOdenurn
1.0
M09
Pohm*M
50
M9ff9
4,530
4,640
1.260
1,470
1,640
1,780
2.270
3,410
Sodum
50
Mog
1,150
1,210
1,050
1,320
887
972
1,220
1,530
Calcium
50
MVxg
15,500
15,400
1.560
6,340
8,710
16,400
4,100
15,900
Maveslurn
0.5
mpIK9
1,850
1.770
1,460
1,570
1.700
1,740
2,780
3,500
Boron
1.0
Mog
27.00
30.00
21.00
24.00
22.00
27.00
15.00
20.00
E 80 8
ir: tii5}iSFv}iiFr }'ri:Ft:
P s <i?:{:ixxx:x:..:..:.„v.:.!Jn:.:....x:.....x..::.
a rdei ..ri•
'.
:.::.....:::.:.
.:ii•:::.
....:. v..wr
'• r ::
..: vn fix:i-•::
vx
.xtt'x"S$ vr.: x::
::NQ.r:
••••
�•.•r::: x: :i�5. 'k:
i,vx x:nt:. `$i
F..-:Stik+S'•:
.'i:ixi n:
v::x::: rxnv::
::iVp:n
. .N}FFF::::
� nx:x : :v::::.
t.
.�..: ::n .Si.-x ..wx
is
�•:.n.r..
. ND>%'
<v�►e:� :s<
:.i.
4,4'-0DE
1.67
Heptect#or epoWe
1.67
: 151A
.: .:: x:: `t`•i:+ :.... r.
.esttekies e e ::
.7 rb%rdt .
..C:_.h.r,?F.i
r ::}?i::•tYttr:i�?}�}.sxr,w4t{:.,•:.'}.r�t.....�:.:.x:::y...ac:...,v....,S..x::.:.:J:...:
•xi'tn.n .
-x:::::......:.
-...
....: .; ..
a...::.:A:. ;•:{:•:{•.:-..-.N
... .v
:
;y>� ,.w..•..a:;a:r:rrw'�.:i
t:`•.
... ...:.w
<.:iX:.: FC:ii:�<;.i<r?,:5�N�%`Dp1is<ii+:,<;:
: t:4:Lk`. ri: '4a:•5
x.,•:x:xnt:.....x:
:�9.':5:F�t:2S�?t5)5S?:::'�::: t
r vF:v}Fri'
' 11 D::>�:}:SF.....•.tr�ni
•:::'i5x.5.kn...:5;..ti.. ���.:�:<}.`::•?:
:viiYir'i •. ••••••••..
trtNN�>�:::.'<.t«?a.No.<s>:::...
:.r._JS_?.'.xa:. nci5t5..
fi.r�:i•.::i..xi `5>t.•.:.
'
:•:; i:s.Nit:::;:S{t.:i{.t:.ti.$i.:..
t.;v>v<>
5{. >.
PAr
...... ...vl
eVaitn
i
,•::Q..::rn.::., ::,:..•...
.},...n{r•{:y-..;.rin
•,ct:'{
:
•:�.:ir3.::.:
.f»:$:.t:`rfi...i::.
Page 3 of 7
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
All Solis - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Soils
Lab Sample 0
99-0406-021
99-0406-022
99-0406-023
99-0406-024
99-0406-001
99-0406-002
99-0406-011
99-0406-012
Sample Date
02105M9
02105M9
02108199
02108M
02104/99
02M4199
02105M
021 09
Lab Fite No.
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99.0406
99-0406
Test
Method
Constituent
Detection
Llmit
Units
Pivot 013
Shallow
Pivot 013
Deep
Pivot 014
Shallow
Pivot 014
Deep
Pivot 015
Shallow
Pivot 015
Deep
Pivot 016
Shallow
Pivot 016
Deep
SM::92228::'
rzV.," T, mfAtrti}P,
i,::.:rx�:Ot'lft:>:.6lifdmr�'�; .........:...}.
�;. �.
r.J�
}rrry r:}:,
r:�:: xw.v ': -
�jnt
v},1W.4,rvr
:}::-}.•$�}
'b
x�}r: »
.5. ijJ•xitixi
...�
S
::}:.v
}y?,. >
..$....fx
r
Total Coffm
1.00
coU
nt
nt
nt
nt
nt
M
M
., t..:v
e-PA:���.}.:::m::.r..4ar-�trate+ilit
:n...: w:
. ►.o�tbvt�:...
r........::.::......:.............:.....:r.:...r..r:.:.......r::.,.:,.:>:..r:n....r.::::::.�:�:
.;tw:: {Kz_tt:
:� }•:$$::}$yz:
}sx$r
......wr .:.v'}': z-z
'::}i.'if,'�;f•;x:;:;'
tss;
��t:��: :.Irt
��::�:::�.k}}:•.::,:.H.::::::
{_t,♦
$ .�:r:..
.:: r: :s:5i2k3::i}:
TPH
10.0
1 mgrKg
18
M
35
69
nt
221
ND
... .. -}.. tx ..
: z,...+v'�i :�
. •:......
.�,,,u.-r.•:...-'-:�.-:.•::.w...::x.,:N�tia
n{N.-
.,vv"l.` .::.... : $»E.`3}yG
r
71Vitiatel::.
, ... ...
»wx:zz,.•
.. ,:
,...w,....:...
o
:{:..,: .v :...•
.r.. n+,.r x:.
�•"
...:::.:--'--..
.V..t,.: :l.
, .,. .. .... .....
'$ ��.......:..w.:.
,,;:::: trr.:.,....•
.::,{.; •: -: -..:.t
'^� �x'.r....a�:r.
ii::.y::::z•:{i+z,:tbi:
:,,».:rv..::.,; ....
r:.}..w�,n,::::r.r.•r.
::::.
ro}.,.x
,-::.....: �::'.�.r•;,$
...........::
�i::r:::::r::::..,}.t :;
.,,,,..x,.:...,.:.:r.,;:....:.n:..•r:rvr
.t::.;:{.{r.,,-::::{•:::.:.ii...
:.r.::.
. . 'Kc-n :.;
::.:.::{::r:::x:::::r.
EPA 351AM
Total K aM IfIrogen
I mglKg
400.0
760.0
1000.0
1000.0
345.0
350.0
343.0
380.0
EPA 350.3M
Ammonia
1.0
1 mwxg
EPA354AM
Nitrite
0.10
m
0.1
EPA 353.3
Nitrate
1.0
mgiK
2.0
1.6
2.1
5.2
18.2
6.4
1.6
,»»v}vi}n
v�.v:'::rx: 'wr
EPA 9253
:u::'• ,M
}t}.. :vwrrU}:•
Chloride
:rx".-0L•ru Jv
50
:: i:%K..:.
m9mg
»,vim ww.:
230
:.•.•.•. r:. -r:
';}ifl"?:
310
:+S:d:
•xx::
170
'.•
-nvsr:.-.-: :�:
280
m?i}:'
1.100
'
270
500
$: is vf±:-n i:L:::::_':j:$::
470
EPA 9038
$ulfate
50
m9mg
180
93
330
83
462
312
312
511
3.2.191
Sodium Adsorption Ratio
calculated
ratio
1.600
4.700
1.400
2.400
6.200
7-500
4.100
3.300
SM 23208
AWnfty as Bicarbonate
50
mglKg
160
400
240
900
500
200
200
SM 23208
AAcaf *as Carbonate
50
m
160
240
240
240
100
160
. ..
4.
:� 1 v.v::
.,: ••r:}:rx•:..,,�,;w;}y .: :,..�.�:.-::xi}}:}:x xsr}}::i.
z. : :k.:
..�: xlYlercu-r.,�}.},m:,}}i:
n.::{:. r. ...{. ::::::::.. ... ..
Mermy
«.}:: .;-...,};..>Y.;
.r: {: {.. :: ...:::..:
0.01y�
...........
x}r::
:: rv. .:.v{.
{.}ti+;;i:.:.
0.01
:::+{i+..:i.}
0.01
}}>:ar,}>:o
' :$$:?::
r•s.
is t[.
.;
<'s�,y,,z
0.02
.:};uacYr:•;;;;:}}:...<�
.:<xs$r
':v$}$:vv
�•rx-}}••. - r}}>:}::;;::}:...
xrJ$ is>F ::iT}i?:
�
:}>}}:i•YY:
ji'}:Cw ::
...YSSrv:•n:::is
£5:•,.': r$.'+':�::$:
0.02
EPA.601nBx..
r.INetah.Tlhui Icy! rx::�::•r.
Arsenic
2.5
mgfKR
6.7
5.6
6.4
6.5
2.8
5.0
4.8
3.5
Cadmium
0.5
rnqfKg
1.37
1.44
1.95
1.68
130
1.81
1.69
1.77
Chromium
0.5
8.48
9.30
11.60
11.00
10.80
12.00
12.00
10.80
True
5.0
m
29.1
28.5
37.8
33.7
32.2
32.6
31.6
30.2
CMW
0.5
mg1Kg
25.60
11.70
18,70
17.30
13.20
15.40
10.80
8.00
Nickel
1.0
"Vog
8.2
8.0
10.3
10.1
9.1
9.6
9.3
9.3
Lead
1.5
ff Kfflg
10.2
8.3
12.9
12.7
9.4
12.0
11.0
11.4
Selenium
2.0
M emn
1.0
mog
Potassium
50
1,510
1,540
1,710
1,380
Z210
2,190
Z490
2.520
Sodium
50
m9mg
813
894
829
1,030
1,400
1,130
1,280
1,360
Calcium
50
mg/Kg
7,900
17,200
Z440
4,370
1 4.320
6,560
9.380
13,600
Magnesium
0.5
Oxog
1,720
1.820
1,680
1,640
2,700
2,540
3,070
3,240
Borax
1.0
rngfKg
16.00
17.00
23.00
23.00
18.00
20.00
17.00
16.00
v . ,r:.
•: Yfi
Ep/4.806tA:x
::.:.:.v:.:::v::x,:.,.x:r:rxvrv,.rvw:,.xxrv:,,x.::,::::;:::..:.::rx,..r
r .. L ..:
"}N:�t':.:fr.«:w:5.:�2'::fsfi'.: �•.»:
e0...:ti,,:... ............. {;.. ¢
Peitleld.. ...$.........$.....:....
:$fin <sirvn::::::..........
::r.
:};::#%•:ir':
xw:x:.,....x:::.::.w::::.rxxxr........•::::x:frv:::
:a"•r"'Cr.{: .:}.v:rv.:
ND..:-�::}:�::<:;,�..1tt:.x::.,:.::x:xxxr�.xr.:.x::.,.,rxr.:.nt�:;-.:.w:}
rvvry ;r;:::$::Yr.-::.'•:....,».-.»,:.v::..:
}}}::::}xrvw:.,:v
rrr:xfrvvr:.x:xr...
.rry •.:f$,,,:.:
-., .:;«^>
_..:x:.� w:::::...::'::,..::..:x:..�;:.:
::::{fa.
px.:,..:.:-:.:.t.:,.
::�<:n:.iV..v.:.r...,:..:.:rntM.,..::..:..::•:NR�r.,�:��
:}$::}:{x r.
:2�::l..^.'..
„
C:r.$$}:
..
::....::::.
':::�:,.>si^r`.
..n :•.:.
-:..rr... 1Sf.Ms,:
4,4'4DDE
1.67
tMM9
2.40
tachtor a
1.67
.8BO.�
fEPP:.AA
"i
at�. . i eh .I # :. s :......
r.x
:$:v}}: SYmw:..::..v}.:v
.........
::
,...rv...}:�:.
w''':�: }i>j: ii
�.:.�x:.NR..:: :.. r
...:.........::..,......
:.v....
t::>:::nw.,.ND:r»$»
' '' }+'
�a `M..nt}�$i.rv: :
:..:..
.. nF::. rr
;:sa<,:r...: N p;;�.:;
..
{'.}}}':•..';;•Y;,
:::v.}:}nf,::M,;,.
>.,.v:?..r;.�i$::•S:i
r�'}xx .
.........
?;x::,.:�..>.•rv,:}Y
is
.'a.:i.$••:.i.. 'IQ::
.. ..........
:>.v}:..:.
Vu...::,.:rx.N..O
...... .:v, •..:
..........<........
Yili .'v': }...1x:.•v.v..:...
•..:: r:}:r.;." :i:•.,•?.••.,•;:;
. :
SPeO
l
v
c
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....w.M..c
Page 4 of 7
-..-_+...a � rG--.-•-•- ..--+-..� '., _..-.a�.+� M.v.<.y H.a.a,�-..� � ..... _.:� r,.� 4-�y 3� t� f •+�-.-y a....-J._� � ..-.�.s.o-� � �
EN4760 -Wilson Land Application Site - Contamination Baseline Analysis
All Solis - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline -Solis
Lab Sample 6
99-0406-033
99-04OM34
99-0406-031
99-0406-032
99-0406-013
99-0406-014
99-0406-015
99-0406-016
Sample Date
02106199
02/06/99
02/06/99
02/06/99
02/05199
02MM9
02/05199
02/05/99
Lab File No.
99.0406
99-0406
99-0406
99-0406
99-0406
994406
99-0406
99-0406
Teat
Method
Constituent
Detection
Limit
Units
Pivot 917
Shallow
Perot 917
Deep
Pivot 018
Shallow
Pivot #18
Deep
Pivot 419
Shallow
Pivot 019
Deep
Pivot 1120
Shallow
Pivot 920
Deep
SM}9222Di.�
.. ,,,v
. ,;;xx ?s:�•..
xrs;`r, •.
Taut>Gbitfpitii:3" : +
"{
ras?x• �
:wu•i$i::lnn
---iYs »rr.:.
k - 4- F•hW58n--
n,. ,<..wa.
x nvn.�. �,.
.:e..
:::::::.......:...:-
'.':xx»::^'^'^...r
Yr.,}..w.•:.,.:x:..:"
.
:}}}oza,a}��;}nu
:'Frvr
.',: � r s^r
.::�&•
}r' 5s
.�•'�9��.z
}i 7;�.. ...................
"
Total CoRorm
1.00
collgran
nt
nt
trt
nt
nt
rit
nt
nt
ivy`.
P :416r'D..
rod :&•Y:
/}rti:£4•,
v:10.0.
„rkv:l,v. :r.G:
.A:{: x'm.,
x
::Sf}Y:^ .. i..
: »:28
.
�'^x✓'»x ..5::
'�::lx'Lx.
TPH
21
nt
nt
27
M
11
nt
;M:R4•rx :ia
......»y .�::»:.::.
..< .
.titiii>N • i.sr::'.•:;:•.w
»:x.x •:: .•..
.{. 1 Wing"'.
�!n is ...Nit.
~K 9nt
�
..nr:
:
r...;.-,•:i:%}:
::
:{x
:}}}}in.rvwi}.:.}:,}
:
«... x: r:::»»xirr
» ::
.- :> w
::<:;<}>sr.<i<:::is.ti<:s::,::;x:`i::
:
.x xJ360.0
:^•.:i::::.. :::iiss:s::::s;::'s.^.M^:r:::
.:
EPA 351.4M
Total ahl n
mr:::: g
720.0
20.4
800.0
7.3
283.0
259.0
440.0
EPA 350.3M
Ammonia
1.0
EPA 354AM
Nitrite
0.10
mTxg
EPA 353.3
Mt*e
1.0
mog
7.7
6.7
14.1
6.0
2.0
1.0
3.2
.......�.i. .v.•v.: ..
:nw:...,v:,,v...v,x. v::, •:
EPA 9253
:•: :... }.': ..... .. .:::: :.. .; :... ....,..
.�„Mxn4£1b s':Catib i rtrzx
Chloride
.........fir; ..:.v.:;•i
.t:::: xxv:L'::4i:..n..:-nv»:::::.
50
}:4ii:-}:%}}}:
}r :»:-v::::: »:::::..:.fi.:.
240
"ri. Jli F%}:v'.:v}}i
:.Y. ;..;.....fi.,.
300
Aw . x
imam
900
450
091<i
90
Yi'!.•ii�:irir}}:
::f>s
90
%i}:Lv: :•:ii'i' riri:
110
J'iiiv'i:i:4-i::;•}:.i}:•}:is
:s. :::•ws�:.
130
EPA 9038
Sutiate
50
1 m9fK2
137
230
131
220
60
57
91
3.1191
Sodium Atimption Ratio
calculated
ratio
1.400
3.800
3.100
4.400
1.000
0.800
0.900
1.800
SM 23208
AWnRy as Bicarbonate
50
mog
1 320
400
1,040
440
120
280
500
40
SM 2320B
AlkdZr as Carbonate
50
mqfKg
320
480
320
320
CP
1 .... ....
„:5.'•.'•'•Sv.m`'
..............N�...............,,.:..........:..;:..,.}:::.�.«{.:::•:.:::•.`Y.'{{:..-:
i:•ir.G»
:rF:i..;n
,V,:::::n;sssr:i5;sn;z
:: f:.vrrSSr.
.,.;•: ».�sif};
fi::w�.;<
,%i,.
:{{{.}s:;:::::;<;a•'��
;:{;•;:::: v.%
4rrf:r
>#s»
�::::�;,::
M
0.01
M09
0.02
0.02
0.01
0.01
0.02
0.01
0.01
d^ yltf :%:
CG'1�ff/�'601013:.'
::q:A,}:;i.1•}A}: .. ... •:% ...-....... •:: +:%irii:;{J:v:{i
y
x;:D�ttaia:i':itra anicf'}i'} ':}Y::
Arsenic
ax..v :x.
y'".,N'•;F» ...%-
2.5
}•:y':':•:%}}}:
-:::..-.•» ::.,,..
1 mqfKg
:%ii}}}i:%:i......::i'•'.
- ,.,
fiC` }}i;:v'�'i�'m,':`•:
5.41
:•
.{A"#.:ve:.��.2M;a'.•:
.
6.8
;d:.r:.S:.»:.,-:::"2:
:..?....,.5"£,...
4.1
S:L::::::::„rv;::ua}:w:2•
..
5.6
}' r}}'J.`}:•:•:;;;{;%:v:.i:'.r};v...
.'^.CSu::•: ::a"5�::.
6.2
•r.AtiS.#.S';::*�::.:.wrr:i.'•;
.n
3.6
-::Yr�'s:»ac•'£w`�rlc-
6.2
"{v}}}i:
:;i3C.i, '}:;%..:xx.
5.6
Cadmium
0.5
1.85
2.20
1.60
2.20
1.65
1.99
0.97
1.57
Chromium
0.5
f0.60
1B.10
11.80
13.00
11.40
11.60
VI
9.90
Zinc
5.0
m
34.3
43.9
36.2
42.1
30.1
32.9
24.2
30.8
CMW
0.5
m
14.40
11.20
18.70
19.10
8.20
9.14
14.40
17.70
ncckel
1.0
mixg
9.4
13.0
&1
11.8
9.4
10.0
7.4
7.9
Lead
1.5
mqIKq
17.3
17.1
40.1
17.1
10.8
12.5
7.0
12.9
Selenium
2.0
mOL
Molybdenum
1.0
mqIKq
Potassium
50
mgfKg
1,640
4,310
1,460
1.860
1,880
1420
987
1,110
Sodium
50
mg(Kg
771
1,200
893
1,160
1,120
881
564
655
Caldum
50
mgtKg
2,950
7,060
3,040
10,200
• 2,310
1,480
1,370
1.580
M
0.5
mgfKg
1,660
1,840
1,520
1,710
2,140
1,690
1,230
1,340
Boron
1.0
W2
18.00
33.00
19.00
27.00
1&00
24.00
16.00
18.00
s60 1
.A..
6 v \{i v
t%ld f ..f..t.::,....
,�:r:r:r:r::::::.r.:
D.>.::::..
<:::,:<.. nt:<Y>=>::{:
{ D��......
;;;h. t`-
D
,:.N .::..:}
:1it�<::
..'�;:�k
.
.
4,,f.DDE
1.67
,Heptachlor
)dde
1.67
.. }..
•.H151
.. y {. r. ... r.n.........
teftl .1 rblcYrdts::.
r}..,v:..r»r.:.:..
r.:..•.... r...nn
.... ...........
F..:vr t\w�:::....,x.w
•»:,;:::::.
:. n,.,,
. D:<::>:�;..:
ln.+A+r .. r.::x.
�`»><>:: t:''.uNs
i::::::. w:::h
" ,.:AID:>::>s>ss.:„;%„;;z
:: {:.•: i:::
n ...}:•}:;;.;.:;:..
ND}::•:::..:...
-.:.•. ;rr..
EP..: .: ,.
':H OH2{.
.A... »,
... .:. .:.:. ..::::.. ; :. , .::,:, ..:
0
at b a b 16 td: •:::
P sli rlh Bi 13
:. n. �
:.: • :..r
�'.•�•Yrr �:::�...
fi'i:::' .. •:,
•:{{{.
:::....
:r,�.:. -r
n
��}:r:�Nt)k',�::
•:.
6S
.. -,
:{{Sr:
. i?
.:i:.'•S '.
�i,S:v::fi4`::.
N } 1tt•:: {.:.
»r.NQ�x�,»>
�xfiti��"~:
. ;;;
EPl1r'8270l�::.
.....
,.............::.:,%r:•»,}�;iN�:.{<%}:%;;;;:%:v::.;}.,:.}...�•}}}>�.::.}}.}rr}iN}:;:.�•:N:%�x:.
Stm .Vdistlit!»i}.sc�r;;' �:V..x».w:.c....,,,•,...x.
_...................................
x:.�.:.,a
<..............................AND...:.....«:.}}�:nEv<::.�::;��><::h1�.�...:.
:;c;:Y;:.x;;az.
...�;�...
»x.,
...s,
.3.,,,,. t;:::.��,:�5
h.......•--..
s"mks.;'' rss;.::wssz,s
..:-...
...;ter..:: ,.
..1►tX.._:::..t.....
s w�stJDv�"'s£
.:�{....
s::,za>; •ntsn`:'i'
Page 5 of 7
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
All Soils - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Soils
Lab Sample S
99-0406-029
99-0406-030
99-0406-041
99-0406-042
99-0406-027
99-0406-028
99-0331-005
99-0331-006
Sample Date
021OW9
02108M
02109/99
02/009
02108l99
021OW9
021020
OM2199
Lab File No.
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
ON331
99-0331
Teat
Method
Constituent
Detection
Limit
Unite
Pivot 921
Shallow
Pivot 921
Deep
Pivot 822
Shallow
Pivot #22
Deep
Flood Plain
Shallow
Flood Plain
Deep
Cotton Bum
Shallow
Cotton Bum
Dee
5M ,2BY.{�1
.....
WIIII,Vt�E
n...... ..vxr r..,..
'}� rnw L
.. iiN: n.......A
r: }r3%}2
.iv.wxx:.
ill wYF
v:... x:�`i:�. ik•:xn..
}k4 l
n.... r:.`:�:M ....:
-.... .....,+�»`.w:i:
%ii k /}
:-}::'»x. rr: ':'r'�....
<r 4}}ki G•
}m.iC ... •.:N.4�T,w
} T^
::d'i.�::.,.."J nx...xr�.4rr'f...
f
.x S 4J}h
x..: .�:f :��Fi�.
Total COMM
1.00
coU
M
nt
nt
nt
nt
nt
ND
ND
.•::-.
...-
4ftt.1..
•.'C..:. ...l..v.Jx..:
-•Ji}+•1{H,
-xT.aOili.'.etfo ebm. te0ir1�a0..
TPH
-r.-.v.
.rl�,,,,.....
10.0
r: r: h•}.::»S
:r:::.vvv: -:
.,-rxk.
.».i:vri}•.•
.,+.ry:..'{.vy
23
,.,.:::::
.:»»:•: � xx::�:a<+:
nt
i:�:>
ND
::::::...:::::»:�4k,,::rmrx
nt
15
nt
27
ND
LIEPPA
iY.:.
:::51AM
TotalK' daM
m
1300.0
880.0
12.0
14.0
1400.0
13DO.0
1560.0
410.0
50.3M
Ammonia
1.0
23.9
24.7
EPA354.1M
N"e
0.10
1.5
1.4
EPA 353.3
Nitrate
1.0
mog
2.8
9.4
2.8
2.6
1.1
45.4
12.5
.v:rr.r .rx::.
.,..,...:.::.:... r.. r.
............. r..... r.
EPA 9253
...... ,:. { . ... .:....Yr:iv»:
»..,•..... y . rrrx.:..
.r.. Id .-v:.,.............:..........
i .Cattofti.7Alk�i
Chloride
..................................
»r.:x::,...,....
50
.v......::. uv
.}i:}}}}: �.•Y.4J::::::
.....:....:...
x.•.:rx+x....v.-::w
170
:.. r......::::':.......
x.
n....v:- !i....v.,.
150
.. .. •:::: •.�:
..-... r...r
Yhwrcr.k,.
370
-•:::::::.
w:::x:.. ::..
......,..•.:•:.v:-nv::x.
200
•rr:::::.. r:»::: :.::.::::.,-:::.:::r
.vx::r»:r✓: »::::::::
80
:•J:411:1}
••.•..rw.w::::::: :•:
...... •.v: x:::.v:
60
:}r..': }:
^"•"'
'!4J"» :
J•:r:•}}:4iivrJ}:4}rr.Y:l
r.•.•.. x. ». r....... rvl..
60
EPA 9038
Sulfate
50
mog
144
110
302
268
32-191
Sodium Adsap5on Refio
calculated
ratio
1.900
2.000
2.400
2,000
0.500
0.500
0.004
0.004
SM 2320B
AAcalli es Bicarbonate
50
m
640
1.400
920
960
200
1201
84
30
SM 2320B
AW ' as Carbonate
50
mog
320
560
200
80
nt
nt
.r
:1:PA
4Yr:vJ: :J:4JJY.^}}Y.-}:
vrx.r:xmi .....: }irr v.;-r:
4. c,.Y :;.::!!{{!{!{{r{: n;.}ir{:v:
M
...:..:.v ":.
)will:$ :: rYr::
0.01
:
,r{r!r
Nome
0.02
}v• ... ..
511':•$:J 4f+>}::
0.02
' ::hl:
0.01
...............
.C:{:l:"J:v::,v,<:l.i:
0.02
` -:4:•}
0.01
.riJY.:,
0.03
0.02
Arsenic
2.5
myxg
6.6
6.0
xl
4,2
4.0
6.7
3.6
4.7
Cadmium
0.5
1.81
1.93
1.58
Z27
1.53
1.65
Chromium
0.5
mog
11.40
12.20
12.60
17.20
9.48
10.20
15.40
14.40
Zinc
5.0
RVA9
33.2
33.8
34.3
42.5
30.8
31.3
42.2
33.8
Copper
0.5
m!yKg
9.15
72.90
8.85
10.50
19.60
11.60
9.93
6.75
N*ei
1.0
m
9.6
10.0
10.5
13.3
8.3
8.1
12.0
4.8
Lead
1.5
moo
12.3
13.6
12.7
14.5
13.1
21.8
18.6
7.3
Selenium
2.0
Molybdenum
1.0
nxj/Kg
1.1
1.1
Potassium
50
mgNO
1,600
1,540
3,450
4,280
1,430
1,450
5,030
3,920
Sown
50
mpg
653
823
901
948
309
409
259
171
Calcium
50 1
mqrKg
2,480
9,580
2,960
6,000
2,4801
1,420
6,840
4.550
Magnesium
0.5
mog
1,630
1,590
1,680
1,640
1,510
1,510
4.080
3.850
Boron
1.0
20.00
24.00
25.00
32.00
18.00
18.00
9.15
5.48
:: f
A. EP 80 '
B..A>
...l. -. .r
,:awri:.'r�} :wits :
P ti�ti �sss'sz%
a}:•>:
•ill"v4y ri:}}:
-:
x•.t:;<
.;:}»>::�<;v;H::
` : ram:•:
>;
:••l::lx:<:l wi.
D.
x
4,4'-DDE
1.67
ugfKq
3.35
Heptachlor de
1.67
e1bti d t.•h;l.:»}i�.,}:;l..�.'.:. 2.;.:B.l.:.:.fi.n{r„G4<••i..}� JSir :
::r.l.,}.m..:4.•.:.:.vx..::•}!};}{}.:!.}•
:.4. k.,{•ili!i.Sxr}xi.,Jx4'4..:
N D'€:,�}:x.'•.i.::x.
:••.iS•.:J ,:r,:"•.w::!l::.:::r
wy>�.:,•'i!'.iws'm.:J.,.:.l�..:}.i>.::.
:":: t-:!.-:•J},w.r.rw:.r,i!....:r+.:44..;:.
:anv�'.<:..
:,;!r}.;.:r{•.„'4)•Y:x:S:.::.: ND€;;?.:1r::.:
''
:#:.f:.:�•-w:`�:r4:::-.#'Kr:•:�:-A ""
'PA:
Q:%
..ri::4:.•.t.:}`•.::4.:.
•t. •.}:rv,ri:# '::.
.•r.:' ^.„{:.!-`-rr:r:.s{4.{.1:,.:r:i.:: i
::4»}Y.3.i.x..?:.:C.;� iVDpi��J:'•4-•:»4::::•i<r}•}r:::
i' s
�"• .':t rPs4:
..
EPR:827
r rr. 1 , ! x. .x..n
r .^: v#'^;,. .fiKt.:
it fat(le�.:�l ^w. r
r.4 .. .rn.,..
:ix}:};}•;.,
:r:..:..
:::•}rFSYt
v. J .. ;,l} ....r
x:,3i.-
r: hi:,,;:'�,:
.F .....
;a*'rr
................:...
........... ..................}�
..w
}.r::, .:w:4;
>�=�- n -J�
:, :}}J:a:
D.
hN
Page 6 of 7
EN-1760 -Wlson Land Application Site - Contamination Baseline Analysis
All Soils - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Soils
Lab Sample 9
Current Baseline
Sample Date
Range and Average t
This Assessment
IM,
Lab Rle No.
Test
Method
Constituent
Detection
Limit
Units
Low
High
Avg.
M-w-we
Total Cowform
1.00
ceftern
NO
71
1.83
EP,Jk4t8ia is
- - �Toa!§Wq
TPH
10.0
ND
292
52.39
.0 - -.100w,
EPA 351AM
Total Kid Aahl N"en
rng/Kg
ND
1560.0
497.6
EPA 350.3M
AffwyvoMa
1.0
ni%%g
ND
I 42.1
3.86
EPA354.11A
Ni"e
0.10
nvfflg
NO
1.7
0.18
EPA 353.3
IftWo
1.0
mg/Kg
NO
45.4,
6.15
LE
...
7,77 7,71--f-
.777.
........... -
EPA 9253
Woride
50 1
m999
ND
1,100
294
EPA 9038
Sulfate
50
mgIKg
NO
606
197
3.2.191
Sodium Ad lion Redo
calculated
ratio
0.004
6.200
2.307
SM 2320B
Afkalnity as Bicarbonate
50
rng/Kg
NO,
1.480
409.71
SM 2320B
Wkefinfiy as Carbonate
50
mglKg
NO
1,0401205.24
merm
0.01
mgrKg
NO
0.03
0.0131
EPA6tNOt1:,
Meta i7w fiRUM
Arsenic
2.5
=
nxfflg
IM2,
NO
M
6.8
ME
4.66
Cadmium
0.5
mog
ND,
2.27
1.58
lChromium
0.5
mg/Kg
8.48
17.20
12.13
Zinc
5*0
nvg,%g
24.2
44.6
34.0
COPIT
0.5
mg/Kg
5.68
72.90
14.56
Nickel
1.0
rnqIKg
4.8
13.3
9.89
Lead
1.5
rngfKg
5.7
40.1
13.61
Selenium
2.0
mgNg
NO,
4.3
0.09
M*bderlum
1.0
mog
NO
1.2
0.09
Potassium
50
moL
987
987
5,030
2,473
Sodium
50
_M22jL
rnqXq
171
1,530
959
Calcium
50
mg/Kg
1,370
58,800
8.774
Magneskrn
0.5
mog
1,230
4,080
2,162
Boron
1.0
5.48
34.00
19.66
WK8081
P*tQqId;FTMWffiMK
NNW
_Tj
4,4!-DDE
1.67
uog
NO
3,49.
0.34
Hep acNor ='�Ado
1.67
ND
1.88
0.07
PisticidtMb I - ---- -- I
...
. . . . . . . . . . .
Page 7 of 7
Soil —Shallow Samples
Detected Constituents 1 Parameters
.�.__..•� � �..� ._� , �.� ;�-1 � �� "`�.. �� i � �� `mil �`�7 A"l
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
Shallow Sails - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Soils
Lab Sample #
99-0406-025
99-0331-003
99-0331-001
99-0406-009
99-0406-037
M406-040
99-0406-005
99-0406-007
Safnple Date
02/08199
02/02199
02/02199
02/04199
02/09199
02M9199
02104199
021009
Lab File No.
99-0406
99-0331
99-0331
M406
99-0406
99-0406
99-0406
99-0406
Test
Method
Conetltuent
Detection
Limit
Units
Pivot #1
Shallow
Pivot 92
Shallow
Pivot #3
Shallow
Pivot 94
Shallow
Plvot #5
Shallow
Pivot #6
Shallow
Pivot #7
Shallow
Pivot 98
Shallow
hw:.:}:
Sh1;92228„k:.,.:n,.,,�r.sx.�,,.TotaE:Cdtifarm':'•,��s,:}<;
.c :,x::. .. wr{•++•:x
.,•�:::u;:vr":::x.
:;, t•{
.}<>:.}}:,}}}:�<:.,.::::::::�.�;,
.a,. .. :, •}:..rc>c{{;aq}.:,..,
.,..Y}.)
.v:t{-:•}}}>:.s-n}<,�>;::::::x:�.:::::.vr:.,
- ,':'o :•r.:}-::
..."R..}..}..a,wffi:r:
.:., .: ;}:r}}}
...:>.w:;;Nh�{>s::}{<}}
-:>r,'s.:e•
::}:: .r ;5.^.1.+.K
v:::}:::a�:�::::.,.:::
:;:':3,�:'.^.'y:„..,,x.
,,.�.,,.»:x:x:::::::.{xx:x::::.v::::::::.:.
},•..,:}:.,.,:r.::.......,
f{�',:},}�:}.•M;.. ..,+t='xaGRP."3:ti?:,,t:.
n.::f:£.._:::::::}.�:•.
Total Coffform
1.00
ceU
rrt
7
3
nt
nt
nt
nt
M
EPh.'('1.:::::.:I"M
>*t:-Fefrvro+iliOro a
ii'H
10.0
mi
28
NO
ND
292
NO
ND
236
220
:.... ::.,•: nn. v
.vkr. ::�:s';.':'.�:,,:•.}s1:y<r:Nti(4�
rxrvl.. {:'E£f: '-:..• : :: •�,:: .::;...
:\'„ •.i::f}$
:Nifta'f Yi.
:>r}»�f„
....... ::f1.
:':•.tv.
':.:^.v,•r} }r}rr}::.
..hw..
�:4'r>ii
:`v$jri
x;�:;. »��
n..k...
'}Y:.}}
{iif•$:{:n
r}:ti}f•}}}'
..;:rw:::�"�=
� >;c>x�:c::�:>�:
EPA 351AM
Total K"
720.0
631.0
493.0
470.0
14.0
480.0
380.0
EPA 350.3M
Arrnnonis
1.0
m9fKq
36.2
42.1
EPA 354AM
Nitrite
0.10
ffKYKq
1.2
1.5
EPA 353.3
Nitrate
1.0
mglKfl
3.1
11.7
12.1
3.6
5.1
4.1
11.0
11.2
EPA 9253
.w."�s.•�'�:to ..�:. 3i.' :
Chloride
r..::<;;.;�.:
50
mqIKq
:}{:r r .:........
240
.
.a.
470
»>
410
�#:=»>3rraxtN^ws>:N:
330
0
350
:swr>"'s's'
280
EPA 9038
Sulfate
50
mgIKq
180
353
254
140
384
316
3.1191
So& n A lion Redo
calculeted
ratio
2.000
0.008
0.009
3.100
2.600
1.700
2.900
2.300
SM 23208
AWnity es Bicarbonate
50
mog
320
110
84
120
480
720
300
240
SM 23208
Alkali ' as Carbonate
50
mgtKg
2401
nt
fit
240
240
160
::i:PAp47.1A>{•
ti}r.•u
.......... { area xr
....,.: x.•r•'}xk.
:'i}}}};i
x:r:nrw..::
�
'-TW�:.:v�>�r :ice{:::
rt�I�{i
•:>•
:::}3: r-.^rWrSSS:.
r}%:ri}iiiin'.:.
M
0.01
mgtKg
0.01
0.02
0.03
0.02
0.01
0.01
0.02
- -
�r frn�
Arsenic
.........:::::{:.�::.::r::......,..:.r:..:;.:.rNN.:.{.{{
2.5
i{:2:}:
mWXV
6.2
::J${{ {4i}fi
:,{r,
4.3
{ .v'+b:L.rv{:'.••'h:
:..::{:::{{{:,......:..:..
}SS'r:-}#'}{'i::i
3.4
: }?{
..>•...... <r.,.::.;.r..
} : 6.1
::N;:� w:�{:
:. {" 3.0
:}{{:
4.2
Cadmium
0.5
1.76
1.89
1.66
2.10
1.72
1.44
Ch Htffn
0.5
mgtKg
11.00
11.20
11.90
12.40
13.30
15.30
9.76
9.15
zinc
5.0
nVK9
30.5
26.7
29.5
32.9
34.0
41.8
27.5
27.2
Copper
0.5
mgfKg
13.70
5.68
6.37
8.71
8.34
9.73
51.10
11.40
M&OI
1.0
8.7
8.7
8.7
9.9
10.4
11.8
8.7
8.3
Lead
1.5
11.2
5.7
14.3
11.2
14.2
1&0
10.4
7.7
Selenium
2.0
mLK9
4.3
mowenurn
1.0
Potessim
50
mgfKg
1,300
2,950
3,300
2,490
3.390
3,990
1,850
2,310
Sedum
50 ,
m
690
587
616
1,360
903
1,040
1,470
1.070
Calcium
50
4,650
14,300
2,200
10,800
5,720
2,830
14,700
10.500
M um
0.5
m
1.460
3.190
2,430
2,900
1,730
1.770
2.390
2.430
Boron►
1.0
19.00
8.41
7.77
20.00
22.00
28.00
17.00
13.00
EP.A:8.0. 61A. �n•�.:
Peettalde"e'•:4•:.r{uvw'::t}':_}.j:i::.i:i.},_::x?n}.`.v]$r.•.imi,{v,{,:x;:•::4.•h:.`;:r:{.j.,'..rc.wi::7:nfi.,'n:.•..
snag:.
. .
N
px"rc
NDt,{....
NQ�;<::::.
4,V-DDE
1.67
3.49
Heptachlor a
1.67
1.88
81 i fx
A. aM:
F.P.. ..
...•'•'� ..
:: .:..,.: .. r..n :::: .r:..
ei. ta.....,,}rrx,:tn.:.}n-:
P. . tcid rbrerd
t.,i1 �.................,.
> .:...:....::f: r:,
:rc:rx .n,rc..r.:.,,::
_............
t{t^:t -:
.xr. f... r..:::::.
:r::.
......:.
{t{{.r} .:NQa�>::
vxnvt•:
o-r.;{{..r. :r::r,
v{}'rr}{S
....r::::. '.^•.'i.'•}.^'•.:S}'�::'•{`t
r�.
:i• yr:
•�,.•,,.:
$.'•fir{::: Os::z�a?
�:�:ao>�x�
P � �tlnata�. r
O.0 '
A.s1x?...�..
1
Se ...a a (lets
m1Y.l t..«.�,:.:;rrx::.:.N:.•x:.,.x:::y.........:..n.r...�:'{::{,>.�:.....,.n....
�r:.h ::.v.�
x D
:��}::� Q:nr.rr...�.,.r.Y
.k E}Mvry
........
.. �><YN:rA:..:{�1
.., .......
.
•nti:�<N'm;.,.it<;{{{;
Page 1 of 3
•_•Tl �. r:�l ,�..] ...�7 '�7�.1 �'`"7.. -i] � "�l1 "�`>1�`�1 '-'"I
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
Shallow Soils - Constituents and Parameters Detected
EN-1761
Wilson land Application Site
Contamination Baseline - Soils
Lab Sample 4
99-0406-035
99-0406-017
99-0406419
99-0406-003
99-0406-021
99-0406-023
99-0406401
99-0406-011
Sample Date
02109/99
02105/99
02105199
02M4/99
02/05199
02/08199
02104/99
02/05/99
Lab He No.
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
Test
Method
Constituent
Detection
Limit
Units
Pivot A9
Shallow
Pivot A10
Shallow
Pivot 911
Shallow
Pivot #12
Shallow
Pivot i113
Shallow
Pivot 614
Shallow
Pivot #15
Shallow
Pivot 616
Shallow
.rr.,�>.r�'.�}�:.
xG•:
..
`;ev"'o. "'^.: {2
xxn..r.•.w .:>�...:........
�: ..:5,',^.^.:�{.
.n-x::::::::::.
,.rxw nn....i.}:i-•>s;}}}.??::V:;,;:::,...:n,,.....�;::;
, .!.,•r::::Kc;::R.^,•Y}
......
.. ar;<:�..: r
.......:::::.�.n-:::r:r.n....,•::::::.,r
>nN}�
-1::«v.:.,-.xrrxn-
:}�: � :,•r_,•
•r :�
.::} .:::r.
'{Y. «:�3N:
x:::::....:.,
}-' ;'r :3:32�}°°5•!y:
.:::...r.....:xrr.:..w.n...rx:::.
3::�.'�?�xn \•.err;&
Total Cofiform
1.00
toll
nt
M
nt
nt
nt
nt
nt
nt
Lp:A�:41&1::
t�
QM : � iI
11'etra! itin:= dr�3c tbotll�•�,:;.
_
'
<{:�:.
r>r•n
..tfi��
. N.•' x
x£.}. ,..<:
{::;,::a;:��
TPH
10.0
21
19
24
110
18
35
69
221
"k?!
::: x:;;;?•....... ...
:..:::.............:...
v{{:J •�1
...iwnu .vrxy .:{:
..I�IttYi ..Nitrnlss..
. ........ ..
:: x::n...:: r... ... ... ..:: ....
�.nn.;:?n
.wnvn...vv:m
...:: .. .. ..
ny.}wrv.,....
.n-:..:.v,..•::?.•.
�.:
rr}<:- .m-.vmrnvv.^.':.vnvv
::: r:.•: r: . .r.. x.%:
�� i'
-.:.; ..r. ...
.... xx: «�mnW:
;{;{�
�!{�
v:.w::::. x::
vv nv::.m-.Win
vxx.:.,•..:::::: x::: rn
::}ri-:-}x'•
kx y,
EPA 351AM
Totes KOM Wrogem
MgNg
17.0
309.0
299.0
548.0
400.0
1000.0
345.0
343.0
EPA 350.3M
Ammonis
1.0
mog
EPA354AM
We
0.10
EPA 353.3
Nitrate
1.0
mgIKg
3.7
2.0
3.1
5.5
2.0
2.1
18.2
....
... ..,-vxr: }rr. m:.
.7,
........ .. ..:.:..
,. :.
EPA 9253
.: ..
.wn,•x •:. .. ..: :::xrr:.:
.. .. ..
� .. !.. .:. x.
?. . .:••!... 11...(.,.... .�
Chloride
?:..fiv..., rr:.....
::• ..........
.:rx:: r:::r.�:
,err., r:......
..... XCfy::......
50
.r. .....; :: •>
�::..... ,.
;••?.;•.
..{{ .....n..
:.,-.,.r+ir;:: r;:: •r-:•}•.•::•::
«,,,:.:. rr:. r:.rn.a•.
:x.n..
JP.hX!....... nv„ni•.
300
••::................:...
,mnxrrr.r..
::::::?:•.... ........
270
!;:.::...,.:::
.n..«.cfr..rr.».
rm......:�•.
v'.Ci,vf.......... Y.....
320
{
:::::::::::..: x:;:r:..
470
- :�}: •;!;: ;:v., .',...
�.. .n..r.r.n.rrw.r
n}:.4i!;!:n:v i:v:,:i.
230
r:. rr :•;:
}/xnr:.:
170
:. �ryr:!:!.,::::.
•rn..;' .r.v.:.n:::.
n•}'Tc`t.'•''/N.!!i!??bir:;.
1,100
x.w: •«.::::::.:.
,.
500
EPA 9038
Sulfate
50
mqIKg
252
250
221
491
180
330
462
312
3.2.191
Sodium Adsorption Ratio
calculated
ratio
3.000
3.300
2.400
6.300
1.600
1.400
6.200
4.100
SM 2320B
AlIcalinify as Ucarbonate
50
mqIKg
880
200
120
460
160
900
200
SM 2320B
Odnity as Carbonate
50
60
160
240
160
240
100
: .::::
z.-xr.�:.,,.:a:.w;:r ••} ....... _. n.
:...: v!x
a,.;,..::!.;<;:!;.:r_},}:!.r.;.:;;..
•.v(:'.:vx::m.w::r
:..r._:rr.: •.:....r;:ur:;}}}•rrsfi:;y..................,.r:.v?.vx
: r: xv;:.4r}:......a•\v'}}^'>,{'t•
•:::
�;x'•S`:
..}}.
.!.::x:::{{>:., .0.01
0.01
0.01
0.02
0.01
x......
:: f:
iyr.Yr:•YrY: }...
:....:v.
-}:AFSravrrnh-0,-v`':%J,
..
...........
2.6
X
:.:
....::::::::..
-r:r
......... ?.:::
02.14
tx�.- ...... M..............
:X?i
Arsenic
4.8
5.8
4.5
3.9
6.7
6.4
2.8
4.8
Cadmium
0.5
214
1.64
2 09
1.71
1.37
1.95
1.70
1.69
Chromium
0.5
mog
1 15.00
11.10
11.901
9.47
8.48
11.601
10.80
12.00
Znc
5.0
g
40.7
311
36.0
30.8
29.1
37.8
32.2
31.6
Copper
0.5
mgIKg
10.70
28.60
17.30
8.66
25.60
18.70
13.20
10.80
Ndel
1.0
ffKYKg
11.9
9.0
10.5
8.8
8.2
10.3
9.1
9.3
Lead
1.5
13.8
14.7
14.0
11.7
10.2
12.9
9.4
11.0
Selenium
2.0
Mol�bdenum
1.0
Potassium
50
mgfKg
4,530
1,260
1,640
2,270
1,510
1,710
2,210
2,490
Sodium
50
mqIKg
1,150
1,050
887
1,220
813
829
1,400
1,280
Calcium
50
15.500
1,560
8,710
4.100
7,900
2,440
4,320
9,380
Mtnneslum
0.5
m
1,850
1,460
1,700
2,780
1,720
1,680
2,700
3,070
Boron
1.0
m
27.00
21.00
22.00
15.00
16.00
23.00
18.00
17.00
?x..
'. x:
..
EF/1r3081A...P.
xn.:.rn..;: y? ...::::.: •:.:.-!.:...::.:.::..!r<!.
::: }. n..fi<}n::. }:. }:}.. k,h•.......
:::x ..: .. ...'}r{}r:
:est ¢
-,.•.:rm:::::....,
:-
S}� :, r. r:.....?.`•..
k•W.xrm.
.},}: t:}.•':..'{t}::
n,.:..x::::'.
W?rr:... Ra}'7Sr..rr.A-.x
;«::.;•,:?.rrr:!:-.
x
:...:.
r.----- iVa .... :.::
-.. rr�
.. ... :..
..4 . r;
r.r.
::::::xND°".�.�
r'•x''^:' ..S:^}
:F.:O
r .... ...
,�.r....Narr.r....
:!;r.�r.
................_.
:x•Nr>:4:.}Zc-}x
:•f{n.: •. :hv:: r.:r
......,..::;,
.a;:;- ::.}:
p:::�<.:<;
...,.n...N ..........
,,,..
4,V-DDE
1.67
uqIKq
2.40
Heptachlor )dde
1.67
uwxg
X.
.. __.......r.
':80 82
�f'A. r..Sr.
d e
... ......:::.•o=....:....:.h.,....::.:,.::::.::::;:.......,•::�
«
4d.1 ...r{r..:xn,.::x.•,
P6 a
1<hl0zinst..:13 n i< . s n
;:::»....:
Yr::�.��r:;:::>;;:..:rn!.}::m.�f:
:.;:;::rs:.
:
..........
...i.•F... �::•r..
:.
xr:...}.�it1.....r,.
.N�;�:�.:
:imii: xa,•
:: :<
>}}�t.,<:.Np>-.vr?r
:s53
:.w :_«
D�N..
;•wi1 .n..xn...,
.b.,.an >.3r �::
«, •-
:.. b..
,•, }
.:::.
.. •
1i274
EPA. ......
y x: f:: «w r.«xx}.w .rx:.
..... ......... .. .
G
$` rili•Yo � lit!}"
.<?!<;!;,?«<!•�:;<}:X.;}r}:<::.}:<{<;{:.:::!..:}:
...................
.... ...... .
•,..;..::
.::.......:.,.:........!::....................1...................ttt............n....N
x:;.>}}X.}} :
.. ..
�... ,
r}}, r :.:, ........
r r.- . ,v:.v... i:..vvx.:xni..
:}rr.m.r►
.......:..........::::..:.::.:::.
r
::.:....
nxr.:. R.
....................
nr .........
n .. •Y
..n.!;.!
..........#t...............�!..11
;:. sr;;::s.:•
Page 2 of 3
EN-1760 - Wilson Land Application Site - Contamination Baseline Analysis
Shallow Solis - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Soils
Lab Simple 0
99-0406-033
99-0406-031
99-0406-013
99-0406-015
99-0406-029
99-04OR41
99-0406-027
99-0331-005
Simple Data
02106M
02106199
02105/99
02105/99
02108/99
02109199
02108199
02102/99
Lab File No.
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0331
Teat
Method
Constituent
Detection
Limit
Units
Pivot 017
Shallow
Ptvot #18
Shallow
Pivot #19
Shallow
Pivot #20
Shallow
Ptvot #21
Shallow
Pivot #22
I Shallow
Flood Pialn
Shallow
Cotton Burt!
Shallow
��y�j+12FR4.}$}:
17R1��j� ::.:.:
:�v. vr.
..:;;-...- ?, .,. :. .. :. ::.:.. :v...v:♦•
f}:}}.k•:vw'l}� .{��y :: .r.} v}5.+tj ..r :.
w.vkvr:'^.:NSR��:MVM.lDllllti:+,?v.♦+:+•�v;
n•:m v::.•.v.
v.4 <'
,-::::..,-::v».n•.
»::::::::::::..
.,5•
.v�.n:::w..:...:n
:: r: n..vvnv.
-. /:::: -�v:-
... .:..
+ ?\+}.•r+F.$.'$.'
xxn?,vmx»:.:::::::
:i�$i�'
...v.. - -,�.. >...
»...?v .:::
»:: m. v:.�•.�.
:r ^}: }:i4}}-
F:::.:::. •::::........
.:x: mv: ^:..•.....v.
v:.v: x:.':.'::
n :.v}x:.::
�`:•}:':?Ll.{3:::
:::`.vY•.
J$?$$4$:•}}:%?•}arm':'
}::.v.»avnvrx r:/..r
rni}}rriEJ$k'}}t. A.�}'}
:Hume: m:r..:,•.vv:
^i $.:n.A........$$$.
.:::::::.v::::.W.....
v v�
ii:k?ti•}: '•':v1r}}}:::}}:
"-.,» r; };, ..
nv$4i$rxr mx.:vr.•.
Total Conform
1.00
coygram
nt
nt
Ilt
nt
nt
nt
nt
ND
..Sit
. :...
EP:A.410.1.�,...:.v>:
a}}••}}}' .:-M
� ..
Tah1P...6ttohutn.. drocati9on.}xk;
..rr:ak•:.».:-hv.'fi
a„r:: r::::::.x
.. s..:t+.w..t{?•:(;.,;?{.::.Ytnvr:Fn-vn-:
.::::.,:.:::::•:::::r:....:::::::::::::::::::::::::.
x:Fr
:..:..:.x...v:x
.}nxxxn-xx:.
.. ..... K..'
..::x..v:r....:.:......
W}.:::}:}}:•i:........r:..::x}
•}:.. ..............
:::a
$$s $x:$r'
ivt'
-'::>+<}}:?.s:ii:k:.:.
_::::::r, .c}»: $$k«
\ .};: ;.};+-:;{^�
TPH
10.0
Mft
21
28
27
11
23
ND
15
27
�.v: r:: x:.v.vr»: x::.
(�� x.'c33`n`0.`
Q tWP}:' Nit. r«1Nflt� .xe«;�
.v; r,•.:w.vnv �
a�e$x::,$$:>+
':nv:
:v::::::::::::.
.�::::::::::•v:::: }:: r.
$:
..:,�«}}}..}.r .v:.•.
�>$$exk•�'x
.a:::va .
::::.•.•.•r:n:. vx.^
.v: :x::.v:::::: :v:;
's«•;;�isf;,;asssri:;;a'
W.•.♦w 'F:.v>
EPA351AM
Total KjeldaN Nitrogen
720,0
800.0
283.0
259.0
1300.0
12.01
1400.0
1560.0
EPA 350.3M
Ammonia
1.0
mglKg
23.9
EPA354AM
Nitrite
0.10
mog
1.5
EPA 353.3
Nh%
1.0
ff KAg
7.7
14.1
2.0
3.2
2.8
9A
2.6
45.4
r.. rr, x.r. F ,,,,��tt
':r.»w..x:r:.v:wn+i.
.....................
EPA 9253
..yy��SS{{,,����tr�y s
... /� tkXr
\+'J.<w:?•} a !.� I :::: ...::}..v:::m
..........� ....5.....YC4i�7iz-l.Rikal n ....:x...
Chloride
............. nr..
., t-:: :r
........:..t•....t ..
50
,.r}:..,w.,r.»:..x:»m:.:Fr:.•r:r.....r:}}...ra>:ra.....
v: nv: w:r:.
.,..?....:.....
..t........}.
v: m:r::: F........ k..
.......... ...........
240
.......................
900
.5.,..r:xa�:::x»mr:r.
:.:::: e:.r»:x: rvrx:
90
..;':'r .:
:x::::.vr:\+v...v:+:
110
::.:,.:»:»::.r::».,•:
?•.'•:$Gr:
:r: ».4. %r...
':::•r 'rn'vrrin�
170
-. r:
-n. a... xx:«a:$..;
t»:rnvrr$,/{
370
;n , :;::'t.}:.
" k"?.
80
��$::::t.:u: r}`:;;::r>::',$:
EPA 9038
Sulfate
50
137
131
60
57
144
302
3.2.191
Sodium Adsorp#on Ratio
calculated
ratio
1.400
3.100
1.000
0.900
1.900
2.400
0.500
0.004
SM 2320B
Alkdrity as Bicarbonate
50
MOO
320
1.040
120
500
640
920
200
84
SM 2320B
AAcd ' as Carbonate
50
320
320
320
200
nt
. " is
T ,�-Y
..1�7 .. M:
'+•*"•""'k: vr. x+.. �....
v.'v$nvY.v T�•}EAU:•}ib}}}:
erg. .rlffifF. i+••... rrnw.•.•n
.............:.r:-:<;;... .............
mmm
..:., .n ... rn
<•:.
r
.................................
0.01
.:::: w::::: -.
nwYKg
,...
.vmvrtrt:..?.........r:»t;>:}:..
0.02
-':F.:.-rr. r:•
........
0.01
r
---�-�----.�..
0.02
.�k:y;
0.01
0.02
r.:
tier;?
0.01
.. �k•..:..xr>.
0.02
0.03
♦ -
'• • Si.
E.P .......
.A.i3t1.1.0.B.»
mvn v
»: v. .... .....
m .:; Snr
... .. ...: .. .o..:•
a v :..x;..:...-....
M M.. 0 . rMx.a:x
.., .t .:?... Eh....� h.. #� .. .....
Arsenic
:::,..:«}}:•
«..
.:: :v:.:v......
....
..................
2.5
: ::v; •rr..
-.:-•:$....::
.. �........tit.:a::?•}:a<c:?•a..;a•:a}:x;?:
....................:.....::........
mqNg
...::•a :.. :...........
.:nnn.-..:: m:::::.
5.4
........+v........n♦vv:::w.::}i}:
x:.va,•..:.v.v:.,- ..:i
t.:::vx:. •: W>n
,..Hell».:x.W$ .>:::...:.:.,.:::.:a:n,:na,:?:.:;..,.......r:xx»x
4.1
:.t+. • }:'t4::.
.::.n.}r. F.�mxkmo-:??..
6.2
:. ..,... ,
.., ..
6.2
try:}}.
h}`;X..
::::..:,
xxwnw�+»,.:tm:.�,�..>twM:.::;,t.::.
6.6
.: ».r:t:::.}3<::S"'
•;};
4.2
nnvnv-.
k.f�,"r7:•N:
.:,?????.:?�::<:::N
:tt.t .
6.7
::f•;•}:
;;:_�:}.•�:;.�
::.t.:�.....<,;.:.:+..
4.7
Cadmium
0.5
mwxg
1.85
1.60
1.65
0.97
1.81
1.581
1.53
Chromium
0.5
mgVKR
10.60
11.80
11.40
8.71
11.40
12.50
9.48
15.40
Zinc
5.0
M09
34.3
36.2
30.1
24.2
33.2
34.3
30.8
42.2
Copper
0.5
mog
14.40
18.70
8.20
14.40
9.15
8.85
19.60
9.93
Ndel
1.0
weyKg
9.4
&1
9.4
7.4
9.6
10.5
8.3
12.0
Lead
1.5
niog
17.3
40.1
10.8
7.0
12.3
12.7
13.1
18.6
Selenium
2.0
motmemn
1.0
1.1
Potassium
50
M09
1,640
1,460
1,860
987
1,600
3,450
1,430
5,030
Sodium
50
M09
771
893
1,120
564
653
901
309
259
Catdium
50
mqft
2,950
3.0401
2,310
1,370
2.480
2,960
2,480
6,840
M
0.5
mgffg
1,660
1,520
2,140
1,230
1,630
1,680
1.510
4,080
Boron
1.0
mg/Kg
18.00
19.00
1&00
16.00
20.00
25.00
18.00
9.15
•Y�
>..
EPA.8Rt31A...
vv^.y9Y^v::.r..:ka xx?15r ik•`:
Pe#tlOMar...r..k:»x.,:...»....v..:...:.
::�s$
7GVf}'}+:'GC:.
:t•:': NQ.:......
:.:.:..,
..
$:fi:
:?�;::::}4'•:'�$'':•�=:
�:
4,4'-DOE
1.67
3.35
tachior a
1.67
UOg
GP .'l31t3 •�::.
. .. ...
f et• : des:;r�wr::;.:.�r.}.>Na
es cNd .�Herbht ......vs...
: v
:. h •0t
P.0 .higHrlhta�0 nG
•.::?}rite.
.w .`s:&»>
tit. .....':;.}
:W}: Y} '?•i}ire.
� . r
'`
.....::n
....
.: ::::::;n
.........
;.it:;::
....
:r�•z
? .},
EPA.Qi�".54#n..Y.ia11..
+...:,.: ,...:...................
.. ». r:
....:rt..................v;:,..�..
v;v..............,..,?t:.......:Y;;:,.Np.»:::,.:,tt:.,t;;.nt.....,-.r<.,:;tt.}}nt:,}::?t:}:.....:�.NQ...................n#............�}v<.:.n.....,.....
vrr}::'}:.....:...:....:
::ire?•;
::.:::....
:; :::;:?:
'f. r w
Y..\.;�?n;
..trt:;n:<;::�:�:>.......
Q':;t.}}}:-;i:
Page 3 of 3
Soil — Deep Samples
Detected Constituents 1 Parameters
EN-1760 -Wilson Land Application Site - Contamination Baseline Analysis
Deep Soils - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline -Soils
Lab Simple 1!
99-0406-026
99-0331-004
99-0331-002
99-0406-010
99-0406-038
99-0406439
99-0406-006
Sample Date
02108199
02/02199
02M2199
02M4199
02/09/99
02/09/99
02M4199
Lab File No.
99-0406
99-0331
99-0331
99-0406
99-0406
99-0406
99-0406
Test
Method
Constituent
Detedlon
Limit
Units
Pivot #1
Deep
Pivot #2
Deep
Pivot 93
Deep
Pivot #4
Deep
Pivot 05
Deep
Pivot 16
Deep
Pivot 97
Deep
Y.�t
Total Collor
1.00
coV
nt
1
ND
IM
M
M
nt
:}G}}
::.3r$"::
:•.^•....
:rP.,}:fi}.h.
.r rr 4..,.:::..:::
::55'+:.
}.:., •:: n:..: :.::•..:.
..,�:::..::..:,i}rw
.. r.✓: i7,S..:mn.
r rn.:..:-: ..
•: x..4�;::,I,.y'.•:v
-::.v:Nx:n.:
::,�"\ii::i:;iv::+n '::
.S.•.
is '^:cv!^,.:ax Y}
} W:11
TPH
10.0
MOL
nt
ND
ND
11
nt
nt
j, }
i}i}iv
EPA 351.4M
Total K eldaM en
1500.0
444.0
498.0
490.0
43.0
13.0
370.0
EPA 350.3M
Ammonia
1.0
MqMg
19.7
38.9
EPA354.1M
Iffte
0.10
nvfflg
1.1
1.7
EPA 353.3
Iffbate
1.0
Mog
3.4
16.2
14.2
3.4
1A
4.1
2.2
EPA 9253
in t YN
Chloride
50
Mgxg
240
500
230
340
310
220
EPA 9038
Stdfate
50
M09
147
131
119
342
3.2.191
Sodium Adsorption Ratio
c deulated
ratio
2.200
0,008
0.012
1.600
2.600
1.900
2.000
SM 2320B
Mdrity as Bicarbonate
50
mgfKg
440
820
98
240
1,480
200
SM 23208 1AIkefit
as Carbonate
50
320
nt
ntj
240
400
1,040
s
`1:PA :!
"x47
.x. :.nK .
etcu
M
:.•:h: ^-'
0.01
9
.iC::y::•v%v5:`ntiTi$
0.02
F'>3i::
0.02
0.02
0.02
0.01
iv
EP 1C
:6010Bx
} •:.,a;:•t:•'.•r.':•:
.Ww�:xnv a
;•:#letafs'x" d nICl::t .
dir
v�..v ':.
%::fS::::
Mitt#.
: �;-n
':iC}i:,+ :">.'•.
::::k9+xs:.,:::ti':'::
" Y'7:: •s
:::�?:� ;�}$i
:'•\
:.::^\+?:;;•::
.:'�.n.
.vl :.S:n. .
�..,�.•arx,: �;,•^`:
S^.?:::Gr'r::ti:nv::
Arsenic
2.5
nwyKg
5.0
3.1
5.5
6.4
5A
3.3
Cadm6mr
0.5
nvftg
2.07
1.92
2.09
2.26
1.42
ChMrrf" n
0.5
Mqxq
11.60
11.80
15.30
IZ30
16.10
17.10
9.87
Zinc
5.0
nwyKg
34.5
28.0
38.4
34.0
40A
44.6
25.1
Conw
0.5
w.YKq
11.20
6.04
8.47
15.40
9.98
1030
7.34
Nickel
1.0
10.5
9.8
11.7
11.0
12.2
13.3
7.5
Lead
1.5
mqIKq 1
14.6
12.4
16.4
14.9
17.4
13.1
9.4
Selenium
2.0
nxyKg
M emum
1.0
1.2
1.1
Potassium
50
-TOL
mfyKg
1,360
3.030
3,630
2,630
3,760
4.290
2,110
Sodium
50
mq1Kq
817
757
929
1.310
1,280
1.120
1,090
Callum
50
mqIKq
9,710
58,800
12,100
26,2001
16,300
4.470
5,940
Mamesium
0.5
mog
1,510
3,460
3,460
2,9801
1,760
1,760
2.260
Baron
1.0
MgL
24.00
5.99
6.07
20.00
29.00
34.00
13.00
8 8
EPA 0 A
:::.v.
Ds i m+}}}G}}}Y.•%•,kv:::: :`S:.
.tic lei ..:. x::: r::: ri: xx:f: �o:u:} }}}:,...;4
w:x
4.::.,.::..:
n}Y:i'`>`<:%:.'r
r:.
Gam':: �`}...::: ;::.t:.
;• tl. x. }xn:.:
-::.:.::
x: r::.. :::; s}x
:<:}?}:::. ' ..::::.
-.}>:i:.i:;5n. ;:`�^.}.•..
NY•r':''�r.:'�r'
rY1.Gx
ri?:r'�.''::
4,4'4DDE
1.67
Heptachfor o)dde
1.67
.
EP1k. 8151 4s
EP :8082....:b
..A... ...x.hl.4.tilt4t:«::Nt31,.,n,.:::.�''-->:rtit`x.x..v.
4h .}. xxk xr.
},. . 3•..: x}:::::::aSrxr
.estiddes.l` . er eTdel:.�>%•r <:r::m:x::. n
.N bi
.
c
r n.ww .nnn.
.r.}::rxr:Sxxx:.
.. f«.:;.%;::,i:...:.
;:.}}}.:•mr<;:a.,;:.
r..mti•:4>ii}}i:
.n n•:n n"::::.:.
x�.
:,'.:: ,.. :r.•;
:4}}%.}}%•. ...................
:Nfi.
,:,:}<}>}:n <N<nN.,
t........
.:,,:::rx: •: :n.:.x:n
. ,.. iF;..}
<•• ,C:'x
:sz's,.::
....... NQ:�.}:.;:
.,.... ..Y:i1G'�'.
:...,r\:} .........
.•Yxn.. x<::}
;;;;;.�;::ND.........«.r:,,;.n
: -M. :;:::x.,.:nY:;::}:::.
.........-.- .,.
if<}}f.;.. "ti:S':';;i
t:r;
...a<.....;;•ri:;.ri
..
, <s
o:h,^.N,?; ,<' .a:•i}Y :'
: t xx.....r.
.......;.....:......#tt;:wN::v,.h}.:.nt}:..:«;.:.}
?a>:::}:-
�:<j<�3:it-:::�;:«.:Ffis#�;:::�1
Jrw:: "',i>
,
' t:.a.. .:�:r.
".'+;:5:' i•.i fl':F:
...itt�•':>N{::::
...
..r•:
1s2 oc�.
l4 7
.. ..
,. ;.:':. .. .. .v..'r' �......J'}i}i}u ii,
ri . ...t.
sen,lv,il n� :.w`S.:w:.fi:...n .F.rY.v}::::}::,,.
sR .r:::::::::...w:.wry%<.:�,,,,..}:«.....................::...r::..:......
vi}}h. :}�»i}-
r:.r..v<.:r.r....,:}.
v:.:ir:•:
f;•i}}%: ;:: •:: .... ;...;
:;�}: nt,:�::r. .I.in
,,,;,.. ,.n.�;:<.:
ND '�
;:,,..:->:. ,..:
.i
��tti•v :... ;J}}:4:w
:r.;..w}}
............,...x.:r:
;v
v
Page 1 of 3
EN-1760 -Wilson Land Application Site - Contamination Baseline Analysis
Deep Solis - Constituents and Parameters Detected
EN-1761
Wilson Land Application Site
Contamination Baseline - Sells
Lob Semple 8
99-0406-008
99-0406-036
99-0406-Oi8
99-0406-020
99-0406-404
99-0406-022
99-0406-024
99-0406-002
Sample Date
02/04199
02109199
02105199
02=9
02/04199
02105199
021009
02/04199
Lob File No.
99-0406
99-0406
99-0405
99-0406
99-0406
994406
09-0406
99-0406
Test
Method
con2tItuent
Detection
Limit
Units
PIMIO
Deep
Pivot 69
i Deep
Pivot #10
Deep
Pivot #11
Deep
Pivot #12
Deep
Pivot #13
Deep
PIvot#14
Deep
PIvot#15
Deep
�Micolffoyffi
220
�
f.
',-Nn,-Iffilm�
TON cortform
1.00
"t
nt
nt
nt
rd
nt
nt
114
--gwown
MMO!
355-77
MUM
TPH
10.0
mwxq
NO
nt
nt
nt
nt
lit
nt
nt
55
IMMORM
EPA 351AM
Total Kjoefil K"en
M7%g
460.0
380.0
- 530.0
450.0
760.0
1000.0
350.0
EPA 350.3M
Ammonia
1.0
mog
EPA354.1M
We
0.10
mog
OA
0.1
EPA 353.3
Kdrate
1.0
mgfKg
10.0
2A
.5.8
3.8
1.6
5.2
5.4
w I-TRI-ty-
'-w-F-7-7,
2.5i"=.-
mgw,5
ANN"
EPA 9253
Chloride
50
mgtKg
350
300
650
360
560
310
280
270
EPA 9038
Sulfate
50
mog
393
254
373
232
606
93
83
312
3.2.191
Sodium Ad Lion Ro5o
calculated
reft
3.100
3.800
4.300
2.800
5.100
4.700
2.400
2.500
SM 2320B
ARM" as Bicarbonate
50
mg/Kg
240
1,320
200
200
300
400
240
500
SM 2320B
as Carbonate
50
nxftg
160
40
160,
240
240
240
rLrr
Mercury
.........
0.01
-'0
....
mwx9
ME-
0.02
0.02
0.02
0.01
0.02
0.01
0.02
Arsenic
2.5
1 mTX9
4.61
5.4
6.4
5.31
6.7
5.6
6.5
5.01
Cadmium
nO. 5
mgIKg
1.71
ZO?
2.03
227
1.76
1.44
1.68
1.81
Chromium
0.5
mqIKq_
10.80
15.20
12.60
13.90
12.50
9.30
11.00
12.00
z=
5.0
mog
31A
41.3
35.8
40.9
34.6
28.5
33.7
32.6
CMW
0.5
9.15
9.75
15.80
21.00
10.70
11.70
17.30
15.40
Mad
1.0
_TOL
mglKg
9.1
11.7
10.4
lZI
11.4
8.0
10.1
9.6
Lem
1.5
nvyKg
11.2
10.4
23.1
14.7
112
8.3
IV
12.0,
seferft"
2.0
m!YKq
MdMentffn
1.0
PAL
Potassium
50
mqIKg
2,380
4,640
1,470
1.780
3,410
1,540
1,380
2,190
Sodium
50
mgtKg
1,180
1,210
1,320
972
1,530:
894
1,030
1,130
Calcium
50 1
mqXq
5.970
15.4001
6,340
16,400
15,900
17.2001
4,370
6,560
Mavmsim
0.5
rrKYKq
Z770
1.770
1,570
1,740
3,500
1,8201
1.640
2,540
Boron
1.0
m
16.00
30.00
24.00
27.00
20.00
17.001
23.00
20.00
4.V-DDE
1.67
Heptechfor q)oxida
1.67
ug/Kg 1
WEMAIN
PA-41
Pj�kNe'S-*':j-
ER F-7
:i .. ..... .........
t
....... ft't ..........
.........
Page 2 of 3
EN4760 -Wilson Land Application Site - Contamination Baseline Analysis
Deep Soils - Constituents and Parameters Detected .
EN-1761
Wilson Land Application Site
Contamination Baseline - Soiis
Lab Sam left
99-040M12
99-0406-034
99-0406-032
99-0406-014
99-0406-016
99-0406-030
99-0406-042
99-0406-028
99-0331-006
Sam le Date
021009
02/009
02/06199
02105/99
02/05199
02108/99
02109/99
02108/99
02102/99
Lab Fite No.
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0406
99-0331
Test
Method
Constltuent
Detection
Limit
Units
Pivot ft16
Deep
Pivot #17
Deep
Pivot 918
Deep
Pivot #19
Deep
Pivot 920
Deep
Pivot 021
Deep
Pivot 922
Deep
Flood Plain
Deep
Cotton Bum
Deep
..n,•
uM p •:.
Sid:922213;. .,,.
: n•,.• r .µ, r
S:':G.W#•.:}:`Y: T y �t t� :Y. : riR
-n-n•...r n
:,Srn::...k�i\.t:.i.QDD/.V.tii1Y:;^:'x,•::
rr, w..,Yn. :.:..
r .2.,Yr.,.: tr
. ..::.•.�::,•:
:�,MrcY
...
d.,a:::.ws�}
-,,,.:..Y.:::.r::
x::<;J•:;: •.:>}r::...<w}}>z
n„t •-xn:r .•
?wt; ;.!,ri.:.. .:?,
.:.. n.....
w'r }};:
..:n•Sk
�?•,.:`: •:='::c:
............ �..
wwsh•,is..�i:.:;::}::}•.::•i•w
.....r
""- .:•:}?:4So-SGaS<S:
.+.a iw..
:::., ....,�,.,.-.,.-rrr...n
... :..:.,,....
..,,":�,•:'1 r
xxaixSis:S:a;- Y.a}}
...:Y,..•:
,.«..::. :Ar.J.s:::w.
n...
%:t�: .:: :rr.':�,Y
::•..,,,,,.` .,Gr:ry ..-
r. .. t�cy'r:#
.v::.Y.:
Y:hf^' ••}�}x!/.:
.. .::..ry.. n,..::
:{�' tx. :/:i5k:,'ci
.r}f'`�:�•:,:: .Y.:r.,.
.
�:3rrs'.:•#Tt:;r:.:::q:
.n i:rsti}5::
,�,r:n.::. «.
Total Coliform
1.00
eoV
nt
nt
rd
nt
nt
nt
M
M
ND
�: , •.
:4 8
EPA..1 .1...
::.•:.•.•.
a d rbv
.Ta a' :etr !um'
t I:P ... ... to..
.:�}•N�}sn�,w::.:};::�.:s::
�:::>:�
.r�.:.<;
J
::�:.
>}
Nnt
TPH
10.0
mgrKg
ND
nt
at
at
M
nt
M
ND
.v,.:::n.......
�•,�nvr::r:w::.:vn..K..Y,. .%,,$Y:...
... ........ n.r........6Y.
..:. ::.:t:w::i:.:.::.:..:..:..::..,:...:. Nftmd6ti..f...Nltri�tbia.r... .S.i.rrr.,A.�.n.\.�.
x:
n
.
WNW,
.v
.•:•}}Fv
:}:.}....i:.l:. i:r:.n��;.:•�•.r..'..i:::::
:.¢'.^.?!:!l.` :fi•:tii:;$i.^
::Yiin"{•i•':,v
Itw
EPA 351AM
Total K'eldaM NitoM
I mgIKq
380.0
20.4
7.3
360.01
440.0
880.0
14.0
1300.0
410.0
EPA 350.3M
Arnrnonia
1.0
mg/Kg
24.7
EPA354.114
INitrite
0.10
m
1.4
EPA 353.3
Nitrate
1.0
mgjKg
1.6
6.7
5.0
1.0
1
2.8
1.1
12.5
_...................
............................
.....................
EPA 9253
....... - . �nn� :
..........�/»..��lrn ..........
Chloride
.}k::.,.,;::ii
.�,:. n.:.:.
............ n....
50
::t-:tt.... ..
. rr}}iSxG
.n.:... ......
- .:: �: �:r: ,,,..
�i9%..er}.:`. 'i.}w
- ......:Mf.
470
..-.- ::::n
.':?VSS:isi;:...,�,�...
300
:r:.�;::.:r r1,,.a.
:'.'•Y:"`
tw.,.-.rr ...':n.}..
.....iNK•I:�Ktit
450
is :� x .. ;;:::::tom."-;
.,...r.:.:.:_:,,:i}:..:...-::;.::.:;;r
!. 'k?. ,.......
90
, }:'#.. ,;}i.:4"�Y�-�!::
...
130
2:r'%%.y.�r ,•n
�••.------w.,;5.ow::,n.
150
.���µw ry.::
%{"iN..iSS.Y.ii{{xyv..x:
200
"'1G::;�^
r.;,`'3,:'r++;+,4.rr �}
60
rfix:;rn.
-%%c�Sov:t:,-sarsh:.`'::
60
EPA 9038
Sulfate
50
511
230
220
91
110
268
3.2.191
Sodium Admption Ratio
calculated
ratio
3.300
3.800
4.400
0.800
1.800
2.000
2.000
0.500
0.004
SM 23206
IMalinity as 8karbonate
50
nvfflg
200
400
440
280
40
1400
960
120
30
SM 23208
Alkali ' as Carbonate
50
mglKg
160
480
320
1
560
80
nt
: :?
' :1 -;
.....r: .:: .:. rv.vr,.v:.•::r. °^,:!}(nt rwr}
.••• 'i:F.w:.,.}}n,vr:nideu'ev Y •«:c}i •M.xr�:
M
.r..�, n'ins:{.:.vYFrv:4
;:wnv::
0.01
.'v: w•}$±�+s
r.v:
.:i. :r:'%nv 5i.
':in;,ir,..v..:n. ...::.
0.02
bi ^i'y ..
n....:.. ... r.::
0.02
}:n.... r::.....
0.01
.Y... '''•J8'';',.::'}
rr: R2
0.01
-_..'ti}r
.n:, }.LrYi......L.. n::!}::
n n�
eF:-}}}}:vk'•�i
0.02
,v:C•i:56• r"
vw.3i�5.4'45k:vi:`.Si':+m..
:nwr
0.01
rcnA'Y `r>:..
0.02
...
. ::;.
EP .60 tin
A �
,r. '��.}s:«••
.. ..
.e}r}x tx.Metal .Ino hcs.w �w:....e.�..
r
.. t . ......_..
Arsenic
:ras>s,s:?:<;:�
r.....
�ii�t.:<;n,..............>...
2.5
� vnner}:}}:.
.'ri::. :n•.
.}}:. .S
.,. •:::: r
x�a:z}:
:• ..:.t'...v:n': •
:r::.
,ittir,.}.,.:..t:,:<....
3.5
iC. .:.}:
.;t.. ::}':a:`::
•..,....a:t......>:::
6.8
n:} ::»..•
?:}x;x>:n^:
i.:ri..
5.6
.
`\=3i`
fi,.. #.�ti::d
3.6
<r..;:a:}>:>::>:.>i;•a•:i::•s>:.,
,:,,:}:
5.6
:,{,. :.if a„
6.0
Mom. }:.x
4.0
::3w;•.R;: N}wSc',•`Y:::
3.6
rr} i:.
r,.t
Ce"Urn
0.5
mog
137
2.20
2.20
1.99
1.57
1.93
127
1.65
Chromium
0.5
mqIKg
10.80
16.10
13.00
11.66
9.90
12.20
17.20
10.20
14.40
Zinc
5.0
mog
30.2
43.9
42.1
32.9
30.8
33.8
42.5
31.3
33.8
Copper
0.5
mglKg
8.00
11.20
19.10
9.14
1730
72.90
10.50
11.60
635
Nickel
1.0
9.3
13.0
11.8
10.0
7.9
10.9
13.3
&1
4.8
Lead
1.5
11.41
17.1
17.1
115
12.9
13.6
14.5
21.8
7.3
Selenium
2.0
mqIKq
Motodenurn
1.0
mqIKq
1.1
Potassium
50
mqIKq
2,520
4.310
1.860
1,420
1.110
1,540
4.280
1,4501
3,920
Sodium
50
mTxg
1,360
1.200
1,160
881
655
823
948
4091
171
Calcium
50
nwAg 1
13,600
7.060
10,200
1.4801
1,580
9,580
6,000
1.4201
4.550
Meg nesium
0.5
rnqIK9
3,240
1.840
1,710
1.590
1.340
1.590
1.840
1,510
3,850
Boron
1.0
16.00
33.00
27.00
24.00
18.00
24.00
32.00
18.00
5.48
EPA.._ Bik..:.
.i+.
. sc}sr:yt
..�.z..
t ':SGi}}J }i}xr::v.:. ii:Ji-'v' ::w.(No.-v:•e>ir•
Fss. kidrn.:::::::::::.,.:::::::nn..n.:::..�`}}n:s::.
'�••r,r,N�
4:rr:.Y:.t�t
iii•
• ant. �->:
�:�....nt.�:>�w�;nE..Y
�:'
<:::bE;:::
:n�>}C:
,.Mn
��'.`r''ti''r;,dt-
:.}
?q�.:. :Iln�iN.-
t.
nn :
-.]n"',:::: .'�.r�'.n wv:
<�:n..Y..
4,,V-DDE
1.67
H tachior de
1 1.67
ulyKg
Et'A:8151A• .
.«
..
�, . irides:::;
Pestktd i.Hftbt rn..n,.:rrr.",rn..
r. r...�•«i.}' ii::;i..a •
-�}}� •}
a::: r s:
� �-.w,::
......,.........,
}w}:}w}s:?Ya
•:tt.,:i.:::...:}Trt'
......:...
. ..:• 5'' • ..
�E .: eY:.:
:.... .......
:,'••Yr}y,':::
`�nL.;i in„�.-
, :n•: • .wn ...nJ
,'�. Yi:�.:
..
.a:.;•:i:a
nYnt>:.in:.:.:,:.„;i<«i.:,nt
..
MaGs,fr.:.. :max c>.
.........
r' (-, r lists
Kn,.�t .,,...............n
a.
.•:i#s}.::v::,..:
,si 'E>s'
..`..
::;#::oz:
. wear nt n
....::,-:. ND' Y
. f
EP.A:tlo82.:.
'
P0.. tiro•.�.
�
}Ar
. ;n :;: •
k......:..:r.,..r:n
ta:
. . ••:.;,::>•:�
�:
h :�#>:r
. }:..:b ;> :
mv;�: ., .�;�;.>:'>
:s;��.:,
. :.•w,Y..
0 .5e
..
:..v.YS:.. ..w•5.
. eta111 �n>•..ix .. ... '#ih'n.�..it?a..
mN1r' ei:::..,...:«:,i...-:.;:;�.r..:.::..,.:.;:>.:<i
r5: rvr .......
... m;.::{.,;•.:.::.
..::.:.......f.......:..
rv{......
).
ny.:. nv.
...i K } :S::r/.7•.
:..:... ...
a,.rnt:,..Ni,<,
.: ,:».,w: r:.w n
nrr:rr..:n
.......... t�:.,�;i.,::ria..
::::::
Yr.} .,+,{.
�:n:}.::::.r..n..,:::x:nt•�.�.;>:..r:...-,
t.....r.,
v;.J' ti}}:...
;;
,......._ ...x<..
t:�::>t•:;'>':.w.Y:
�....>z.n_...,�,...,........h...................
,:•;}::
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_......
::5:'
i:bt:.v :9i#`':tia:::,
.a::..:�. .....:.:%,,:
.:nit; . {
57:
Page 3 of 3
Appendix D
Sludqe Sample Results
Detected Constituents 1 Parameters
EN-1760 - Wilson Land Application Site - Contamination Baseline
Sludges - Detected Constituents / Parameters
EN-1161
Wilson Land Application Site
Contamination Baseline - Sludges
Lab Sample #
99-0488-001
99-0488-002
99-0488-003
Current Baseline
Guidelines
Sample Date
02116/99
02116/99
02116/99
NSSS
National
Average
EPA
Sludge
Ceilings
Lab File No.
East Pond
Mddle Pond
West Pond
Test
Method
Constituent
Detection
Limit
Units
East
Pond
Middle
Pond
West
Pond
Low
High
Avg.
SM9 2228 .:
otst•1; rf .:
.::a.,,;$$�;T ...I.....rttr.:t .�. �.:::::
•::r�$ �::.
..
ii:k,.. a>N
�:. ix,..
.ri,,:N t.:.
�::k:V:�;,':.$
..:x::0
> .etf01 :i f6ca fG ...;}� ;;
e
.vr:.:r
:.•:.y$rv::::::.,:•rv:
., �:�„•
^^':'^.}">::'r
:?:;t'
:::s:.,
,..&x:
x:. �$.'}c:»:c
•::;'�i::v:%$'ria:•
y;.', :$rrz
;5•lsf
.;�.;:;.
i3::^v?<
.:G$$i:%i«S -'
:3$$;fi:'s•
TPH
10.0
mg/Kg
97
NO
49
NO
97
49
TPH (Reservoir Water)
10.0
mg/Kg
NO
NO
NO
NO
NO
NO
...:
.. .xww,:.-rv.:.: n,.-v
•..•w„
:::::
,M,x::nvv-:-:
,x.•..vx:rx:...-v:::r:.
..v4,v::.v.:::
.' ."".^,`a,•,.
::f1.:
""
:N4
EPA 351AM
Total Kjeldahl Nitrogen
3.0
mglKg
1,630
1,490
1,460
1460
16301
1527
EPA 350.3M
Ammonia
1.0
mg/Kg
20.6
26.3
20.6
20.6
26.31
22.5
K•vt:.
:vi$ }"-'N \•.:roY.L'+:v..v:n
�.ry
:6C,[}}{Yn:k i
;v$}�tohsl�CaGo s:f• >Kahn
m$
::
:•}S$fih:
•:: li:S$353�:}vvi'.v:.
:: if::::
3}$$x'}'
.'mnr+:"^'vv iiv:{ry:.`rp.
m'{im.:: k.
'>.~�.:
}}xt.,
:'i$%/.......
::
.v mw ?'.Sii'
-ij%$Y}:+fi. ♦
.:Q:r-Si$$S..}nv
EPA 9253
Chloride
50
mglKg
400
390
240
240
400
343
EPA 9038
Suffate
50
mg/Kg
2,050
2.870
1.360
1360
2870
2093
SM2320B
Alkalinity as Bicarbonate
50
mg/L
1,280
720
720
720
1280
907
• !t>..::$::'::;:`
;� inn
t:S:<:,
: :'i?Slv.?'?'
+. 5
Vr33:.,I:.
�.
Mercury
0.01
mg/Kg
0.35
0.17
0.16
0.16
0.35
023
4.1
57
:: ,..
;6(N:0
-.-:: -: : -x:rrv: .::. :.,< :..,:::..,.,,.. x:r,x:r. ,..,�:{::::::
.�•�' eta stii'cs .
.,:M is-f. .:
ttt..::rvr:rv{.,:
_xx.r-:: ,{,.::.:
s.^r.rtsN
;,�;•$$
y�,'
N:}:$$$
i.�.
N�$:.};;'.
Cadmium
0.5
mg/Kg
0.84
0.64
NO
0.84
0.49
85
Chromium
0.5
mg/Kg
14.00
7.28
10.80
7.28
14.00
10.69
258.0
3000
T=
5.0
mglKg
66.3
43.9
61.1
43.9
66.3
57.1
1693.0
7500
Copper
0.5
mglKg
26.4
15.8
21.7
15.8
26A
21.3
665.0
4300
Nickel
1.0
mg/Kg
9.4
4.4
8.3
4.4
9.41
7A
77.01
420
Lead
1.5
mglKg
15.81
9.1
143
9.1
15.8
13.2
195.0
840
Molybdenum
1.0
mg/Kg
3.5
2.1
3A
2A
3.5
3.0
13.1
75
Potassium
50
mg/Kg
1,780
1,130
1.170
1130
1780
1360
Sodium
50
mg/Kg
672
628
513
513
672
604
Caldum
50
mg/Kg
13,400
12,000
6,130
6130
13400
10510
Magnesium
0.5
mg/Kg
1,430
1,120
1,070
1070
1430
1207
Boron
10
mg/Kg
11.0
NO
11
3.7
EP��8. rr
� •'s... •}}}3}Niv ".vmv.•:x:.
..:e..�..tf+�..d..e.....:.:::ru't.,'us.,t•°:.fi•$.fi+':F.:}.:•rv.^:^:::.rr$:. $:$:S.$:$S$:.$x:$:S:..::.rv.«w:.:, .{:{::«.:.•$..?{.`...:.:..•.....:.:. <
}ii}i}..... }:ti; :•::"
::.x. :.,•.:l.:.n.....,k::.:,£:•+.:
.•ro,'J»6}%,:GiJt.:•
:$x: r:::: :::,...,....r,.
..�...; ... .....:.m
..•,:.Gr.»9xF.S:::..N x.$:F:::::•:-:-.-,:
.v .v.-... :}}yr.•:LX-:i
..}•S.;rvFOrvj;x:^' N , • :•.-.
•,•tt�a:.try
.R
r
p
p$
.•.•i}•i..P,.k•2'".••r....:i:
>.8....1...6.
t
7H.
�'
D.:
:.
•' •:;S�it}:9s:
$.'r:i:,<'3•:4i.5'•''Si:.{i::
...e.3.t.C....dS
..
y1p pp,nx::rv-
N'
'M
N.
:VME :
T:
:i.
•.
EBA.827.00M•
. lJ � '%.,,,};$:{:{^F ttit4}:t $':.\:i:.,
S4fii V. I�trle.�:3,��:..:�.�::.::.r...........x:.....:.
........:}::v
}:}�wrxr,�rx,.,
::. r:: e:ro:::: nz:
,
' i:4�:. r. .....
xx.ND
}
,$�x::::,ND... .
}xr:{::..NQ:,,t:.�:..,.ND�
�?<ND::{.{:ND��
•r : } v:
�><{:...
<{�::{t{{ttt<;,t::
Page 1 of 1
7
Appendix E
Laboratory Reports and
Chain=OfCustody Reports
(Appendix E is bound separately from this report)
r
e-
Baseline Assessment — Appendix E
(Laboratory and Chain -Of -Custody Reports)
Wilson Land Application Site
(Municipal Wastewater Land Application Site)
3,943 Acres
North of Wilson, Texas
Lynn County, Texas
Project Number: EN-1761
Prepared for:
City of Lubbock, Lubbock, Texas
� N PRQ':Ec
Ergineed g soluHon�s vAh o view for tomorrow
6310 Genoa Avenue, Suite E, Lubbock, Toms
(8M 794-1100
March 1999
ndix E
Laboratory Reports
and
Chain -of -Custody Reports
A Separate Appendix to
ENPROTEC's Report
EN-1761
"Baseline Assessment -
Wilson Land Application Site"
> � � 2209 Vviscons_n S!r. er. ,;-:ate 200
Dallas, Texas r5229
9 72.620- 7966
S00-394-2672
� 1+'11'�nfr7enla"! �aDnratvries, .�.�. 972-620.7963 r-aX - Hrra.il: cerie-C . a-nixom
�- CERTES ENVIRONMENTAL LABORATORIES
ANALYTICAL REPORT
Certes File Number: 99-0307
Client Project I.D.:
EN 1761
Prepared for:
ENPROTEC INC.
6310 Genoa Avenue, Suite E
Lubbock, TX 79424
Attention:
Jerry Oldham
Report Date:
02/26/99
Included are the results of chemical analyses for the samples submitted to Certes Environmental
Laboratories, L.L.C., on 02/02/99. All analytical results met Quality Control requirements as set by the
industry accepted criteria. Please refer to the Laboratory Quality Control Results section of this report.
This report must be reproduced in its entirety.
Sincerely,
Certes Environmental Laboratories, L.L.C.
4
v
Amy LaSalle
President
i
2209 Wisconsin Street Sui:e 200
OaNas. Texas 76229
072.620.7. 66
IMP 800-394-2872
972-620.7963 PAX , crrtati: certas a::,.corr
February 23, 1999
CASE NARRATIVE
ENPROTEC, INC.
99-0307
Samples for Certes project number 99-0307 were received at the laboratory on 02/02/99.
PEST/PCB -
LCS/LCSD recoveries were below acceptable Certes Quality Control limits. The results ran low
due to the addition of fluorisil to the extracts. Pesticide analytes typically have low recoveries
when fluorisil is added. The fluorisil was added because the samples were also used for PCB
analysis. (PCB's are not affected by fluorisil.)
The samples (307-1—>3) had no reportable values. However, fluorisil was added to the extracts.
This will reduce the recoveries up to 75%. The peaks in the chromatogram were extremely
small, and it is possible that the results would still be below the detection limit.
No other issues were noted during the analysis of these samples. Please feel free to call me at
(972) 620-7966 if you have any questions.
Sincerely,
Alicia Garriotte
Quality Control Manager
Certes Environmental Laboratories
F
Results of Analyses CEL File No.: 99-0307
Report Date: 02r26/99
i
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared
Analyzed
By Dilution
Client Sample ID:
WELL 10932 0201991400
Sample
Number:
99-0307-001
Date Sampled:
02/01/99
Sample Matrix:
Liquid
Time Sampled:
14:00
Sampled
By:
LW
EPA 6010B
Arsenic
<0.050
mg/L
0.050
02/04/99
02/04/99
KJC
1
Cadmium
Chromium
<0.005
<0.005
mg/L
mg/L
0.005
0.005
02/04/99
02/04/99
02/04/99
02/04/99
KJC
KJC
1
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/04/99
02/05/99
ADD
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/04/99
02/04/99
KJC
1
Copper
0.010
mg/L
0.010
02/04/99
02/04/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/04/99
02/04/99
KJC
1
r
Lead
<0.015
mg/L
0.015
02/04/99
02/04/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/04/99
02/04/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/04/99
02/04/99
KJC
1
EPA 8081A
4,4'-DDD
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
4,4'-DDE
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
4,4'-DDT
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
�..
alpha-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
j
beta-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
alpha -Chlordane
<0.05
µg/L
0.05
02/04/99
02/08/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/04/99
02/08/99
JCA
1
Dieldrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan 1
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
Endosulfan II
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
t
Endrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endrin aldehyde
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
i
gamma-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/04/99
02/08/99
JCA
1
Toxaphene
< 1.0
µg/L
1.0
02/04/99
02/08/99
JCA
1
1
"Quality Control Surrogate
02/04/99
02/08/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
63%
60-140%
02/04/99
02/08/99
JCA
1
Decachlorobiphenyl (SS)
77%
60-140%
02/04/99
02/08I99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1221
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Page 2 of 13
Certes Environmental Laboratories
Z2C9 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872- FAX =-2-620-7963- Email: certes@aol.ccm
'L--a:ytical Chemistry Environmental Sciences r-esearch Microbiology
F
4
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-001 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8082
Aroclor-1232
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1248
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1254
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
"Quality Control Surrogate
02/04/99
02/08/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
63%
60-140%
02/04/99
02/08/99
JCA
1
Decachlorobiphenyl (SS)
77%
60-140%
02/04/99
02/08/99
JCA
1
EPA 8151A
2,4-D
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
2,4-DB
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
2,4,5-T
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
2,4,5-TP (Silvex)
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Dalapon
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Dicamba
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Dichloroprop
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Dinoseb
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
MCPA
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
MCCP
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
SN19222B
Total Coliform
2
col/l00mL 1
02/02/99
02/03/99
BWB
I
EPA 418.1
TPH
< 1
mg/L
1
02/03/99
02/04/99
SAB
I
EPA 8270C
Benzoic acid
<50
µg/L
50
02/02/99
02/08/99
AN
I
4-Chloro-3-methylphenol
<20
µg/L
20
02/02/99
02/08/99
AN
I
2-Chlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
I
2,4-Dichlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
2,4-Dimethylphenol
< 10
µg/L
10
02/02/99
02/08/99
AN
I
4,6-Dinitro-2-methylphenol
<50
µg/L
50
02/02/99
02/08/99
AN
I
2,4-Dinitrophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
2-Methylphenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
4-Methylphenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
2-Nitrophenol
<10
µg/L
10
02/02/99
02/08/99
AN
1
4-Nitrophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
Pentachlorophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
Phenol
18
µg/L
10
02/02/99
02/08/99
AN
1
2,4,5-Trichlorophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
2,4,6-Trichlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Acenaphthene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Acenaphthylene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Anthracene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Benzidine
<20
µg/L
20
02/02/99
02/08/99
AN
1
Page 3 of 13
Certes Environmental Laboratories
-209 Wisconsin Street. Suite 200 Dallas. Texas, 75229 -972-620.7966.800-394-2872 - F='-. c'2.620-7963 - Email: certes 4aol.com
-a+ytical Chemistry Environmental Sciences ==search Microbiology
l
r
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
r, Sample: 99-0307-001 continued...
EPA 8270C Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
bis-(2-chloroethyl) ether
bis-(2-chloroethoxy) methane
bis-(2-chloroisopropyl) ether
bis-(2-ethylhexyl) phthalate
4-Bromophenyl-phenylether
Butylbenzylphthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl-phenylether
Chrysene
I Dibenzo(a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1 3,3-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
Di-n-butylphthalate
2,6-Dinitrotoluene (2,6-DNT)
! DI-n-octylphthalate
Azobenzene
Fluoranthene
I Fluorene
r Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
r Indeno(1,2,3-cd)pyrene
Isophorone
r2-Methylnaphthalene
Naphthalene
r 2-Nitroaniline
Reporting
Date
Date
Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
<20
µg/L
20
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L.
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
<20
µg/L
20
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
<20
µg/L
20
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
I
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
I
< 10
µg/L
10
02/02/99
02/08/99
AN
1
<20
µg/L
20
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/09/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
I
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
< 10
µg/L
10
02/02/99
02/08/99
AN
1
<50
µg/L
50
02/02/99
02/08/99
AN
1
Page 4 of 13
..ertes Environmental Laboratories
=_09 Wisconsin Street. Suite 200 Dallas. Texas. 75229. 972-620-7966. 800-394.2872 - == :'2-620-7963- Email: certes@aol.com
nalytical Chemistry Environmental Sciences ==search Microbioiogy
r
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-001 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C
3-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
4-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
Nitrobenzene (NB)
< 10
µg/L
10
02/02/99
02/08/99
AN
1
N-Nitrosodimethylamine
<20
µg/L
20
02/02/99
02/08/99
AN
1
N-Nitrosodiphenylamine
< 10
µg/L
10
02/02/99
02/08/99
AN
1
N-Nitrosodipropylamine
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Phenanthrene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Pyrene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
1,2,4-Trichlorobenzene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
"Quality Control Surrogate
02/02/99
02/08/99
AN
1
Nitrobenzene-d5 (SS)
74%
49-118%
02/02/99
02/08/99
AN
i
2-Fluorobiphenyl (SS)
59%
43-116%
02/02/99
02/08/99
AN
1
Terphenyl-d14 (SS)
69%
33-144%
02/02/99
02/08/99
AN
1
3.2.191
Sodium Absorbtion Ratio
3.97
02/09/99
KJC
l
EPA 351.4
Total Kjeldahl Nitrogen
0.47
mg/L
0.20
02/08/99
CO
1
EPA 6010B
Potassium
39.3
mg/L
10.0
02/04/99
02/09/99
KJC
10
Sodium
263
mg/L
10.0
02/04/99
02/09/99
KJC
10
Calcium
105
mg/L
10.0
02/04/99
02/09/99
KJC
10
Magnesium
138
mg/L
0.1
02/04/99
02/09/99
KJC
10
Sbi 4500CLB
Chloride
550
mg/L
50
02/05/99
02/05/99
BWB
10
EPA 375.4
Sulfate
168
mg/L
25
02/08/99
02/08/99
DJD
5
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/03/99
02/03/99
DJD
1
EPA 3533
Nitrate
<0.10
mg/L
0.10
02/05/99
02/05/99
DJD
1
EPA 6010B
Boron
0.869
mg/L
0.010
02/04/99
02/09/99
KJC
1
SN14500NH3.D
Ammonia
<0.10
mg/L
0.10
02/03/99
02/03/99
BWB
1
SINt 2320B
Alkalinity as Bicarbonate
580
mg/L
50
02/08/99
02/08/99
BWB
10
Client Sample 1D: WELL 10932 0201991500
Sample Number: 99-0307-002
Date Sampled:
02/01/99
Sample Matrix:
Liquid
Time Sampled:
15:00
Sampled By:
LW
EPA 6010B
Arsenic
<0.050
mg/L
0.050
02/04/99 02/04/99
KJC 1
Cadmium
<0.005
mg/L
0.005
02/04/99 02/04/99
KJC 1
Chromium
<0.005
mg/L
0.005
02/04/99 02/04/99
KJC 1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/04/99 02/05/99
ADD 1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/04/99 02/04/99
KJC 1
Copper
<0.010
mg/L
0.010
02/04/99 02/04/99
KJC 1
Nickel
<0.010
mg/L
0.010
02/04/99 02/04/99
KJC 1
Page S of 13
a Certes Environmental Laboratories
7209 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966.800-394-2872 - = 2-620-7963- Email: certesdaol.com
i
--.alytical Chemistry Environmental Sciences ;=e_earch Microbiology
i Results of Analyses CEL File No.: 99-0307 Report Date: 02/26/99
Reporting
Date
Date
Analyzed
r.,
Sample: 99-0307-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Lead
<0.015
mg/L
0.015
02/04/99
02/04/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/04/99
02/04/99
KJC
1
p ~
Molybdenum
<0.050
mg/L
0.050
02/04/99
02/04/99
KJC
1
i
EPA 8081A
4,4'-DDD
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
4,4'-DDE
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
t..
4,4'-DDT
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
alpha-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
l
beta-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
alpha -Chlordane
<0.05
µg/L
0.05
02/04/99
02/08/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/04/99
02/08/99
JCA
1
.-4
Dieldrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan I
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan II
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
t
Endrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
l
Endrin aldehyde
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
gamma-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
f
Heptachlor epoxide
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/04/99
02/08/99
JCA
1
Toxaphene
< 1.0
µg/L
1.0
02/04/99
02/08/99
JCA
1
"Quality Control Surrogate
02/04/99
02/08/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
68%
60-140%
02/04/99
02/08/99
JCA
1
Decachlorobiphenyl (SS)
80%
60-140%
02/04/99
02/08/99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
l
Aroclor-1221
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1232
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1248
<5.0
µg/L
5.0
02/04/99
02/09/99
JCA
1
Aroclor-1254
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
"Quality Control Surrogate
02/04/99
02/08/99
JCA
I
2,4,5,6-Tetrachloro-m-xylene (
Decachlorobiphenyl (SS)
68%
80%
60-140%
60-140%
02/04/99
02/04/99
02/08/99
02/08/99
JCA
JCA
1
I
EPA 8151A
2,4-D
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
r'
2,4-DB
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Page 6 of 13
FCertes Environmental Laboratories
-__9 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620-7966.600-394-2872 - _= :72-620-7963• Email: certesdaol.ccm
--a:y;ical Chemistry Environmental Sciences ==search Microbiology
k
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
r
Sample: 99-0307-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8151A
2,4,5-T
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
2,4,5-TP (Silvex)
<0.004
µgIL
0.004
02/05/99
02/05/99
AR
1
Dalapon
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Dicamba
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
Dichloroprop
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
^,
a
Dinoseb
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
MCPA
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
r
MCCP
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
l
SM 9222B
Total Coliform
< 1
coV100mL
1
02/02/99
02/03/99
BWB
1
EPA 418.1
TPH
< 1
mg/L
1
02/03/99
02/04/99
SAB
1
EPA 8270C
Benzoic acid
<50
µg/L
50
02/02/99
02/08/99
AN
1
!
4-Chloro-3-methylphenol
<20
µg/L
20
02/02/99
02/08/99
AN
1
.-
2-Chlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
2,4-Dichlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
I
2,4-Dimethylphenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
r
4,6-Dinitro-2-methylphenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
2,4-Dinitrophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
2-Methylphenol
4-Methylphenol
<50
< 10
µg/L
µg/L
50
10
02/02/99
02/02/99
02/08/99
02/08/99
AN
AN
I
I
2-Nitrophenol
< 10
µg/L,
10
02/02/99
02/08/99
AN
1
4-Nitrophenol
<50
µgIL
50
02/02/99
02/08/99
AN
I
...
Pentachlorophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
Phenol
< 10
µg/L
10
02/02/99
02/08/99
AN
I
2,4,5-Trichlorophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
2,4,6-Trichlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Acenaphthene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Acenaphthylene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Anthracene
< 10
µg/L
10
02/02/99
02/08/99
AN
l
Benzidine
<20
µg/L
20
02/02/99
02/08/99
AN
I
Benzo(a)anthracene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Benzo(a)pyrene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Benzo(b)fluoranthene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Benzo(g,h,i)perylene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Benzo(k)fluoranthene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Benzyl alcohol
<20
µg/L
20
02/02/99
02/08/99
AN
1
bis-(2-chloroethyl) ether
< 10
µg/L
10
02/02/99
02/08/99
AN
I
bis-(2-chloroethoxy) methane
< 10
µg/L
10
02/02/99
02/08/99
AN
1
bis-(2-chloroisopropyl) ether
< 10
µg/L
10
02/02/99
02/08/99
AN
I
*'
bis-(2-ethylhexyl) phthalate
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Page 7 of 13
r-•
i Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966. 800-394-2872 • _='•. ?'2-620-7963 • Email: certes@aol.com
--a:vtical Chemistry Environmental Sciences=esearch Microbic!ooy
I
r
Results of Analyses CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilation
EPA 8270C 4-Bromophenyl-phenylether
<10
µg/L
10
02/02/99
02/08/99
AN
1
Butylbenzylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
4-Chloroaniline
<20
µg/L
20
02/02/99
02/08/99
AN
1
2-Chloronaphthalene
<10
µg/L
10
02/02/99
02/08/99
AN
1
4-Chlorophenyl-phenylether
<10
µg/L
10
02/02/99
02/08/99
AN
1
Chrysene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Dibenzo(a,h)anthracene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Dibenzofumn
<10
µg/L
10
02/02/99
02/08/99
AN
1
1,2-Dichlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
1,3-Dichlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
1,4-Dichlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
3,3-Dichlorobenzidine
<20
µg/L
20
02/02/99
02/08/99
AN
1
Diethylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
Dimethylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
Di-n-butylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
2,6-Dinitrotoluene (2,6-DNT)
<10
µg/L
10
02/02/99
02/08/99
AN
1
DI-n-octylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
Azobenzene
<20
µg/L
20
02/02/99
02/08/99
AN
1
Fluoranthene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Fluorene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Hexachlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Hexachlorobutadiene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Hexachlorocyclopentadiene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Hexachloroethane
<10
µg/L
10
02/02/99
02/08/99
AN
1
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Isophorone
<10
µg/L
10
02/02/99
02/08/99
AN
1
2-Methyinaphthalene
<10
µg/L
10
02/02/99
02/09/99
AN
1
Naphthalene
<10
µg/L
10
02/02/99
02/08/99
AN
1
2-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
I
3-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
4-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
Nitrobenzene (NB)
<10
µg/L
10
02/02/99
02/08/99
AN
I
N-Nitrosodimethylamine
<20
µg/L
20
02/02/99
02/08/99
AN
1
N-Nitrosodiphenylamine
<10
µg/L
10
02/02/99
02/08/99
AN
I
N-Nitrosodipropylamine
<10
µg/L
10
02/02/99
02/08/99
AN
I
Phenanthrene
<10
µg/L
10
02/02/99
02/08/99
AN
I
Pyrene
<10
µg/L
10
02/02/99
02/08/99
AN
I
1,2,4-Trichlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
"Quality Control Surrogate
02/02/99
02/08/99
AN
1
Page 8 of 13
4 Certes Environmental Laboratories
2209 Wisconsin Street. Suite 200 Dallas. Texas, 7,229.972 620 7966.800-394-2872 • = c-2-620-7963- Ernail: certes@aol.com
Analytical Chemistry Environmental Sciences = = search Microbiology
t
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C
Nitrobenzene-d5 (SS)
68%
49-118%
02/02/99
02/08/99
AN
1
2-Fluorobiphenyl (SS)
56%
43-116%
02/02/99
02/08/99
AN
1
Terphenyl-dl4 (SS)
71%
33-144%
02/02/99
02/08/99
AN
1
3.2.191
Sodium Absorbtion Ratio
6.18
02/09/99
KJC
1
EPA 351.4
Total Kjeldahl Nitrogen
0.54
mg/L
0.20
02/08/99
CO
I
EPA 6010B
Potassium
22.1
mg/L
10.0
02/04/99
02/09/99
KJC
10
Sodium
376
mg/L
10.0
02/04/99
02/09/99
KJC
10
Calcium
98.9
mg/L
10.0
02/04/99
02/09/99
KJC
10
Magnesium
112
mg/L
0.1
02/04/99
02/09/99
KJC
10
Sbi 4500CI.B
Chloride
530
mg/L
50
02/05/99
02/05/99
BWB
10
EPA 375.4
Sulfate
173
mg/L
25
02/08/99
02/08/99
DJD
5
EPA 354.1
Nitrite
0.04
mg/L
0.01
02/03/99
02/03/99
DJD
I
EPA 3533
Nitrate
<0.10
mg/L
0.10
02/05/99
02/05/99
DJD
1
EPA 6010B
Boron
0.389
mg/L
0.010
02/04/99
02/09/99
KJC
1
SM4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/03/99
02/03/99
BWB
1
SM 2320B
Alkalinity as Bicarbonate
670
mg/L
50
02/08/99
02/08/99
BWB
10
Client Sample ID: WELL 21152 0201991530
Sample Number:
99-0307-003
Date Sampled:
02/01/99
Sample Matrix:
Liquid
Time Sampled:
15:30
Sampled By:
LW
EPA 6010E
Arsenic
<0.050
mg/L
0.050
02/04/99
02/04/99
KJC
I
Cadmium
<0.005
mg/L
0.005
02/04/99
02/04/99
KJC
I
Chromium
<0.005
mg/L
0.005
02/04/99
02/04/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/04/99
02/05/99
ADD
I
EPA 6010E
Zinc
0.062
mg/L
0.050
02/04/99
02/04/99
KJC
I
Copper
0.027
mg/L
0.010
02/04/99
02/04/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/04/99
02/04/99
KJC
1
Lead
<0.015
mg/L
0.015
02/04/99
02/04/99
KJC
I
Selenium
<0.040
mg/L
0.040
02/04/99
02/04/99
KJC
I
Molybdenum
<0.050
mg/L
0.050
02/04/99
02/04/99
KJC
1
EPA 8081A
4,4'-DDD
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
4,4'-DDE
<0.050
µg/L,
0.050
02/04/99
02/08/99
JCA
I
4,4'-DDT
<0.050
µg/L.
0.050
02/04/99
02/08/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
alpha-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
beta-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
Page 9 of 13
Certes Environmental Laboratories
_=C9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.500-394.2672 - % c"2.620.7963 • Email: ceries@aol.com
--siy;ical Chemistry Environmental Sciences earch Microbiology
r
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-003 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
alpha -Chlordane
<0.05
µg/L
0.05
02/04/99
02/08/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/04/99
02/08/99
JCA
I
Dieldrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan I
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
Endosulfan II
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
Endrin
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
Endrin aldehyde
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
I
gamma-BHC
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
l
Heptachlor
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/04/99
02/08/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/04/99
02/08/99
JCA
I
Toxaphene
< 1.0
µg/L
1.0
02/04/99
02/08/99
JCA
1
**Quality Control Surrogate
02/04/99
02/08/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
*38%
60-140%
02/04/99
02/08/99
JCA
I
Decachlorobiphenyl (SS)
70%
60-140%
02/04/99
02/08/99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
I
Aroclor-1221
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1232
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
I
Aroclor-1242
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
I
Aroclor-1248
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1254
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/04/99
02/08/99
JCA
1
**Quality Control Surrogate
02/04/99
02/08/99
JCA
I
2,4,5,6-Tetrachloro-m-xylene (
*38%
60-140%
02/04/99
02/08/99
JCA
I
Decachlorobiphenyl (SS)
70%
60-140%
02/04/99
02/08/99
JCA
1
EPA 8151A
2,4-D
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
2,4-DB
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
2,4,5-T
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
2,4,5-TP (Silvex)
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
l
Dalapon
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
Dicamba
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
Dichloroprop
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
Dinoseb
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
l
MCPA
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
1
MCCP
<0.004
µg/L
0.004
02/05/99
02/05/99
AR
I
Sl4f 9222B
Total; Coliform
< 1
col/100mL 1
02/02/99
02/03/99
BWB
1
EPA 418.1
TPH
< 1
mg/L
1
02/03/99
02/04/99
SAB
I
Page 10 of 13
k. Certes Environmental Laboratories
=C9 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972-620-7966.600-394-2872 • :-2-620-7963-Emaii:certes@aol.com
=-aiytical Chemistry Environmental Sciences -=search Microbiology
Results of Analyses CEL File No.: 99-0307
Report Date: 02/26/99
r =
Reporting
Date
Date
Analyzed
Sample: 99-0307-003 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
r
EPA 8270C Benzoic acid
<50
µg/L
50
02/02/99
02/08/99
AN
1
4-Chloro-3-methylphenol
<20
µg/L
20
02/02/99
02/08/99
AN
1
!^
2-Chlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
t
2,4-Dichlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
2,4-Dimethylphenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
4,6-Dinitro-2-methylphenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
i.
2,4-Dinitrophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
2-Methylphenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
t
4-Methylphenol
< 10
µg/l.,
10
02/02/99
02/08/99
AN
I
2-Nitrophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
1
�•
4-Nitrophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
Pentachlorophenol
<50
µg/L
50
02/02/99
02/08/99
AN
1
� ''''
',
Phenol
< 10
µg/L
10
02/02/99
02/02/99
02/08/99
AN
1
�
2,4,5-Trichlorophenol
<50
µg/L
50
02/08/99
AN
1
2,4,6-Trichlorophenol
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Acenaphthene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Acenaphthylene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Anthracene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Benzidine
<20
µg/L
20
02/02/99
02/08/99
AN
1
Benzo(a)anthracene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
r
Benzo(a)pyrene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Benzo(b)fluoranthene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Benzo(g,h,i)perylene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Benzo(k)fluoranthene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
`
Benzyl alcohol
<20
µg/L
20
02/02/99
02/08/99
AN
1
bis-(2-chloroethyl) ether
< 10
µg/L
10
02/02/99
02/08/99
AN
1
�
bis-(2-chloroethoxy) methane
< 10
µg/L
10
02/02/99
02/08/99
AN
1
bis-(2-chloroisopropyl) ether
< 10
µg/L
10
02/02/99
02/08/99
AN
1
bis-(2-ethylhexyl) phthalate
< 10
µg/L
10
02/02/99
02/08/99
AN
1
i
4-Bromophenyl-phenylether
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Butylbenzylphthalate
< 10
µg/L
10
02/02/99
02/08/99
AN
1
4-Chloroaniline
<20
µg/L
20
02/02/99
02/08/99
AN
1
t
2-Chloronaphthalene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
r-
4-Chlorophenyl-phenylether
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Chrysene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Dibenzo(a,h)anthracene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
Dibenzofuran
< 10
µg/L
10
02/02/99
02/08/99
AN
1
1,2-Dichlorobenzene
< 10
µg/L
10
02/02/99
02/08/99
AN
1
�•.
1,3-Dichlorobenzene
< 10
µg/L
10
02/02/99
02/08/99
AN
I
Page 11 of 13
PM
Certes Environmental Laboratories
--09 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.600-394.2672 - F :72-620-7963. E+nail: certesoaol.com
VIM=-aiytical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-003 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8270C
1,4-Dichlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
3,3-Dichlorobenzidine
<20
µg/L
20
02/02/99
02/08/99
AN
1
Diethylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
Dimethylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
Di-n-butylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
2,6-Dinitrotoluene (2,6-DNT)
<10
µg/L
10
02/02/99
02/08/99
AN
1
Di-n-octylphthalate
<10
µg/L
10
02/02/99
02/08/99
AN
1
Azobcnzene
<20
µg/L
20
02/02/99
02/08/99
AN
1
t
Fluoranthene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Fluorene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Hexachlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
I
Hexachlorobutadiene
<10
µg/L
10
02/02/99
02/08/99
AN
1
r
Hexachlorocyclopentadiene
<10
µg/L
10
02/02/99
02/08/99
AN
I
ff
Hexachloroethane
<10
µg/L
10
02/02/99
02/08/99
AN
1
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Isophorone
<10
µg/L
10
02/02/99
02/08/99
AN
1
2-Methylnaphthalene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Naphthalene
<10
µg/L
10
02/02/99
02/08/99
AN
1
2-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
3-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
4-Nitroaniline
<50
µg/L
50
02/02/99
02/08/99
AN
1
-
Nitrobenzene (NB)
<10
µg/L
10
02/02/99
02/08/99
AN
1
N-Nitrosodimethylamine
<20
µg/L
20
02/02/99
02/08/99
AN
1
r
N-Nitrosodiphenylamine
<10
µg/L
10
02/02/99
02/08/99
AN
1
N-Nitrosodipropylamine
<10
µg/L
10
02/02/99
02/08/99
AN
1
Phenanthrene
<10
µg/L
10
02/02/99
02/08/99
AN
1
Pyrene
<10
µg/L
10
02/02/99
02/08/99
AN
1
1,2,4-Trichlorobenzene
<10
µg/L
10
02/02/99
02/08/99
AN
1
"Quality Control Surrogate
02/02/99
02/08/99
AN
1
I
Nitrobenzene-d5 (SS)
69%
49-118%
02/02/99
02/08/99
AN
1
.,
2-Fluorobiphenyl (SS)
56%
43-116%
02/02/99
02/08/99
AN
1
I
w
Terphenyl-dl4 (SS)
70%
33-144%
02/02/99
02/08/99
AN
1
3.2.191
Sodium Absorbtion Ratio
5.91
02/09/99
KJC
1
EPA 351.4
Total Kjeldahl Nitrogen
030
mg/L
0.20
02/08/99
CO
1
EPA 6010B
Potassium
27.4
mg/L
10.0
02/04/99
02/09/99
KJC
10
Sodium
320
mg/L
10.0
02/04/99
02/09/99
KJC
10
Calcium
97.1
mg/L
10.0
02/04/99
02/09/99
KJC
10
Magnesium
75.9
mg/L
0.1
02/04/99
02/09/99
KJC
10
SM 4500C1.B
Chloride
400
mg/L
50
02/05/99
02/05/99
BWB
10
Page 12 of 13
Mertes Environmental Laboratories
'7209 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966. 600-394-2872 • _ :-2.620-7963 - Email: certesCaol.com
r- ,analytical Chemistry Environmental Sciences earch Microbiology
l
Results of Analyses
CEL File No.: 99-0307
Report Date: 02/26/99
Reporting
Date
Date
Analyzed
Sample: 99-0307-003 Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 375.4
Sulfate
368
mg/L
50
02/08/99
02/08/99
DJD
10
t
EPA 354.1
Nitrite
0.01
mg/L
0.01
02/03/99
02/03/99
DJD
1
EPA 353.3
Nitrate
3.57
mg/L
0.50
02/05/99
02/05/99
DJD
5
EPA 6010B
Boron
0.545
mg/L
0.010
02/04/99
02/09/99
KJC
l
Sh14500NH3.D
Ammonia
<0.10
mg/L
0.10
02/03/99
02/03/99
BWB
1
SM 2320B
Alkalinity as Bicarbonate
400
mg/L
50
02/08/99
02/08/99
BWB
10
* Surrogate recovery is out of range
F
Page 13of13
7
Certes Environmental Laboratories
2209 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 • : -2.620.7963 • Email: certes@aol.com
f alytical Chemistry Environmental Sciences = =search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
Ca
K
x
Matrix S ike
Batch Number
W020399
W020399
W020399
W020399
W020399
Date Prepared
02/03/99
02/03/99
02/03/99
02/03/99
02/03/99
Date Anal ed
02/09/99
02/09/99
02/09/99
02/09/99
02/09/99
Spiked Sample ID
0307-1
0307-1
0307-1
0307-1
0307-1
Sample Measured Result
105
39.3
138
263
0.87
Spike Level
(mg/L) ( ) (mg/Kg) ( )
250
250
250
250
0.50
Spike Result
(m )( )(mg/Kg) (
353
298
412
574
1.37
% Recovery
99
104
110
124
100
Spike Duplicate Result
(m )( ) (mg/Kg) ()
351
293
408
557
1.36
% Recovery Duplicate
98
102
108
118
98
Relative Percent Difference (RPD)
1
2
1
3
1
Control Limits %low %hi
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<1.00
<1.00
<0.010
<1.00
<0.010
Laboratory Control Sample
Spike Level
(m ( ) (mg/Kg) ( )
0.50
5.00
0.50
25.0
0.50
Spike Result
(me/L. ( ) (m )
0.544
4.70
0.495
24.4
0.505
% Recovery
109
94
99
98
101
Spike Duplicate Result
(m ) ( (mg/Kg) )
0.524
4.92
0.494
24.6
0.507
% Recovery Duplicate
105
98
99
98
101
Relative Percent Difference (RPD)
4
5
0
0
0
Control Limits %low%hi
80-120
80-120
80-120
80-120
80-120
µg/l = micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
'BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% — percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
_7:9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972.620.7966.800.394.2872 - c'2.620-7963 • Email: certes@aol.com
--:viical Chemistry Environmental Sciences=a=earch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
As
Cd =
Cr
Cu
Z.
MO;_
Matrix S ike
Batch Number
W020399
W020399
W020399
W020399
W020399
Date Prepared
02/03/99
02/03/99
02/03/99
02/03/99
02/03/99
Date Analyzed
02/04/99
02/04/99
02/04/99
02/04/99
02/04/99
Spiked Sample ID
0307-1
0307-1
0307-1
0307-1
0307-1
Sample Measured Result
<0.050
<0.005
<0.005
0.010
0.028
Spike Level
(m ) (mg/Kg) )
0.50
0.50
0.50
0.50
0.50
Spike Result
(m ( (mg/Kg) ( )
0.482
0.458
0.422
0.452
0.505
% Recovery
96
92
84
88
95
Spike Duplicate Result
(m ) ( ) (mg/Kg) (p
0.479
0.459
0.422
0.451
0.504
% Recovery Duplicate
96
92
84
88
95
Relative Percent Difference RPD
0
0
0
0
0
Control Limits (%low -%hi )
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.005
<0.005
<0.010
<0.010
Laboratory Control Sample
Spike Level
(m ) ( ) (mg/Kg) (jig/Kg)
0.50
0.50
0.50
0.50
0.50
Spike Result
(m ( (mg/Kg) (jig/Kg)
0.469
0.491
0.446
0.468
0.483
% Recovery
94
98
89
94
97
Spike Duplicate Result
m ) ( (mg/Kg) )
0.483
OA99
0.455
0.474
0.489
% Recovery Duplicate
197
100
91
94
98
Relative Percent Difference (RPD)
3
2
2
1
1
Control Limits (%low%hi
80-120
80-120
80-120
M120
80-120
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percenta¢e Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmentaf Laboratories
=09 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - _= 72.620 7963 •Email: certes@aol.com
.-Inn tical Chemistry Environmental Sciences =esearch Microbiology
r
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
Nt
Pb
k
Se
Zn
Hgs.
Matrix S ike
Batch Number
W020399
W020399
W020399
W020399
T020499
Date Prepared
02/03/99
02/03/99
02/03/99
02/03/99
02/04/99
Date Analyzed
02/04/99
02/04/99
02/04/99
02/04/99
02/05/99
Spiked Sample ID
0307-1
0307-1
0307-1
0307-1
PB-1
Sample Measured Result
<0.010
<0.015
<0.020
<0.050
<0.000I
Spike Level
(m ( (m ) (jig/Kg)
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ) ) (mg/Kg) )
0.448
0.444
0.483
0.491
0.0049
% Recovery
90
89
97
98
98
Spike Duplicate Result
(m ( ) (mg/Kg) ( )
0.438
0.446
0.489
0.488
0.0048
% Recovery Duplicate
88
89
98
98
97
Relative Percent Difference RPD
2
0
1
0
1
Control Limits (%low -%hi
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.010
<0.015
<0.020
<0.050
<0.000I
Laboratory Control Sample
Spike Level
m ) ( ) (mg/Kg)
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ( ) (mg/Kg) ( )
0.481
0.488
0.480
0.494
0.0049
% Recovery
96
98
96
99
97
Spike Duplicate Result
m ) m ( )
0.479
0.477
0.488
0.501
0.0049
% Recovery Duplicate
96
95
98
100
97
Relative Percent Difference (RPD)
0
2
2
1
0
Control Limits %low%hi h
80-120
80-120
80-120
80-120
80-120
µg/1= micrograms per liter (ppb)
µVTg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
2209 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972.620- r 966.800-394-2872 - -'72-620-7963 - Email: certes Q aol.com
Analytical Chemistry Environmental Sciences ==Search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
`2 , Ammonia
Nitrite
Nitrate
:,..,Sulfate., ..
t
i
Matrix Spike
I
Batch Number
NH3020399
NO2020399
NO3020599
SO4020899
Date Prepared
02/03/99
02/03/99
102/05/99
02/08/99
Date Analyzed
02/03/99
02/03/99
102/05/99
02/08/99
Spiked Sample ID
0291-1
0307-1
0307-1
0363-1
Sample Measured Result
<0.10
<0.010
<0.10
23.5
Spike Level
(m ) ( ) (mg/Kg) ( )
1.00
0.10
0.50
10.0
Spike Result
m ) ( (mg/Kg) )
0.82
0.092
0.424
34.4
% Recovery
82
92
185
109
Spike Duplicate Result
(m ) (mg/Kg) )
0.89
0.090
0.51
34.5
% Recovery Duplicate
89
90
1 102
110
Relative Percent Difference (RPD)
8
8
1 17
1
Control Limits (%low -%hi
80-120
0-20
1 0-20
0-20
I
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.10
<0.010
<0.10
<5.00
Laboratory Control Sample
I
Spike Level
(m ( (mg/Kg) )
1.00
0.10
0.50
10.0
Spike Result
(m ( (mg/Kg) ( )
0.95
0.098
0.49
9.37
% Recovery
95
98
197
94
Spike Duplicate Result
(m )(m ) )
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
Control Limits %low%hi )
90-110
90-110
90-110
90-110
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
Wisconsin Street. Suite 200 Callas, Texas, 75229.972.620 7966.800-394.2872- _= :72.620.7963• Email: cortesd•aol.com
- ..tical Chemistry Environmental Sciences = e=earth Microbioicay
r
F
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
Chloride
Bicarbonate
Total
Kjeldahl
Nitrogen
TPH
418.1:.
Matrix Spike
Batch Number
CI-2599
Bicarb-2899
0217L
W99-007
Date Prepared
02/05/99
02/08/99
02/05/99
02/03/99
Date Analyzed
02/05/99
02/08/99
02/05/99
02/04/99
Spiked Sample 1D
0307-3
0307-1
46387
RW
Sample Measured Result
400
580
0.47
<1.00
Spike Level
(mQ/L) ( ) (mg/Kg) ( )
500
500
2.50
5.00
Spike Result
(m ( (mg/Kg) )
960
1030
3.43
4.90
% Recovery
112
90
119
98
Spike Duplicate Result
(m )( (m ( )
950
1060
N/A
4.80
% Recovery Duplicate
110
96
N/A
96
Relative Percent Difference (RPD)
2
6
N/A
2
Control Limits (%low -%hi
80-120
80-120
180-120
80-120
Method Blank
(m ) ( ) (mg/Kg) ( )
<5.00
<5.00
<0.20
<1.00
Laboratory Control Sample
Spike Level
m ) ( (mg/Kg) )
50.0
50.0
4.00
N/A
Spike Result
(m (mg/Kg) (jig/Kg)
53.0
47.0
4.17
N/A
% Recovery
106
94
104
N/A
Spike Duplicate Result
(m (mg/Kg) )
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
Control Limits %low -%hi
90-110
90-110
90-110
80-120
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD — Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=209 Wisconsin Street. Suite 200 Dallas, Texas, 75229.972-620.7966-800.394-2872 - 772.620-7963 - Email: certes@aol.com
--a;ytical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
Lindane
Heptachlor
Atdrin
Dieldrita
Matrix S ike
Batch Number
PST99006
PST99006
PST99006
PST99006
Date Prepared
02/04/99
02/04/99
02/04/99
02/04/99
Date Analyzed
02/08/99
02/08/99
02/08/99
02/08/99
Spiked Sample 1D
N/A
N/A
N/A
N/A
Sample Measured Result
N/A
N/A
N/A
N/A
Spike Level
(m )( )(m )( )
N/A
N/A
N/A
N/A
Spike Result
(m )(gg/L) (mg/Kg) ()
N/A
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
N/A
Spike Duplicate Result
(m )( ) (mg/Kg) ()
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
Control Limits %low -%hi
N/A
N/A
N/A
N/A
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.050
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
m ( (mg/Kg) ( )
0.40
0.40
0.40
1.00
Spike Result
(m ) (mg/Kg) (
0.190
0.189
0.209
0.344
% Recovery
48*
48
52
34'
Spike Duplicate Result
(m ) (mg/Kg) ( )
0.251
0.225
0.248
0.313
% Recovery Duplicate
63
56
62
31 *
Relative Percent Difference (RPD)
28
17
17
9
Control Limits %low %hi
50-119
46-117
44-104
48-119
*Outside Control Limits
µg/1= micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentaze Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
__C9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972.620-7966.800-394.2872 - = 272-620-7963 - Email: certes?aol.com
,',r,a;vtical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
DDT:.
Arochlor 1260
Matrix Spike
Batch Number
PST99006
PST99006
PCB99006
Date Prepared
02/04/99
02 04/99
02/04/99
Date Analyzed
02/08/99
02 08/99
02/08/99
Spiked Sample ID
N/A
N A
N/A
Sample Measured Result
N/A
N A
N/A
Spike Level
(m )( (mg/Kg) ()
N/A
N A
N/A
Spike Result
(m ) ( (mg/Kg) (
N/A
N 'A
N/A
% Recovery
N/A
N A
N/A
Spike Duplicate Result
(m )( ) (mg/Kg) )
N/A
N A
N/A
% Recovery Duplicate
N/A
N A
N/A
Relative Percent Difference RPD
N/A
N A
N/A
Control Limits %low%hi )
N/A
N A
48-139
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.050
<0.050
<5.00
Laboratory Control Sample
Spike Level
(m ) ( (mg/Kg) )
1.00
1.00
5.00
Spike Result
(m ( ) (mg/Kg) ( )
0.285
0.642
4.01
% Recovery
28•
64
80
Spike Duplicate Result
m (mg/Kg) )
0.253
0.635
4.90
% Recovery Duplicate
25•
64
98
Relative Percent Difference (RPD)
12
1
20
Control Limits %low -%hi
62-133
59-148
48-139
;Outside Control Limits
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I — milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
'209 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620.7966.800-394-2872 • _= =72-620-7963 • Email: certes@aol.com
--aiytical Chemistry Environmental Sciences =search Kcrobiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
aTotal
s
Coliform
Batch Number
TC-020299
Date Prepared
0202199
Date Analyzed
02 03/99
Sample ID
0307-1
Sample Result
(m ( ) (mg/Kg) ( )
<1.00
Sample Duplicate Result
m ( (mg/Kg) ( )
<1.00
Relative Percent Difference (RPD)
0
Control Limits
0-20
Method Blank
(ms/L) (ue/L.) (mp-/K¢) (utJKQ)
<1.00
Laboratory Control Sample
Spike Level
m )( ) (mg/Kg) () N'A
Spike Result
m ( (mg/Kg) ( ) N'A
% Recovery N A
Control Limits (%low -%hi N A
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg - milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplictate
Certes Environmental laboratories
=_C9 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872 - _= =-2-620-7963 • Email: certes@aol.com
.-a;ytical Chemistry Environmental Sciences = =search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
Herbicides
Duplicate
Batch Number
GA269-161
Date Prepared
02'08/99
Date Analyzed
02'08/99
Sample 1D
99EN0421
% Recovery
103
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.20
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micrornhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
VJisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 • = ?72-620-7963- Email: certes@aol.com
-- r : tical Chemistry Environmental Sciences = : Search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0307
Aceua h
p
thene
Py rene; `
1,4
Dtchloro-
benzene
a-Nitroso- ..
di=n
proPYlamine
1 4-
��
�Trichloro- .
benzene ,
2 4 Dini-.
,..-
trotoluene
Matrix Spike
Batch Number
129364-6
129364-6
129364-6
129364-6
129364-6
129364-6
Date Prepared
02/02/99
02/02/99
02/02/99
02.'02/99
02/02/99
02/02/99
Date Analyzed
02/08/99
02/08/99
02/08/99
01*08/99
02/08/99
02/08/99
Spiked Sample ID
990079
990078
990078
990078
990078
990078
Spike Level
(m )( )(m )( )
100
100
100
100
100
100
% Recovery
138
87
105
104
128
92
% Recovery Duplicate
135
87
102
98
126
87
Relative Percent Difference (RPD)
2
1
3
6
2
6
Control Limits (%low -%hi
47-145
52-125
20-124
10-230
44-142
39-139
Method Blank
(m )( )(m )( )
<10
<10
<10
<10
<10
<10
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
-209 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972.620-7966.600.394.2872 - =-X z72.620-7963 • Email: certes@aol.com
`aiytical Chemistry Environmental Sciences ==search Microbiology
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, SUite 200
- ----_- _ _ ---__ .-- Dallas, Texas 75229
972-620-7966 972-620-7963 Fax
Analysis(es) Requested
Client Name
Gail f,vter_
Phone No.
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fax No.
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Sample ID
Dale
Time
Matrix'
No; 8 Type of Container',
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2 Container Type: V - 40m1 VOA Vial;':.G - Amber or Glass 1 Liter,J - 250m1 Wide=mouth Glass Jar, O Other
131'reservalive:': ' HCI - Hydrochloric Acid..' HNO : = Nitric Acid; H,SO, -Sulfuric Add; O = Other.`
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ClienLEWiect ID
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Special Instructions (including specific detection limits
PCLrs � it"aA reSuAls aS c3J31lab IQ,
Certes Job Number
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Relinquished by
Date
Time
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Received By Laboratory
NOTE: By submitting these samples. you agree to the terms and conditions contained In Cert ' Schedule of, Fees. Caries cannot accept verbal changes. Please FAX written changes. to (972) 620-7963. .
L _ - I _-_: L_ L_ L -d L __ I C __ -L__,: -t_ --L-_ A.— - -- L.r L_ L__ L_' l—f L___
/ y , �, �,1209 Wisconsin, Street. Suite 200
'.� .I eS Dallas. Texas 75229
972-620- 7966
*.. 800-394-2872
u ri7r ;?iy�rr3iLr�s�. i._.u. 972-620-7963 Fr,X _mail: certes c..com
�- CERTES ENVIRONMENTAL LABORATORIES
ANALYTICAL REPORT
Certes File Number: 99-0406
Client Project I.D.:
EN1761
Prepared for:
ENPROTEC INC.
6310 Genoa Avenue, Suite E
Lubbock, TX 79424
Attention:
Mark Schneider
Report Date:
03/02/99
Included are the results of chemical analyses for the samples submitted to Certes Environmental
Laboratories, L.L.C., on 02/09/99. All analytical results met Quality Control requirements as set by the
industry accepted criteria. Please refer to the Laboratory Quality Control Results section of this report.
This report must be reproduced in its entirety.
Sincerely,
Certes Environmental Laboratories, L.L.C.
4'Jz
Amy LaSalle
President
FM
=„virorm�n:� S.
i - -
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
i
t
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared
Analyzed
By
Dilution
I
Client Sample ID: PIVOT 15 SHALLOW
Sample Number: 99-0406-001
Date Sampled:
02/04/99
Sample
Matrix:
Solid
Time Sampled:
11:00
Sampled By:
LW
EPA 9253
Chloride
1100
mg/Kg
500
02/17/99
02/17/99
BWB
10
EPA 9038
EPA 354.1M
Sulfate
Nitrite
462
<0.2
mg/Kg
mg/Kg
100
0.2
02/17/99
02/15/99
02/17/99
02/15/99
JMO
JMO
2
2
EPA 353.3
Nitrate
18.2
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
900
mg/Kg
25
02/16/99
02/16/99
DJD
5
EPA 6010B
Boron
18
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
2210
mg/Kg
50
02/15/99
02126/99
OX
1
!^
Sodium
1400
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
4320
mg/Kg
50
02/15/99
02f23/99
OX
1
Magnesium
2700
mg/Kg
0.50
02/15/99
02/26/99
OX
1
t�
Arsenic
2.8
mg/Kg
2.5
02/15/99
02/17/99
OX
1
t
Cadmium
1.70
mg/Kg
0.50
02/15/99
02/17/99
OX
1
r..
Chromium
10.8
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
32.2
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
13.2
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
9.1
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
9.4
mg/Kg
1.5
02/15/99
02/17/99
OX
1
1.
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 8081A
4,4'-DDD
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDE
1.87
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDT
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
p
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
r•.
beta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
gamma-BHC
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Endosulfan II
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Page
2 of 67
f , Certes Environmental Laboratones
_2C9 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620.7966 • SOC-394-2872 - == :72-620-7963 - Email: certes @aol.com
i
' -a:vtical Chemistry Environmental Sciences = =search Microbiology
jam•
l
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-001 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
I
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/20/99
JCA
1
**Quality Control Surrogate
02/15/99
02/20/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
. 87%
60-140%
02/15/99
02/20/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/20/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
0220/99
JCA
1
**Quality Control Surrogate
02/15/99
0220/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
87%
60-140%
02/15/99
0220/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
0220/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP(Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/19/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
69
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
345
mg/Kg
6
02/18/99
02/18/99
ARM
1
3.2.191
Sodium Absorbtion Ratio
6.2
02/16/99
0224/99
OX
1
* Surrogate recovery Is out of range
Page 3 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas. 75229 .972-620-7966.800.394-2872 • c72.620-7963 • Email: certeseaol.com
-�-a:ytical Chemistry Environmental Sciences =search Microbiology
;
r Results of Analyses CEL File No.: 99-0406 Report Date: 03/02/99
t
,.,
Result
Units
Reporting
Limit
Date Date Analyzed
Prepared Analyzed By
Dilution
--
Client Sample ID: PIVOT 15 DEEP
Sample Number:
99-0406-002
Date Sampled:
02/04/99
Sample Matrix:
Solid
r
Time Sampled:
11:05
Sampled By:
LW
EPA 9253
Chloride
270
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
312
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 3533
Nitrate
5.4
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
r
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
1
�•
Alkalinity as Bicarbonate
500
mg/Kg
250
02/16/99
02/16/99
DJD
5
EPA 6010B
Boron
20
mg/Kg
10
02/15/99
02/19/99
OX
1
Potassium
2190
mg/Kg
50
02/15/99
02/26/99
OX
1
Sodium
1130
mg/Kg
50
02/15/99
02/26/99
OX
1
-
Calcium
6560
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
2540
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
5.0
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Cadmium
1.81
mg/Kg
0.50
02/15/99
02/17/99
OX
1
r"
i
Chromium
12.0
mg/Kg
0.50
02/15/99
02/17/99
OX
1
I
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
32.6
mg/Kg
5.0
02/15/99
02/17/99
OX
1
d
Copper
15.4
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
9.6
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
12.0
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
350
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
2.5
02/16/99
02/24/99
OX
1
OM
Client Sample ID: PIVOT 12 SHALLOW
Sample Number. 99-0406-003
Date Sampled:
02/04/99
Sample Matrix:
Solid
Time Sampled:
12:10
Sampled By:
LW
EPA 9253
Chloride
470
mg/Kg
50
02/17/99 02/17/99
BWB
1
EPA 9038
Sulfate
491
mg/Kg
100
02/17/99 02/17/99
JMO
2
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99 02/15/99
JMO
1
EPA 3533
Nitrate
5.5
mg/Kg
1.0
02/15/99 02/15/99
BWB
1
EPA 3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/Kg
50
02/16/99 02/16/99
DJD
1
Page 4 of 67
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966.800-394-2872 • = .-2.620-7963 • Email: certes®aol.com
A-a:ytical Chemistry Environmental Sciences ==search Microbiology
Fft
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-003
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
SM 2320B
Alkalinity as Bicarbonate
460
mg/Kg
250
02/16/99
02/16/99
DJD
5
EPA 6010B
Boron
15
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
2270
mg/Kg
50
02/15/99
02/26/99
OX
1
Sodium
1220
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
4100
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
2780
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
3.9
mg/Kg
2.5
02/15/99
02/17/99
OX
1
*'
Cadmium
1.71
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
9.47
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
30.8
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
8.66
mg/Kg
0.50
02/15/99
02/17/99
OX
1
PM
Nickel
8.8
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
11.7
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
,..,
4,4'-DDE
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDT
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
i.
gamma-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r
Endosulfan II
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r"
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
t
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
-
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
"Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
81%
60-140%
02/15/99
02/18/99
JCA
1
Page 5 of 67
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966.800-394-2872 - =-72.620-7963 • Email: certescaol.com
- .ytical Chemistry Environmental Sciences = =search Microbiology
7
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-003 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Decachlorobiphenyl (SS)
"0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
I
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
l
2,4,5,6-Tetrachloro-m-xylene (
81%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
110
mg/Kg
10
02/15/99
02/15/99
BM
l
EPA 351AM
Total Kjeldahl Nitrogen
548
mg/Kg
6
02/18/99
02/18/99
ARM
1
3.2.191
Sodium Absorbtion Ratio
5.3
02/16/99
02/24/99
OX
1
• Surrogate recovery is out of range
Client Sample ID: PIVOT 12 DEEP Sample Number. 99-0406-004
Date Sampled: 02/04/99 Sample Matrix: Solid
Time Sampled: 12:15 Sampled By: LW
EPA 9253
Chloride
560
mg/Kg
50
02/17/99
02/17/99
BWB
EPA 9038
Sulfate
606
mg/Kg
100
02/17/99
02/17/99
JMO
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
EPA 3533
Nitrate
<1.0
mg/Kg
1.0
02/15/99
02/15/99
BWB
EPA 3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SM 2320B
Alkalinity as Carbonate
<250
mg/Kg
250
02/16/99
02/16/99
DJD
Alkalinity as Bicarbonate
300
mg/Kg
250
02/16/99
02/16/99
DJD
EPA 6010B
Boron
20
mg/Kg
10
02/15/99
02/18/99
OX
Potassium
3410
mg/Kg
50
02/15/99
02/26/99
OX
Page 6 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620-7966. 800-394.2872 - F E-2-620-7963 - Email: certes@aol.com
r•
^asytical Chemistry Environmental Sciences c --- Search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-004 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Sodium
1530
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
15900
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
3500
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
6.7
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Cadmium
1.76
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
12.5
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010E
Zinc
34.6
mg/Kg
5.0
02/15/99
02/17/99
OX
I
Copper
10.7
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
11.4
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
12.2
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
450
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
5.1
02/16/99
02/24/99
OX
1
Client Sample ID: PIVOT 7 SHALLOW Sample Number: 99-0406-005
Date Sampled: 02/04/99 Sample Matrix: Solid
Time Sampled: 14:05 Sampled By: LW
EPA 9253
Chloride
350
mg/Kg
50
02/17/99
02/17/99
BWB
EPA 9038
Sulfate
384
mg/Kg
100
02/17/99
02/17/99
JMO
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
EPA 3533
Nitrate
11.0
mg/Kg
10.0
02/15/99
02/15/99
BWB
EPA 350.3M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SN12320B
Alkalinity as Carbonate
<250
mg/Kg
250
02/16/99
02/16/99
DJD
Alkalinity as Bicarbonate
300
mg/Kg
250
02/16/99
02/16/99
DJD
EPA 6010B
Boron
17
mg/Kg
10
02/15/99
02/18/99
OX
Potassium
1850
mg/Kg
50
02/15/99
0226/99
OX
Sodium
1470
mg/Kg
50
02/15/99
02/26/99
OX
Calcium
14700
mg/Kg
50
02/15/99
0223/99
OX
Magnesium
2390
mg/Kg
0.50
02/15/99
02/26/99
OX
Arsenic
<2.5
mg/Kg
2.5
02/15/99
02/17/99
OX
Cadmium
1.72
mg/Kg
0.50
02/15/99
02/17/99
OX
Chromium
9.76
mg/Kg
0.50
02/15/99
02/17/99
OX
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
EPA 6010B
Zinc
27.5
mg/Kg
5.0
02/15/99
02/17/99
OX
Copper
51.1
mg/Kg
0.50
02/15/99
02/17/99
OX
Page 7 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas. Texas. 75229. 972.620.7966 • 800-394-2872 • _ :'2-620-7963 • Email: certes@aol.com
,alytical Chemistry Environmental Sciences = = search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-005 Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
r
}
EPA 6010B
Nickel
8.7
mg/Kg
1.0
02/15/99
02/17/99
OX
1
S
Lead
10.4
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
I
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 8081A
4,4'-DDD
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
4,4'-DDT
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
alpha-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
w _
Endosulfan II
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
Endrin keytone
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
C
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
'
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
2,4,5,6-Tetrachloro-m-xylene (
71%
60-140%
02/15/99
02/15/99
02/18/99
02/18/99
JCA
JCA
I
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
p^p
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
[._
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
�-
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1260
<25
jig/Kg
25
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
71%
60-140%
02/15/99
02/18/99
JCA
i
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
I
Page 8 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966.800.394-2872 - = -s2-620.7963 • Email: certes®aot.com
�"` ,analytical Chemistry Environmental Sciences ::---search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
-
Reporting
Date
Date
Analyzed
Sample: 99-0406-005 continued...
Result
Units
Limit
Prepared
Analyzed
By Dilution
.�
EPA 8151A
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
t...
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
f"
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM 1
EPA 418.1
TPH
236
mg/Kg
10
02/15/99
02/15/99
BM 1
EPA 351AM
Total Kjeldahl Nitrogen
480
mg/Kg
6
02/18/99
02/18/99
ARM l
3.2-191
Sodium Absorbtion Ratio
2.9
02/24/99
OX 1
r`
* Surrogate recovery is out of range
�.� Client Sample ID: PIVOT 7 DEEP Sample Number: 99-0406-006
Date Sampled: 02/04/99 Sample Matrix: Solid
Time Sampled: 14:10 Sampled By: LW
EPA 9253
Chloride
220
mg/Kg
50
02/17/99
02/17/99
BWB
EPA 9038
Sulfate
342
mg/Kg
50
02/17/99
02/17/99
JMO
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
r
j
EPA 3533
Nitrate
2.2
mg/Kg
1.0
02/15/99
02/15/99
BWB
11
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SM 2320B
Alkalinity as Carbonate
<250
mg/Kg
250
02/16/99
02/16/99
DJD
ti
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DJD
EPA 6010B
Boron
13
mg/Kg
10
02/15/99
02/18/99
OX
Potassium
2110
mg/Kg
50
02/15/99
02/26/99
OX
Sodium
1090
mg/Kg
50
02/15/99
02/26/99
OX
Calcium
5940
mg/Kg
50
02/15/99
02/23/99
OX
Magnesium
2260
mg/Kg
0.50
02/15/99
02/26/99
OX
Arsenic
33
mg/Kg
2.5
02/15/99
02/17/99
OX
Cadmium
1.42
mg/Kg
0.50
02/15/99
02/17/99
OX
Chromium
9.87
mg/Kg
0.50
02/15/99
02/17/99
OX
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
EPA 6010B
Zinc
25.1
mg/Kg
5.0
02/15/99
02/17/99
OX
Copper
734
mg/Kg
0.50
02/15/99
02/17/99
OX
r�
1
Nickel
7.5
mg/Kg
1.0
02/15/99
02/17/99
OX
Lead
9.4
mg/Kg
1.5
02/15/99
02/17/99
OX
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
Page 9 of 67
OW
Certes Environmental Laboratories
7209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 - F:_. 7-72-620-7963 - Email: certes@aol.com
--a ytical Chemistry Environmental Sciences Fesearch Microbiology
E:
tew, Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
i
Reporting
Date
Date
Analyzed
Sample: 99-0406-006 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
r
i EPA 6010B
Mol
Molybdenum
Y
<1.0
mg/Kg
1.0
02/15/99
02/17/99
OX 1
EPA 351.4M
Total Kjeldahl Nitrogen
370
mg/Kg
75
02/17/99
02/17/99
TAL 1
d 3.2.191
Sodium Absorbtion Ratio
2.0
02/24/99
OX 1
r EPA 418.1
TPH
11
mg/Kg
10
02/24/99
02/24/99
BWM 1
Client Sample 1D: PIVOT 8 SHALLOW
Sample Number: 99-0406-007
Date Sampled:
02/04/99
Sample
Matrix:
Solid
Time Sampled:
15:15
Sampled
By:
LW
r"
EPA 9253
Chloride
280
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
316
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
I
EPA 353.3
Nitrate
11.2
mg/Kg
10.0
02/15/99
02/15/99
BWB
10
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
160
mg/Kg
100
02/16/99
02/16/99
DJD
2
Alkalinity as Bicarbonate
240
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010B
Boron
13
mg/Kg
10
02/15/99
02/18/99
OX
I
Potassium
2310
mg/Kg
50
02/15/99
02/26/99
OX
1
Sodium
1070
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
10500
mg/Kg
50
02/15/99
02/23/99
OX
1
rMagnesium
2430
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
4.2
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Cadmium
1.44
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
9.15
mg/Kg
0.50
02/15/99
02/17/99
OX
I
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
27.2
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
11.4
mg/Kg
0.50
02/15/99
02/17/99
OX
1
w6
Nickel
8.3
mg/Kg
1.0
02/15/99
02/17/99
OX
I
Lead
7.7
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 8081A
4,4'-DDD
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
-
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Page 10 of 67
ow
Certes Environmental Laboratories
1209 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2672 • c_ 172-620-7963 • Email: certes@aof.com
Microbiology =.^alytical Chemistry Environmental Sciences =.search
C
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
d
Reporting
Date
Date
Analyzed
Sample: 99-0406-007
Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8081A
gamma-BHC
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
`
Heptachlor epoxide
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
`
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/15/99
02/18/99
JCA
1
-'
Decachlorobiphenyl(SS)
*0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 110112
Aroclor-1016
<25
jig/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
I
r
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
y{
r
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
I
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
"Quality Control Surrogate
02/15/99
02/18/99
JCA
1
.j.
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/15/99
02/18/99
JCA
1
6
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
I
r`
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
B
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
I
EPA 418.1
TPH
220
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
380
mg/Kg
6
02/18/99
02/18/99
ARM
1
Page 11 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972-620.7956 - 600-394-2872 - ==X z72-620-7963 • Email: certes@aol.com
P=.-aiyticat Chemistry Environmental Sciences =:search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Sample: 99-0406-007 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
OM
I
3.2.191
Sodium Absorbtion Ratio
2-3
02/24/99
OX
1
Surrogate recovery is out of range
r
6
Client Sample ID: PIVOT 8 DEEP
Sample Number:
99-0406-008
Date Sampled:
02/04/99
Sample Matrix:
Solid
Time Sampled:
15:20
Sampled
By:
LW
EPA 9253
Chloride
350
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
393
mg/Kg
100
02/17/99
02/17/99
JMO
2
j
EPA 354.1M
Nitrite
0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
�+
EPA 3533
Nitrate
10.0
mg/Kg
10.0
02/15/99
02/15/99
BWB
10
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
160
mg/Kg
50
02/16/99
02/16/99
DID
1
Alkalinity as Bicarbonate
240
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010B
Boron
16
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
2380
mg/Kg
50
02/15/99
02/26/99
OX
1
Sodium
1180
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
5970
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
2770
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
4.6
mg/Kg
2.5
02/15/99
02/17/99
OX
I
Cadmium
1.71
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
10.8
mg/Kg
0.50
02/15/99
02/17/99
OX
1
i,
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
I
EPA 6010B
Zinc
31.4
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
9.15
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
9.1
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
11.2
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
I
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
460
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
3.1
02/24/99
OX
1
EPA 418.1
TPH
< 10
mg/Kg
10
02/24/99
02/24/99
BWM
1
Client Sample 1D: PIVOT 4 SHALLOW
P
Sample Number. 99-0406-009
Date Sampled:
02/04/99
Sample Matrix:
Solid
Time Sampled:
16:30
Sampled By:
LW
EPA 9253
Chloride
470 mg/Kg 50 02/17/99 02/17/99
BWB 1
EPA 9038
Sulfate
353 mg/Kg 100 02/17/99 02/17/99
JMO 2
Page 12 of 67
r-.
Certes Environmental Laboratories
209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620-7966.800.394-2872 - _ :72-620-7963 - Email: certescaol.com
r�
A,^atytical Chemistry Environmental Sciences ==search Microbiology
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99 .
Reporting
Date
Date
Analyzed
Sample: 99-0406-009 Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
r
i
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 353.3
Nitrate
3.6
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
120
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
20
mg/Kg
10
02/15/99
02/18/99
OX
1
i
Potassium
2490
mg/Kg
50
02/15/99
02/26/99
OX
I
Sodium
1360
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
10800
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
2900
mg/Kg
0.50
02/15/99
0226199
OX
1
{
Arsenic
3.4
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Cadmium
1.89
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
12.4
mg/Kg
0.50
02/15/99
02/17/99
OX
I
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
I
EPA 6010B
Zinc
32.9
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
8.71
mg/Kg
0.50
02/15/99
02/17/99
OX
1
{
Nickel
9.9
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
11.2
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
I
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
4,4'-DDE
< 1.67
jig/Kg
1.67
02/15/99
02/19/99
JCA
1
4,4'-DDT
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
f
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
alpha-BHC
< 1.67
jig/Kg
1.67
02/15/99
02/19/99
JCA
I
.,
beta-BHC
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
gamma-BHC
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
jig/Kg
I.67
02/15/99
02/18/99
JCA
1
Endosulfan II
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
u
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrinkeytone
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
pw
Endrin aldehyde
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r.
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Page 13 of 67
Certes Environmental Laboratories
-209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 - FIX ?72-620-7963- Email: certesCaol.com
~a:ytical Chemistry Environmental Sciences=esearch Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-009
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
r
EPA 8081A
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
l
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
*0%
60-140%
02/15/99
02/18/99
JCA
1
'
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
r--
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
t
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/19/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
y
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
*0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151 A
2,4-D
<100
µg/Kg
100
02/ 18199
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/19/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
i
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
292
mg/Kg
10
02/15/99
02/15/99
BM
1
F
EPA 351AM
Total Kjeldahl Nitrogen
470
mg/Kg
6
02/18/99
02/18/99
ARM
1
3.2.191
Sodium Absorbtion Ratio
3.1
02/24/99
OX
1
• Surrogate recovery Is out of range
Client Sample ID: PIVOT 4 DEEP
Sample Number:
99-0406-010
Date Sampled:
02/04/99
Sample Matrix:
Solid
Time Sampled:
16:35
Sampled By:
LW
EPA 9253
Chloride
230
mg/Kg
50
02/17/99 02/17/99
BWB 1
EPA 9038
Sulfate
<50
mg/Kg
50
02/17/99 02/17/99
JMO 1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99 02/15/99
JMO 1
EPA 353.3
Nitrate
3.4
mg/Kg
1.0
02/15/99 02/15/99
BWB 1
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB 1
Page 14 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872 - Fr:. 2-620-7963 - Email: certescaol.com
r^
—.^aiytical Chemistry Environmental Sciences F.Search Microbiology
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
k
Reporting
Date
Date Analyzed
Sample: 99-0406-010 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
SM 2320B
Alkalinity as Carbonate
240
mg/Kg
75
02/16/99
02/16/99
DJD
1.5
Alkalinity as Bicarbonate
240
mg/Kg
80
02/16/99
02/16/99
DJD
1.5
EPA 6010B
Boron
20
mg/Kg
10
02/15/99
02/18/99
OX
1
4 ,
+-
Potassium
2630
mg/Kg
50
02/15/99
02/26/99
OX
1
Sodium
1310
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
26200
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
2980
mg/Kg
0.50
02/15/99
02/26/99
OX
1
rw
Arsenic
<2.5
mg/Kg
2.5
02/15/99
02/17/99
OX
1
r
Cadmium
1.92
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
123
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
1
EPA 6010B
Zinc
34.0
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
15.4
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
11.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
14.9
mg/Kg
1.5
02/15/99
02/17/99
OX
1
r
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
,,.
EPA 351AM
Total Kjeldahl Nitrogen
490
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
1.6
02/24/99
OX
1
EPA 418.1
TPH
11
mg/Kg
10
02/24/99
02/24/99
BWM
1
Client Sample ID: PIVOT 16 SHALLOW
Sample Number:
99-0406-011
i
Date Sampled:
02/05/99
Sample
Matrix:
Solid
Time Sampled:
10:15
Sampled
By:
LW
EPA 9253
Chloride
500
mg/Kg
500
02/17/99
02/17/99
BWB
10
EPA 9038
Sulfate
312
mg/Kg
50
02/17/99
02/17/99
JMO
1
�.
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
r
EPA 3533
Nitrate
< 1.0
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
100
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
17
mg/Kg
10
02/15/99
02/19/99
OX
1
Potassium
2490
mg/Kg
50
02/15/99
02/26/99
OX
1
A
Sodium
1280
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
9380
mg/Kg
50
02/15/99
02/23/99
OX
1
t
Magnesium
3070
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
4.8
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Page 15 of 67
FS
i. - Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972-620-7966.800.394.2872 - _=. :72-620-7963 • Email: certes@aol.com
Analytical Chemistry Environmental Sciences - =search Microbiology
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
i
Reporting
Date
Date
Analyzed
Sample: 99-0406-011
Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
0.50
EPA 6010B
Cadmium
1.69
mg/Kg
02/15/99
02/17/99
OX
1
Chromium
12.0
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
31.6
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
10.8
mg/Kg
0.50
02/15/99
02/17/99
OX
1
'
Nickel
9.3
mg/Kg
1.0
02/15/99
02/17/99
OX
1
Lead
11.0
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium.
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
I
EPA 8081A
4,4'-DDD
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
I
4,4'-DDE
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDT
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
I
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
<1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/I8/99
JCA
I
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
jig/Kg
20.0
02/15/99
02/18/99
JCA
1
"Quality Control Surrogate
02/15/99
02/18/99
JCA
1
t
2,4,5,6-Tetrachloro-m-xylene (
72%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/I8/99
JCA
1
r
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Page 16 of 67
Certes Environmental Laboratories
'209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 • =72-620-7963 • Email: certes®aol.com
A^alytical Chemistry Environmental SciencesBe arch Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-011 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
�.
EPA 8082
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
72%
60-140%
02/15/99
02/18/99
JCA
1
[
!`
Decachlorobiphenyl(SS)
*0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/19/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
221
mg/Kg
10
02/15/99
02/15/99
BM
1
r
EPA 351AM
Total Kjeldahl Nitrogen
343
mg/Kg
6
02/18/99
02/18/99
ARM
1
l
3.2.191
Sodium Absorbtion Ratio
4.1
02/24/99
OX
1
* Surrogate recovery is out of range
E
Client Sample ID: PIVOT 16 DEEP
Date Sampled: 02/05/99
Time Sampled: 10:20
Sample Number: 99-0406-012
Sample Matrix: Solid
Sampled By: LW
EPA 9253
Chloride
470
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
511
mg/Kg
100
02/17/99
02/17/99
JMO
2
EPA 354AM
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
�+
C
EPA 3533
Nitrate
1.6
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
160
mg/Kg
50
02/16/99
02/16/99
DJD
l
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
16
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
2520
mg/Kg
50
02/15/99
02/26/99
OX
1
l
Sodium
1360
mg/Kg
50
02/15/99
02/26/99
OX
1
Calcium
13600
mg/Kg
50
02/15/99
02/23/99
OX
1
Magnesium
3240
mg/Kg
0.50
02/15/99
02/26/99
OX
1
Arsenic
3.5
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Cadmium
1.77
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
10.8
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
Page 17 of 67
` Certes Environmental Laboratories
�+ 22^.9 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972-620.7966.800-394-2872 - c72-620-7963 • Email: certes®aol.com
1 A^alvtical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-012
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 6010B
Zinc
30.2
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
8.00
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
93
mg/Kg
1.0
02/15/99
02/17/99
OX
1
'
Lead
11.4
mg/Kg
1.5
02/15/99
02/17/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
380
mg/Kg
75
02/17/99
02/17/99
TAL
1
r
3.2.191
Sodium Absorbtion Ratio
33
02/24/99
OX
1
EPA 418.1
TPH
< 10
mg/Kg
10
02/24/99
02/24/99
BWM
1
Client Sample 1D: PIVOT 19 SHALLOW
Sample Number: 99-0406-013
Date Sampled:
02/05/99
Sample Matrix:
Solid
[[
Time Sampled:
11:10
Sampled By:
LW
EPA 9253
Chloride
90
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
60
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 3533
Nitrate
2.0
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 232011
Alkalinity as Carbonate
Alkalinity as Bicarbonate
<50
120
mg/Kg
mg/Kg
50
50
02/16/99
02/16/99
02/16/99
02/16/99
DJD
DJD
I
1
EPA 6010B
Boron
18
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1880
mg/Kg
50
02/15/99
02/26/99
OX
1
Sodium
1120
mg/Kg
50
02/15/99
02/26/99
OX
I
Calcium
Magnesium
2310
2140
mg/Kg
mg/Kg
50
0.50
02/15/99
02/15/99
02/23/99
0226/99
OX
OX
1
I
Arsenic
6.2
mg/Kg
2.5
02/15/99
02/17/99
OX
1
Cadmium
1.65
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Chromium
11.4
mg/Kg
0.50
02/15/99
02/17/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
30.1
mg/Kg
5.0
02/15/99
02/17/99
OX
1
Copper
8.20
mg/Kg
0.50
02/15/99
02/17/99
OX
1
Nickel
Lead
9.4
10.8
mg/Kg
mg/Kg
1.0
1.5
02/15/99
02/15/99
02/17/99
02/17/99
OX
OX
1
I
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/17/99
OX
1
r
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/17/99
OX
1
`
EPA 8081A
4,4'-DDD
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
..
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Page 18 of 67
Certes Environmental Laboratories
-209 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972.620-7966. 800.394.2872 • _;.-. =72-620.7963 • Email: certescaol.com
A;ytical Chemistry Environmental Sciences =search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
i
Reporting
Date
Date
Analyzed
Sample: 99-0406-013
Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8081A
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
<1.67
µgfKg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
t
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan Il
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
84%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
t.6
(
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
l
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
;•�•
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
'
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
I,.
2,4,5,6-Tetrachloro-m-xylene (
84%
60-140%
02/15/99
02/18/99
JCA
1
'
Decachlorobipheny) (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 9151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
I
7
Dalapon
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
r
Dicamba
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
►-
Dichloroprop
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Page 19 of 67
7
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966.800-394-2872 • F= a72.620-7963 - Email: certes@aol.com
rAnalytical Chemistry Environmental Sciences Research Microbiology
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
"
Reporting
Date
Date
Analyzed
Sample: 99-0406-013 Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8151A
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
27
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
283
mg/Kg
6
02/18/99
02/18/99
ARM
1
!
3.2.191
Sodium Absorbtion Ratio
1.0
02/24/99
OX
1
* Surrogate recovery is out of range
t
Client Sample 1D: PIVOT 19 DEEP
P
Date Sampled: 02/05/99
Time Sampled: 11:15
Sample Number. 99-0406-014
Sample Matrix: Solid
Sampled By: LW
EPA 9253
Chloride
90
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
<50
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
�.,
EPA 3533
Nitrate
1.0
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
t.
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
l
Alkalinity as Bicarbonate
280
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
24
mg/Kg
10
02/15/99
02/18/99
OX
l
Potassium
1420
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
881
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
1480
mg/Kg
50
02/15/99
02/18/99
OX
1
r+�
Magnesium
1590
mg/Kg
0.50
02/15/99
02/18/99
OX
1
t
Arsenic
3.6
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.99
mg/Kg
0.50
02/15/99
02/18/99
OX
l
Chromium
11.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
32.9
mg/Kg
5.0
02/15/99
02/18/99
OX
1
t
Copper
9.14
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
10.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
12.5
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
360
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
0.8
0224/99
OX
1
Page 20 of 67
FCertes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966.800-394-2872 - = c'2-620-7963 • Email: certesCaol.com
Analytical Chemistry Environmental Sciences _ search Microbiology
r"
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared
Analyzed
By
Dilution
Client Sample ID: PIVOT 20 SHALLOW
Sample Number:
99-0406-015
Date Sampled:
02/05/99
Sample
Matrix:
Solid
f"
Time Sampled:
12:20
Sampled By:
LW
I
EPA 9253
Chloride
110
mg/Kg
50
02/17/99
02/17/99
BWB
I
EPA 9038
Sulfate
57
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 3533
Nitrate
3.2
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
I
SM 2320B
Alkalinity as Carbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
1
J
Alkalinity as Bicarbonate
500
mg/Kg
250
02/16/99
02/16/99
DJD
5
EPA 6010B
Boron
16
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
987
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
564
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
1370
mg/Kg
50
02/15/99
02/18/99
OX
1
Magnesium
1230
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
6.2
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
0.97
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
8.71
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
24.2
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
14.4
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
7.4
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
7.0
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDT
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
t
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r.,
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
d
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
i
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
^
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Page 21 of 67
FCertes Environmental Laboratories
7209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620.7966 - 800.394-2872 - :72-620-7963 • Email: certes®aol.com
�`-.-=-.ytical Chemistry Environmental Sciences=esearch Microbiology
#r#
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
d
Reporting
Date
Date
Analyzed
Sample: 99-0406-015
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8081A
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
jug/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r
I
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
r
**Quality Control Surrogate
02/15/99
02/18/99
JCA
I
2,4,5,6-Tetrachloro-m-xylene (
84%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
r.,
EPA 8082
Aroclor-1016
<25
jug/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
jug/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
`
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
�...
P
"Quality Control Surrogate
02/15/99
02/18/99
JCA
l
2,4,5,6-Tetrachloro-m-xylene (
84%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
*0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
r
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
11
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
259
mg/Kg
6
02/18/99
02/18/99
ARM
1
3.2.191
Sodium Absorbtion Ratio
0.9
0224/99
OX
1
EPA 8270C
Benzoic acid
<1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
4-Chloro-3-methylphenol
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
2-Chlorophenol
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
4'
2,4-Dichlorophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
l
2,4-Dimethylphenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
l
4,6-Dinitro-2-methylphenol
<660
jig/Kg
660
02/17/99
0223/99
ANA
l
7
r.,
Page 22 of 67
Certes Environmental Laboratories
2209 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 • :-2.620-7963 • Email: certescaol.com
-:,-�alytical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-015 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8270C 2,4-Dinitrophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
r"
4-Methylphenol
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
i
2-Nitrophenol
<660
jug/Kg
660
02/17/99
0223/99
ANA
1
4-Nitrophenol
<1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
r
i
E;
Pentachlorophenol
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
Phenol
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Acenaphthene
<330
µg/Kg
330
02/17/99
0223199
ANA
1
Acenaphthylene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Anthracene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
7
Benzidine
<2500
µg/Kg
2500
02/17/99
0223/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Benzo(b)fluoranthene
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(k)fluoranthene
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
�^
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
PM
4-Bromophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
t
Burylbenzylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
�•
4-Chloroaniline
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2-Chloronaphthalene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Chrysene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Dibenzo(a,h)anthracene
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
r.,,
Dibenzofuran
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
I
1,2-Dichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,3-Dichlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
7
1,4-Dichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1
3,3-Dichlorobenzidine
<670
jig/Kg
670
02/17/99
0223199
ANA
1
Diethylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
t
Dimethylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Di-n-butylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
FM
2,6-Dinitrotoluene (2,6-DNT)
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Page 23 of 67
r.
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620.7966.800-394.2872 -:72-620-7963 • Email: certesCaol.com
rAnalytical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-015 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C DI-n-octylphthalate
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
Fluoranthene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
Fluorene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorobutadiene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorocyclopentadiene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachloroethane
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
Indeno(1,2,3-cd)pyrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Isophorone
<660
µg/Kg
660
02/17/99
02/23/99
ANA
I
2-Methylnaphthalene
<330
jig/Kg
330
02/17/99
0223/99
ANA
I
Naphthalene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
'2-Nitroaniline
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
3-Nitroaniline
< 1650
jig/Kg
1650
02/17/99
0223/99
ANA
1
4-Nitroaniline
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
Nitrobenzene (NB)
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
N-Nitrosodimethylamine
<330
jig/Kg
330
02/17/99
0223/99
ANA
I
N-Nitrosodiphenylamine
<660
µg/Kg
660
02/17/99
0223/99
ANA
I
N-Nitrosodipropylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
I
Phenanthrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Pyrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,2,4-Trichlorobenzene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
"Quality Control Surrogate
02/17/99
0223/99
ANA
1
Nitrobenzene-d5 (SS)
39%
43-139%
02/17/99
0223/99
ANA
1
2-Fluorobiphenyl (SS)
52%
50-124%
02/17/99
0223/99
ANA
1
Terphenyl-dl4 (SS)
42%
62-145%
02/17/99
0223/99
ANA
I
* Surrogate recovery is out of range
,.� Client Sample ID: PIVOT 20 DEEP
I.
Date Sampled: 02/05/99
Time Sampled: 12:25
Sample Number: 99-0406-016
Sample Matrix: Solid
Sampled By: LW
EPA 9253
Chloride
130
mg/Kg
50
02/17/99
02/17/99
BWB
EPA 9038
Sulfate
91
mg/Kg
50
02/17/99
02/17/99
JMO
EPA 354.IM
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
EPA 3533
Nitrate
< 1.0
mg/Kg
1.0
02/15/99
02/15/99
BWB
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SM 2320B
Alkalinity as Carbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
Alkalinity as Bicarbonate
40
mg/Kg
50
02/16/99
02/16/99
DJD
EPA 6010B
Boron
18
mg/Kg
10
02/15/99
02/19/99
OX
' - Page 24 of 67
r"
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972-620-7966.600-394-2872 - == ?2-620-7963 • Email: certes 0 aol.com
n
^atytical Chemistry Environmental Sciences =search Microbiology
FM
F
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-016
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 6010B
Potassium
1110
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
655
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
1580
mg/Kg
50
02/15/99
02/18/99
OX
1
Magnesium
1340
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
5.6
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.57
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
9.90
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
4
EPA 6010B
Zinc
30.8
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
17.7
mg/Kg
0.50
02/15/99
02/19/99
OX
1
Nickel
7.9
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
12.9
mg/Kg
1.5
02/15/99
02/19/99
OX
1
.�
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
440
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
1.8
02/24/99
OX
1
Client Sample ID: PIVOT 10 SHALLOW
Sample Number: 99-0406-017
Date Sampled:
02/05/99
Sample
Matrix:
Solid
Time Sampled:
14:10
Sampled By:
LW
EPA 9253
Chloride
270
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
250
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 3533
Nitrate
2.0
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
21
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1260
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
1050
mg/Kg
50
02/15/99
02/19/99
OX
1
Calcium
1560
mg/Kg
50
02/15/99
02/18/99
OX
1
Magnesium
1460
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
5.8
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.64
mg/Kg
0.50
02/15/99
02/18/99
OX
I
Chromium
11.1
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
31.7
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Page 25 of 67
F. Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620-7966.800.394-2872 = c72-620-7963 • Email: certes@aot.com
t^ A--a:ytical Chemistry Environmental Sciences ==search Microbiology
I
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-017 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Copper
28.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
9.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
14.7
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081 A
4,4'-DDD
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
jig/Kg
1.67
02/15/99
02/19/99
JCA
1
Endrin
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
<1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/19/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/19/99
JCA
1
**Quality Control Surrogate
02/15/99
02/19/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
85%
60-140%
02/15/99
02/19/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/19/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/19/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/19/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/I8/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/19/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/19/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/l8/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
85%
60-140%
02/15/99
02/19/99
JCA
1
Decachlorobiphenyl(SS)
*0%
60-140%
02/15/99
02/19/99
JCA
1
Page
26 of 67
Certes Environmental Lanoratories
=?09 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 - F=',.:'2-620-7963 • Email: certes@aol.com
Ana,ytical Chemistry Environmental Sciences ==search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-017 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8151A
2,4-D
< 100
µg/Kg
100
02/18/99
02/19/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/19/99
ARM
1
2,4,5-T
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/19/99
ARM
1
Dichloroprop
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
19
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
309
mg/Kg
6
02/18/99
02/18/99
ARM
1
3.2.191
Sodium Absorbtion Ratio
3.3
02/24/99
OX
1
* Surrogate recovery is out of range
Client Sample ID: PIVOT 10 DEEP
Sample Number. 99-0406-018
Date Sampled:
02/05/99
Sample
Matrix:
Solid
Time Sampled:
14:15
Sampled
By:
LW
EPA 9253
Chloride
550
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
373
mg/Kg
100
02/17/99
02/17/99
JMO
2
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
I
EPA 3533
Nitrate
5.8
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
160
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010E
Boron
24
mg/Kg
10
02/15/99
02/I8/99
OX
1
Potassium
1470
mg/Kg
50
02/15/99
02/19/99
OX
1
Sodium
1320
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
6340
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1570
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
6.4
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
2.03
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
12.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010E
Zinc
35.8
mg/Kg
5.0
02/15/99
02/19/99
OX
1
Copper
15.8
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
10.4
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
23.1
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Page 27 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.600-394.2872 - F.-':-, c'2.620-7963 • Email: certescaol.com
f Anwytical Chemistry Environmental Sciences =._search Microbiology
F
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
i
Reporting
Date
Date
Analyzed
Sample: 99-0406-018
continued...
Result
Units
Limit
Prepared
Analyzed
By Dilution
f
EPA 6010B
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX 1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX 1
EPA 351AM
Total Kjeldahl Nitrogen
380
mg/Kg
75
02/17/99
02/17/99
TAL 1
3.2.191
Sodium Absorbtion Ratio
4.3
02/24/99
OX 1
Flo Client Sample ID: PIVOT 11 SHALLOW Sample Number: 99-0406-019
t Date Sampled: 02/05/99 Sample Matrix: Solid
Time Sampled: 15:00 Sampled By: LW
EPA 9253
Chloride
320
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
221
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 3533
Nitrate
3.1
mg/Kg
1.0
02/15/99
02/15/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
160
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
120
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
22
mg/Kg
10
02/15/99
02/19/99
OX
1
Potassium
1640
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
887
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
8710
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1700
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
4.5
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
2.09
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
11.9
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
36.0
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
173
mg/Kg
0.50
02/15/99
02/18/99
OX
I
Nickel
10.5
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
14.0
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
4,4'-DDE
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
I
4,4'-DDT
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
Page 28 of 67
FCertes Environmental Laboratories
12:9 Wisconsin Street, Suite 200 Dallas. Texas. 75229. 972.620-7966. 600-394.2872 • =--2-620-7963- Email: certes®aol.com
FM
I Ara:vtical Chemistry Environmental Sciences ==:=arch Microbiology
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-019 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
gamma-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
80%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
I
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
I
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/19/99
JCA
I
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/19/99
JCA
1
**Quality Control Surrogate
02/15/99
02/19/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
90%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/19/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/19/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/19/99
02/19/99
ARM
I
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/19/99
ARM
1
Dalapon
<100
µg/Kg
100
02/19/99
02/19/99
ARM
1
Dicamba
<100
µg/Kg
100
02/19/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/19/99
02/19/99
ARM
I
Dinoseb
<100
µg/Kg
100
02/18/99
02/19/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 419.1
TPH
24
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
299
mg/Kg
6
02/18/99
02/18/99
ARM
1
Page 29 of 67
7
1 Certes Environmental Laboratories
Wisconsin Street. Suite 200 Dallas, Texas. 75229. 972-620.7966.800.394-2872 - F=:,. ;-2-620-7963• Email: certesCaol.com
A,= :,:ical Chemistry Environmental Sciences -=search Microbiology
p
r
i'
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-019 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
3.2.191 Sodium Absorbtion Ratio
2.4
02/24/99
OX
1
EPA 8270C Benzoic acid
<1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
4-Chloro-3-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
l
2-Chlorophenol
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
2,4-Dichlorophcnol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dimethylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
I
4,6-Dinitro-2-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dinitrophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2-Nitrophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Nitrophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
Pentachlorophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
Phenol
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Acenaphthene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Acenaphthylene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Anthracene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Benzidine
<2500
µg/Kg
2500
02/17/99
02/23/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Benzo(b)fluoranthene
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Benzo(k)fluoranthene
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Bcnzyl alcohol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Bromophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Butylbenzylphthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2-Chloronaphthalcne
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Chrysene
<330
µg/Kg
.330
02/17/99
0223/99
ANA
1
Dibenzo(a,h)anthracene
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
Dibenzofuran
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
1,2-Dichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Page 30 of 67
FCaries Environmental Laboratones
_'M" lisconsin Street. Suite 200 Dallas. Texas. 75229.972.620.7966.800-394.2872 • F :-2-620 7963• Email: certes@aol.com
r
A^a ytical Chemistry Environmental Sciences - _ _earch Microbiology
r
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-019 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C 1,3-Dichlorobenzene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
1,4-Dichlorobenzene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
3,3-Dichlorobenzidine
<670
µg/Kg
670
02/17/99
0223/99
ANA
I
Diethylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Dimethylphthalate
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
Di-n-butylphthalate
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
2,6-Dinitrotoluene (2,6-DNT)
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
DI-n-octylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Fluoranthene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Fluorene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorobutadiene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorocyclopentadiene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachloroethane
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
lndeno(1,2,3-cd)pyrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Isophorone
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2-Methylnaphthalene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Naphthalene.
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
2-Nitroaniline
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
3-Nitroaniline
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
I
4-Nitroaniline
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
Nitrobenzene (NB)
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
N-Nitrosodimethylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
N-Nitrosodiphenylamine
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
N-Nitrosodipropylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Phenanthrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Pyrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,2,4-Trichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
"Quality Control Surrogate
02/17/99
0223/99
ANA
1
Nitrobenzene-d5 (SS)
43%
43-138%
02/17/99
0223/99
ANA
1
2-Fluorobiphenyl (SS)
56%
50-124%
02/17/99
0223/99
ANA
1
Terphenyl-d14 (SS)
43%
62-145%
02/17/99
0223/99
ANA
1
* Surrogate recovery Is out of range
Client Sample 1D: PIVOT 11 DEEP Sample Number: 99-0406-020
Date Sampled: 02/05/99 Sample Matrix: Solid
Time Sampled: 15:05 Sampled By: LW
r, EPA 9253
i
Chloride 360 mg/Kg 50 02/17/99 02/17/99 BWB 1
Page 31 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas. 75229. 972-620-7966 .800.394.2872 • :-2.620.7963- Email: certes@aol.com
Analytical Chemistry Environmental Sciences Search Microbiology
r
I
7-
Results of Analyses
CEL File No.: 99-0406
• Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-020 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 9038
Sulfate
232
mg/Kg
50
02/17/99
02/17/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/15/99
02/15/99
JMO
1
EPA 353.3
Nitrate
3.8
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 350.3M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/Kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
27
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1780
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
972
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
16400
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1740
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
5.3
mg/Kg
2.5
02/15/99
02/19/99
OX
1
Cadmium
2.27
mg/Kg
0.50
02/15/99
02/19/99
OX
1
Chromium
13.9
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
40.9
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
21.0
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
12.1
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
14.7
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
530
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
2.8
02/24/99
OX
1
Client Sample 1D: PIVOT 13 SHALLOW
Sample Number: 99-0406-021
Date Sampled:
02/05/99
Sample Matrix:
Solid
Time Sampled:
15:50
Sampled By:
LW
EPA 9253
Chloride
230
mg/Kg
50
02/17/99 02/17/99
BWB
1
EPA 9038
Sulfate
180
mg/Kg
100
02/18/99 02/18/99
JMO
2
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/16/99 02/16/99
JMO
1
EPA 3533
Nitrate
2.0
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
EPA 350.3M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
160
mg/kg
50
02/16/99 02/16/99
DJD
1
Alkalinity as Bicarbonate
160
mg/Kg
50
02/16/99 02/16/99
DJD
1
EPA 6010B
Boron
16
mg/Kg
10
02/15/99 02/18/99
OX
1
Potassium
1510
mg/Kg
50
02/15/99 02/18/99
OX
1
Sodium
813
mg/Kg
50
02/15/99 02/18/99
OX
1
Page 32 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7956.800-394-2872 • FAX 2-620-7963 • Email: certes®aol.com
A-alytical Chemistry Environmental Sciences F.aSearch Microbiology
r�►
f
C-
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-021 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010E
Calcium
7900
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1720
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
6.7
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
137
mg/Kg
0.50
02/18/99
OX
1
Chromium
8.48
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
29.1
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
25.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
8.2
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
10.2
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
jig/Kg
20.0
02/15/99
02/18/99
JCA
1
"Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
88%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Page 33 of 67
7 Certes Environmental Laboratories
-:_ 3 '. Jisconsin Street, Suite 200 Dallas, Texas. 75229.972.620.7966.800-394-2872 • F : -2-620.7963 • Email: certes@aol.com
~ Ar�=;:;:cal Chemistry Environmental Sciences ==search Microbiology
I
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
'
Reporting
Date
Date
Analyzed
Sample: 99-0406-021
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8082
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
ir `
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
!
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/9Y
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
88%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
< 100
µg/Kg
100
02/18/99
02/19/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
< 100
µg/Kg
100
02/19/99
02/18/99
ARM
1
Dicamba
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
18
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
400
mg/Kg
75
02/17/99
02/17/99
TAL
1
3.2.191
Sodium Absorbtion Ratio
1.6
02/24/99
OX
1
* Surrogate recovery Is out of range
Client Sample ID: PIVOT 13 DEEP
Date Sampled: 02/05/99
Time Sampled: 15:55
Sample Number:
Sample Matrix:
Sampled By:
99-0406-022
Solid
LW
EPA 9253
Chloride
310
mg/Kg
50
02/17/99 02/17/99
BWB
1
EPA 9038
Sulfate
93
mg/Kg
50
02/18/99 02/19/99
JMO
1
,..
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/16/99 02/16/99
JMO
1
EPA 3533
Nitrate
1.6
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/kg
50
02/16/99 02/16/99
DJD
1
Alkalinity as Bicarbonate
400
mg/Kg
50
02/16/99 02/16/99
DJD
1
EPA 6010B
Boron
17
mg/Kg
10
02/15/99 02/18/99
OX
1
Potassium
1540
mg/Kg
50
02/15/99 02/18/99
OX
1
-
Sodium
894
mg/Kg
50
02/15/99 02/19/99
OX
1
Calcium
17200
mg/Kg
50
02/15/99 02/19/99
OX
1
Magnesium
1820
mg/Kg
0.50
02/15/99 02/18/99
OX
1
Arsenic
5.6
mg/Kg
2.5
02/15/99 02/18/99
OX
1
P Page 34 of 67
Certes Environmental Laboratories
==39 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620-7966.800.394-2872 - :'2-620-7963 • Email: certes@aol.com
7 Ana- tical Chemistry Environmental Sciences ==:earth Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
¢
Reporting
Date
Date
Analyzed
Sample: 99-0406-022 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 6010B
Cadmium
1.44
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
9.30
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
28.5
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
11.7
mg/Kg
0.50
02/15/99
02/18/99
OX
1
(
Nickel
8.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
1
Lead
8.3
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
760
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
4.7
02/24/99
OX
1
Client Sample ID: PIVOT 14 SHALLOW
Date Sampled: 02/08/99
Time Sampled: 9:50
Sample Number:
Sample Matrix:
Sampled By:
99-0406-023
Solid
LW
EPA 9253
Chloride
170
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
330
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.1
mg/Kg
0.1
02/16/99
02/16/99
JMO
1
EPA 3533
Nitrate
2.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/kg
50
02/16/99
02/16/99
DJD
1
rl-
Alkalinity as Bicarbonate
<50
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
23
mg/Kg
10
02/15/99
02/18/99
OX
1
�+-
Potassium
1710
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
829
mg/Kg
50
02/15/99
02/18/99
OX
1
t
Calcium
2440
mg/Kg
50
02/15/99
02/19/99
OX
1
.,.
Magnesium
1680
mg/Kg
0.50
02/15/99
02/18/99
OX
1
I
i
Arsenic
6.4
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.95
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
11.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
37.8
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
18.7
mg/Kg
0.50
02/15/99
02/18/99
OX
1
6
Nickel
103
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
12.9
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Page 35 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620.7966.800.394-2872 - = i:-2-620-7963 • Email: certescaol.com
Analytical Chemistry Environmental Sciences = =search Microbiology
J
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-023
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
{
EPA 8081A
4,4'-DDD
<1,67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
2.40
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
j�
4,4'-DDT
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
l
Aldrin
<1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
r
Endosulfan I
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
.-
Endosulfan H
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
i
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
I
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
73%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
ra
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
p
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
€
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
r
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
I
**Quality Control Surrogate
02/15/99
02/18/99
JCA
I
2,4,5,6-Tetrachloro-m-xylene (
73%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
I
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
r�
2,4,5-T
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
I
2,4,5-TP (Silvex)
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Page 36 of 67
Certes Environmental Laboratories
-=:9 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 • = 2-620-7963 - Email: certes@aol.com
r�
f A-- vocal Chemistry Environmental Sciences = =search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-023
Continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8151A
Dicamba
<100
pg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
t
EPA 418.1
TPH
35
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
1000
mg/Kg
10
02/18/99
02/18/99
STR
1
r
3.2.191
Sodium Absorbtion Ratio
1.4
0224/99
OX
1
* Surrogate recovery is out of range
Client Sample ID: PIVOT 14 DEEP
Sample Number. 99-0406-024
Date Sampled:
02/08/99
Sample Matrix:
Solid
Time Sampled:
9:55
Sampled By:
LW
EPA 9253
Chloride
280
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
EPA 354.1 M
Sulfate
Nitrite
83
0.1
mg/Kg
mg/Kg
50
0.1
02/18/99
02/16/99
02/19/99
02/16/99
JMO
JMO
1
1
EPA 3533
Nitrate
5.2
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/kg
50
02/16/99
02/16/99
DJD
1
+
Alkalinity as Bicarbonate
240
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
23
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1380
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
1030
mg/Kg
50
02/15/99
02/18/99
OX
1
I
Calcium
4370
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
Arsenic
1640
6.5
mg/Kg
mg/Kg
0.50
2.5
02/15/99
02/15/99
02/19/99
02/19/99
OX
OX
1
1
Cadmium
1.68
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
11.0
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
33.7
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
173
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
10.1
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
12.7
mg/Kg
1.5
02/15/99
02/18/99
OX
1
'
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
1000
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
2.4
0224/99
OX
1
Page 37of 67
i Certes Environmental Laboratories
:209 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620.7966.800-394.2872- F;-:::'2-620-7963- Email: certes®aol.com
i Ar-- ytical Chemistry Environmental Sciences Research Microbiology
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
Client Sample ID: PIVOT 1 SHALLOW
Sample Number:
99-0406-025
Date Sampled:
02/08/99
Sample
Matrix:
Solid
Time Sampled:
10:40
Sampled By:
LW
EPA 9253
Chloride
240
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
180
mg/Kg
50
02/18/99
02/18/99
JMO
I
EPA354.1M
Nitrite
<1.0
mg/Kg
1.0
02/16/99
02/16/99
JMO
10
EPA 3533
Nitrate
3.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
I.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
240
mg/kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
320
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
19
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1300
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
690
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
4650
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1460
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
6.2
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.76
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
11.0
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
30.5
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
13.7
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
8.7
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
11.2
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081A
4,4'-DDD
< 1.67
jig/Kg
1.67
02/15/99
02/24/99
JCA
1
4,4'-DDE
< I.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
4,4'-DDT
< 1.67
jig/Kg
1.67
02/15/99
02/24/99
JCA
1
Aldrin
< 1.67
jig/Kg
1.67
02/15/99
02/24/99
JCA
1
alpha-BHC
<1.67
µg/Kg
1.67
02/15/99
0224/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
0224/99
JCA
1
delta-BHC
< 1.67
jig/Kg
1.67
02/15/99
0224/99
JCA
1
gamma-BHC
< 1.67
jig/Kg
1.67
02/15/99
0224/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
0224/99
JCA
1
gamma -Chlordane
< 1.67
jig/Kg
1.67
02/15/99
0224/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
0224/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
0224/99
JCA
1
Endosulfan II
< 1.67
µg/Kg
1.67
02/15/99
0224/99
JCA
1
Page 38 of 67
FCartes Environmental Laboratories
:==9'�,isconsin Street. Suite 200 Dallas. Texas.75229.972.620-7966.600-394.2872- F 620-7963• Email:certesCaol.com
Ana:.:t;cai Chemistry Environmental Sciences -=search Microbiology
i
FResults of Analyses CEL File No.: 99-0406 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
r.
Sample: 99-0406-025 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Endosulfan sulfate
<1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Endrin keytone
<1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Endrin aldehyde
<1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Heptachlor
<1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Methoxychlor
<1.67
µg/Kg
1.67
02/15/99
02/24/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/24/99
JCA
1
"Quality Control Surrogate
02/15/99
02/24/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
63%
60-140%
02/15/99
02/24/99
JCA
1
Decachlorobiphenyl (SS)
79%
60-140%
02/15/99
02/24/99
JCA
1
a
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/24/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
0224/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/24/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/24/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/24/99
JCA
1
I
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/24/99
JCA
1
�-.
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/24/99
JCA
1
"Quality Control Surrogate
02/15/99
02/24/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
63%
60-140%
02/15/99
02/24/99
JCA
1
Decachlorobiphenyl (SS)
79%
60-140%
02/15/99
02/24/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
r-
m
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
28
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
720
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
2.0
02/16/99
0224/99
OX
1
EPA 8270C
Benzoic acid
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
4-Chloro-3-methylphenol
2-Chlorophenol
<660
<330
µg/Kg
µg/Kg
660
330
02/17/99
02/17/99
02/23/99
02/23/99
ANA
ANA
1
1
2,4-Dichlorophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2,4-Dimethylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
r
Page 39 of 67
Certes Environmental Laboratories
s209 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620-7966. 800-394-2872 - _ :-=-620-7963 • Email: certes®aol.com
nagtical Chemistry Environmental Sciences ==Search Microbiology
FResults of Analyses CEL File No.: 99-0406 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-025 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 8270C 4,6-Dinitro-2-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dinitrophenol
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
r2-Methylphenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
`
4-Methylphenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2-Nitrophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
I
4-Nitrophenol
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
Pentachlorophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
I
Phenol
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Acenaphthene
<330
µg/Kg
330
02/17/99
0223/99
ANA
I
Acenaphthylene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
r
Anthracene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
l .
Benzidine
<2500
µg/Kg
2500
02/17/99
0223/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/17/99
0223/99
ANA
I
Benzo(b)fluoranthene
<660
µg/Kg
660
02/17/99
0223/99
ANA
I.
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(k)fluoranthene
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
02/17/99
0223/99
ANA
I
bis-(2-chloroethyl) ether
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
4-Bromophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Butylbenzylphthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2-Chloronaphthalene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Chrysene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Dibenzo(a,h)anthracene
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
Dibcnzofutan
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
1,2-Dichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,3-Dichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,4-Dichlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
3,3-Dichlorobenzidine
Diethylphthalate
<670
<660
µg/Kg
µg/Kg
670
660
02/17/99
02/17/99
0223/99
0223/99
ANA
ANA
1
1
Dimethylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
i'
Di-n-butylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Page 40 of 67
l;
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620.7966.800.394-2872
- F-.,
:-2-620-7963 - Email: certesQaol.com
��a.ytical Chemistry Environmental Sciences
==:=arch
Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
i
7
Samnle: 99-0406-025 continued...
EPA 8270C 2,6-Dinitrotoluene (2,6-DNT)
Dl-n-octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene (NB)
N-N itrosod imethylam ine
N-Nitrosodiphenylamine
N-Nitrosodipropylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
"Quality Control Surrogate
Nitrobenzene-d5(SS)
2-Fluorobiphenyl (SS)
Terphenyl-d14 (SS)
Reporting
Date
Date
Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
02/17/99
02/23/99
ANA
1
42%
43-138%
02/17/99
02/23/99
ANA
1
56%
50-124%
02/17/99
02/23/99
ANA
1
47%
62-145%
02/17/99
02/23/99
ANA
1
Client Sample ID: PIVOT 1 DEEP
Date Sampled: 02/08/99
Time Sampled: 10:45
Sample Number: 99-0406-026
Sample Matrix: Solid
Sampled By: LW
EPA 9253
Chloride
240
mg/Kg
50
02/17/99 02/17/99
BWB I
EPA 9038
Sulfate
147
mg/Kg
50
02/18/99 02/18/99
JMO I
EPA 354.1 M
Nitrite
< 1.0
mg/Kg
1.0
02/16/99 02/16/99
JMO 10
EPA 3533
Nitrate
3.4
mg/Kg
1.0
02/15/99 02/16/99
BWB I
EPA 3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB 1
SM 2320B
Alkalinity as Carbonate
320
mg/kg
50
02/16/99 02/16/99
DJD 1
Alkalinity as Bicarbonate
440
mg/Kg
50
02/16/99 02/16/99
DJD 1
Page 41 of 67
Certes Environmental Laboratories
-=:9 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620.7966 - 800-394.2872 - c-2.620-7963 - Email; certes@aol.com
A! -a ,; :;cal Chemistry Environmental Sciences search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-026
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 6010B
Boron
24
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1360
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
817
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
9710
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1510
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
5.0
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
2.07
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
11.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
34.5
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
11.2
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
10.5
mg/Kg
1.0
02/15/99
02/18/99
OX
1
.-
Lead
14.6
mg/Kg
1.5
02/15/99
02/18/99
OX
1
r
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
I
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
1500
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
2.2
0224/99
OX
1
F
Client Sample ID: FLOOD PLAIN SHALLOW
Date Sampled: 02/08/99
Time Sampled: 11:40
Sample Number:
Sample Matrix:
Sampled By:
99-0406-027
Solid
LW
fpp1'
EPA 9253
Chloride
80
mg/Kg
50
02/17/99
02/17/99
BWB
1
t
EPA 9038
Sulfate
<50
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
i
EPA 353.3
Nitrate
2.6
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA3503M
Ammonia
<1.0
mg/Kg
LO
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
200
mg/kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
200
mg/Kg
50
02/16/99
02/16/99
DID
1
EPA 6010B
Boron
18
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1430
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
309
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
2480
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1510
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
6.7
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.53
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
9.48
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 747IA
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
Page
42 of67
=
Certes Environmental Laboratories
"29 Wisconsin Street, Suite 200 Dallas, Texas. 75229. 972.620.7966.800-394.2872 • _=. :72.620-7963 • Email: certes@aol.com
r
Ara -Aical Chemistry Environmental Sciences
=_.earth
Microbiology
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Samnle: 99-0406-027 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Zinc
30.8
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
19.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
8.3
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
13.1
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081A
4,4'-DDD
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
4,4'-DDT
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
beta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan 1
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan11
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
"Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
83%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
"Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
93%
60-140%
02/15/99
02/18/99
JCA
1
Page 43 of 67
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972.620.7966.800.394-2872 • _=._='2.620-7963 • Email: Certescaol.com
r-
Analytical Chemistry Environmental Sciences = es -earth Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-027 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8082
Decachlorobiphenyl (SS)
* 0%
60-140'/o
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
I
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
15
mg/Kg
10
02/15/99
02/15/99
BM
I
EPA 351AM
Total Kjeldahl Nitrogen
1400
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
0.5
0224/99
OX
1
* Surrogate recovery is out of range
Client Sample ID: FLOOD PLAIN DEEP
Sample Number: 99-0406-028
Date Sampled:
02/08/99
Sample
Matrix:
Solid
Time Sampled:
11:45
Sampled
By:
LW
EPA 9253
Chloride
60
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
<50
mg/Kg
50
02/18/99
02/18/99
JMO.
1
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
EPA 3533
Nitrate
1.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
80
mg/kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
120
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
18
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1450
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
409
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
1420
mg/Kg
50
02/15/99
02/18/99
OX
1
Magnesium
1510
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
3.6
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.65
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
10.2
mg/Kg
0.50
02/15/99
02/18/99
OX
I
EPA -471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
313
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
11.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
8.1
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Page 44 of 67
t^
Certes Environmental Laboratories
-:9 Wisconsin Street, Suite 200 Dallas, Texas, 75229 •972-620.7966. 800-394-2872 - = .—c'-320-7963- Email: certes@aol.com
ra , : cal Chemistry Environmental Sciences —-:earch Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Sample: 99-0406-028 continued...
EPA 6010B Lead
Selenium
r Molybdenum
EPA 351AM Total Kjeldahl Nitrogen
3.2.191 Sodium Absorbtion Ratio
r
Reporting
Date
Date
Analyzed
Result
Units
Limit
Prepared Analyzed
By Dilution
21.9
mg/Kg
1.5
02/15/99
02/18/99
OX 1
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX 1
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX 1
1300
mg/Kg
10
02/18/99
02/18/99
STR 1
0.5
02/16/99
02/24/99
OX 1
Client Sample 1D: PIVOT 21 SHALLOW Sample Number: 99-0406-029
Date Sampled: 02/08/99 Sample Matrix: Solid
Time Sampled: 12:50 Sampled By: LW
EPA 9253
Chloride
170
mg/Kg
50
02/17/99
02/17/99
BWB
EPA 9038
Sulfate
144
mg/Kg
50
02/18/99
02/18/99
JMO
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
EPA 3533
Nitrate
2.8
mg/Kg
1.0
02/15/99
02/16/99
BWB
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SM 2320B
Alkalinity as Carbonate
320
mg/kg
50
02/16/99
02/16/99
DJD
Alkalinity as Bicarbonate
640
mg/Kg
50
02/16/99
02/16/99
DJD
EPA 6010E
Boron
20
mg/Kg
10
02/15/99
02/18/99
OX
Potassium
1600
mg/Kg
50
02/15/99
02/18/99
OX
Sodium
653
mg/Kg
50
02/15/99
02/18/99
OX
Calcium
2480
mg/Kg
50
02/15/99
02/19/99
OX
Magnesium
1630
mg/Kg
0.50
02/15/99
02/18/99
OX
Arsenic
6.6
mg/Kg
2.5
02/15/99
02/19/99
OX
Cadmium
1.81
mg/Kg
0.50
02/15/99
02/18/99
OX
Chromium
11.4
mg/Kg
0.50
02/15/99
02/18/99
OX
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
EPA 6010E
Zinc
33.2
mg/Kg
5.0
02/15/99
02/18/99
OX
Copper
9.15
mg/Kg
0.50
02/15/99
02/18/99
OX
Nickel
9.6
mg/Kg
1.0
02/15/99
02/18/99
OX
Lead
123
mg/Kg
1.5
02/15/99
02/18/99
OX
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/19/99
OX
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
4,4'-DDE
335
µg/Kg
1.67
02/15/99
02/18/99
JCA
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/18/90
JCA
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
Page 45 of 67
t _ Certes Environmental Laboratories
c09 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.600.394-2372 - F- 2-620-7963 - Email: certes@aol.com
r'+- a yucal Chemistry Environmental Sciences = _ _-arch Microbiology
r
F
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-029 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
delta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma-BHC
< 1.67
jig/Kg
1.67
02/15/99
02/18/99
JCA
I
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan II
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endosulfan sulfate
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin keytone
<1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/18/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/18/99
JCA
1
**Quality Control Surrogate
02/15/99
02/18/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/15/99
02/18/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/18/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
23
mg/Kg
10
02/15/99
02/15/99
BM
1
Page 46 of 67
Certes Environmental Laboratories
_2C9 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 - _= =72-620-7963 • Email: certes@aol.com
i
Ara :-tical Chemistry Environmental Sciences = = search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting Date Date
Analyzed
Sample: 99-0406-029 continued...
Result Units
Limit Prepared Analyzed
By Dilution
EPA 351.4M Total Kjeldahl Nitrogen
1300 mg/Kg
10 02/18/99 02/18/99
STR 1
3.2.191 Sodium Absorbtion Ratio
1.9
02/24/99
OX 1
* Surrogate recovery is out of range
Client Sample ID: PIVOT 21 DEEP
Sample Number: 99-0406-030
Date Sampled:
02/08/99
Sample Matrix:
Solid
Time Sampled:
12:55
Sampled
By:
LW
EPA 9253
Chloride
150
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
110
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
EPA353.3
Nitrate
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
560
mg/kg
50
02/16/99
02/16/99
DID
1
Alkalinity as Bicarbonate
1400
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
24
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1540
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
823
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
9580
mg/Kg
50
02/15/99
02/19/99
OX
1
Magnesium
1590
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
6.0
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.93
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
12.2
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
33.8
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
72.9
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
10.9
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
13.6
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
990
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
2.0
02/24/99
OX
1
Client Sample ID: PIVOT 18 SHALLOW Sample Number: 99-0406-031
Date Sampled: 02/06/99 Sample Matrix: Solid
Time Sampled: 11:00 Sampled By: LW
EPA 9253 Chloride 900 mg/Kg 500 02/17/99 02/17/99 BWB 10
EPA 9038 Sulfate 131 mg/Kg 50 02/18/99 02/18/99 JMO 1
Page 47 of 67
t^
Certes Environmental Lat)oratories
:209 Wisconsin Street, Suite 200 Dallas, Texas, 75229 972 620 7906.800.394-2872 • :-'%620-7963 • Email: certesQaol.com
r
A -a vtical Chemistry Environmental Sciences =search Microbiology
F
F",
r1k
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-031 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
EPA 353.3
Nitrate
14.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
320
mg/kg
100
02/16/99
02/16/99
DJD
2
Alkalinity as Bicarbonate
1040
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010E
Boron
19
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1460
mg/Kg
50
02/15/99
02/19/99
OX
1
Sodium
893
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
3040
mg/Kg
50
02/15/99
02/26/99
OX
1
Magnesium
1520
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
4.1
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
1.60
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
11.8
mg/Kg
0.50
02/15/99
02/18/99
OX
I
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
36.2
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
18.7
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
8.1
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
40.1
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081A
4,4'-DDD
<1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
I
4,4'-DDE
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
I
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
beta-BHC
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endosulfan II
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
I
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Page 48 of67
' Certes Environmental Laboratories
__-9 Wisconsin Street, Suite 200 Dallas. Texas, 75229 •972-620.7966-800.394.2872 - F-., 2.620-7963 • Email: certes�aol.com
Ana.yucai Chemistry Environmental Sciences , . = _aarch Microbiology
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-031
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
,.
EPA 8081A
Methoxychlor
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/26/99
JCA
1
"Quality Control Surrogate
02/15/99
02/26/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
62%
60-140%
02/15/99
02/26/99
JCA
1
Decachlorobiphenyl (SS)
90%
60-140%
02/15/99
02/26/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/26/99
JCA
l
r�
"Quality Control Surrogate
02/15/99
02/26/99
JCA
l
2,4,5,6-Tetrachloro-m-xylene (
62%
60-140%
02/15/99
02/26/99
JCA
1
Decachlorobiphenyl (SS)
90%
60-140%
02/15/99
02/26/99
JCA
1
I ,
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
I
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
„
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
28
mg/Kg
10
02/15/99
02/15/99
BM
I
EPA 351.4M
Total Kjeldahl Nitrogen
800
mg/Kg
10
02/18/99
02/18/99
STR
1
i
3.2.191
Sodium Absorbtion Ratio
3.1
02/24/99
OX
1
Client Sample ID: PIVOT 18 DEEP
Sample Number. 99-0406-032
Date Sampled:
02/06/99
Sample Matrix:
Solid
Time Sampled:
11:05
Sampled By:
LW
EPA 9253
Chloride
450
mg/Kg
50
02/17/99 02/17/99
BWB 1
EPA 9038
Sulfate
220
mg/Kg
50
02/18/99 02/18/99
JMO l
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99 02/16/99
JMO 2
EPA 353.3
Nitrate
5.0
mg/Kg
1.0
02/15/99 02/16/99
BWB l
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB 1
Page 49 of 67
7
f ' Certes Environmental Laboratories
_::9 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620.7966.800.39-1-2872 • = c 2 620 7963 • Email: certescaol.com
A -- Chemistry Environmental Sciences ==search Microbiology
f
J
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-032 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
SM 2320B
Alkalinity as Carbonate
320
mg/kg
50
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
440
mg/Kg
50
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
27
mg/Kg
10
02/15/99
02/18/99
OX
1
Potassium
1860
mg/Kg
50
02/15/99
02/18/99
OX
1
Sodium
1160
mg/Kg
50
02/15/99
02/18/99
OX
1
Calcium
10200
mg/Kg
50
02/15/99
02/26/99
OX
1
Magnesium
1710
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Arsenic
5.6
mg/Kg
2.5
02/15/99
02/18/99
OX
1
Cadmium
2.20
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Chromium
13.0
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
42.1
mg/Kg
5.0
02/15/99
02/18/99
OX
1
Copper
19.1
mg/Kg
0.50
02/15/99
02/18/99
OX
1
Nickel
11.8
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
17.1
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
73
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
4.4
02/24/99
OX
1
Client Sample 1D: PIVOT 17 SHALLOW Sample Number: 99-0406-033
Date Sampled: 02/06/99 Sample Matrix: Solid
Time Sampled: 12:20 Sampled By: LW
EPA 9253
Chloride
240
mg/Kg
50
02/17/99
02/17/99,
BWB
EPA 9038
Sulfate
137
mg/Kg
50
02/18/99
02/18/99
JMO
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
EPA 3533
Nitrate
7.7
mg/Kg
1.0
02/15/99
02/16/99
BWB
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SM 2320B
Alkalinity as Carbonate
320
mg/kg
100
02/16/99
02/16/99
DJD
Alkalinity as Bicarbonate
320
mg/Kg
100
02/16/99
02/16/99
DJD
EPA 6010B
Boron
18
mg/Kg
10
02/15/99
02/18/99
OX
Potassium
1640
mg/Kg
50
02/15/99
02/18/99
OX
Sodium
771
mg/Kg
50
02/15/99
02/18/99
OX
Calcium
2950
mg/Kg
50
02/15/99
02/26/99
OX
Magnesium
1660
mg/Kg
0.50
02/15/99
02/18/99
OX
Arsenic
5.4
mg/Kg
2.5
02/15/99
02/18/99
OX
Cadmium
1.85
mg/Kg
0.50
02/15/99
02/18/99
OX
Page 50 of 67
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972.620-7966.800-394-2872 • F 2-620-7963 • Email: cedes@aot.com
Anaiytical Chemistry Environmental Sciences==_earch Microbiology
r
d
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-033 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 6010B Chromium
10.6
mg/Kg
0.50
02/15/99
02/18/99
OX
1
EPA 7471A Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B Zinc
34.3
mg/Kg
5.0
02/15/99
02/18/99
OX
1
i
Copper
14.4
mg/Kg
0.50
02/15/99
02/18/99
OX
1
+.,
Nickel
9.4
mg/Kg
1.0
02/15/99
02/18/99
OX
1
Lead
17.3
mg/Kg
1.5
02/15/99
02/18/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/15/99
02/18/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/15/99
02/18/99
OX
1
EPA 8081A 4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
I
Aldrin
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
I
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
�.
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Dieldrin
< 1.67
jig/Kg
1.67
02/15/99
02/20/99
JCA
1
Endosulfan I
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endosulfan Il
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endosulfan sulfate
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
r
t
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
r"
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
��
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
I
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
I
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/20/99
JCA
1
**Quality Control Surrogate
02/15/99
02/20/99
JCA
1
r.
2,4,5,6-Tetrachloro-m-xylene (
67%
60-1400/a
02/15/99
02/20/99
JCA
I
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/20/99
JCA
1
EPA 8082 Aroclor-1016
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
i
Aroclor-1260
<25
µg/Kg
25
02115/99
02/20/99
JCA
I
Page Sl of 67
f
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas. 75229. 972.620.7966. 800-394.2872 • _=.
:72-620.7963 • Email: certes@aol.com
r
i
Ara:ytical Chemistry Environmental
Sciences
: search
Microbiology
r
d
F
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-033 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8082
**Quality Control Surrogate
02/15/99
02/20/99
JCA
1
2,4,5,6-Tetmchloro-m-xylene (
67%
60-140%
02/15/99
02/20/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/20/99
JCA
1
EPA 8151A
2,4-D
<100
jug/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
jug/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
jug/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
jug/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
jug/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
21
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
720
mg/Kg
10
02/18/99
02/18/99
STR
1
3.2.191
Sodium Absorbtion Ratio
1.4
02/24/99
OX
1
EPA 8270C
Benzoic acid
<1650
jig/Kg
1650
02/17/99
02/23/99
ANA
1
4-Chloro-3-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2-Chlorophenol
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
2,4-Dichlorophenol
<660
jig/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dimethylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4,6-Dinitro-2-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dinitrophenol
<1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2-Nitrophenol
<660
jug/Kg
660
02/17/99
02/23/99
ANA
1
4-Nitrophenol
<1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
Pentachlorophenol
<1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
Phenol
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Acenaphthene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
Acenaphthylene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
Anthracene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Benzidine
<2500
µg/Kg
2500
02/17/99
02/23/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Benzo(b)fluoranthene
<660
jig/Kg
660
02/17/99
02/23/99
ANA
1
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Page 52 of 67
F Certes Environmental Laboratories
r
="�9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - FAX '-:-820-7963 • Email: certes saol.com
IWO
--a vtical Chemistry Environmental Sciences R=saarch Microbiology
4
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
r
Reporting
Date
Date
Analyzed
Sample: 99-0406-033 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
l
EPA 8270C Benzo(k)fluoranthene
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
02/17/99
02/23/99
ANA
I
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/17/99
02/23/99
ANA
I
r
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Bromophenyl-phenylether
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Flo
Butylbenzylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
02/17/99
0223/99
ANA
I
2-Chloronaphthalene
<330
µg/Kg
330
02/17/99
0223/99
ANA
I
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
i
Chrysene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Dibenzo(a,h)anthracene
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
g
Dibenzofuran
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
I
1,2-Dichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
••
1,3-Dichlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
I
1,4-Dichlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
70
3,3-Dichlorobcnzidine
<670
µg/Kg
670
02/17/99
02/23/99
ANA
1
i
Diethylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Dimethylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Di-n-butylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2,6-Dinitrotolucne (2,6-DN10
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
DI-n-octylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Fluoranthene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Fluorene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
+�
Hexachlorobenzene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
Hexachlorobutadiene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Hexachlorocyclopentadiene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
rHexachloroethane
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
'
Indeno(1,2,3-cd)pyrene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
POO
Isophorone
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2-Methylnaphthalene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
Naphthalene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
G
2-Nitroaniline
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
. -
3-Nitroaniline
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
4-Nitroaniline
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
,+l
Nitrobenzene (NB)
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
N-Nitrosodimethylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
r`
N-Nitrosodiphenylamine
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Page 53 of 67
ram+
t
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 - F- - :72.620-7963 • Email: Certes@aol.com
-a.vtical Chemistry Environmental Sciences = -.'arch Microbiology
Results of Analyses CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Sample: 99-0406-033
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8270C
N-Nitrosodipropylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Phenanthrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Pyrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,2,4-Trichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
**Quality Control Surrogate
02/17/99
0223/99
ANA
1
Nitrobenzene-d5 (SS)
35%
43-138%
02/17/99
02/23/99
ANA
1
2-Fluorobiphenyl (SS)
49%
50-124%
02/17/99
0223/99
ANA
1
tt^
Terphenyl-dl4 (SS)
43%
62-145%
02/17/99
0223/99
ANA
1
* Surrogate recovery is out of range
Client Sample ID:
PIVOT 17 DEEP
Sample Number:
99-0406-034
Date Sampled:
02/06/99
Sample Matrix:
Solid
Time Sampled:
12:25
Sampled By:
LW
t
EPA 9253
Chloride
300
mg/Kg
50
02/17/99
02/17/99
BWB
1
'..,
EPA 9038
Sulfate
230
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
EPA 353.3
Nitrate
6.7
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 350.3M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
-
SM 2320B
Alkalinity as Carbonate
480
mg/kg
100
02/16/99
02/16/99
DJD
2
Alkalinity as Bicarbonate
400
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010B
Boron
33
mg/Kg
10
02/16/99
02/19/99
OX
1
Potassium
4310
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
1200
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
7060
mg/Kg
50
02/16/99
02/19/99
OX
1
Magnesium
1840
mg/Kg
0.50
02/16/99
02/19/99
OX
1
!
Arsenic
6.8
mg/Kg
2.5
02/16/99
02/19/99
OX
1
{
Cadmium
2.20
mg/Kg
0.50
02/16/99
02/19/99
OX
1
r,
Chromium
16.1
mg/Kg
0.50
02/16/99
02/19/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
43.9
mg/Kg
5.0
02/16/99
02/19/99
OX
1
Copper
11.2
mg/Kg
0.50
02/16/99
02/19/99
OX
1
-
Nickel
13.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
Lead
Selenium
17.1
<2.0
mg/Kg
mg/Kg
1.5
2.0
02/16/99
02/16/99
02/19/99
02/19/99
OX
OX
1
1
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
*`
EPA 351AM
Total Kjeldahl Nitrogen
20.4
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
3.8
02/16/99
0224/99
OX
1
Page 54 of 67
r^
Certes Environmental Laboratories
=09 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620.7966.800.394.2872 - _= :72.620-7963 • Email: certescaol.com
_tical Chemistry Environmental Sciences ==search Microbiology
P
E
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
Client Sample ID: PIVOT 9 SHALLOW
Sample Number:
99-0406-035
Date Sampled:
02/09/99
Sample
Matrix:
Solid
Time Sampled:
11:00
Sampled
By:
LW
EPA 9253
Chloride
300
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
252
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
EPA 3533
Nitrate
3.7
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 35031%
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
I
SM 2320B
Alkalinity as Carbonate
560
mg/kg
100
02/16/99
02/16/99
DJD
2
Alkalinity as Bicarbonate
880
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010B
Boron
27
mg/Kg
10
02/16/99
02/19/99
OX
I
Potassium
4530
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
1150
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
15500
mg/Kg
50
02/16/99
02/19/99
OX
I
Magnesium
1850
mg/Kg
0.50
02/16/99
02/19/99
OX
I
Arsenic
4.8
mg/Kg
2.5
02/16/99
02/19/99
OX
1
Cadmium
2.14
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Chromium
15.0
mg/Kg
0.50
02/16/99
02/19/99
OX
I
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
40.7
mg/Kg
5.0
02/16/99
02/19/99
OX
1
Copper
10.7
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Nickel
11.9
mg/Kg
1.0
02/16/99
02/19/99
OX
1
Lead
13.8
mg/Kg
1.5
02/16/99
02/19/99
OX
I
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
EPA 8081A
4,4'-DDD
<1.67
jig/Kg
1.67
02/15/99
02/20/99
JCA
I
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
beta-BHC
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
I
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
0220199
JCA
1
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
I
Endosulfan II
< 1.67
jig/Kg
1.67
02/15/99
0220/99
JCA
I
Page SS of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966.800.394-2872 ==. : -2-620-7963 - Email: certescaol.com
r.^aNtical Chemistry Environmental Sciences =-=_=arch Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-035 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin keytone
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/20/99
JCA
1
**Quality Control Surrogate
02/15/99
02/20/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
62%
60-140%
02/15/99
02/20/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/20/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1260
<25
jig/Kg
25
02/15/99
02/20/99
JCA
1
**Quality Control Surrogate
02/15/99
02/20/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
62%
60-140%
02/15/99
02/20/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/20/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
21
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
17
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
3.0
02/16/99
02/24/99
OX
1
* Surrogate recovery as out of range
r.
Page 56 of 67
k : Certes Environmental Laboratories
-22'9 Wisconsin Street, Suite 200 Dallas, Texas. 75229. 972-620-7966 .800-394-2872 - F-., .-2-620-7963. Email: certeseaol.com
;--=: tical Chemistry Environmental Sciences = =search Microbiology
r
r
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
Client Sample ID: PIVOT 9 DEEP
Sample Number:
99-0406-036
Date Sampled:
02/09/99
Sample Matrix:
Solid
Time Sampled:
11:05
Sampled By:
LW
EPA 9253
Chloride
300
mg/Kg
50
02/17/99
02/17/99
BWB
I
EPA 9038
Sulfate
254
mg/Kg
50
02/19/99
02/19/99
JMO
I
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99
02/16/99
JMO
2
EPA 3533
Nitrate
2.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
I
EPA 3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
480
mg/kg
100
02/16/99
02/16/99
DID
2
Alkalinity as Bicarbonate
1320
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010B
Boron
30
mg/Kg
10
02/16/99
02/19/99
OX
1
Potassium
4640
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
1210
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
15400
mg/Kg
500
02/16/99
02/23/99
OX
I
Magnesium
1770
mg/Kg
0.50
02/16/99
02/19/99
OX
I
Arsenic
5.4
mg/Kg
2.5
02/16/99
02/19/99
OX
I
Cadmium
2.07
mg/Kg
0.50
02/16/99
02/19/99
OX
I
Chromium
15.2
mg/Kg
0.50
02/16/99
02/19/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
I
EPA 6010B
Zinc
413
mg/Kg
5.0
02/16/99
02/19/99
OX
1
Copper
9.75
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Nickel
11.7
mg/Kg
1.0
02/16/99
02/19/99
OX
I
Lead
10.4
mg/Kg
1.5
02/16/99
02/19/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
< 10
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
3.8
02/16/99
02/24/99
OX
1
Client Sample ID: PIVOT 5 SHALLOW
Sample Number: 99-0406-037
Date Sampled:
02/09/99
Sample Matrix:
Solid
Time Sampled:
12:10
Sampled By:
LW
EPA 9253
Chloride
410
mg/Kg
50
02/17/99 02/17/99
BWB
1
EPA 9038
Sulfate
254
mg/Kg
50
02/18/99 02/18/99
IMO
I
EPA 354.1M
Nitrite
<0.2
mg/Kg
0.2
02/16/99 02/16/99
JMO
2
EPA 3533
Nitrate
5.1
mg/Kg
1.0
02/15/99 02/16/99
BWB
I
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB
I
SM 2320B
Alkalinity as Carbonate
240
mg/kg
100
02/16/99 02/16/99
DJD
2
Page 37 of 67
t
�- Certes Environmental Latoratories
_209 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972.620.7966.800-394.2872 - ;_= - :"2.620-7963 • Email: certes@aol.com
.-L a.ytical Chemistry Environmental Sciences _ search Microbiology
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-037 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
7
t
SM 2320B
Alkalinity as Bicarbonate
480
mg/Kg
100
02/16/99
02/16/99
DJD
2
EPA 6010B
Boron
22
mg/Kg
10
02/16/99
02/19/99
OX
1
Potassium
3390
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
903
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
5720
mg/Kg
50
02/16/99
02/19/99
OX
1
PIK
Magnesium
1730
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Arsenic
6.1
mg/Kg
2.5
02/16/99
02/19/99
OX
1
7
Cadmium
1.66
mg/Kg
0.50
02/16/99
02/19/99
OX
I
Chromium
13.3
mg/Kg
0.50
02/16/99
02/19/99
OX
]
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
]
EPA 6010B
Zinc
34.0
mg/Kg
5.0
02/16/99
02/19/99
OX
1
Copper
8.34
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Nickel
10.4
mg/Kg
1.0
02/16/99
02/19/99
OX
1
A
Lead
14.2
mg/Kg
1.5
02/16/99
02/19/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
I
EPA 8081A
4,4'-DDD
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDE
3.49
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
4,4'-DDT
<1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
l
alpha -Chlordane
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
gamma -Chlordane
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
]
Dieldrin
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Endosulfan I
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
•.
Endosulfan II
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
d
Endosulfan sulfate
< 1.67
µg/Kg
1.67
02/15/99
02/20/99
JCA
1
Endrin
Endrin keytone
< 1.67
< 1.67
µg/Kg
µg/Kg
1.67
1.67
02/15/99
02/15/99
0220/99
0220/99
JCA
JCA
1
1
Endrin aldehyde
<1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Heptachlor
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Heptachlor epoxide
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
0220/99
JCA
l
r�
Toxaphene
<20.0
µg/Kg
20.0
02/15/99
02/20/99
JCA
1
"Quality Control Surrogate
02/15/99
02/20/99
JCA
l
r-
2,4,5,6-Tetrachloro-m-xylene (
89%
60-140%
02/15/99
02/20/99
JCA
1
Page 58 of 67
" Certes Environmental Laboratories
_209 Vlisconsin Street, Suite 200 Dallas. Texas. 7 5229.972-620.7966.800-394-2872 - = _--2-620-7963 • Email: certes c aol.com
Analyticai Chemistry Environmental Sciences = _earch Microbiology
i
i
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-037 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/20/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/20/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
0220/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02120/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02120/99
JCA
1
"Quality Control Surrogate
02/15/99
02/20/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
89%
60-140%
02/15/99
02/20/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02120/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
µg/Kg
100
02/19/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
MC PA
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA418.1
TPH
<10
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351.4M
Total Kjeldahl Nitrogen
< 10
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
2.6
02/16/99
02/24/99
OX
I
* Surrogate recovery is out of range
Client Sample ID: PIVOT 5 DEEP
Sample Number:
99-0406-038
Date Sampled:
02/09/99
Sample Matrix:
Solid
Time Sampled:
12:15
Sampled By:
LW
EPA 9253
Chloride
340
mg/Kg
50
02/17/99 02/17/99
BWB
1
EPA 9038
Sulfate
131
mg/Kg
50
02/I8/99 02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.5
mg/Kg
0.5
02/16/99 02/16/99
JMO
5
EPA 3533
Nitrate
1.4
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99 02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
400
mg/kg
100
02/16/99 02/16/99
DJD
2
Alkalinity as Bicarbonate
1480
mg/Kg
100
02/16/99 02/16/99
DJD
2
EPA 6010B
Boron
29
mg/Kg
10
02/16/99 02/19/99
OX
1
Potassium
3760
mg/Kg
50
02/16/99 02/19/99
OX
1
Page 59 of 67
r
f
l Certes Environmental Laboratories
:209 Wisconsin Street, Suite 200 Dallas, Texas. 75229. 972-620.7966. 600.394.2872 - :-2.620-7963- Email: certesclaol.com
'� Ara:/tical Chemistry Environmental Sciences = =search Microbiology
I
r
i
L'.
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-038 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Sodium
1280
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
16300
mg/Kg
50
02/16/99
02/19/99
OX
I
Magnesium
1760
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Arsenic
6.4
mg/Kg
2.5
02/16/99
02/19/99
OX
1
Cadmium
2.09
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Chromium
16.1
mg/Kg
0.50
02/16/99
02/19/99
OX
1
EPA 7471A
Mercury
0.02
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
40.4
mg/Kg
5.0
02/16/99
02/19/99
OX
1
Copper
9.98
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Nickel
12.2
mg/Kg
1.0
02/16/99
02/19/99
OX
1
Lead
17.4
mg/Kg
1.5
02/16/99
02/19/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
EPA 351AM
Total Kjeldahl Nitrogen
43
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
2.6
02/24/99
OX
1
Client Sample ID: PIVOT 6 DEEP
Sample Number: 99-0406-039
Date Sampled:
02/09/99
Sample
Matrix:
Solid
Time Sampled:
13:30
Sampled By:
LW
EPA 9253
Chloride
310
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
119
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 3543M
Nitrite
<0.5
mg/Kg
0.5
02/16/99
02/16/99
JMO
5
EPA 353.3
Nitrate
4.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 350.3M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
1040
mg/kg
100
02/16/99
02/16/99
DID
2
Alkalinity as Bicarbonate
< 100
mg/L
100
02/16/99
02/16/99
DID
2
EPA 6010B
Boron
34
mg/Kg
10
02/16/99
02/19/99
OX
I
Potassium
4290
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
1120
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
4470
mg/Kg
50
02/16/99
02/19/99
OX
1
Magnesium
1760
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Arsenic
5.4
mg/Kg
2.5
02/16/99
02/19/99
OX
1
Cadmium
2.26
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Chromium
17.1
mg/Kg
0.50
02/16/99
02/19/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/19/99
ADD
1
EPA 6010B
Zinc
44.6
mg/Kg
5.0
02/16/99
02/19/99
OX
I
Copper
10.7
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Page 60 of 67
Certes Environmental Laboratories
_::9 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620.7::-3 - 800-394.2872 • :-2-620-7963 • Email: ce tesCaol.com
--a.v!ical Chemistry Environmental Sciences =_:catch Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-039
continued...
Result
Units
Limit
Prepared
Analyzed
By Dilution
EPA 6010B
Nickel
13.3
mg/Kg
1.0
02/16/99
02/19/99
OX 1
Lead
13.1
mg/Kg
1.5
02/16/99
02/19/99
OX 1
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX 1
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX 1
EPA 351AM
Total Kjeldahl Nitrogen
13
mg/Kg
10
02/18/99
02/18/99
ETT 1
3.2.191
Sodium Absorbtion Ratio
1.9
02/24/99
OX 1
Client Sample ID: PIVOT 6 SHALLOW Sample Number. 99-0406-040
Date Sampled: 02/09/99 Sample Matrix: Solid
Time Sampled: 13:25 Sampled By: LW
EPA 9253
Chloride
330
mg/Kg
50
02/17/99
02/17/99
BWB
EPA 9038
Sulfate
140
mg/Kg
50
02/18/99
02/18/99
JMO
i.
EPA 354.1M
Nitrite
<0.5
mg/Kg
0.5
02/16/99
02/16/99
JMO
EPA 3533
Nitrate
4.1
mg/Kg
1.0
02/15/99
02/16/99
BWB
s_.
EPA 3503M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
SM 2320B
Alkalinity as Carbonate
< 100
mg/kg
100
02/16/99
02/16/99
DJD
Alkalinity as Bicarbonate
720
mg/L
100
02/16/99
02/16/99
DJD
EPA 6010B
Boron
28
mg/Kg
10
02/16/99
02/19/99
OX
Potassium
3990
mg/Kg
50
02/16/99
02/19/99
OX
Sodium
1040
mg/Kg
50
.02/16/99
02/19/99
OX
Calcium
2830
mg/Kg
50
02/16/99
02/19/99
OX
Magnesium
1770
mg/Kg
0.50
02/16/99
02/19/99
OX
Arsenic
3.0
mg/Kg
2.5
02/16/99
02/19/99
OX
i
Cadmium
Chromium
2.10
153
mg/Kg
mg/Kg
0.50
0.50
02/16/99
02/16/99
02/19/99
02/19/99
OX
OX
!!t
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
EPA 6010B
Zinc
41.8
mg/Kg
5.0
02/16/99
02/19/99
OX
Copper
9.73
mg/Kg
0.50
02/16/99
02/19/99
OX
Nickel
11.8
mg/Kg
1.0
02/16/99
02/19/99
OX
Lead
18.0
mg/Kg
1.5
02/16/99
02/19/99
OX
'
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
v
4,4'-DDE
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
4,4'-DDT
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
Aldrin
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
alpha-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
i
Page 61 of 67
Certes Environmental Laboratories
-2'9 e. isconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.600-394-2872 - = :72-620.7963 - Email: certescaol.com
Ana:yucai Chemistry Environmental Sciences = =search Microbiology
r
r
I
7m
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-040 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
beta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
delta-BHC
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
gamma-BHC
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
alpha -Chlordane
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
gamma -Chlordane
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
Dieldrin
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
Endosulfan I
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
Endosulfan II
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
Endosulfan sulfate
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
Endrin
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Endrin keytone
< 1.67
jig/Kg
1.67
02/15/99
02/26/99
JCA
1
Endrin aldehyde
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Heptachlor
<1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Heptachlor epoxide
1.88
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Methoxychlor
< 1.67
µg/Kg
1.67
02/15/99
02/26/99
JCA
1
Toxaphcne
<20.0
µg/Kg
20.0
02/15/99
02/26/99
JCA
1
"Quality Control Surrogate
02/15/99
02/26/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
77%
60-140%
02/15/99
02/26/99
JCA
1
Decachlorobiphenyl (SS)
102%
60-140%
02/15/99
02/26/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/26/99
JCA
1
"Quality Control Surrogate
02/15/99
02/26/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
77%
60-140%
02/15/99
02/26/99
JCA
1
Decachlorobiphenyl (SS)
102%
60-140%
02/15/99
02/26/99
JCA
1
EPA 8151A
2,4-D
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
<100
jig/Kg
100
02/19/99
02/18/99
ARM
1
2,4,5-T
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloro prop
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
<100
µg/Kg
100
02/19/99
02/18/99
ARM
1
MCCP
<100
jig/Kg
100
02/18/99
02/18/99
ARM
1
Page 62 of 67
" Certes Environmental Laboratories
:_:9 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972.620.7566. 800-394.2872 - =--2.620.7963 • Email: certescaol.com
Ana .::.cal Chemistry Environmental Sciences ==search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-040 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 418.1
TPH
< 10
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
14
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
1.7
02/16/99
02124/99
OX
1
EPA 8270C
Benzoic acid
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
4-Chloro-3-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2-Chlorophenol
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
2,4-Dichlorophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dimethylphenol
<660
jig/Kg
660
02/17/99
02/23/99
ANA
1
4,6-Dinitro-2-methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,4-Dinitrophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Methylphenol
<660
jig/Kg
660
02/17/99
02/23/99
ANA
1
2-Nitrophenol
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
4-Nitrophenol
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
l
Pentachlorophenol
<1650
jig/Kg
1650
02/17/99
02/23/99
ANA
1
Phenol
<330
jig/Kg
330
02/17/99
02/23/99
ANA
I
2,4,5-Trichlorophenol
<660
jig/Kg
660
02/17/99
02/23/99
ANA
1
2,4,6-Trichlorophenol
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
Acenaphthene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
Acenaphthylene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Anthracene
<330
jig/Kg
330
02/17/99
0223/99
ANA
1
Benzidine
<2500
µg/Kg
2500
02/17/99
0223/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Benzo(b)fluoranthene
<660
µg/Kg
660
02/17/99
0223/99
ANA
l
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Benzo(k)fluoranthene
<660
jig/Kg
660
02/17/99
0223/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
02/17/99
0223/99
ANA
l
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
4-Bromophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Butylbenzylphthalate
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
2-Chloronaphthalene
<330
jig/Kg
330
02/17/99
0223199
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
Chrysene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
Dibenzo(a,h)anthmcene
< 1650
µg/Kg
1650
02/17/99
0223/99
ANA
1
Page 63 of 67
r
E Certes Environmental Laboratories
9 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620-7966.800-394-2872 • ==.° : -2-620-7963 -Email: certescaol.com
r Ana:ytical Chemistry Environmental Sciences==:aarch Microbiology
7 Results of Analyses CEL File No.: 99-0406 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
�.,
Sample: 99-0406-040 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Dibenzofuran
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
1,2-Dichlorobenzene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
1,3-Dichlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
1,4-Dichlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
r
3,3-Dichlorobenzidine
<670
µg/Kg
670
02/17/99
02/23/99
ANA
1
(j
Diethylphthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Dimethylphthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
Di-n-butylphthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
2,6-Dinitrotoluene (2,6-DNT)
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
DI-n-octylphthalate
<660
µg/Kg
660
02/17/99
02/23/99
ANA
I
Fluoranthene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Fluorene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
Hexachlorobenzene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
i
Hexachlorobutadiene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Hexachlorocyclopentadiene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
Hexachloroethane
<330
µg/Kg
330
02/17/99
02/23/99
ANA
I
'
Indeno(1,2,3-cd)pyrene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
�.,
Isophorone
<660
jig/Kg
660
02/17/99
02/23/99
ANA
I
2-Methylnaphthalene
<330
jig/Kg
330
02/17/99
02/23/99
ANA
1
Naphthalene
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
2-Nitroaniline
<660
µg/Kg
660
02/17/99
02/23/99
ANA
1
3-Nitroaniline
< 1650
µg/Kg
1650
02/17/99
02/23/99
ANA
1
4-Nitroaniline
< 1650
jig/Kg
1650
02/17/99
02/23/99
ANA
1
Nitrobenzene (NB)
<660
µg/Kg
660
02/17/99
0223/99
ANA
1
N-Nitrosodimethylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
N-Nitrosodiphenylamine
<660
µg/Kg
660
02/17/99
0223/99
ANA
I
N-Nitrosodipropylamine
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
<330
µg/Kg
330
02/17/99
02/23/99
ANA
1
POWPhenanthrene
Pyrene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
1,2,4-Trichlorobenzene
<330
µg/Kg
330
02/17/99
0223/99
ANA
1
"Quality Control Surrogate
02/17/99
0223/99
ANA
1
Nitrobenzene-d5 (SS)
38%
43-138%
02/17/99
0223/99
ANA
1
2-Fluorobiphenyl (SS)
55%
50-124%
02/17/99
0223/99
ANA
1
Terphenyl-dl4 (SS)
47%
62-145%
02/17/99
0223/99
ANA
1
t.
r
Page 64 of 67
Certes Environmental Laboratories
-209 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 - _= ° : -620-7963. Email: certes@aol.com
A -a ytical Chemistry Environmental Sciences=-_earch Microbiology
i'
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
F
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
Client Sample 1D: PIVOT 22 SHALLOW
Sample Number:
99-0406-041
Date Sampled:
02/09/99
Sample
Matrix:
Solid
Time Sampled:
14:25
Sampled
By:
LW
EPA 9253
Chloride
370
mg/Kg
SO
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
302
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.5
mg/Kg
0.5
02/16/99
02/16/99
JMO
5
EPA 3533
Nitrate
9.4
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
I
EPA3503M
Ammonia
<1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
`
SM 2320E
Alkalinity as Carbonate
< 100
mg/kg
100
02/16/99
02/16/99
DJD
2
r
Alkalinity as Bicarbonate
920
mg/L
100
02/16/99
02/16/99
DJD
2
i
EPA 6010B
Boron
25
mg/Kg
10
02/16/99
02/19/99
OX
1
Potassium
3450
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
901
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
2960
mg/Kg
50
02/16/99
02/19/99
OX
1
Magnesium
1680
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Arsenic
4.2
mg/Kg
2.5
02/16/99
02/19/99
OX
1
Cadmium
1.58
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Chromium
12.5
mg/Kg
0.50
02/16/99
02/19/99
OX
1
EPA 7471A
Mercury
0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010B
Zinc
34.3
mg/Kg
5.0
02/16/99
02/19/99
OX
l
r+
r
Copper
8.85
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Nickel
10.5
mg/Kg
1.0
02/16/99
02/19/99
OX
1
*:.
Lead
12.7
mg/Kg
1.5
02/16/99
02/19/99
OX
1
lj
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
1
Molybdenum
<1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
y
i
EPA 8081A
4,4'-DDD
<1.67
µg/Kg
1.67
02/15/99
0221/99
JCA
1
4,4'-DDE
< 1.67
jig/Kg
1.67
02/15/99
0221/99
JCA
1
4,4'-DDT
<1.67
jig/Kg
1.67
02/15/99
0221/99
JCA
1
Aldrin
< 1.67
jig/Kg
1.67
02/15/99
0221/99
JCA
1
alpha-BHC
<1.67
jig/Kg
1.67
02/15/99
0221/99
JCA
1
beta-BHC
< 1.67
jig/Kg
1.67
02/15/99
0221/99
JCA
1
k
1
delta-BHC
< 1.67
µg/Kg
1.67
02/15/99
02/21/99
JCA
1
gamma-BHC
< 1.67
µg/Kg
1.67
02/15/99
0221/99
JCA
1
alpha -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
02/21/99
JCA
I
gamma -Chlordane
< 1.67
µg/Kg
1.67
02/15/99
0221/99
JCA
I
Dieldrin
<1.67
µg/Kg
1.67
02/15/99
0221/99
JCA
1
Endosulfan i
<1.67
µg/Kg
1.67
02/15/99
0221/99
JCA
1
Endosulfan lI
<1.67
µg/Kg
1.67
02/15/99
02/21/99
JCA
1
Endosulfan sulfate
<1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
I
Page 65 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 • Fes; ..= 2-620-7963 • Email: certesCaol.com
i M-a.ytical Chemistry Environmental Sciences P.=search Microbiology
Results of Analyses CEL File No.: 99-0406 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0406-041 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Endrin
<1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
1
Endrin keytone
<1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
1
Endrin aldehyde
<1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
1
Heptachlor
< 1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
1
Heptachlor epoxide
<1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
1
Methoxychlor
<1.67
jig/Kg
1.67
02/15/99
02/21/99
JCA
1
Toxaphene
<20.0
jig/Kg
20.0
02/15/99
02/21/99
JCA
1
**Quality Control Surrogate
02/15/99
02/21/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
* 56%
60-140%
02/15/99
02/21/99
JCA
1
Decachlorobiphenyl (SS)
* 0%
60-140%
02/15/99
02/21/99
JCA
1
EPA 8082
Aroclor-1016
<25
jig/Kg
25
02/15/99
02/21/99
JCA
1
Aroclor-1221
<25
jig/Kg
25
02/15/99
02/21/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/15/99
02/21/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/15/99
02/21/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/15/99
02/21/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/15/99
02/21/99
JCA
1
Aroclor-1260
<25
µg/Kg
25
02/15/99
02/21/99
JCA
1
**Quality Control Surrogate
02/15/99
02/21/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene(
*56%
60-140%
02/15/99
02/21/99
JCA
1
Decachlorobiphenyl (SS)
*0%
60-140%
02/15/99
02/21/99
JCA
1
EPA 8151A
2,4-D
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4-DB
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-T
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dalapon
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dicamba
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dichloroprop
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
Dinoseb
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCPA
< 100
µg/Kg
100
02/18/99
02/18/99
ARM
1
MCCP
<100
µg/Kg
100
02/18/99
02/18/99
ARM
1
EPA 418.1
TPH
<10
mg/Kg
10
02/15/99
02/15/99
BM
1
EPA 351AM
Total Kjeldahl Nitrogen
12
mg/Kg
10
02/18/99
02/18/99
ETT
1
3.2.191
Sodium Absorbtion Ratio
2.4
02/16/99
02/24/99
OX
1
* Surrogate recovery is out of range
Page 66 of 67
FCertes Environmental Laboratories
_=9 Wisconsin Street, Suite 200 Dallas, Texas, 75229. 972.620-7966.800-394-2872 • = :-2-620-7963 • Email: certes@aol.com
F'
Ana:ytical Chemistry Environmental Sciences = =search Microbiology
Results of Analyses
CEL File No.: 99-0406
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared Analyzed
By
Dilution
i
Client Sample ID:
PIVOT 22 DEEP
Sample
Number:
99-0406-042
Date Sampled:
02/09/99
Sample
Matrix:
Solid
r
Time Sampled:
14:30
Sampled
By:
LW
EPA 9253
Chloride
200
mg/Kg
50
02/17/99
02/17/99
BWB
1
EPA 9038
Sulfate
268
mg/Kg
50
02/18/99
02/18/99
JMO
1
EPA 354.1M
Nitrite
<0.5
mg/Kg
0.5
02/16/99
02/16/99
JMO
5
EPA 353.3
Nitrate
2.8
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
EPA 350.3M
Ammonia
< 1.0
mg/Kg
1.0
02/15/99
02/16/99
BWB
1
}
SM 2320B
Alkalinity as Carbonate
<3202
mg/kg
3202
02/16/99
02/16/99
DJD
2
Alkalinity as Bicarbonate
960
mg/L
100
02/16/99
02/16/99
DJD
2
EPA 6010E
Boron
32
mg/Kg
10
02/16/99
02/19/99
OX
1
Potassium
4280
mg/Kg
50
02/16/99
02/19/99
OX
1
Sodium
948
mg/Kg
50
02/16/99
02/19/99
OX
1
Calcium
6000
mg/Kg
50
02/16/99
02/19/99
OX
1
Magnesium
1840
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Arsenic
4.0
mg/Kg
2.5
02/16/99
02/19/99
OX
1
Cadmium
2.27
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Chromium
17.2
mg/Kg
0.50
02/16/99
02/19/99
OX
1
EPA 7471A
Mercury
<0.01
mg/Kg
0.01
02/17/99
02/18/99
ADD
1
EPA 6010E
Zinc
42.5
mg/Kg
5.0
02/16/99
02/19/99
OX
1
Copper
10.5
mg/Kg
0.50
02/16/99
02/19/99
OX
1
Nickel
13.3
mg/Kg
1.0
02/16/99
02/19/99
OX
1
�^
Lead
14.5
mg/Kg
1.5
02/16/99
02/19/99
OX
1
k[
Selenium
<2.0
mg/Kg
2.0
02/16/99
02/19/99
OX
1
Molybdenum
< 1.0
mg/Kg
1.0
02/16/99
02/19/99
OX
1
EPA 351AM
'total Kjeldahl Nitrogen
14
mg/Kg
10
02/19/99
02/18/99
ETT
1
L
l
3.2.191
Sodium Absorbtion Ratio
2.0
02/24/99
OX
1
r
ra
Page 67 of 67
Certes Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas. Texas, 75229. 972-620.7933.800-394-2872 • = _-2.620.7963- Email: certes@aol.com
tk -a:ytical Chemistry Environmental Sciences = =search Microbiology
Environmental Laboratories, L.L.C.
Certes 22U9 Wisconsin Street, Suite 200
Analysis(es) Requested
^- Dallas, Texas 75229
972-620-7966 972-620-7963 Fax
Client Name _
Phone No.
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A.?q— L A S111 CAS
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Site Location
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Sample ID
Date
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No. t4 Type of Container'
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Certes Job Number
Standard: Date Required 2 5
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Relinquished by Sar
Date
Time
Received By
1-
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FG -
Relinquished
Date
Time
Received By
Relinquished by
Date
Time
Received By Laboratory
NOTE: By submitting these samples, you agree to the terms and conditions contained In Certes' Schedule of Fees: Cerles cannot accept verbal changes. Please FAX written changes to (972) 620-7963.
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200 Analysis(es) Requested
... _ Dallas, Texas 75229
972-629-7966 972-629-7963 Fax
Client Name
Phone No.
tRC)L.
Iv
Client Address
Fax No.
Ct'kO tG
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L4\ oJi- —114 -1
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Sample ID
Date
Time
Matrix'
o. & Type of Container=
No:
V G J O P3
(�-
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2• '9�
S
tlo� lb S1rw p,,�
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Sampled By
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AS03
2 Container Type V - 40ml VOA Vial; G Amber or Glass 1 Liter. J - 250ml Wide -mouth Glass'Jar• O = Other 1'i1 oz b 6:oz tL
-
•
3 Preservative HCI - Hydrochloric Add ." "NO= _ Nitdc Add; _j H,SO. Sulfuric Acld; O Other
TAT
Client Project ID
Special Instructions (including specific detection limits)
Certes Job Number
Standard: Date Required
F_ 11 11 b k
P P''..' � `
'�9- �`�j��j
RUSH: Date Required
4)
Relinquished by Sampler
Date
Time
Received By
2 o0
IL ir0�
Relinquished by
Date
Time
Received By
Relinquished by
Date
Time
Received By Laboratory
NOTE: By submitting these samples, you agree to the terms and conditions contained in Cartes Schedule of Fees: Certes cannot accept verbal changes. Please FAX written changes to (972) 620-7963.
__ . T _ _1 _ _1 TM_l ----1 - _-1 - � .� 1, �",7 �7 —1 _ - i�—1 ---1 _ � --1 ___A .__...I -- -I
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Analysis(es) Requested Y
Dallas, Texas 75229
-' 972-620-7966 972-620-7963 fax
Client Name
Phone No.
`
o t)O
Client Address
Fax No.
to
0
3 t 0 irtJ 0A, �-C' E
o -1-1
i
Billing Address City State Zip
. 0-
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Purchase Order No.
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t ►y
A s - L
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Project Manager
Site Loca
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Certes
Sample
Date
Time"
Matrix'
No. A Type of Container:
V
G
J
O
P�
.No.
S1M-
5
�-
�-o t S D
2 q
1 0
vo
o'L� t SS.S
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OL SS, I
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t Matrix:._ . :.. A.- Air Bag; C -Charcoal Tube;.. L -Liquid; .OL -Oil; S - Sal, SD - Solid; SL - Sludge; WP - Wipe; W - Water/Wastewater
2 Container Type:. V - 40ml VOA Vial; G = Amber or Glass / Liter, J - 250ml Wide=mouth Glass Jar, O - Other
3 Preservative: HC1- Hydrochloric Acid; HNO="- Nitric Add: ; H,SO, - Sulfuric Acid;, O - Other.
TAT
Client Project ID
Special Instructions (including specific detection limits)
Certes Job Number
Standard: Date Required %- t S
is \, b
P �.. S ! a X Q e JJ, S Rr� �� •�
-' Z /,%
RUSH: Date Required
Relinquished by Sampler
Date
'�-
Time
Received By
8
�
0 �3891
Relinquished by
Date
Time
Received By
Relinquished by
Date
Timex
Received By Laboratory
S
NOTE: By submitting these samples. you agree to the terms and conditions contained In Certes'S&kdu19
of Fees: Certes cannot accept verbal changes. Please FA written changes to (972) 620.7963. ,:. .
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Dallas, Texas 75229
972-620-7966 972-629-7963 Fax
Analysis(es) Requested
Client Name
Phone No.
_44,.-+
J1
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1'
d
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4
CIO
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Client Address
Lolls, (0154tA
Fax No.
Billing Address 1 city L State Zip y
Purchase Order No.
C1-3. >7
To ensure proper Dining, please reference quotation number.
iA S C P
Project Manager
�. a
Site Location
�` o LA..� 11P �. tJ►���
Certes
Sample ID
Date
Time.
Matrix
No, 6 Type of Container:
V..
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J
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P3
31
O.10q tC te)
i.
t \ OJ
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b Ok q l k C4
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AAc1.GL
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p,,Jar li oceol
'a.-O 3
s
v
Sampled By
S ezQ `�
1 Matrix:... A - Air Bag; . C - Charcoal Tube;.. L - Liquid; . OL - Oil; S - Soil; SD - Solid; SL - Sludge; : WP - Wipe; W - Water/Wastewater
2 Container Type r V -.40mt VOA Vial, G Amber or Glass 1 Liter, J - 250ml Wide=mot Glass Jar. O - Other. 4 wi__ — q s
3 Preservative. HCI = Hydrochbric Acid-"- HNO= ; Nitric Add; : H,SO. = Sulfuric Acid.: O = Other.
TAT
Standard: Date Required 0-
RUSH: Date Required
Client Project ID
C ►� ? b 1
Special Instructions (including specific detection limits)
qL L ,
Certes Job Number
Relinquished by Sa '
Date
2.
Time
! o
Received 13
(_
Relinquished
Date
Time
Received By
Relinquished by
Date !gJ$!EV1,qw-ime
�19d
Received By Laboratory
NOTE: By submitting these samples, you agree to the terms and conditions contained in CerleV.ScWule of Fees. Cartes can of accept verbal changes. Please FAX written changes to (972) 6M1-7963. .
%, - -- � .. - _ - 1 nn z- - - r - _ .. i-
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Dallas, Texas 75229
Analysis(es) Requested
972.629-7966 972-629-7963 Fax
Client Name
Phone No.
EHP 0TZG
( 'iy4-\1 o
L
J 4
Client Address
Fax No.
\ ct�
—1(A o 11 g
Billing Address City State Zipki
C kA
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2
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Purchase Order No.
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\1cc
S Q �� C
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W .1 ,� LAt-k . "t% S: =
Cedes
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Sample ID
Date
Time
Matrix
No. & Type of Container'
V'
G
J
O
P ,
f
5
2
p3 \\oG
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1\0
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t Matrix:..; .. A - Air Bag; C - Charcoal Tube;.. L - Liquid; OL - Oil; S - Sal; SD - Solid;: SL Sludge; WP Wipe W WaterM/astewater
2 Container Type: V - 40ml VOA Vial G Amber or Glass 1 Liter, J - 250ml Wide -mouth Glass Jar. O - Other
AtA (.G L' �
3 Preservative: HCI - HydroehIo Acid HNO= =Nitric Add.,- H,SO4 - Sulfuric Add; ' O attter "
TAT
Client Project ID
Special Instructions specific detection limits)
Certes Job Number
Standard: Date Required t
-(including
`
Gv—\?b(
"tt Date Required
—
Relinquished by Sampler
Date
Time
Received By
Relinquished by
Dater
Time
Received By
Relinquished by
Date lt�
Time 0100
Received By Laboratory
NOTE: By submitting these samples. you agree to the terms and conditions contained in Certes' Schedule of Fees. Ceries cannot accept verbal changes. Please FAX written changes to (972) 620-7963.
2209 t'Visconsin Street. Sutte 2CC
f_ `•'�-� y, Dallas. Texas 75229
972-620- 7966
300-394-2872
j
072-6270-7963 FAX .::i�i:.iirJl �S.1f:.1 :J►Ji �JL. -.�
fi
CERTES ENVIRONMENTAL LABORATORIES
ANALYTICAL REPORT
Certes File Number: 99-0432
Client Project I.D.:
EN-1761
Prepared for:
ENPROTEC INC.
6310 Genoa Avenue, Suite E
Lubbock, TX 79424
Attention:
Mark Schneider
Report Date:
03/02/99
Included are the results of chemical analyses for the samples submitted to Certes Environmental
Laboratories, L.L.C., on 02/11/99. All analytical results met Quality Control requirements as set by the
industry accepted criteria. Please refer to the Laboratory Quality Control Results section of this report.
This report must be reproduced in its entirety.
Sincerely,
Certes Environmental Laboratories, L.L.C.
f -- Amy LaSalle
President
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Result
Units
Limit
Prepared Analyzed
By Dilution
Client Sample ID: 10842
Sample Number: 99-0432-001
Date Sampled:
02/10/99
Sample
Matrix:
Liquid
Time Sampled:
17:15
Sampled
By:
LW
EPA 8081A
4,4'-DDD
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
4,4'-DDE
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
4,4'-DDT
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
I
alpha-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
I
beta-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
alpha -Chlordane
<0.05
µg/L
0.05
02/15/99
02/26/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/15/99
02/26/99
JCA
1
Dieldrin
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endosulfan I
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endosulfan II
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
I
Endrin
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endrin aldehyde
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
gamma-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
I
Methoxychlor
<0.10
µg/L
0.10
02/15/99
0226/99
JCA
1
Toxaphene
< 1.0
µg/L
1.0
02/15/99
02/26/99
JCA
I
"Quality Control Surrogate
02/15/99
0226/99
JCA
I
2,4,5,6-Tetrachloro-m-xylene (
65%
60-140%
02/15/99
0226/99
JCA
1
Decachlorobiphenyl (SS)
82%
60-140%
02/15/99
0226/99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1221
<5.0
µg/L.
5.0
02/15/99
0226/99
JCA
1
Aroclor-1232
<5.0
µg/L.
5.0
02/15/99
0226/99
JCA
1
Aroclor-1242
<5.0
µg/l.
5.0
02/15/99
0226/99
JCA
1
Aroclor-1248
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1254
<5.0
µg/L.
5.0
02/15/99
0226/99
JCA
1
Aroclor-1260
<5.0
µg/L,
5.0
02/15/99
0226199
JCA
1
"Quality Control Surrogate
02/15/99
0226/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
65%
60-140%
02/15/99
0226/99
JCA
1
Decachlorobiphenyl (SS)
82%
60-1400/6
02/15/99
0226/99
JCA
1
EPA 8151 A
2,4-D
<0.50
µg/L
0.50
02/18/99
02/18/99
CO
1
2,4-DB
< 1.0
µg/L
1.0
02/18/99
02/18/99
CO
I
Page 2 of 22
Certes Environmental Laboratories
=7C9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972.620.7966.800.394.2872 - --2.620.7963 - Errad: certes,&aol.com
Ana,y:ical Chemistry Environmental Sciences - _ search Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-001
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
r.,
EPA 8151A
2,4,5-T
<0.50
µg/L
0.50
02/18/99
02/18/99
CO
I
2,4,5-TP (Silvex)
<0.50
µg/L
0.50
02/18/99
02/18/99
CO
I
Dalapon
<0.50
µg/L
0.50
02/18/99
02/18/99
CO
1
r
Dicamba
<0.50
µg/L
0.50
02/18/99
02/18/99
CO
1
r,.
Dichloroprop
< 1.0
µg/L
1.0
02/18/99
02/18/99
CO
1
t
t
Dinoseb
< 1.0
µg/L
1.0
02/18/99
02/18/99
CO
I
MCPA
< 160
µg/L
160
02/18/99
02/18/99
CO
1
r'
MCCP
<200
µg/L
200
02/18/99
02/18/99
CO
1
SM 4500CI.B
Chloride
440
mg/L
50
02/18/99
02/18/99
BWB
10
EPA 375.4
Sulfate
197
mg/L
100
02/17/99
02/17/99
JMO
20
r„
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/12/99
02/12/99
BWB
I
EPA 353.3
Nitrate
3.30
mg/L
1.00
02/16/99
02/16/99
BWB
10
+"
SM4500NH3.D
Ammonia
0.39
mg/L
0.10
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DID
1
Alkalinity as Bicarbonate
314
mg/L
5
02/16/99
02/16/99
DJD
1
r•
EPA 6010B
Boron
0.625
mg/L
0.010
02/15/99
02/19/99
OX
1
I
Potassium
13.9
mg/L
1.0
02/15/99
02/18/99
OX
1
�.•
Sodium
198
mg/L
1.0
02/15/99
02/18/99
OX
1
t
Calcium
77.2
mg/L
1.0
02/15/99
02/19/99
OX
1
Magnesium
23.4
mg/L
0.010
02/15/99
02/18/99
OX
1
7
Arsenic
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Cadmium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
0-
Chromium
0.010
mg/L
0.005
02/15/99
02/18/99
OX
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Copper
0.097
mg/L
0.010
02/15/99
02/18/99
OX
1
.:
Nickel
<0.010
mg/L
0.010
02/15/99
02/18/99
OX
1
Lead
<0.015
mg/L
0.015
02/15/99
02/18/99
OX
1
Selenium
<0.040
mg/L
0.040
02/15/99
02/18/99
OX
I
Molybdenum
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
FIR
EPA 120.1
Conductivity
1810
umhos/cm2 1
03/01/99
03/01/99
DID
1
Client Sample 1D: WELL U
Sample Number:
99-0432-002
Date Sampled: 02/11/99
Sample Matrix:
Liquid
Time Sampled: 10:50
Sampled By:
LW
EPA 8081A 4,4'-DDD
<0.050 µg/L 0.050 02/15/99 02/26/99
JCA 1
4,4'-DDE
<0.050 µg/L 0.050 02/15/99 02/26/99
JCA I
Page 3 of 22
f Certes Environmental Laboratories
_709 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972.620.7966.800-394-2872- = S 620.7963• Email: certes(I�Iaol.com
--�.ytical Chemistry Environmental Sciences - =:=arch Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
r
Reporting
Date
Date
Analyzed
Sample: 99-0432-002 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 8081A
4,4'-DDT
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
alpha-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
-
beta-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
^,
alpha -Chlordane
<0.05
µg/L
0.05
02/15/99
0226/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/15/99
0226/99
JCA
1
Dieldrin
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endosulfan I
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endosulfan II
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endrin
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Endrin aldehyde
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
i
Endrin keytone
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
gamma-BHC
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/15/99
0226/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/15/99
0226/99
JCA
1
Toxaphene
<1.0
µg/L
1.0
02/15/99
0226/99
JCA
1
**Quality Control Surrogate
02/15/99
0226/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (*
57%
60-140%
02/15/99
0226/99
JCA
1
Decachlorobiphenyl (SS)
87%
60-140%
02/15/99
0226/99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
l
P
Aroclor-1221
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1232
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1248
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
w
Aroclor-1254
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
**Quality Control Surrogate
02/15/99
0226/99
JCA
1
r..
2,4,5,6-Tetrachloro-m-xylene (
* 57%
60-140%
02/15/99
0226/99
JCA
1
[
Decachlorobiphenyl (SS)
87%
60-140%
02/15/99
0226/99
JCA
1
EPA 8151A
2,4-D
<2
µg/L
2
02/18/99
02/18/99
ARM
1
f`
2,4-DB
<2
µg/L
2
02/18/99
02/18/99
ARM
1
t
2,4,5-T
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
02/18/99
02/18/99
ARM
1
P
Dalapon
<2
µg/L
2
02/18/99
02/18/99
ARM
1
t.:
Dicamba
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dichloroprop
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Page 4 of 22
r
Certes Environmental Laboratories
=_:3 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - ='2.620-7963 - Email: certes ii�aol.com
_.::cal Chemistry Environmental Sciences = =:sarch Microbiology
7 Results of Analyses CEL File No.: 99-0432 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
..:
EPA 8151A
Dinoseb
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/18/99
02/18/99
ARM
1
SM 4500CI.B
Chloride
430
mg/L
50
02/18/99
02/18/99
BWB
10
EPA 375.4
Sulfate
301
mg/L
50
02/17/99
02/17/99
JMO
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/13/99
02/13/99
DWT
1
EPA 353.3
Nitrate
8.56
mg/L
1.00
02/16/99
02/16/99
BWB
10
SM4500NH3.D
Ammonia
0.17
mg/L
0.10
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
216
mg/L
5
02/16/99
02/16/99
DJD
1
EPA 6010E
Boron
0.453
mg/L
0.010
02/15/99
02/18/99
OX
1
Potassium
11.8
mg/L
1.0
02/15/99
02/18/99
OX
1
i
Sodium
180
mg/L
1.0
02/15/99
02/18/99
OX
1
Calcium
77.8
mg/L
1.0
02/15/99
02/19/99
OX
1
Magnesium
23.3
mg/L
0.010
02/15/99
02/18/99
OX
1
j
Arsenic
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Cadmium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
Chromium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
EPA 6010E
Zinc
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Copper
0.682
mg/L
0.010
02/15/99
02/18/99
OX
1
Nickel
<0.010
mg/L
0.010
02/15/99
02/18/99
OX
1
p.6
Lead
<0.015
mg/L
0.015
02/15/99
02/18/99
OX
1
t
Selenium
0.064
mg/L
0.040
02/15/99
02/18/99
OX
1
Molybdenum
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
SM 9222D
Fecal Coliform
<1
col/l00mL
1
02/16/99
02/17/99
BWB
1
SM 9222B
Total Coliform
<1
col/l00mL
1
02/16/99
02/17/99
BWB
1
EPA 418.1
TPH
< 1
mg/L
1
02/15/99
02/15/99
BM
1
r
}
EPA 8270C
Benzoic acid
<50
µg/L
50
02/15/99
02/17/99
DL
1
!!
4-Chloro-3-methylphenol
<20
µg/L
20
02/15/99
02/17/99
DL
1
r
2-Chlorophenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
2,4-Dichlorophenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
2,4-Dimethylphenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
4,6-Dinitro-2-methylphenol
<50
µg/L
50
02/15/99
02/17/99
DL
1
2,4-Dinitrophenol
<50
µg/L
50
02/15/99
02/17/99
DL
1
2-Methylphenol
<50
µg/L
50
02/15/99
02/17/99
DL
1
4-Methylphenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
2-Nitrophenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
r
4-Nitrophenol
<50
µg/L,
50
02/15/99
02/17/99
DL
1
Page 5 of 22
r
Certes Environmental Laboratories
_-09 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966. 800.394.2872 - FAX c-2.620-7963 - Email: certes@aol.com
j . --vtical Chemistry Environmental Sciences R=__aarch Microbiology
rResults
of Analyses CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
r.
Sample: 99-0432-002 continued...
Result Units
Limit
Prepared Analyzed
By Dilution
EPA 8270C Pentachlorophenol
<50
µg/L
50
02/15/99
02/17/99
DL
1
Phenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
p
2,4,5-Trichlorophenol
<50
µg/L
50
02/15/99
02/17/99
DL
1
2,4,6-Trichlorophenol
<10
µg/L
10
02/15/99
02/17/99
DL
1
.,
Acenaphthene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Acenaphthylene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Anthracene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Benzidine
<20
µg/L
20
02/15/99
02/17/99
DL
1
Benzo(a)anthracene
<10
µg/L
10
02/15/99
02/17/99
DL
1
.A.
Benzo(a)pyrene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Benzo(b)fluoranthene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Benzo(g,h,i)perylene
<10
µg/L
10
02/15/99
02/17/99
DL
1
''4
Benzo(k)fluoranthene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Benzyl alcohol
<20
µg/L
20
02/15/99
02/17/99
DL
1
bis-(2-chloroethyl) ether
<10
µg/L
10
02/15/99
02/17/99
DL
1
t,
bis-(2-chloroethoxy)methane
<10
µg/L
10
02/15/99
02/17/99
DL
1
bis-(2-chloroisopropyl) ether
<10
µg/L
10
02/15/99
02/17/99
DL
1
bis-(2-ethylhexyl) phthalate
<10
µg/L
10
02/15/99
02/17/99
DL
1
4-Bromophenyl-phenylether
<10
µg/L
10
02/15/99
02/17/99
DL
1
Butylbenzylphthalate
<10
µg/L
10
02/15/99
02/17/99
DL
1
4-Chloroaniline
<20
µg/L
20
02/15/99
02/17/99
DL
1
2-Chloronaphthalene
<10
µg/L
10
02/15/99
02/17/99
DL
1
y
4-Chlorophenyl-phenylether
<10
µg/L
10
02/15/99
02/17/99
DL
1
G
Chrysene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Dibenzo(a,h)anthracene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Dibenzofuran
<10
µg/L
10
02/15/99
02/17/99
DL
1
1,2-Dichlorobenzene
<10
µg/L
10
02/15/99
02/17/99
DL
1
1,3-Dichlorobenzene
<10
µg/L
10
02/15/99
02/17/99
DL
1
r1,4-Dichlorobenzene
<10
µg/L
10
02/15/99
02/17/99
DL
1
3,3-Dichlorobenzidine
<20
µg/L
20
02/15/99
02/17/99
DL
1
r
Diethylphthalate
<10
µg/L
10
02/15/99
02/17/99
DL
1
Dimethylphthalate
<10
µg/L
10
02/15/99
02/17/99
DL
1
Di-n-butylphthalate
<10
µg/L
10
02/15/99
02/17/99
DL
1
2,6-Dinitrotoluene(2,6-DNT)
<10
µg/L
10
02/15/99
02/17/99
DL
1
DI-n-octylphthalate
<10
µg/L
10
02/15/99
02/17/99
DL
1
Azobenzene
<20
µg/L
20
02/15/99
02/17/99
DL
1
Fluoranthene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Fluorene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Hexachlorobenzene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Page 6 of 22
r
Certes Environmental Laboratories
7209 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872
- FA
: -_ 620-7963 - Email: certesdaol.com
Analytical Chemistry Environmental Sciences
F
a: = arch
Microbiology
Results of Analyses CEL File No.: 99-0432 Report Date: 03/02/99
r
Reporting
Date
Date
Analyzed
Sample: 99-0432-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Hexachlorobutadiene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Hexachlorocyclopentadiene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Hexachloroethane
<10
µg/L
10
02/15/99
02/17/99
DL
1
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Isophorone
<10
µg/L
10
02/15/99
02/17/99
DL
1
2-Methylnaphthalene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Naphthalene
<10
µg/L
10
02/15/99
02/17/99
DL
1
2-Nitroaniline
<50
µg/L
50
02/15/99
02/17/99
DL
1
3-Nitroaniline
<50
µg/L
50
02/15/99
02/17/99
DL
1
4-Nitroaniline
<50
µg/L
50
02/15/99
02/17/99
DL
1
Nitrobenzene (NB)
<10
µg/L
10
02/15/99
02/17/99
DL
1
N-Nitrosodimethylamine
<20
µg/L
20
02/15/99
02/17/99
DL
1
N-Nitrosodiphenylamine
<10
µg/L
10
02/15/99
02/17/99
DL
1
N-Nitrosodipropylamine
<10
µg/L
10
02/15/99
02/17/99
DL
1
Phenanthrene
<10
µg/L
10
02/15/99
02/17/99
DL
1
Pyrene
<10
µg/L
10
02/15/99
02/17/99
DL
1
1,2,4-Trichlorobenzene
<10
µg/L
10
02/15/99
02/17/99
DL
1
"Quality Control Surrogate
02/15/99
02/17/99
DL
1
Nitrobenzene-d5 (SS)
65%
49-118%
02/15/99
02/17/99
DL
1
2-Fluorobiphenyl (SS)
67%
43-116%
02/15/99
02/17/99
DL
1
Terphenyl-d14 (SS)
90%
33-144%
02/15/99
02/17/99
DL
1
EPA 120.1 Conductivity
1810
umhos/cm2
1
03/01/99
03/01/99
DJD
1
* Surrogate recovery is out of range
Client Sample ID: WELL P Sample Number: 99-0432-003
Date Sampled: 02/11/99 Sample Matrix: Liquid
Time Sampled: 14:00 Sampled By: LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
4,4'-DDE
<0.050
µg/L .
0.050
02/15/99
02/26/99
JCA
4,4'-DDT
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
Aldrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
alpha-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
beta-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
delta-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
alpha -Chlordane
<0.05
µg/L
0.05
02/15/99
02/26/99
JCA
gamma -Chlordane
<0.05
µg/L
0.05
02/15/99
02/26/99
JCA
Dieldrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
Endosulfan 1
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
Page 7 of 22
Certes Environmental Laboratories
9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - FAX .--2-v-20-7963 • Email: certesd aol.com
--=..ical Chemistry Environmental Sciences r_.=arch Microbiology
.w
'
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-003 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Endosulfan II
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endrin aldehyde
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
.-
Endrin keytone
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
R !.
gamma
<0.050
µg/i.
0.050
02/15/99
02R6/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
rHeptachlor
epoxide
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/15/99
02/26/99
JCA
1
r1�
Toxaphene
< 1.0
µg/L
1.0
02/15/99
02/26/99
JCA
1
**Quality Control Surrogate
02/15/99
02/26/99
JCA
1
2,4,5,6-Tetmchloro-m-xylene (
* 55%
60-140%
02/15/99
02/26/99
JCA
1
Decachlorobiphenyl (SS)
89%
60-140%
02/15/99
02/26/99
JCA
1
- •
EPA 9082
Aroclor-1016
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
Aroclor-1221
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
r
Aroclor-1232
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
r"
Aroclor-1248
<5.0
µg/L.
5.0
02/15/99
02/26/99
JCA
I
_
Aroclor-1254
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
I
Aroclor-1260
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
**Quality Control Surrogate
02/15/99
02/26/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (*
55%
60-140%
02/15/99
02/26/99
JCA
1
,..
Decachlorobiphenyl (SS)
89%
60-140%
02/15/99
02/26/99
JCA
1
EPA 8151A
2,4-D
<2
µg1l,
2
02/18/99
02/18/99
ARM
1
2,4-DB
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4,5-T
<2
µg/L
2
02/18/99
02/18/99
ARM
1
!
2,4,5-TP (Silvex)
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dalapon
<2
µg/L
2
02/18/99
02/18/99
ARM
1
i
Dicamba
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dichloroprop
<2
µg/L
2
02/19/99
02/18/99
ARM
1
Dinoseb
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/18/99
02/18/99
ARM
1
7
SM 4500CLB
Chloride
650
mg/L
50
02/18/99
02/18/99
BWB
10
+..
EPA 375.4
Sulfate
574
mg/L
100
02/17/99
02/17/99
JMO
20
r-
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/13/99
02/13/99
DWT
1
1
EPA 3533
Nitrate
12.0
mg/L
1.00
02/16/99
02/16/99
BWB
10
SM4500NH3.D
Ammonia
0.18
mg/L
0.10
02/15/99
02/16/99
BWB
1
r
SM 232013
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Page 8 of 22
eft
` Certes Environmental Laboratories
209 Wisconsin Street. Suite 200 Dallas. Texas. 75229 -972-620.7966. 800.394-2872 - FAX 2-620.7963 • Email: certes@aol.com
r.vtical Chemistry Environmental Sciences Research Microbiology
PW
i
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-003 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
SM 2320B
Alkalinity as Bicarbonate
248
mg/L
5
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
0.539
mg/L
0.010
02/15/99
02/18/99
OX
1
Potassium
14.2
mg/L
1.0
02/15/99
02/18/99
OX
1
Sodium
149
mg/L
1.0
02/15/99
02/18/99
OX
1
Calcium
126
mg/L
1.0
02/15/99
02/19/99
OX
1
Magnesium
24.3
mg/L
0.010
02/15/99
02/18/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Cadmium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
Chromium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Copper
0.614
mg/L
0.010
02/15/99
02/18/99
OX
1
Nickel
<0.010
mg/L
0.010
02/15/99
02/18/99
OX
1
Lead
<0.015
mg/L
0.015
02/15/99
02/18/99
OX
1
Selenium
0.056
mg/L
0.04
02/15/99
02/18/99
OX
1
Molybdenum
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
* Surrogate recovery is out of range
Client Sample 1D: WELL S
Sample Number:
99-0432-004
Date Sampled: 02/11/99
Sample Matrix:
Liquid
Time Sampled: 15:45
Sampled By:
LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
4,4'-DDE
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
4,4'-DDT
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
alpha-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
beta-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
alpha -Chlordane
<0.05
µg/L
0.05
02/15/99
02/26/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/15/99
02/26/99
JCA
1
Dieldrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endosulfan I
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endosulfan II
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endrin
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endrin aldehyde
<0.056
µg/L
0.050
02/15/99
02/26/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
gamma-BHC
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Page 9 of 22
Certes Environmental Laboratories
:9 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872 • FAX 2.620-7963 • Email: certes@aol.com
Ar_=Iytical Chemistry Environmental Sciences Fe5earch Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-004 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Heptachlor
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/15/99
02/26/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/15/99
02/26/99
JCA
1
Toxaphene
< 1.0
µg/L
1.0
02/15/99
02/26/99
JCA
1
**Quality Control Surrogate
02/15/99
02/26/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
*37%
60-I400/a
02/15/99
02/26/99
JCA
1
Decachlorobiphenyl (SS)
65%
60-140%
02/15/99
02/26/99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
Aroclor-1221
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
Aroclor-1232
<5.0
µg/L
5.0
02/15/99
02/26/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
I
Aroclor-1248
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1254
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/15/99
0226/99
JCA
1
**Quality Control Surrogate
02/15/99
0226/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
*37%
60-140%
02/15/99
0226/99
JCA
1
Decachlorobiphenyl (SS)
65%
60-140%
02/15/99
0226/99
JCA
1
EPA 8151A
2,4-D
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4-DB
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4,5-T
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dalapon
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dicamba
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dichloroprop
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dinoseb
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/18/99
02/18/99
ARM
1
SM 4500CLB
Chloride
310
mg/L
50
02/18/99
02/18/99
BWB
10
EPA 375.4
Sulfate
244
mg/L
50
02/17/99
02/17/99
JMO
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/13/99
02/13/99
DWT
1
EPA 3533
Nitrate
10.8
mg/L
1.00
02/16/99
02/16/99
BWB
10
SM4500NH3.D
Ammonia
035
mg/L
0.10
02/15/99
02/16/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
1150
mg/L
5
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
0.420
mg/L
0.010
02/15/99
02/18/99
OX
I
Potassium
10.4
mg/L
1.0
02/15/99
02/18/99
OX
1
Sodium
135
mg/L
1.0
02/15/99
02/18/99
OX
1
Calcium
69.5
mg/L
1.0
02/15/99
02/19/99
OX
1
Magnesium
23.0
mg/L
0.010
02/15/99
02/18/99
OX
1
Page 10 of 22
Certes Environmental Laboratories
- :9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 • FAX =-2-=20-7963 • Email: Certes q:�aol.com
.,tical Chemistry Environmental Sciences Fe:=arch Microbiology
n�
Results of Analyses CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Sample: 99-0432-004 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 6010B Arsenic
<0.050
mg/L
0.050
02/15/99
02/19/99
OX
1
Cadmium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
Chromium
<0.005
mg/L
0.005
02/15/99
02/18/99
OX
1
EPA 7470A Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
""
EPA 6010B Zinc
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
Copper
0.072
mg/L
0.010
02/15/99
02/18/99
OX
1
Nickel
<0.010
mg/L
0.010
02/15/99
02/18/99
OX
1
i
Lead
<0.015
mg/L
0.015
02/15/99
02/18/99
OX
1
Selenium
<0.040
mg/L
0.040
02/15/99
02/18/99
OX
1
.+.
Molybdenum
<0.050
mg/L
0.050
02/15/99
02/18/99
OX
1
a
s._
* Surrogate recovery is out of range
_.._
Client Sample ID: WELL F
Sample Number: 99-0432-005
Date Sampled: 02/15/99
Sample Matrix:
Liquid
Time Sampled: 11:30
Sampled By:
LW
?•
EPA 8081 A 4,4'-DDD
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
4,4'-DDE
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
4,4'-DDT
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
r'
alpha-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
beta-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
alpha -Chlordane
<0.05
µg/L
0.05
02/17/99
02/23/99
JCA
1
gamma -Chlordane
<0.05
µg/L
0.05
02/17/99
02/23/99
JCA
1
s.
Dieldrin
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endosulfan I
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endosulfan II
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
r
Endrin
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
�.,
Endrin aldehyde
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
gamma-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
{ _
Heptachlor epoxide
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/17/99
02/23/99
JCA
1
PO
Toxaphene
< 1.0
µg/L
1.0
02/17/99
02/23/99
JCA
1
"Quality Control Surrogate
02/17/99
02/23/99
JCA
1
r►
2,4,5,6-Tetrachloro-m-xylene (
75%
60-1400/a
02/17/99
02/23/99
JCA
1
Page 11 of 22
r
Certes Environmental Laboratories
_-:9 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966. 800-394-2872 • F-* *, ;'2.620-7963 • Email: certescaol.com
r--e .:,ical Chemistry Environmental Sciences - _ B parch Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-005 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Decachlorobiphenyl (SS)
97%
60-140%
02/17/99
02/23/99
JCA
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1221
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1232
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1248
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1254
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
"Quality Control Surrogate
02/17/99
02/23/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
75%
60-140%
02/17/99
02/23/99
JCA
1
Decachlorobiphenyl (SS)
97%
60-140%
02/17/99
02/23/99
JCA
1
EPA 8151A
2,4-D
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4-DB
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4,5-T
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
02/18/99
02/19/99
ARM
1
Dalapon
<2
µg/L
2
02/19/99
02/19/99
ARM
1
Dicamba
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dichloroprop
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dinoseb
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/18/99
02/18/99
ARM
1
SM 4_WOCI.B
Chloride
240
mg/L
50
02/19/99
02/18/99
BWB
10
EPA 375.4
Sulfate
286
mg/L
50
02/17/99
02/17/99
JMO
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/16/99
02/16/99
JMO
1
EPA 353.3
Nitrate
19.9
mg/L
10.0
02/19/99
02/18/99
BWB
100
SM4500NH3.D
Ammonia
035
mg/L
0.10
02/17/99
02/17/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
218
mg/L
5
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
0.535
mg/L
0.010
02/17/99
02/22/99
OX
1
Potassium
22.4
mg/L
1.0
02/17/99
02/22/99
OX
1
Sodium
125
mg/L
1.0
02/17/99
0222/99
OX
1
Calcium
< 1.0
mg/L
1.0
02/17/99
02/22/99
OX
1
Magnesium
24.1
mg/L
0.010
02/17/99
0222/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
Page 12 of 22
im-
Certes Environmental Laboratories
-=:H Wisconsin Street. Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 - FAX =72.620-7963 • Email: tortes@aol.com
r.:;ical Chemistry Environmental Sciences Research Microbiology
7 Results of Analyses CEL File No.: 99-0432 Report Date: 03/02/99
Reporting
Date Date
Analyzed
�- Sample: 99-0432-005 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 6010B Nickel
<0.010
mg/L
0.010
02/17/99 02/19/99
KJC I
Lead
<0.015
mg/L
0.015
02/17/99 02/19/99
KJC 1
Selenium
<0.040
mg/L
0.040
02/17/99 02/19/99
KJC 1
l
Molybdenum
<0.050
mg/L
0.050
02/17/99 02/19/99
KJC 1
r.,, Client Sample ID: WELL G Sample Number: 99-0432-006
Date Sampled: 02/15/99 Sample Matrix: Liquid
Time Sampled: 12:30 Sampled By: LW
EPA 8081A
4,4'-DDD
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
.,
4,4'-DDE
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
0.
4,4'-DDT
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
Aldrin
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
-"
alpha-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
rt"
beta-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
Iv.
delta-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
alpha -Chlordane
<0.05
µg/L
0.05
02/17/99
0223/99
JCA
gamma -Chlordane
<0.05
µg/L
0.05
02/17/99
0223/99
JCA
Dieldrin
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
�-
Endosulfan I
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
Endosulfan II
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
Endosulfan sulfate
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
1�
Endrin
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
Endrin aldehyde
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
Endrin keytone
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
gamma-BHC
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
Heptachlor
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
r `
Heptachlor epoxide
<0.050
µg/L
0.050
02/17/99
0223/99
JCA
l
Methoxychlor
<0.10
µg/L
0.10
02/17/99
0223/99
JCA
Toxaphene
< 1.0
µg/L
1.0
02/17/99
0223/99
JCA
"Quality Control Surrogate
02/17/99
0223/99
JCA
"
2,4,5,6-Tetrachloro-m-xylene (
74%
60-140%
02/17/99
0223/99
JCA
�.•
Decachlorobiphenyl (SS)
94%
60-140%
02/17/99
0223/99
JCA
EPA 8082
Aroclor-1016
<5.0
µg/L,
5.0
02/17/99
0223/99
JCA
Aroclor-1221
<5.0
µg/L
5.0
02/17/99
0223/99
JCA
r
f
Aroclor-1232
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
Aroclor-1242
<5.0
µg/L
5.0
02/17/99
0223/99
JCA
Aroclor-1248
<5.0
µg/L
5.0
02/17/99
0223/99
JCA
Page 13 of 22
;W
I- Certes Environmental Laboratories
Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966. 800-394-2872 • i= .x L-620-7963- Email: certes@aol.ccm
r'r Ar a.ytical Chemistry Environmental Sciences F _ s _ arch Microbiology
rok
t
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-006
continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
�..
EPA 8082
Aroclor-1254
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1260
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
"Quality Control Surrogate
02/17/99
02/23/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
74%
60-140%
02/17/99
0223/99
JCA
1
Decachlorobiphenyl (SS)
94%
60-140%
02/17/99
0223/99
JCA
1
EPA 8151A
2,4-D
<2
µg/L
2
02/18/99
02/18/99
ARM
1
2,4-DB
<2
µg/L
2
02/18/99
02/18/99
ARM
1
!"
2,4,5-T
<2
µg/L
2
02/18/99
02/18/99
ARM
1
`
2,4,5-TP (Silvex)
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dalapon
<2
µg/L
2
02/18/99
02/18/99
ARM
1
�.
Dicamba
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dichloroprop
<2
µg/L
2
02/18/99
02/18/99
ARM
1
e`
Dinoseb
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/18/99
02/18/99
ARM
1
SM 4500CLB
Chloride
140
mg/L
50
02/18/99
02/18/99
BWB
10
E—•
EPA 375.4
Sulfate
101
mg/L
25
02/17/99
02/17/99
JMO
5
r.,
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/16/99
02/16/99
JMO
1
j
EPA 353.3
Nitrate
2.35
mg/L
1.00
02/18/99
02/18/99
BWB
10
SM4500NH3.D
Ammonia
0.20
mg/L
0.10
02/17/99
02/17/99
BWB
1
r`
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
272
mg/L
5
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
0.463
mg/L
0.010
02/17/99
0222/99
OX
1
Potassium
15.8
mg/L
1.0
02/17/99
02/22/99
OX
1
Sodium
125
mg/L
1.0
02/17/99
0222/99
OX
1
Calcium
85.3
mg/L
1.0
02/17/99
0222/99
ON
1
.
Magnesium
20.1
mg/L
0.010
02/17/99
0222/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
t
Cadmium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
1
Chromium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
Poo
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
s
f
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
I!~"
Nickel
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
a.
Lead
0.017
mg/L
0.015
02/17/99
02/19/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/17/99
02/19/99
KJC
1
t..
Molybdenum
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
EPA 8270C
Benzoic acid
<50
µg/L
50
02/19/99
03/01/99
MJB
1
E"
4-Chloro-3-methylphenol
<20
µg/L
20
02/19/99
03/01/99
MJB
1
Page 14 of 22
rr
I
Carlos Environmental Laboratories
-7:9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966. 800-394-2872 • F.I's .---2-620-7963-E.-nail:certes@aol.com
r- A-a.ytical Chemistry Environmental Sciences __ arch Microbiology
r
Results of Analyses CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-006 continued...
Result Units
Limit
Prepared Analyzed
By
Dilution
v,
EPA 9270C 2-Chlorophenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2,4-Dichlorophenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
E
2,4-Dimethylphenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4,6-Dinitro-2-methylphenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
•-•
2,4-Dinitrophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
2-Methylphenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
4-Methylphenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2-Nitrophenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4-Nitrophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
Pentachlorophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
'
Phenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2,4,5-Trichlorophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
2,4,6-Trichlorophenol
<10
µg/L
10.
02/19/99
03/01/99
MJB
1
Acenaphthene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Acenaphthylene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Anthracene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
`
Benzidine
<20
µg/L
20
02/19/99
03/01/99
MJB
1
rIK
$enzo(a)anthracene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzo(a)pyrene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzo(b)fluoranthene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzo(g,h,i)perylene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
r
Benzo(k)fluoranthene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
,.�.
Benzyl alcohol
<20
µg/L
20
02/19/99
03/01/99
MJB
1
bis-(2-chloroethyl) ether
<10
µg/L
10
02/19/99
03/01/99
MJB
1
bis-(2-chloroethoxy)methane
<10
µg/L
10
02/19/99
03/01/99
MJB
1
bis-(2-chloroisopropyl)ether
<10
µg/L
10
02/19/99
03/01/99
MJB
1
bis-(2-ethylhexyl)phthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4-Bromophenyl-phenylether
<10
µg/L
10
02/19/99
03/01/99
MJB
1
t
t
Butylbenzylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4-Chloroaniline
<20
µg/L
20
02/19/99
03/01/99
MJB
1
r
2-Chloronaphthalene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4-Chlorophenyl-phenylether
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Chrysene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
r
Dibcnzo(a,h)anthracene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
-
Dibenzofuran
<10
µg/L
10
02/19/99
03/01/99
MJB
1
1,2-Dichlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
I
'r
1,3-Dichlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
1,4-Dichlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
3,3-Dichlorobenzidine
<20
µg/L
20
02/19/99
03/01/99
MJB
1
R
f
_.._
Page 15 of 22
F0
Certes Environmental Laboratories
-2:9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - FAX ;-2-_20-7953 • Email: certes@aol.com
f - - .::cal Chemistry Environmental Sciences Fesearch Microbiology
N
Results of Analyses CEL File No.: 99-0432 Report Date: 03/02/99
r
Reporting
Date
Date
Analyzed
Sample: 99-0432-006 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Diethylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Dimethylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Di-n-butylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2,6-Dinitrotoluene (2,6-DNT)
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Di-n-octylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Azobenzene
<20
µg/L,
20
02/19/99
03/01/99
MJB
1
Fluoranthene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Fluorene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Hexachlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Hexachlorobutadiene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Hexachlorocyclopentadiene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Hexachloroethane
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Isophorone
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2-Methylnaphthalene
<10
µg/L,
10
02/19/99
03/01/99
MJB
1
Naphthalene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2-Nitroaniline
<50
µg/L
50
02/19/99
03/01/99
MJB
1
3-Nitroaniline
<50
µg/L
50
02/19/99
03/01/99
MJB
1
4-Nitroaniline
<50
µg/L
50
02/19/99
03/01/99
MJB
1
Nitrobenzene (NB)
<10
µg/L
10
02/19/99
03/01/99
MJB
1
N-Nitrosodimethylamine
<20
µg/L
20
02/19/99
03/01/99
MJB
1
N-Nitrosodiphenylamine
<10
µg/L
10
02/19/99.
03/01/99
MJB
I
N-Nitrosodipropylamine
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Phenanthrene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Pyrene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
1,2,4-Trichlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
"Quality Control Surrogate
02/19/99
03/01/99
MJB
I
Nitrobenzene-d5 (SS)
65%
49-118%
02/19/99
03/01/99
MJB
I
2-Fluorobiphenyl (SS)
60%
43-116%
02/19/99
03/01/99
MJB
1
Terphenyl-dl4 (SS)
66%
33-144%
02/19/99
03/01/99
MJB
1
Client Sample ID: WELL B Sample Number. 99-0432-007
Date Sampled: 02/15/99 Sample Matrix: Liquid
Time Sampled: 14:30 Sampled By: LW
EPA 8081A 4,4'-DDD
<0.050 µg/L 0.050
02/17/99 02/23/99
JCA 1
4,4'-DDE
<0.050 µg/L, 0.050
02/17/99 02/23/99
JCA 1
4,4'-DDT
<0.050 µg/L 0.050
02/17/99 02/23/99
JCA 1
Page 16 of 22
Certes Environmental Laboratories
-09 Wisconsin Street, Suite 200
Dallas. Texas, 75229.972.620-7966.800.394-2872 - FAX Z
-2-620-7963 - Email: certes@aol.com
A--=—.nical Chemistry
Environmental Sciences Research
Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-007 Continued.:.
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8151A
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/19/99
02/18/99
ARM
1
SNI4500CLB
Chloride
34
mg/L
5
02/18/99
02/18/99
BWB
1
EPA 375.4
Sulfate
66
mg/L
25
02/17/99
02/17/99
JMO
5
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/16/99
02/16/99
JMO
1
EPA 353.3
Nitrate
11.4
mg/L
1.00
02/18/99
02/18/99
BWB
10
SN14500NH3.D
Ammonia
0.24
mg/L
0.10
02/17/99
02/17/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
314
mg/L
5
02/16/99
02/16/99
DJD
1
EPA 6010B
Boron
0.496
mg/L
0.010
02/17/99
02/22/99
OX
1
Potassium
13.4
mg/L
1.0
02/17/99
02/22/99
OX
1
Sodium
121
mg/L
1.0
02/17/99
02/22/99
OX
1
Calcium
38.2
mg/L
1.0
02/17/99
02/22/99
OX
1
Magnesium
18.4
mg/L
0.010
02/17/99
02/22/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/17/99
02/19/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/17/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
EPA 418.1
TPH
< 1
mg/L
1
02/17/99
02/17/99
SAB
1
Client Sample ID: WELL A
Date Sampled: 02/15/99
Time Sampled: 15:15
Sample Number: 99-0432-008
Sample Matrix: Liquid
Sampled By: LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/17/99 02/23/99
JCA
1
4,4'-DDE
<0.050
µg/L
0.050
02/17/99 02/23/99
JCA
1
4,4'-DDT
<0.050
µg/L
0.050
02/17/99 02i23/99
JCA
1
Aldrin
<0.050
µg/L
0.050
02/17/99 02/23/99
JCA
1
alpha-BHC
<0.050
µg/L
0.050
02/17/99 02/23/99
JCA
1
beta-BHC
<0.050
µg/L
0.050
02/17/99 02/23/99
JCA
1
delta-BHC
<0.050
µg/L
0.050
02/17/99 02/23/99
JCA
1
alpha -Chlordane
<0.05
µg/L
0.05
02/17/99 02/23/99
JCA
1
Page 18 of 22
Certes Environmental Laboratories
=c09 Wisconsin Street. Suite 200 Dallas, Texas, 75229. 972-620-7966.800-394-2872 • r7-:,: 0':-620-7963- Email: certes@aol.com
--_ ..Iical Chemistry Environmental Sciences F:=search Microbiology
r
Y
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
,.,
Sample: 99-0432-008 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
gamma -Chlordane
<0.05
µg/L
0.05
02/17/99
02/23/99
JCA
1
Dieldrin
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
tow
Endosulfan 1
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
`
Endosulfan 11
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endrin
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endrin aldehyde
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Endrin keytone
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
gamma-BHC
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Heptachlor
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/17/99
02/23/99
JCA
1
Methoxychlor
<0.10
µg/L
0.10
02/17/99
02/23/99
JCA
1
LI
Toxaphene
< 1.0
µg/L
1.0
02/17/99
02/23/99
JCA
1
**Quality Control Surrogate
02/17/99
02/23/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
* 23%
60-140%
02/17/99
02/23/99
JCA
1
r
Decachlorobiphenyl (SS)
95%
60-140%
02/17/99
02/23/99
JCA
1
t
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1221
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1232
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1242
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1248
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
!
Aroclor-1254
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Aroclor-1260
**Quality
<5.0
µg/L
5.0
02/17/99
02/23/99
JCA
1
Control Surrogate
02/17/99
02/23/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (*
23%
60-140%
02/17/99
02/23/99
JCA
1
Decachlorobiphenyl (SS)
95%
60-140%
02/17/99
02/23/99
JCA
1
EPA 8151A
2,4-D
<2
µg/L
2
02/18/99
02/19/99
ARM
1
2,4-DB
<2
µg/L
2
02/18/99
02/19/99
ARM
1
2,4,5-T
<2
µg/L
2
02/18/99
02/19/99
ARM
1
I'
2,4,5-TP (Silvex)
<2
µg/L
2
02/18/99
02/18/99
ARM
1
�.
Dalapon
<2
µg/L
2
02/19/99
02/18/99
ARM
1
Dicamba
<2
µg/L
2
02/18/99
02/18/99
ARM
1
Dichloroprop
<2
µg/L.
2
02/19/99
02/19/99
ARM
1
k `
Dinoseb
<2
µg/L
2
02/18/99
02/18/99
ARM
1
°
MCPA
<2
µg/L
2
02/18/99
02/18/99
ARM
1
MCCP
<2
µg/L
2
02/18/99
02/18/99
ARM
1
SM 4500CI.B
Chloride
52
mg/L
5
02/18/99
02/19/99
BWB
1
EPA 375.4
Sulfate
76
mg/L
25
02/17/99
02/17/99
JMO
5
7
EPA 3t4.1
Nitrite
<0.01
mg/L
0.01
02/16/99
02/16/99
JMO
1
Page 19 of 22
PM
Certes Environmental Laboratories
i __:-- Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620-7966. 800-394-2872 • : -2-620-7963. Email: cortexdaol.com
A -a;,,cal Chemistry Environmental Sciences __arch Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
fi-
Sample: 99-0432-008 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
EPA 353.3
Nitrate
2.30
mg/L
1.00
02/18/99
02/18/99
BWB
10
SM4500NH3.D
Ammonia
0.14
mg/L
0.10
02/17/99
02/17/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/16/99
02/16/99
DJD
1
Alkalinity as Bicarbonate
302
mg/L
5
02/16/99
02/16/99
_ DJD
1
�:..
EPA 6010B
Boron
0.581
mg/L
0.010
02/17/99
02/22/99
OX
1
a
Potassium
12.7
mg/L
1.0
02/17/99
02/22/99
OX
1
Sodium
82.6
mg/L
1.0
02/17/99
02/22/99
OX
1
Calcium
45.5
mg/L
1.0
02/17/99
02/22/99
OX
1
Magnesium
20.5
mg/L
0.010
02/17/99
02/22/99
OX
I
Arsenic
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/17/99
02/19/99
KJC
1
EPA :470A
Mercury
<0.0001
mg/L
0.0001
02/15/99
02/16/99
ADD
1
EPA 601013
Zinc
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/17/99
02/19/99
KJC
1
Lead
0.015
mg/L
0.015
02/17/99
02/19/99
KJC
I
r=
Selenium
<0.040
mg/L
0.040
02/17/99
02/19/99
KJC
1
I
Molybdenum
<0.050
mg/L
0.050
02/17/99
02/19/99
KJC
1
SM 9222D
Fecal Coliform
<1
col/100mL
1
02/16/99
02/17/99
BWB
I
SM 9222B
Total Coliform
< 1
col/100mL
1
02/16/99
02/17/99
BWB
1
y
EPA 41&1
TPH
<1
mg/L
1
02/17/99
02/17/99
SAB
1
EPA 9270C
Benzoic acid
<50
µg/L
50
02/19/99
03/01/99
MJB
1
E
4-Chloro-3-methylphenol
<20
µg/L,
20
02/19/99
03/01/99
MJB
1
J
2-Chlorophenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4
2,4-Dichlorophenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2,4-Dimethylphenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4,6-Dinitro-2-methylphenol
<50
µg/L,
50
02/19/99
03/01/99
MJB
1
2,4-Dinitrophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
2-Methylphenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
4-Methylphenol
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2-Nitrophenol
<10
µg/L,
10
02/19/99
03/01/99
MJB
1
4-Nitrophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
Pentachlorophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
1
Phenol
13
µg/L
10
02/19/99
03/01/99
MJB
1
2,4,5-Trichlorophenol
<50
µg/L
50
02/19/99
03/01/99
MJB
I
2,4,6-Trichlorophenol
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Acenaphthene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Acenaphthylene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
e
t
Page
20 of 22
Certes Environmental Laboratories
_::9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620.7966.800.394-2872 • FAX 2-620-7963 • Email: cortes@aol.com
Ar: _ ical Chemistry Environmental Sciences Research Microbiology
Results of Analyses
CEL File No.: 99-0432
Report Date: 03/02/99
r-
r
Reporting
Date
Date
Analyzed
Sample: 99-0432-008 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Anthracene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzidine
<20
µg/L
20
02/19/99
03/01/99
MJB
1
Benzo(a)anthracene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzo(a)pyrene
<10
µgIL
10
02/19/99
03/01/99
MJB
1
Benzo(b)fluoranthene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzo(g,h,i)perylene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Benzo(k)fluoranthene
<10
µg/L
10
02/19/99
03/01/99
MJB
l
Benzyl alcohol
<20
µg/L
20
02/19/99
03/01/99
MJB
1
bis-(2-chloroethyl) ether
<10
µg/L
10
02/19/99
03/01/99
MJB
1
bis-(2-chloroethoxy) methane
<10
µg/L
10
02/19/99
03/01/99
MJB
I
bis-(2-chloroisopropyl) ether
<10
µgIL
10
02/19/99
03/01/99
MJB
1
bis-(2-ethylhexyl) phthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4-Bromophenyl-phenylether
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Butylbenzylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
I
4-Chloroaniline
<20
µgIL
20
02/19/99
03/01/99
MJB
1
2-Chloronaphthalene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
4-Chlorophenyi-phenylether
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Chrysene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Dibenzo(a,h)anthracene
<10
µgIL
10
02/19/99
03/01/99
MJB
1
Dibenzofuran
<10
µg/L
10
02/19/99
03/01/99
MJB
1
1,2-Dichlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
1,3-Dichlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
1,4-Dichlorobenzene
<10
µgIL
10
02/19/99
03/01/99
MJB
I
3,3-Dichlorobenzidine
<20
µg/L
20
02/19/99
03/01/99
MJB
1
Diethylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Dimethylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Di-n-butylphthalate
<10
µgIL
10
02/19/99
03/01/99
MJB
1
2,6-Dinitrotoluene (2,6-DNI)
<10
µg/L
10
02/19/99
03/01/99
MJB
I
DI-n-octylphthalate
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Azobenzene
<20
µg/L
20
02/19/99
03/01/99
MJB
I
Fluoranthene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Fluorene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Hexachlorobenzene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Hexachlorobutadiene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Hexachlorocyclopentadiene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Hexachloroethane
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Isophorone
<10
µg/L
10
02/19/99
03/01/99
MJB
I
2-Methylnaphthalene
<10
µg/L
10
02/19/99
03/01/99
MJB
I
Page 21 of 22
Certes Environmental Laboratories
-209 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972.620.7966.800-394-2872 • FAX c-:-620-7963 • Ernail: certes (4aol.com
r-aivtical Chemistry Environmental Sciences Re:=arch Microbiology
Results of Analyses CEL File No.: 99-0432
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0432-008 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Naphthalene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
2-Nitroaniline
<50
µg/L
50
02/19/99
03/01/99
MJB
1
3-Nitroaniline
<50
µg/L
50
02/19/99
03/01/99
MJB
1
4-Nitroaniline
<50
µg/L
50
02/19/99
03/01/99
MJB
1
Nitrobenzene (NB)
<10
µg/L
10
02/19/99
03/01/99
MJB
1
N-Nitrosodimethylamine
<20
µg/L
20
02/19/99
03/01/99
MJB
1
N-Nitrosodiphenylamine
<10
µg/L
10
02/19/99
03/01/99
MJB
1
�.
N-Nitrosodipropylamine
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Phenanthrene
<10
µg/L
10
02/19/99
03/01/99
MJB
1
Pyrene
1,2,4-Trichlorobenzene
<10
<10
µg/L
µg/L
10
10
02/19/99
02/19/99
03/01/99
03/01/99
MJB
MJB
1
1
**Quality Control Surrogate
02/19/99
03/01/99
MJB
1
Nitrobenzene-d5 (SS)
72%
49-119%
02/19/99
03/01/99
MJB
1
2-Fluorobiphenyl (SS)
66%
43-116%
02/19/99
03/01/99
MJB
1
Terphenyl-d14 (SS)
68%
33-144%
02/19/99
03/01/99
MJB
1
Surrogate recovery Is out of range
Page 22 of 22
Certes Environmental Laboratories
�r =729 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7366.800-394.2872 - F- -. c-2-620-7963 • Email: certes@aol.com
I - : ;ical Chemistry Environmental Sciences r _ _ =arch Microbiology
Results of Analyses - Laboratory Quality Control File No.: 99-0432
E
As
B
Ca
Cd
Laboratory Control Sample
Batch Number
021599
021599
1CVS
021599
Date Prepared
02/15/99
02/15/99
02/19/99
02/15/99
Date Analyzed
02/22/99
02/22/99
02/19/99
02/18/99
% Recovery
106
101
102
95
% Recovery Duplicate
102
99
98
97
Relative Percent Difference (RPD)
4
2
4
2
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.050
<0.010
<1.00
<0.005
wisn Y
Cr
.
CuK
1VIg
i ...
Laboratory Control Sample
Batch Number
021599
021599
021599
021599
Date Prepared
02/15/99
02/15/99
02/15/99
02/15/99
Date Analyzed
02/18/99
02/18/99
02/19/99
02/19/99
% Recovery
95
116
109
163*
% Recovery Duplicate
96
183*
107
112
Relative Percent Difference (RPD)
1
67*
2
51 *
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.005
<0.010
<1.00
<0.010
*Outside Control Limits
"A = micrograms per liter (ppb) mg/l = milligrams per liter (ppm)
jig/kg = micrograms per kilogram (ppb) mg/kg = milligrams per kilogram (ppm)
< = less than % = percent
MS = Matrix Spike RPD = Relative Percentage Difference
MSD = Matrix Spike Duplicate RW - Reagent Water
LCS = Laboratory Control Sample LCSD - Laboratory Control Sample Duplicate
BS = Blank Spike BSD = Blank Spike Duplicate
µmhos/cm = micromhos/centimeter
Certes Environmental Laboratories
=s:9 Wisconsin Street. Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 - FAX c—s-620-7963 - Email: certes@aol.com
Microbiology ..;ical Chemistry Environmental Sciences Research
Results of Analyses - Laboratory Quality Control File No.: 99-0432
Mo
N to
Ni
Pb
?
Laboratory Control Sample
Batch Number
021599
021599
021599
021599
Date Prepared
02/15/99
02/15/99
02/15/99
02/15/99
Date Analyzed
02/18/99
02/18/99
02/18/99
02/18/99
% Recovery
101
108
98
99
% Recovery Duplicate
100
109
96
99
Relative Percent Difference (RPD)
1
1
2
0
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<1.00
<0.010
<0.015
.. -.:.
Laboratory Control Sample
Batch Number
021599
021599
Date Prepared
02/15/99
02/15/99
Date Analyzed
02/18/99
02/18/99
Recovery
104
112
% Recovery Du licate
102
110
Relative Percent Difference RPD
2
2
Method Blank
(m ) ( (mg/Kg) ( )
<0.040
<0.050
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l - milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD - Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
-7-9 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620-7966. 800-394-2872 - FAX ;'2-620-7963 • Email: certes@aol.com
-=_.;rtical Chemistry Environmental Sciences F=-search Microbiology
Results of Analyses - Laboratory Quality Control
�1
File No.: 99-0432
Aa
r
Cd
Cr
1
Cu
Mo
Matrix Spike
Batch Number
W021199
W021799
W021799
W021799
W021799
Date Prepared
02/17/99
02/17/99
02/17/99
02/17/99
02/17/99
Date Analyzed
02/19/99
02/19/99
02/19/99
02/19/99
02/19/99
Spiked Sample ID
0432-5
0432-5
0432-5
0432-5
0432-5
Sample Measured Result
<0.050
<0.005
<0.005
<0.010
0.011
Spike Level
(m ) ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.50
Spike Result
(mg/L) (µg/L) (mg/Kg) (µg/Kg)
0.480
0.454
0.449
0.456
0.480
% Recovery
96
91
90
91
94
Spike Duplicate Result
(m ( ) (mg/Kg) ( )
0.473
0.456
0.449
0.453
0.477
% Recovery Duplicate
95
91
90
91
93
Relative Percent Difference (RPD)
2
0
0
0
1
Control Limits %low %hi
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) (jigg (mg/Kg) ( )
<0.010
<0.005
<0.005
<0.010
<0.010
Laboratory Control Sample
Spike Level
(m ) ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.50
Spike Result
(m ( ) (m ) (
0.491
0.492
0.484
0.490
0.487
% Recovery
98
98
97
98
97
Spike Duplicate Result
(m ) ( ) (mg,/Kg) ( )
0.491
0.495
0.487
0.484
OA87
% Recovery Duplicate
98
99
97
97
97
Relative Percent Difference (RPD)
0
1
0
1
0
Control Limits %low -%hi
80-120
80-120
80-120
80-120
80-120
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% — percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
:9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 • FAX--2.620-7963 • Email: certes@aol.com
A-= Aical Chemistry Environmental Sciences Research Microbiology
F
Results of Analyses - Laboratory Quality Control File No.: 99-0432
kk
w Se
Zn
Hg
Matrix Spike
Batch Number
W021799
W021799
W021799
W021799
W021599
Date Prepared
02/17/99
02/17/99
02/17/99
02/17/99
02/15/99
Date Analyzed
02/19/99
02/19/99
02/19/99
02/19/99
02/16/99
Spiked Sample ID
0432-5
0432.5
0432-5
0432-5
0432-1
Sample Measured Result
<0.010
<0.015
<0.020
<0.050
<0.000I
Spike Level
(m ) ) (m ) ( )
0.50
0.50
0.50
0.50
0.0010
Spike Result
(m ) ( (mg/Kg) ( )
0.444
0.475
0.496
0.467
0.0010
% Recovery
89
95
99
93
100
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
0.454
0.459
0.495
0.468
0.0012
% Recovery Duplicate
91
92
99
94
118
Relative Percent Difference (RPD)
2
3
0
1
16
Control Limits (%low %hi
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.010
<0.015
<0.020
<0.050
<0.0001
Laboratog Control Sample
Spike Level
(m ( (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ) (mg/Kg) ( )
0.495
0.507
0.479
0.502
0.0057
% Recovery
99
101
96
100
113
Spike Duplicate Result
(m ( (mg/Kg) (jig/Kg)
0.493
0.495
0.497
( 0.498
0.0058
% Recovery Duplicate
99
99
99
99
117
Relative Percent Difference (RPD)
0
2
4
1
3
Control Limits %low -%hi
80-120
80-120
80-120
80-120
80-120
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< — less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS — Blank Spike
µmhos/cm = micromhos/centimeter
mg/l — milligrams per liter (ppm)
mg/kg - milligrams per kilogram (ppm)
% — percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD - Laboratory Control Sample Duplicate
BSD — Blank Spike Duplicate
Certes Environmental Laboratories
72:9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872- Fr'I 2-620-7963- Email: certes@aol.com
-�.ytical Chemistry Environmental Sciences r==_.arch Microbiology
u
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
Alkalinity: `
. Chloride',"
Sulfate
Ammonia ;
Ammonia
Matrix Spike
Batch Number
Alk-021699
CI-21899
SO421799
NH321699
NH321799
Date Prepared
02/16/99
02/18/99
02/17/99
02/15/99
02/17/99
Date Analyzed
02/16/99
02/18/99
02/17/99
02/16/99
02/17/99
Spiked Sample ID
0432-1
0432-1
0432-7
0432-1
0432-7
Sample Measured Result
314
440
65.8
0.387
0.241
Spike Level
(m ) ( (mg/Kg) (jig/Kg)
250
500
20.0
1.00
1.00
Spike Result
(mg/L) (µg/L) (mg/Kg) (jig/Kg)
276
930
93.5
1.32
1.00
% Recovery
110
98
109
93
76
Spike Duplicate Result
(m ) ) (mg/Kg) ( )
266
930
88.4
1.36
1.06
% Recovery Duplicate
106
98
103
97
82
Relative Percent Difference (RPD)
4
0
6
4
8
Control Limits %low -%hi
80-120
75-125
75-125
75-125
75-125
Method Blank
(m ) (µ ) (m ) (µ )
<5.00
<5.00
<5.00
<0.010
<0.10
Laboratory Control Sample
Spike Level
m ( ) (mg/Kg) (jig/Kg)
100
50.0
20.0
1.00
5.00
Spike Result
(m ) ) (mg/Kg) (
100
52.0
19.4
0.91
5.06
% Recovery
100
104
97
91
106
Spike Duplicate Result
(m ( (mg/Kg) (
N/A
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
N/A
Control Limits %low -%hi
90-110
90-110
1 85-115
90-110
90-110
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg - milligrams per kilogram (ppm)
% = percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
--C9 Wisconsin Street. Suite 200 Dallas, Texas. 75229. 972-620-7966. 600-394-2672- FAX 2.620-7963 • Email: certes@aot.com
` a :nical Chemistry Environmental Sciences Research Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
On
Nitrite
Nitrite �,
Nits to
2,4-D
L
2,
_ S� zP
Matrix S ike
Batch Number
N021,21399
NO2LO21699
NO31,21699
1866
1866
Date Prepared
02/13/99
02/16/99
02/16/99
02/15/99
02/15/99
Date Analyzed
02/13/99
02/16/99
02/16/99
02/18/99
02/18/99
Spiked Sample ID
0432-2
0432-5
0432-1
46758
46758
Sample Measured Result
<0.010
<0.010
3.30
<0.50
<0.50
Spike Level
(m ) ( ) (mg/Kg) )
0.020
0.10
5.00
0.80
0.80
Spike Result
(m ( (m ( )
0.019
0.092
7.69
0.49
0.55
% Recovery
95
92
88
61
69
Spike Duplicate Result
(m ( (m ) )
0.020
0.094
7.80
0.54
0.59
% Recovery Duplicate
100
94
90
67
73
Relative Percent Difference (RPD)
5
2
2
10
6
Control Limits %low -%hi
75-125
75-125
75-125
10-217
10-144
Method Blank
(m ( ) (mg/Kg) ()
<0.010
<0.010
<0.10
<0.50
<0.50
Laboratory Control Sample
Spike Level
(m ( (mg/Kg) ( )
0.050
0.10
0.50
0.80
0.80
Spike Result
(m ) ( (m
0.047
0.11
0.46
0.52
0.55
% Recovery
94
107
92
65
68
Spike Duplicate Result
(m ( (m )
N/A
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
N/A
Control Limits %low -%hi
90-110
90-110
90-110
50/150
50/150
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Cerles Environmental Laboratories
=709 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872- FAX a-2-620-7963- Email: certes@aol.com
Ara vtical Chemistry Environmental Sciences Research Microbiology
r
r
r
I
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
TPH 41&1
. ..
TPH 418.1 .
I
Matrix Spike
Batch Number
W99-009
W99-010
Date Prepared
02/15/99
02/17/99
Date Analyzed
02/15/99
02/17/99
Spiked Sample ID
RW
RW
Sample Measured Result
<1.00
<1.00
Spike Level
m ) (mg/Kg) ( )
5.00
5.00
Spike Result
m ( m ) ( )
5.40
4.70
% Recovery
108
94
Spike Duplicate Result
m ) ( ) (mg/Kg) (jig/Kg)
4.90
4.80
% Recovery Duplicate
99
1 96
Relative Percent Difference (RPD)
9
1 2
Control Limits %low -%hi
80-120
( 80-120
Method Blank
m ) ( ) (mg/Kg) ( )
<1.00
<1.00
Laboratory Control Sample
I
Spike Level
m ( m )
5.00
5.00
Spike Result
m (mg/Kg) )
N/A
N/A
% Recovery
N/A
I N/A
Spike Duplicate Result
m ( (mg/Kg) ( )
N/A
( N/A
% Recovery Duplicate
N/A
N/A
Relative Percent Difference (RPD)
N/A
I N/A
Control Limits %low -%hi
80-120
80-120
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm — micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg - milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
r _09 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.600-394-2872 • c-2-620-7963 • Email: certes@aol.com
J--a:ytical Chemistry Environmental Sciences =_search Microbiology
Results of Analyses - Laboratory Quality Control
µg/1= micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
File No.: 99-0432
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
229 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972.620-7966. 800-394-2872 - FAX :—_-=20-7963 • Email: tortes®aol.com
A-= .;ical Chemistry Environmental Sciences Fes -arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
*_
Cot form
Conductivity;;
x
Duplicate
Batch Number
21699
Cond-030199
Date Prepared
02/16/99
03/01/99
Date Analyzed
02/17/99
03/01/99
Sample ID
0432-2
0432-2
Sample Result (umho/cm)
(m ) ( ) (mg/Kg) ( )
<1.00
( 1910
Sample Duplicate Result (umho/cm)
m ) ( (mg/Kg) ( )
<1.00
1810
Relative Percent Difference RPD)
0
I 0
Control Limits
0-20
0-20
,
Method Blank
(mg/L) (ug/L) (me/Ke) (ug/Ke)
<1.00
I <0.50
Control
Spike Level
m (mg/Kg) ) N/A 500
Spike Result
(m )(m )( ) N/A 491
Recove N/A 98
Control Limits %low -%hi N/A 90-110
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD — Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=�3 Jisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966. 800.394.2872 - F.-I'-.:-=-620.7963 - Email: certes@aol.com
r.�� ;;icai Chemistry Environmental Sciences Search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
1,2,4 Tri
chloro-
benzene ;':
1,3
Dichtoro-
benzene w . °
1,4-
DI hloro-
benzene ''
2,4,-
DWtro-
_.
toluene :
2-Chloro-
phenol
2-Methyl-
naphtha-
lene
Matrix S ike
Batch Number
R2197
SVS99035
SVS99035
SVS99035
SVS99035
SVS99035
Date Prepared
02/ 15/99
02/21 /99
02/21 /99
0? 21 /99
02/21 /99
0221 /99
Date Analyzed
02/17/99
0221/99
0221/99
02.2l/99
0221/99
0221/99
Spiked Sample ID
990217B
0503-2
0503-2
0503-2
0503-2
0503-2
Spike Level
(m )( (mg/Kg) ()
100
100
100
100
200
100
Spike Result
(m (mg/Kg) )
N/A
N/A
N/A
N'A
N/A
N/A
% Recovery
N/A
N/A
N/A
N A
N/A
N/A
Spike Duplicate Result
(m ( )(m ) )
N/A
N/A
N/A
NA
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N -A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N A
N/A
N/A
Control Limits (%low -%hi )
44-142
36-125
30-125
39-139
41-125
41-125
Method Blank
(m )( )(m )(µ )
<10
<10
<10
<10
<20
<10
Laboratory Control Sample
Spike Level
(m ) (mg/Kg) ()
100
100
100
100
200
100
Spike Result
(m ( (mg/Kg) (jig/Kg)
55.5
51.0
51.0
50.5
92.0
41.0
% Recovery
56
51
51
51
46
41
Spike Duplicate Result
(m ) ( (mg/Kg) ( )
64.0
60.5
60.5
58.0
110
46.0
% Recove Duplicate
64
61
61
58
55
46
Relative Percent Difference (RPD)
8
10
10
7
9
5
Control Limits %low -%hi
44-142
36-125
30-125
39-139
41-125
41-125
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< - less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm — micromhos/centimeter
mg/1- milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD — Relative Percentage Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD — Blank Spike Duplicate
Certes Environmental Laboratories
Wisconsin Street, Suite 200 Dallas. Texas. 7 5229.972.620.7966.800-394-2872 - FAX ;'2-620-7963 • Email: certes@aol.com
Ars.ytical Chemistry Environmental Sciences R=search Microbiology
Results of Analyses - Laboratory Quality Control File No.: 99-0432
4-Chloro-
3=methyl-
phenol `
Acenaph- :;
thene .
n-Nitroso-
d-n
propyl
amine
Penta
dsloro
phenol
Phenol
Pyrene
Matrix Spike
Batch Number
R2197
SVS99035
SVS99035
SVS99035
SVS99035
SVS99035
Date Prepared
02/15/99
02/21/99
02/21/99
0221/99
02/21/99
02/21/99
Date Analyzed
02/17/99
0221/99
02/21/99
0221/99
02/21/99
02/21/99
Spiked Sample ID
990217B
0503-2
0503-2
0503-2
0503-2
0503-2
Spike Level
(m )(pg/L) (mg/Kg) ()
200
100
100
200
200
100
Spike Result
(mtr/L) ( ) (mg/Kg)
N/A
N/A
N/A
N `A
N/A
N/A
°'o Recovery
N/A
N/A
N/A
N-A
N/A
N/A
Spike Duplicate Result
(m ( (mg/Kg) ()
N/A
N/A
N/A
NA
N/A
N/A
°.'o Recovery Duplicate
N/A
N/A
N/A
N A
N/A
N/A
Relative Percent Difference RPD
N/A
N/A
N/A
N-A
N/A
N/A
Control Limits (%low -%hi
44-125
49-125
37-125
28-136
15-125
47-136
Method Blank
(m ) ( ) (mg/Kg) ( )
<20
<10
<10
0
<20
<10
Laboratory Control Sample
Spike Level
(m )( (mg/Kg) )
200
100
100
200
200
100
Spike Result
(m ( ) (mg/Kg) (jig/Kg)
108
65.5
59.0
82.0
39.5
79.0
,o Recovery
54
66
59
41
20
79
Spike Duplicate Result
(m ) (mg/Kg)
124
74.5
68.0
95.5
47.0
88.0
4'6 Recovery Duplicate
62
75
68
48
24
88
Relative Percent Difference (RPD)
8
9
9
7
4
9
Control Limits %low -%hi
44-125
49-125
37-125
28-136
15-125
47-136
µg/I = micrograms per liter (ppb)
µ&g = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
pmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mglkg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
209 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800.394-2872 • FAX :-2-620-7963 • Email: certes@aol.com
Ara,}nical Chemistry Environmental Sciences "==Parch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
Phenol :2-Chloro- 14 o- Nitroso-
J1,2,4- . 4-Chloro
phenol Dichlotro- di-n Trichloro- 37methyl-
benzene propylami benzene phenol
�.- ne
Batch Number
SVS99019
SVS99019
SVS99019
SVS99019
SVS99019
SVS99019
Date Prepared
03/01/99
03/01/99
03/01/99
03 01/99
03/01/99
03/01/99
Date Analyzed
03/01/99
03/01/99
03/01/99
03 01/99
03/01/99
03/01/99
Spiked Sample ID
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
Spike Level
(m )( )(m )( )
200
200
100
100
100
200
Spike Result
(m )( )(m )( )
N/A
N/A
N/A
Ni.
N/A
N/A
% Recovery
N/A
N/A
N/A
N A
N/A
N/A
Spike Duplicate Result
(mg/L) ( (mg/Kg) ( )
N/A
N/A
N/A
N A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N A
N/A
N/A
Control Limits (%low%high)
5-112
23-134
20-124
10-230
44-142
22-147
Method Blank
<20 1<20 I<10 I<10 I<10 1<20
Control
Spike Level
(m ) (mg/Kg) ()
200
200
100
100
100
200
Spike Result
(mg/L.) ( (mg/Kg) (jig/Kg)
51
83
41
57
46
98
4'o Recovery
26
42
41
57
46
49
Spike Duplicate Result
(mgJL) (gg/L) ((mg/Kg) ( )
44
81
40
55
45
95
% Recovery Duplicate
22
41
40
55
45
48
Relative Percent Difference (RPD)
17
2
2
4
2
2
Control Limits (%low "/ohi
5-112
23-134
20-124
10-230
44-142
22-147
µo = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (1pm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicau
Cedes Environmental Laboratories
Wisconsin Street, Suite 200 Dallas, Texas, 75229.972-620-7966. 800-394-2872 - F-:, :-2-620.7963- Email: certes@aol.com
�-=..✓zical Chemistry Environmental Sciences r =.-arch Microbiology
t
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
:
Acenaph-
thene _
4-Nltro- ,;
henol
p..
2,4; Dinh-
trotol uene
Peatachloro- .
h
Pyrene .
Matrix Spike
Batch Number
SVS99019
SVS99019
SVS99019
SVS99019
SVS99019
Date Prepared
03/01/99
03/01/99
03/01/99
03/01/99
03/01/99
Date Analyzed
03/01/99
03/01/99
03/01/99
03/01/99
03/01/99
Spiked Sample ID
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
Spike Level
(m )( )(m )( )
100
200
100
200
100
Spike Result
(m )( ) (mg/Kg) ()
N/A
N/A
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
N/A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
N/A
Control Limits (%low%hi
47-145
10-132
39-139
14-176
52-115
Method Blank
(m )( )(m )( )
<10
<'20
<10
<20
<10
Laboratory Control Sample
Spike Level
m ( (mg/Kg) ()
100
200
100
200
100
Spike Result
(m ( ) (mg/Kg) ()
51
65
60
129
70
% Recovery
51
33
60
65
70
Spike Duplicate Result
(me/L) ( (mg/Kg) ( )
49
71
59
136
71
% Recovery Duplicate
49
56
59
68
71
Relative Percent Difference (RPD)
4
9
1
5
1
Control Limits %low -%hi
47-145
10-132
39-139
14-176
52-115
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental laboratories
_=:9 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972.620.7966.800-394-2872 - FA.�,: c'2.620.7963 - Email: certescaol.ccm
Microbiology ,gical Chemistry Environmental Sciences Research
Results of Analyses - Laboratory Quality Control File No.: 99-0432
s
Sq 4
k. s;
Gamma BHC
"'Linda ne)
Heptachlor ,
Aldrin
Matrix S ike
Batch Number
PST99009
PST99009
PST99009
Date Prepared
02/12/99
02/12/99
02/12/99
Date Analyzed
02/26/99
0226/99
02/26/99
Spiked Sample ID
N/A
N/A
N/A
Spike Level
(m ) ( ) (mg/Kg) (jig/Kg)
0.40
0.40
0.40
Spike Result
(m )(pg/L) (mg/Kg) ()
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
Relative Percent Difference (RPD)
NIA
N/A
N/A
Control Limits (%low -%hi )
50-119
46-117
44-104
Method Blank
(m ) (µ ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
(m ) ( ) (m ) ( )
0.40
0.40
0.40
Spike Result
(m ) ( (mg/Kg) ( )
0.266
0.691
0.296
% Recovery
66
172•
74
Spike Duplicate Result
m ( m ) (jig/Kg)
0.246
0.674
0.278
Recovery Duplicate
62
168t
70
Relative Percent Difference (RPD)
7
3
6
Control Limits %low "/ohi
50-119
46-117
44-IO747::7:d
'Outside Control Limits
µg/1= micrograms per liter (ppb) mg/1- milligrams per liter (ppm)
µg/kg = micrograms per kilogram (ppb) mg/kg = milligrams per kilogram (ppm)
< = less than % - percent
MS — Matrix Spike RPD = Relative Percentage Difference
MSD = Matrix Spike Duplicate RW - Reagent Water
LCS — Laboratory Control Sample LCSD = Laboratory Control Sample Duplicate
BS = Blank Spike BSD = Blank Spike Duplicate
µmhos/cm — micromhos/centimeter
Certes Environmental Laboratories
"M Wisconsin Street, Suite 200 Dallas. Texas, 75229 .972.620.7966 - 800.394-2872 - FAX e-2-620.7963 • Email: certes (i�aol.com
r.-=_..tical Chemistry Environmental Sciences Research Microbiology
Results of Analyses - Laboratory Quality Control File No.: 99-0432
:'. .
Dleldrm
Endrin n
44DDT
Matrix Spike
Batch Number
PST99009
PST99009
PST99009
Date Prepared
02/12/99
0112/99
02/12/99
Date Analyzed
02/26/99
02^_6/99
02/26/99
Spiked Sample ID
N/A
N A
N/A
Spike Level
(m ) ( ) (mg/Kg) ( )
1.00
1.00
1.00
Spike Result
(m )( )(m )( )
N/A
N A
N/A
% Recovery
N/A
N A
N/A
Spike Duplicate Result
(m ) ( ) (me/Kg) ( )
N/A
N A
N/A
% Recovery Duplicate
N/A
N A
N/A
Relative Percent Difference (RPD)
N/A
N A
N/A
Control Limits (%low -%hi
48-119
62-133
59-148
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
(m ( (mg/Kg) ( )
1.00
1.00
1.00
Spike Result
(m ) ( ) (mg/Kg) ( )
0.797
0.913
0.846
% Recovery
80
91
85
Spike Duplicate Result
(m ( ) (mg/Kg) )
0.744
0.8:4
0.811
% Recovery Duplicate
74
84
81
Relative Percent Difference (RPD)
7
8
4
Control Limits %low -%hi
48-119
62-133
59-149
pg/l = micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
pmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (Fpm)
mg,/kg = milligrams per kilogram (ppm)
% = percent
RPD — Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicam
Cerles Environmental Laboratories
-_:9 Wisconsin Street. Suite 200 Dallas, Texas, 75229.972.620.7966.800.394-2872 - _= 2.620-7963. Email: certes@aol.com
Ara .-;cal Chemistry Environmental Sciences --=:=arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
a a
Gamma.BHC :
Heptachlor
Aldrin
Matrix S ike
Batch Number
PST99010
PST99010
PST99010
Date Prepared
02/15/99
02'15/99
02/15/99
Date Analyzed
02/20/99
02'20/99
02/20/99
Spiked Sample ID
N/A
N/A
N/A
Spike Level
(m ( ) (mg/Kg) (jig/Kg)
0.40
0.40
0.40
Spike Result
m )( (mg/Kg) ()
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
Control Limits (%low•%hi )
50-119
46-117
44-104
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
m ) (mg/Kg) ( )
0.40
0.40
0.40
Spike Result
(m ) ( ) (mg/Kg) (jig/Kg)
0.280
0.597
0.298
% Recovery
70
149'
74
Spike Duplicate Result -
(m ) ( ) (m )
0.263
0.563
0.291
% Recovery Duplicate
66
141 •
73
Relative Percent Difference (RPD)
6
6
2
Control Limits %low "/ohi
50-119
46-117
44-104
*Outside Control Limits
µg/l = micrograms per liter (ppb) mg/1- milligrams per liter (ppm)
µg/kg = micrograms per kilogram (ppb) mg/kg - milligrams per kilogram (ppm)
< = less than % - percent
NIS = Matrix Spike RPD - Relative Percentage Difference
MSD = Matrix Spike Duplicate RW - Reagent Water
LCS = Laboratory Control Sample LCSD - Laboratory Control Sample Duplicate
BS = Blank Spike BSD = Blank Spike Duplicate
µmhos/cm = micromhos/centimeter
Certes Environmental Laboratories
-=:3 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - FAX 620.7963 • Email: certes6 aol.com
A.- ;ical Chemistry Environmental Sciences F==_zarch Microbiology
Results of Analyses - Laboratory Quality Control File No.: 99-0432
Dieldrin
Endrin
4,4-DDT .
Matrix S ike
Batch Number
PST99010
PST99010
PST99010
Date Prepared
02/15/99
0215/99
02/15/99
Date Analyzed
02/20/99
0220/99
02/20/99
Spiked Sample ID
N/A
N/A
N/A
Spike Level
(m ( ) (mg/Kg) )
1.00
1.00
1.00
Spike Result
(m ) ( (mg/Kg) (jig/Kg)
N/A
N:'A
N/A
% Recovery
N/A
N-A
N/A
Spike Duplicate Result
(m )( (mg/Kg) ()
N/A
N/A
N/A
% Recovery Duplicate
N/A
N,A
N/A
Relative Percent Difference (RPD)
N/A
N A
N/A
Control Limits (%low -%hi
48-119
62-133
59-148
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
(m ) ( ) (mg/Kg) ( )
1.00
1.00
1.00
Spike Result
(m ) ) (mg/Kg) ( )
0.866
0.995
0.940
% Recovery
87
100
94
Spike Duplicate Result
(m ) ( (mg/Kg) )
0.817
0.931
0.881
% Recovery Duplicate
82
93
88
Relative Percent Difference (RPD)
6
7
7
Control Limits %low "/ohi
48-119
62-133
59-148
Mg/l = micrograms per liter (ppb)
µQ, /kg - micrograms per kilogram (ppb)
< — less than
MS = Matrix Spike
.MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1- milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
3'.Visconsin Street. Suite 200 Callas. Texas. 75229. 972-620-7966. 800-394-2872 • FA :'?-620 7963 • Email: certes@aol.com
Ana :-:cal Chemistry Environmental Sciences F=_search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
.. -.
Gamma BHC
(Lindane)
Heptachlor
Aldrin
Matrix Spike
Batch Number
PST99012
PST99012
PST99012
Date Prepared
02/17/99
0217/99
02/17/99
Date Analyzed
02/26/99
0226/99
02/26/99
Spiked Sample ID
N/A
NIA
N/A
Spike Level
(m ) ( (mg/Kg) ( )
0.40
0.40
0.40
Spike Result
(m ( ) (mg/Kg) )
N/A
NIA
N/A
% Recovery
N/A
NA
N/A
Spike Duplicate Result
(m )(m )( )
N/A
N`A
N/A
% Recovery Duplicate
N/A
N'A
N/A
Relative Percent Difference (RPD)
N/A
N A
N/A
Control Limits (%low %hi )
50-119
46-117
44-104
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
(m (mg/Kg) )
0.40
0.40
0.40
Spike Result
(m ) ( (mg/Kg) ( )
0.193
0.418
0.223
% Recovery
48'
105
56
Spike Duplicate Result
(m ) ( ) (mg/Kg) )
0.192
0.395
0.212
% Recovery Duplicate
46'
99
53
Relative Percent Difference (RPD)
6
6
5
Control Limits (%low%hi
50-119
46-117
44-104
*Outside Control Limits
µg/l = micrograms per liter (ppb) mg/1- milligrams per liter (ppm)
µg/kg = micrograms per kilogram (ppb) mglkg = milligrams per kilogram (ppm)
< - less than % - percent
MS = Matrix Spike RPD - Relative Percentage Difference
MSD = Matrix Spike Duplicate RW - Reagent Water
LCS = Laboratory Control Sample LCSD = Laboratory Control Sample Duplicate
BS = Blank Spike BSD - Blank Spike Duplicate
µmhos/cm = micromhos/centimeter
Cartes Environmental Laboratories
219 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966. 800-394-2872 - FAX u'2-620-7963- Email: certes@aol.com
Ara 4ical Chemistry Environmental Sciences Research Microbiology
r
Results of Analyses - Laboratory Quality Control File No.: 99-0432
d.
Dieldrin
Endrin
4,4-DDT ..:'
Matrix Spike
Batch Number
PST99009
PST99009
PST99009
Date Prepared
02/12/99
0212/99
02/12/99
Date Analyzed
02/26/99
02 26/99
0226/99
Spiked Sample ID
N/A
N A
N/A
Spike Level
(m ) ( ) (mg/Kg) ( )
1.00
1.00
1.00
Spike Result
(m )( (mg/Kg) )
N/A
N A
N/A
% Recovery
N/A
N A
N/A
Spike Duplicate Result
(m ) ) (mg/Kg) ()
N/A
N A
N/A
% Recovery Duplicate
N/A
N A
N/A
Relative Percent Difference (RPD)
N/A
N. A
N/A
Control Limits %low -%hi
48-119
62-133
59-148
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
(m ) ( (mg/Kg) )
1.00
1.00
1.00
Spike Result
(m ) (mg/Kg) (jig/Kg)
0.708
0.900
0.779
% Recovery
71
80
78
Spike Duplicate Result
m ( m )
0.708
0.797
0.772
% Recovery Duplicate
71
80
77
Relative Percent Difference (RPD)
0
0
1
Control Limits %low -%hi
48-119
62-133
59-148
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS — Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg - milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD - Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
_i:9 Wisconsin Street. Suite 200 Dallas. Texas. 75229 . 972-620-7966 .800-394-2872 - F-:- ,-2-620-7963 • Email: certes@aol.com
AraMical Chemistry Environmental Sciences=esearch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0432
Arochlor _ f
1260R',;:
,
Artochlor
1260
Arochlor
1260
Matrix Spike
Batch Number
PCB99009
PCB99010
PCB99012
Date Prepared
02/12/99
02115/99
02/17/99
Date Analyzed
0223/99
02,23/99
0223/99
Spiked Sample ID
N/A
N/A
N/A
Spike Level
m (gg/L) (mg/Kg) ()
N/A
N/A
N/A
Spike Result
m ) (jig/L) (mg/Kg) ()
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
Spike Duplicate Result
(m ( ) (mg/Kg) ()
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
Control Limits Now -%hi
48-139
48-139
48-139
Method Blank
(m ) ( ) (mg/Kg) ( )
<5.00
<5.00
<5.00
Laboratory Control Sample
Spike Level
(m ) ( (mg/Kg) (jig/Kg)
5.00
5.00
5.00
Spike Result
m )( )(m )( )
4.36
3.85
3.37
% Recovery
87
77
67
Spike Duplicate Result
(m ( ) m (
4.09
3.77
4.19
% Recovery Duplicate
82
75
84
Relative Percent Difference (RPD)
6
2
21 *
Control Limits %low -%hi
48-139
48-139
48-139
*See Case Narrative
µgel = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
NIS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg - milligrams per kilogram (ppm)
% = percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
__:? Wisconsin Street. Suite 200 Dallas. Texas. 75229. 972.620-7966. 800-394-2872 - FAX v's-620-7963 - Email: certes®aol.com
P-^=_ ..,:,cal Chemistry Environmental Sciences Rc arch Microbiology
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
.�._... Dallas, Texas 75229
972-620-7966 972-620-7963 Fax
Analysis(es) Requested
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Client Name
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No. 6 Type of Container2
Date Time Matrix, V G J O P,
Certes
Sample ID
10 W
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Sampled By
W — p,,
t Matrix:.,-..:. A - Air Bag; . C - Charcoal Tube; . L - Liquid; . OL - Oil; S - Soil;; SD - Solid;-. SL - Sludge; � WP -, Wipe;. W - WateriWastewater
2 Container Type.. V - 40ml VOA dal; . G .-Amber or Glass 1 Liter,, J - 250mi Wide-mouthClass Jar. O - Others
3 Preservative. a HCI - Hydrochloric Acid : HNO,'- Nitric Add; °, H,SO. - Sulfuric Add; O - Other _1 T
TAT
Standard: Date Required
RUSH: Date Required
Client Project ID
Special Instructions (including specific detection limits)
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NOTE: By submitting these samples, you agree to the terms and conditions contained i ertes' Schedule of Fees. Certes cannot accept verbal changes. Please FAX written changes to (972) 620-7963. .
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
-._..r Dallas, Texas 75229
972-620-7966 972-62D-7963 Fax
Analysis(es) Requested
Client Name
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Phone No.
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2 Container Type V - 40m1 VOA Val," G -.Amber or Glass t Liter, J - 250m1 Wide=mouth Glass Jar, O = Other
3 Preservative. , . HCI - Hydrochloric Acid; HNO, = Nitric Acid; H,SO� -Sulfuric Acid;, O Other'
TAT
Standard: Date Required `
RUSH: Date Required
Client Project ID
r N 1, (p `
Special Instructions (including specific detection limits) 1
0. L 1 �"A 1<- i �S C-- � No r\ `'e—
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Relinquished by
Date
Time
Received By
Relinquished by
Dat"ID,
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t Received By Labor
:Je !I
NOTE: By submitting these samples, you agree to the terms and conditions contained In erte ' Sch ule of Certes cannot accept verbal ch es: Please FAX written changes to (972) 620-7963.
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Dallas, Texas 75229
972-620-7966 972-620-7963 Fax
Analysis(es) Requested
Client Name
E
Phone No.
0
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To ensure proper balling, please reference quotation number.
S L�► 1 Q-
Project Manager
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Site Location
Cartes
No•
Sample 1D
Date
Time
Matrix'
No•
Type of Container:
V
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Sampled By
L -
1 Matrix:-... A - Air Bag; C - Charcoal Tube; L - Liquid, OL - Oil; S - Soil; SD - Solid; SL - Sludge, WP -Wipe; W - Water/Wastewater
2 Container Ty pe : V - 40ml VOA Vial; G Amber or Glass 1 Liter, J - 250mt Wide t►outh Glass Jar, 0 - Other,
3 Preservative. HC1- Hydrochloric Acrd HNO -Nitric Acid;' H=SO, =Sulfuric Acid; O -Other.
TAT
Standard: Date Required 01l I "'' " "
RUSH: Date Required
Client Project ID
Special Instructions (including specific detection limits)
ph •lC t4_s,) 1 V S X-S V } ���' �"
Certes Job Number
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Date
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Received By
ep K 900S
Date
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Relinquished by
Date ��
Time
Received By Laboratory
NOTE: By submitting these samples, you agree to the terms and conditions contained in Certes ;Sdhedule of Fees: 0artes cannot accept verbal charges. Please FAX written changes to (972) 620-7963.
2209 Wisconsin St: eet. Saito 200
Dallas. Texas 75229
912-620- 7966
-.- 800-394-2872 _mwV
97c-6 0-7963 FAX =ail: certe� .ccm
CERTES ENVIRONMENTAL LABORATORIES
ANALYTICAL REPORT
Certes File Number: 99-0488
Client Project I.D.:
EN1761
Prepared for:
ENPROTEC INC.
6310 Genoa Avenue, Suite E
Lubbock, TX 79424
Attention:
Mark Schneider
Report Date:
03/02/99
Included are the results of chemical analyses for the samples submitted to Certes Environmental
Laboratories, L.L.C., on 02/17/99. All analytical results met Quality Control requirements as set by the
#_ industry accepted criteria. Please refer to the Laboratory Quality Control Results section of this report.
This report must be reproduced in its entirety.
Sincerely,
Certes Environmental Laboratories, L.L.C.
4
v4
--'�Izc—
Amy LaSalle
President
{ _ �a; i�.:rr._try=nv;r�:i,�.:Zntsf ;r.^�s
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Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date Analyzed
r�
Result
Units
Limit
Prepared Analyzed
By
Dilution
Client Sample ID: EAST POND
Sample Number: 99-0488-00I
�•.
Date Sampled: 02/16/99
Sample Matrix:
Solid
Time Sampled: 10:35
Sampled By:
LW
EPA 8081A 4,4'-DDD
<3.34
jig/Kg
3.34
02/19/99
02/28/99
JCA
2
j
4,4'-DDE
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
4,4'-DDT
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
Aldrin
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
alpha-BHC
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
beta-BHC
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
delta-BHC
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
gamma-BHC
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
alpha -Chlordane
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
gamma -Chlordane
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Dieldrin
<3.34
jig/Kg
3.34
02/19/99
0228/99
JCA
2
.�
Endosulfan 1
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
t „
Endosulfan 11
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Endosulfan sulfate
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Endrin
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
t .
Endrin keytone
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
r
Endrin aldehyde
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Heptachlor
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Heptachlor epoxide
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Methoxychlor
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Toxaphene
<40.0
µg/Kg
40.0
02/19/99
0228/99
JCA
2
"Quality Control Surrogate
2,4,5,6-Tetrachloro-m-xylene (
86%
60-140%
02/19/99
02/19/99
0228/99
0228/99
JCA
JCA
1
Decachlorobiphenyl (SS)
71%
60-140%
02/19/99
0228/99
JCA
1
EPA 8082 Aroclor-1016
<50
µg/Kg
50
02/19/99
0228/99
JCA
2
Aroclor-1221
<50
µg/Kg
50
02/19/99
0228/99
JCA
2
Aroclor-1232
<50
µg/Kg
50
02/19/99
0229/99
JCA
2
r�
Aroclor-1242
<50
µg/Kg
50
02/19/99
0228/99
JCA
2
i
Aroclor-1248
<50
µg/Kg
50
02/19/99
0228/99
JCA
2
Aroclor-1254
<50
µg/Kg
50
02/19/99
0228/99
JCA
2
Aroclor-1260
<50
µg/Kg
50
02/19/99
0228/99
JCA
2
"Quality Control Surrogate
02/19/99
0228/99
JCA
F`
2,4,5,6-Tetrachloro-m-xylene (
86%
60-140%
02/19/99
0228/99
JCA
1
Decachlorobiphenyl (SS)
71%
60-140%
02/19/99
0228/99
JCA
1
r-
EPA 8151A 2,4-D
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
2,4-DB
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
Page 2 of 24
Sertes
Environmental Laboratories
-3 Wisconsin Street. Suite 200 Dallas. Texas. 75229. 972.620-7966.
800-394-2872 - FAX
--2-620-7963 • Email: certes@aol.com
r.
P
:.-a .. ;cal Chemistry Environmental Sciences
Fssearch
Microbiology
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
*-
Sample: 99-0488-001
continued...
Result
Units
Limit
Prepared
Analyzed
By Dilution
i
-
EPA 8151A
2,4,5-T
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
2,4,5-TP (Silvex)
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
r-
Dalapon
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
Dicamba
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
*�
Dichloroprop
<0.1
mg/kg
0.1
0222/99
02/23/99
ARM
1
r
Dinoseb
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
I
MCPA
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
i
MCCP
<0.1
mg/kg
0.1
02/22/99
0223/99
ARM
1
f
EPA 9253
Chloride
400
mg/Kg
50
0222/99
0222/99
BWB
1
r
EPA 9038
Sulfate
2050
mg/Kg
50
02/19/99
02/19/99
DJD
1
jj
EPA354AM
Nitrite
<1.0
mg/Kg
1.0
02/19/99
02/19/99
BWB
10
EPA 353.3
Nitrate
< 1.0
mg/Kg
1.0
0222/99
0222/99
BWB
1
EPA 350.3M
Ammonia
20.6
mg/Kg
1.0
0222/99
0222/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<50
mg/KG
50
0222/99
0222/99
DJD
1
Alkalinity as Bicarbonate
1280
mg/KG
50
0222/99
0222/99
DJD
1
f
EPA 6010E
Boron
11
mg/Kg
10
02/19/99
0225/99
OX
1
Potassium
1780
mg/Kg
50
02/19/99
0225/99
OX
I
i.
Sodium
672
mg/Kg
50
02/19/99
0225/99
OX
1
i
Calcium
13400
mg/Kg
50
02/19/99
02/25/99
OX
1
Magnesium
1430
mg/Kg
0.50
02/19/99
0225/99
OX
1
Arsenic
<2.5
mg/Kg
2.5
02/19/99
0225/99
OX
1
Cadmium
0.84
mg/Kg
0.50
02/19/99
0225/99
OX
1
Chromium
14.0
mg/Kg
0.50
02/19/99
0225/99
OX
1
- A
EPA 7471A
Mercury
0.35
mg/Kg
0.01
0222/99
0223/99
ADD
1
EPA 6010E
Zinc
66.3
mg/Kg
5.0
02/19/99
0225/99
OX
1
Copper
26.4
mg/Kg
0.50
02/19/99
0225/99
OX
1
a '
Nickel
9.4
mg/Kg
1.0
02/19/99
0225/99
OX
1
C:
Lead
Selenium
15.8
<2.0
mg/Kg
mg/Kg
1.5
2.0
02/19/99
02/19/99
0225/99
0225/99
OX
OX
1
1
Molybdenum
3.5
mg/Kg
1.0
02/19/99
0225199
OX
1
r'
EPA 418.1
TPH
97
mg/Kg
10
0222/99
0222/99
SAB
1
(
EPA 8270C
Benzoic acid
< 1650
jig/Kg
1650
0222/99
0223/99
ANA
1
4-Chloro-3-methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
r
2-Chlorophenol
<330
µg/Kg
330
0222/99
0223/99
ANA
1
2,4-Dichlorophenol
<660
jig/Kg
660
0222/99
0223/99
ANA
1
t4
2,4-Dimethylphenol
<660
µg/Kg
660
0222/99
0223/99
ANA
1
4,6-Dinitro-2-methylphenol <660
µg/Kg
660
0222199
0223/99
ANA
1
2,4-Dinitrophenol
< 1650
µg/Kg
1650
0222/99
0223/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Page 3 of 24
f
Certes Environmental Laboratories
=9 Wisconsin Street. Suite 200 Dallas. Texas, 75229 .972-620-7966.
800-394-2872 - FAX :-2-620-7963 • Email: certes@aol.com
r
Ar3:;ical Chemistry Environmental
Sciences
Re arch
Microbiology
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-001 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C 4-Methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2-Nitrophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
4-Nitrophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Pentachlorophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Phenol
<330
µg/Kg
330
0222/99
02/23/99
ANA
1
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Acenaphthene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Acenaphthylene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Anthracene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Benzidine
<2500
µg/Kg
2500
02/22/99
02/23/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
0222/99
02/23/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Benzo(b)fluoranthene
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Benzo(k)fluoranthene
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
4-Bromophenyl-phenylether
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Butylbenzylphthalate
<660
µg/Kg
660
0222/99
02/23/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2-Chloronaphthalene
<330
µg/Kg
330
0222/99
02/23/99
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
02/22/99
0223/99
ANA
1
Chrysene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Dibenzo(a,h)anthracene
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Dibenzofuran
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
1,2-Dichlorobenzene
<330
µg/Kg
330
0222/99
02/23/99
ANA
1
1,3-Dichlorobenzene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
1,4-Dichlorobenzene
<330
µg/Kg
330
0222/99
02/23/99
ANA
1
3,3-Dichlorobenzidine
<670
µg/Kg
670
0222/99
0223/99
ANA
1
Diethylphthalate
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Dimethylphthalate
<660
µg/Kg
660
0222/99
02/23/99
ANA
1
Di-n-butylphthalate
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2,6-Dinitrotoluene (2,6-DNT)
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
DI-n-octylphthalate
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Azobenzene
µg/Kg
02/22/99
02/23/99
ANA
1
Page 4 of 24
W
Certes Environmental Laboratories
_-:'.9 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966. 800-394-2872 - FAX c'2-620-7963• Email: certes@aol.com
Ana::tical Chemistry Environmental Sciences Research Microbiology
f
P
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
.,.
Sample: 99-0488-001 continued...
Result
Units
Limit
Prepared
Analyzed
By
Dilution
k
EPA 9270C Fluoranthene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Fluorene
<330
µg/Kg
330
0222199
02/23/99
ANA
1
r
Hexachlorobenzene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Hexachlorobutadiene
<330
µg/Kg
330
02/22/99
0223/99
ANA
1
,,.
Hexachlorocyclopentadiene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachloroethane
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Indeno(1,2,3-cd)pyrene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Isophorone
<660
µg/Kg
660
0222/99
0223/99
ANA
1
" .
2-Methylnaphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Naphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
t
2-Nitroaniline
<660
µg/Kg
660
02/22/99
0223/99
ANA
1
3-Nitroaniline
< 1650
µg/Kg
1650
0222/99
0223/99
ANA
1
4-Nitroaniline
< 1650
µg/Kg
1650
0222/99
02/23/99
ANA
I
-
Nitrobenzene (NB)
<660
µg/Kg
660
0222/99
0223/99
ANA
1
N-Nitrosodimethylamine
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Me
N-Nitrosodiphenylamine
<660
jig/Kg
660
0222/99
0223/99
ANA
I
N-Nitrosodipropylamine
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Phenanthrene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Pyrene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
1,2,4-Trichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
r
"Quality Control Surrogate
0222/99
0223/99
ANA
1
Nitrobenzene-d5 (SS)
34%
43-138%
0222/99
0223/99
ANA
1
2-Fluorobiphenyl (SS)
51%
50-124%
0222/99
0223/99
ANA
1
Terphenyl-d14 (SS)
43%
62-145%
0222/99
0223/99
ANA
1
EPA 351.4M Total Kjeldahl Nitrogen
1630
mg/Kg
3
0223/99
ARM
1
.••
Client Sample ID: MIDDLE POND
Date Sampled: 02/16/99
Time Sampled: 12:15
Sample Number: 99-0488-002
Sample Matrix: Solid
Sampled By: LW
EPA SNIA 4,4'-DDD
<3.34
jig/Kg
3.34
02/19/99 0228/99
JCA
2
4,4'-DDE
<3.34
µg/Kg
3.34
02/19/99 0228/99
]CA
2
4,4'-DDT
<3.34
µg/Kg
3.34
02/19/99 0228/99
JCA
2
Aldrin
<3.34
µg/Kg
3.34
02/19/99 0228/99
JCA
2
alpha-BHC
<3.34
µg/Kg
3.34
02/19/99 0228/99
JCA
2
beta-BHC
<3.34
µg/Kg
3.34
02/19/99 0228/99
JCA
2
delta-BHC
<3.34
µg/Kg
3.34
02/19/99 0228/99
JCA
2
gamma-BHC
<3.34
µg/Kg
3.34
02/19/99 0228/99
JCA
2
Page 5 of 24
Certes Environmental Laboratories
__:9 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966 •800.394.2872 - FAX :-2.620-7963 • Email: certes@aol.com
t-� !cal Chemistry Environmental Sciences Research Microbiology
r
l
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
d
Reporting
Date
Date
Analyzed
r•
Sample: 99-0488-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
alpha -Chlordane
<3.34
jig/Kg
3.34
02/19/99
02/28/99
JCA
2
gamma -Chlordane
<3.34
jig/Kg
3.34
02/19/99
02/29/99
JCA
2
r
t
Dieldrin
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
Endosulfan 1
<3.34
jig/Kg
3.34
02/19/99
0228/99
JCA
2
Endosulfan 11
<3.34
jig/Kg
3.34
02/19/99
02/28/99
JCA
2
e
j_:
Endosulfan sulfate
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
Endrin
<3.34
jig/Kg
3.34
02/19/99
02/28/99
JCA
2
Endrin keytone
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Endrin aldehyde
<3.34
jig/Kg
3.34
02/19/99
0228/99
JCA
2
Heptachlor
<3.34
jig/Kg
3.34
02/19/99
0228/99
JCA
2
!
Heptachlor epoxide
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
i
Methoxychlor
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
2
Toxaphene
<40.0
µg/Kg
40.0
02/19/99
0228/99
JCA
2
=-
"Quality Control Surrogate
02/19/99
0228/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
71%
60-140%
02/19/99
0228/99
JCA
1
Decachlorobiphenyl (SS)
87%
60-140%
02/19/99
0228/99
JCA
1
EPA 8082
Aroclor-1016
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
Aroclor-1221
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
Aroclor-1232
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
Aroclor-1242
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
Aroclor-1248
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
Aroclor-1254
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
r�
Aroclor-1260
<25
µg/Kg
25
02/19/99
0228/99
JCA
1
"Quality Control Surrogate
02/19/99
0228/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
71%
60-140%
02/19/99
0228/99
JCA
1
Decachlorobiphenyl (SS)
87%
60-140%
02/19/99
0228/99
JCA
1
EPA 8151A
2,4-D
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
r
2,4-DB
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
r
2,4,5-T
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
2,4,5-TP (Silvex)
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
^
Dalapon
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
Dicamba
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
Dichloroprop
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
i
Dinoseb
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
MCPA
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
PM
MCCP
<0.1
mg/kg
0.1
0222/99
0223/99
ARM
1
EPA 9253
Chloride
390
mg/Kg
50
0222/99
0222/99
BWB
1
EPA 9038
Sulfate
2870
mg/Kg
50
02/19/99
02/19/99
DJD
1
EPA 354.1 M
Nitrite
< 1.0
mg/Kg
1.0
02/19/99
02/19/99
BWB
10
Page 6 of 24
r
t
Certes Environmental Laboratories
=209 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.600-394-2872 • FAX -2.620-7963. Email: certes@aol.com
r�
r-namlical Chemistry Environmental Sciences Research Microbiology
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-002 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 353.3
Nitrate
< 1.0
mg/Kg
1.0
02/22/99
02/22/99
BWB
I
EPA 350.31W
Ammonia
26.3
mg/Kg
1.0
02/22/99
02/22/99
BWB
I
SM 2320B
Alkalinity as Carbonate
<50
mg/KG
50
02/22/99
02/22/99
DJD
I
Alkalinity as Bicarbonate
720
mg/KG
50
02/22/99
02/22/99
DID
1
EPA 6010B
Boron
< 10
mg/Kg
10
02/19/99
02/25/99
OX
1
Potassium
1130
mg/Kg
50
02/19/99
02/25/99
OX
1
Sodium
628
mg/Kg
50
02/19/99
02/25/99
OX
I
Calcium
12000
mg/Kg
50
02/19/99
02/25/99
OX
I
Magnesium
1120
mg/Kg
0.50
02/19/99
02/25/99
OX
1
Arsenic
<2.5
mg/Kg
2.5
02/19/99
02/25/99
OX
1
i
Cadmium
<0.50
mg/Kg
0.50
02/19/99
02/25/99
OX
1
Chromium
7.28
mg/Kg
0.50
02/19/99
02/25/99
OX
1
EPA 7471A
Mercury
0.17
mg/Kg
0.01
02/22/99
02/23/99
ADD
1
EPA 6010B
Zinc
43.9
mg/Kg
5.0
02/19/99
02/25/99
OX
1
Copper
15.8
mg/Kg
0.50
02/19/99
02/25/99
OX
1
Nickel
4.4
mg/Kg
1.0
02/19/99
02/25/99
OX
1
Lead
9.1
mg/Kg
1.5
02/19/99
02/25/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/19/99
02/25/99
OX
1
Molybdenum
2.1
mg/Kg
1.0
02/19/99
02/25/99
OX
I
EPA 418.1
TPH
< 10
mg/Kg
10
02/22/99
02/22/99
SAB
1
EPA 8270C
Benzoic acid
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
4-Chloro-3-methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
�,.
2-Chlorophenol
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
2,4-Dichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
I
2,4-Dimethylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
4,6-Dinitro-2-methylphenol <660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2,4-Dinitrophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
4-Methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2-Nitrophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
.-
4-Nitrophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Pentachlorophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Phenol
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
k -
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
I
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
C''
Acenaphthene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Acenaphthylene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Anthracene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
4•
Benzidine
<2500
µg/Kg
2500
02/22/99
02/23/99
ANA
1
Page 7 of 24
Certes Environmental
Laboratories
_2:9 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972-620.7966 •800.394-2872 • F.A.X
c-2-620-7963. Email: certes@aol.com
Ana. tical Chemistry Environmental Sciences
Research
Microbiology
r
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Benzo(a)anthracene
<330
µg/Kg
330
02/22/99
0223/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Benzo(b)fluoranthene
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Benzo(g,h,i)perylene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Benzo(k)fluoranthene
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
0222/99
0223/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
0222/99
0223/99
ANA
1
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
0222/99
0223/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
0222/99
0223/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
4-Bromophenyl-phenylether
<660
µg/Kg
660
0222/99
02/23/99
ANA
1
Butylbenzylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
0222/99
0223/99
ANA
1
2-Chloronaphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Chrysene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Dibenzo(a,h)anthracene
< 1650
µg/Kg
1650
0222/99
0223/99
ANA
1
Dibenzofuran
< 1650
µg/Kg
1650
0222/99
0223/99
ANA
1
1,2-Dichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
1,3-Dichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
1,4-Dichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
3,3-Dichlorobenzidine
<670
µg/Kg
670
0222/99
0223/99
ANA
1
Diethylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Dimethylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Di-n-butylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
2,6-Dinitrotoluene (2,6-DNi)
<660
µg/Kg
660
0222/99
0223/99
ANA
1
DI-n-octylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Azobenzene
µg/Kg
0222/99
0223/99
ANA
1
Fluoranthene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Fluorene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachlorobutadiene
<330
µg/Kg
330
02=N9
0223/99
ANA
1
Hexachlorocyclopentadiene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachloroethane
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Indeno(1,2,3-cd)pyrene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Isophorone
<660
µg/Kg
660
0222/99
0223/99
ANA
1
2-Methylnaphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Naphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
2-Nitroaniline
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Page 8 of 24
k Certes Environmental Laboratories
__:? Wisconsin Street. Suite 200 Dallas. Texas, 75229.972.620•�966.800-394-2872 -FAX : -:•620-7963 • Email: certes@aol.com
A-- : ical Chemistry Environmental Sciences F _=__arch Microbiology
r.
If
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C 3-Nitroaniline
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
4-Nitroaniline
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Nitrobenzene (NB)
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
N-Nitrosodimethylamine
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
N-Nitrosodiphenylamine
<660
µg/Kg
660
02/22/99
02/23/99
ANA
I
N-Nitrosodipropylarnine
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Phenanthrene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Pyrene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
1,2,4-Trichlorobenzene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
"Quality Control Surrogate
02/22/99
02/23/99
ANA
1
Nitrobenzene-d5 (SS)
44%
43-138%
02/22/99
02/23/99
ANA
1
2-Fluorobiphenyl (SS)
50%
50-124%
02/22/99
02/23/99
ANA
1
Terphenyl-d14 (SS)
41%
62-145%
02/22/99
02/23/99
ANA
1
EPA 351AM Total Kjeldahl Nitrogen
1490
mg/Kg
3
02/23/99
02/23/99
ARM
1
Client Sample ID: WEST POND Sample Number: 99-0488-003
Date Sampled: 02/16/99 Sample Matrix: Solid
Time Sampled: 13:30 Sampled By: LW
EPA 8081A 4,4'-DDD
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
4,4'-DDE
<3.34
jig/Kg
3.34
02/19/99
02/28/99
JCA
4,4'-DDT
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Aldrin
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
alpha-BHC
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
beta-BHC
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
delta-BHC
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
gamma-BHC
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
alpha -Chlordane
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
gamma -Chlordane
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Dieldrin
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Endosulfan I
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Endosulfan 11
<3.34
µg/Kg
3.34
02/19/99
0228/99
JCA
Endosulfan sulfate
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Endrin
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Endrin keytone
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Endrin aldehyde
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Heptachlor
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Heptachlor epoxide
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
Page 9 of 24
7
Certes Environmental Laboratories
_:09 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620.7966.800.394-2872 • FAX : 620-7963 • Email:certes@aol.com
--a.;nical Chemistry Environmental Sciences R_.earch Microbiology
FResults of Analyses CEL File No.: 99-0488 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
.••
Sample: 99-0488-003 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Methoxychlor
<3.34
µg/Kg
3.34
02/19/99
02/28/99
JCA
2
Toxaphene
<40.0
µg/Kg
40.0
02/19/99
02/28/99
JCA
2
"Quality Control Surrogate
02/19/99
02/28/99
JCA
1
I
2,4,5,6-Tetrachloro-m-xylene (
105%
60-140%
02/19/99
02/28/99
JCA
1
Decachlorobiphenyl (SS)
68%
60-140%
02/19/99
02/28/99
JCA
1
EPA 8082
Aroclor-1016
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
Aroclor-1221
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
Aroclor-1232
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
Aroclor-1242
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
Aroclor-1248
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
Aroclor-1254
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
Aroclor-1260
<50
µg/Kg
50
02/19/99
02/28/99
JCA
2
"Quality Control Surrogate
02/19/99
02/28/99
JCA
1
2,4,5,6-Tetrachloro-m-xylene (
105%
60-140%
02/19/99
02/28/99
JCA
1
Decachlorobiphenyl (SS)
68%
60-140%
02/19/99
02/28/99
JCA
1
i
EPA 8151A
2,4-D
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
2,4-DB
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
�-
2,4,5-T
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
2,4,5-TP (Silvex)
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
Dalapon
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
Dicamba
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
`-
Dichloroprop
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
Dinoseb
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
MCPA
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
MCCP
<0.1
mg/kg
0.1
02/22/99
02/23/99
ARM
1
r-4,
EPA 9253
Chloride
240
mg/Kg
50
02/22/99
02/22/99
BWB
1
r
EPA 9038
Sulfate
1360
mg/Kg
50
02/19/99
02/19/99
DJD
1
EPA 354.1M
Nitrite
<1.0
mg/Kg
1.0
02/19/99
02/19/99
BWB
10
poll
�.
EPA3533
Nitrate
<1.0
mg/Kg
1.0
02/22/99
02/22/99
BWB
1
{
EPA 3503M
Ammonia
20.6
mg/Kg
1.0
02/22/99
02/22/99
BWB
1
�-+
SM 2320B
Alkalinity as Carbonate
<50
mg/KG
50
02122/99
02/22/99
DJD
1
Alkalinity as Bicarbonate
720
mg/KG
50
02/22/99
02/22/99
DJD
1
EPA 6010E
Boron
< 10
mg/Kg
10
02/19/99
02/25/99
OX
1
~
Potassium
1170
mg/Kg
50
02/19/99
02/25/99
OX
1
Sodium
513
mg/Kg
50
02/19/99
02/25/99
OX
1
Calcium
6130
mg/Kg
50
02/19/99
02/25/99
OX
1
Magnesium
1070
mg/Kg
0.50
02/19/99
02/25/99
OX
1
-
Arsenic
<2.5
mg/Kg
2.5
02/19/99
02/25/99
OX
1
Cadmium
0.64
mg/Kg
0.50
02/19/99
02/25/99
OX
1
Page 10 of 24
C:ertes Environmental Laboratories
7�9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394.2872 - FAX z-2.620-7963 • Email: certes@aol.com
A - = ytical Chemistry Environmental Sciences F-search Microbiology
p
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-003 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Chromium
10.8
mg/Kg
0.50
02/19/99
02/25/99
OX
1
f
EPA 7471A
Mercury
0.16
mg/Kg
0.01
02/22/99
02/23/99
ADD
1
EPA 6010B
Zinc
61.1
mg/Kg
5.0
02/19/99
02/25/99
OX
1
Copper
21.7
mg/Kg
0.50
02/19/99
02/25/99
OX
1
Nickel
8.3
mg/Kg
1.0
02/19/99
02/25/99
OX
1
Lead
14.7
mg/Kg
1.5
02/19/99
02/25/99
OX
1
Selenium
<2.0
mg/Kg
2.0
02/19/99
02/25/99
OX
1
Molybdenum
3.4
mg/Kg
1.0
02/19/99
02/25/99
OX
1
EPA 418.1
TPH
49
mg/Kg
10
0222/99
0222/99
SAB
1
EPA 8270C
Benzoic acid
<1650
µg/Kg
1650
0222199
02/23/99
ANA
1
4-Chloro-3-methylphenol
<660
µg/Kg
660
02/22/99
0223/99
ANA
1
2-Chlorophenol
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
2,4-Dichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2,4-Dimethylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
r..
4,6-Dinitro-2-methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2,4-Dinitrophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
2-Methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
4-Methylphenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2-Nitrophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
4-Nitrophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
77
Pentachlorophenol
< 1650
µg/Kg
1650
02/22/99
02/23/99
ANA
1
Phenol
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
r"
2,4,5-Trichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
2,4,6-Trichlorophenol
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Acenaphthene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Acenaphthylene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Anthracene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
�:.
Benzidine
<2500
µg/Kg
2500
02/22/99
02/23/99
ANA
1
Benzo(a)anthracene
<330
µg/Kg
330
02/22/99
02/23/99
ANA
1
Benzo(a)pyrene
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
Benzo(b)fluoranthene
<660
µg/Kg
660
02/22/99
02/23/99
ANA
1
I
Benzo(g,h,i)perylene
<330
µg/Kg
330
02/22/99
0223/99
ANA
1
Benzo(k)fluoranthene
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Benzyl alcohol
<660
µg/Kg
660
0222199
02/23/99
ANA
1
bis-(2-chloroethyl) ether
<330
µg/Kg
330
0222/99
0223/99
ANA
1
bis-(2-chloroethoxy) methane
<330
µg/Kg
330
0222/99
0223/99
ANA
1
bis-(2-chloroisopropyl) ether
<660
µg/Kg
660
02/22/99
0223/99
ANA
1
bis-(2-ethylhexyl) phthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
e�
4-Bromophenyl-phenylether
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Page Il of 24
t
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas, 75129.972-620.7966.1100-394-2872 • FA.}::' 620 7963 • Email: certes®aol.com
Analytical Chemistry Environmental Sciences R==_aarch Microbiology
7' Results of Analyses CEL File No.: 99-0488 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-003 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
l
EPA 8270C Burylbenrylphthalate`
<660
µg/Kg
660
0222/99
0223/99
ANA
1
4-Chloroaniline
<660
µg/Kg
660
0222/99
0223/99
ANA
1
2-Chloronaphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
4-Chlorophenyl-phenylether
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Chrysene
<330
jig/Kg
330
0222/99
0223/99
ANA
1
a_
Dibenzo(a,h)anthracene
< 1650
jig/Kg
1650
0222/99
0223/99
ANA
1
Dibenzofuran
< 1650
µg/Kg
1650
0222/99
0223/99
ANA
1
1,2-Dichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
1,3-Dichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
1,4-Dichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
L
3,3-Dichlorobenzidine
<670
µg/Kg
670
0222/99
0223/99
ANA
1
Diethylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Dimethylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
L
Di-n-butylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
2,6-Dinitrotoluene (2,6-DNT)
<660
µg/Kg
660
0222/99
0223/99
ANA
1
DI-n-octylphthalate
<660
µg/Kg
660
0222/99
0223/99
ANA
1
Azobenzene
µg/Kg
0222/99
0223/99
ANA
1
^`
Fluoranthene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Fluorene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachlorobutadiene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Hexachlorocyclopentadiene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
--
Hexachloroethane
<330
µg/Kg
330
0222/99
0223/99
ANA
1
lndeno(1,2,3-cd)pyrene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Isophorone
<660
µg/Kg
660
0222/99
0223/99
ANA
1
2-Methylnaphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
i
Naphthalene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
�f
2-Nitroaniline
3-Nitroaniline
<660
< 1650
µg/Kg
µg/Kg
660
1650
0222/99
0222/99
0223/99
0223/99
ANA
ANA
1
1
4-Nitroaniline
< 1650
µg/Kg
1650
0222/99
0223/99
ANA
1
Nitrobenzene (NB)
<660
µg/Kg
660
0222/99
0223/99
ANA
1
f^
l r
N-Nitrosodimethylamine
<330
µg/Kg
330
0222/99
0223/99
ANA
1
N-Nitrosodiphenylamine
<660
µg/Kg
660
0222/99
0223/99
ANA
1
}-�
I
N-Nitrosodipropylamine
<330
µg/Kg
330
0222/99
0223/99
ANA
1
Phenanthmne
<330
µg/Kg
330
0222/99
0223/99
ANA
1
�-+
Pyrene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
P
r
1,2,4-Trichlorobenzene
<330
µg/Kg
330
0222/99
0223/99
ANA
1
"Quality Control Surrogate
0222/99
0223/99
ANA
1
r
E.
Nitrobenzene-d5 (SS)
43%
43-138%
0222/99
0223/99
ANA
1
Page
12 of 24
`
Certes Environmental Laboratories
Wisconsin Street. Suite 200 Dallas, Texas, 75229.972-620-7966.800-394-2872 - Fr'-
c-----620-7963
• Email: certes®aol.com
I
r-=.�„ical Chemistry Environmental Sciences
F=:=arch
Microbiology
FResults of Analyses CEL File No.: 99-0488 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
►- Sample: 99-0488-003 continued...
Result
Units Limit
Prepared Analyzed
By Dilution
EPA 8270C 2-Fluorobiphenyl (SS)
52%
50-124%
02/22/99
02/23/99
ANA I
Terphenyl-dl4 (SS)
42%
62-145%
02/22/99
02/23/99
ANA 1
EPA 351AM Total Kjeldahl Nitrogen
1460
mg/Kg 3
02/23/99
02/23/99
ARM I
Client Sample ID: WELL N
Sample Number: 99-0488-004
Date Sampled:
02/16/99
Sample Matrix:
Liquid
i
Time Sampled:
9:45
Sampled By:
LW
EPA 8081A
4,4'-DDD
<0.050
µg/L,
0.050
02/19/99
0227/99
MGK
1
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
I
1
{
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
02/27/99
MGK
1
Aldrin
<0.050
µg/L
0.050
02/19/99
02/27/99
MGK
I
"
alpha-BHC
<0.050
µg/L
0.050
02/19/99
02/27/99
MGK
1
beta-BHC
<0.050
µg/L
0.050
02/19/99
02/27/99
MGK
I
i'.
delta-BHC
<0.050
µg/L
0.050
02/19/99
02/27/99
MGK
1
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
0227/99
MGK
I
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
0227/99
MGK
I
I
Dieldrin
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
I
Endosulfan 1
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
1
Endosulfan Il
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
1
Endrin
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
I
`
Endrin keytone
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
I
r
gamma-BHC
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
I
Heptachlor
<0.050
µg/L
0.050
02/19/99
02/27/99
MGK
I
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
0227/99
MGK
1
Methoxychlor
<0.10
µg/L
0.10
02/19/99
0227/99
MGK
1
Toxaphene
< 1.0
µg/L
1.0
02/19/99
0227/99
MGK
1
"Quality Control Surrogate
02/19/99
0227/99
MGK
I
2,4,5,6-Tetrachloro-m-xylene (
* 41 %
60-140%
02/19/99
0227/99
MGK
I
Decachlorobiphenyl (SS)
64%
60-140%
02/19/99
0227/99
MGK
I
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
I
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
1
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
I
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
1
j-
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
1
F
Page 13 of 24
Sertes Environmental laboratories
==09 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - F.=',=-:-620.7963 - Email: certes C aol.com
--=:ytical Chemistry Environmental Sciences=__earch Microbiology
FResults of Analyses CEL File No.: 99-0488 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
rSample:
99-0488-004 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
4
EPA 8082
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
0227/99
MGK
1
**Quality Control Surrogate
02/19/99
0227/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene(*41%
60-140%
02/19/99
02/27/99
MGK
1
Decachlorobiphenyl (SS)
64%
60-140%
02/19/99
02/27/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
0222/99
02/23/99
ARM
1
r
2,4-DB
<2
µg/L
2
0222/99
0223/99
ARM
1
2,4,5-T
<2
µg/L
2
0222/99
0223/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
0222/99
0223/99
ARM
1
Dalapon
<2
µg/L
2
0222/99
0223/99
ARM
1
Dicamba
Dichloroprop
<2
<2
µg/L
µg/L
2
2
0222/99
0222/99
0223/99
0223/99
ARM
ARM
1
1
Dinoseb
<2
µg/L
2
0222/99
0223/99
ARM
1
MCPA
<2
µg/L
2
0222/99
0223/99
ARM
1
MCCP
<2
µg/L
2
0222/99
0223/99
ARM
1
SM 4500CLB
Chloride
540
mg/L
50
02/18/99
02/18/99
BWB
10
EPA 375.4
Sulfate
368
mg/L
50
02/19/99
02/19/99
DJD
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 353.3
Nitrate
3.58
mg/L
1.00
02/18/99
02/18/99
BWB
10
SM4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
0222/99
0222/99
DJD
1
Alkalinity as Bicarbonate
352
mg/1;
5
0222/99
0222/99
DJD
1
EPA 6010B
Boron
0.693
mg/L
0.010
02/18/99
0222/99
OX
1
Potassium
28.3
mg/L
1.0
02/19/99
0222/99
OX
1
Sodium
270.2
mg/L
02/19/99
0224/99
OX
1
Calcium
103
mg/L
1.0
02/18/99
0222/99
OX
1
Magnesium
24.2
mg/L
0.010
02/18/99
0222/99
OX
1
G
Arsenic
<0.050
mg/L
0.050
02/19/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/19/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
JMO
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
1
`
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
'
EPA 351.4
Total Kjeldahl Nitrogen
1.0
mg/L
0.4
0223/99
0223/99
ARM
1
* Surrogate recovery Is out of range
Page 14 of 24
Cartes Environmental Laboratories
-2^9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 - FAX :- 620.7963 • Email: certes@aol.com
r :,ical Chemistry Environmental Sciences F=:=arch Microbiology
1
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Result
Units
Limit
Prepared Analyzed
By Dilution
i
Client Sample ID: WELL D
Sample Number: 99-0488-005
Date Sampled: 02/16/99
Sample Matrix:
Liquid
i
Time Sampled: 10:50
Sampled By:
LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK I
r
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK 1
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK 1
Aldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK 1
alpha-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK 1
beta-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
delta-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
0228/99
MGK 1
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
0228/99
MGK I
Dieldrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
Endosulfan I
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
Endosulfan 11
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
Endrin keytone
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
gamma-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Heptachlor
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Methoxychlor
<0.10
µg/L
0.10
02/19/99
0228/99
MGK 1
Toxaphene
<1.0
µg/L
1.0
02/19/99
0228/99
MGK 1
**Quality Control Surrogate
2,4,5,6-Tetrachloro-m-xylene (
* 51 %
60-140%
02/19/99
02/19/99
0228/99
0228/99
MGK 1
MGK 1
Decachlorobiphenyl (SS)
86%
60-140%
02/19/99
0228/99
MGK 1
EPA 8082 Aroclor-1016
<5.0
µg/L
5.0
02/19/99
0228/99
MGK 1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
0228/99
MGK 1
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
0228/99
MGK I
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
0228/99
MGK 1
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
0228/99
MGK 1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
0228/99
MGK 1
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
0228/99
MGK 1
**Quality Control Surrogate
02/19/99
0228/99
MGK 1
2,4,5,6-Tetrachloro-m-xylene (
* 51%
60-140%
02/19/99
0228/99
MGK 1
Decachlorobiphenyl (SS)
86%
60-140%
02/19/99
0228/99
MGK 1
EPA 8151A 2,4-D
<2
µg/L
2
0222/99
0223/99
ARM 1
2,4-DB
<2
µg/L,
2
0222/99
0223/99
ARM 1
Page
IS of 24
Certes
Environmental Laboratories
-=09 Wisconsin Street. Suite 200 Dallas, Texas. 75229. 972-620-7966.800-394-2872
• FAX :':-620-7963. Email: certes®aol.com
.- Aical Chemistry Environmental Sciences
Rssearch
Microbiology
r
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-005 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8151A
2,4,5-T
<2
µg/L
2
02/22/99
02/23/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dalapon
<2
µg/L
2
02/22/99
02/23/99
ARM
i
Dicamba
<2
µg/L
2
02/22/99
02/23/99
ARM
i
Dichloroprop
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dinoseb
<2
µg/L
2
02/22/99
02/23/99
ARM
1
MCPA
<2
µg/L
2
02/22/99
02/23/99
ARM
1
MCCP
<2
µg/L
2
02/22/99
02/23/99
ARM
1
SM 4500CI.B
Chloride
160
mg/L
50
02/18/99
02/18/99
BWB
10
EPA 375.4
Sulfate
182
mg/L
50
02/19/99
02/19/99
DJD
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 353.3
Nitrate
435
mg/L
1.00
02/18/99
02/19/99
BWB
10
SM4500NH3.D
Ammonia
0.51
mg/L
0.10
02/19/99
02/19/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/22/99
02/22/99
DJD
1
Alkalinity as Bicarbonate
240
mg/L
25
02/22/99
02/22/99
DJD
5
EPA 6010B
Boron
0.409
mg/L
0.010
02/18/99
02/22/99
OX
1
Potassium
15.2
mg/L
1.0
02/18/99
02/22/99
OX
1
Sodium
104
mg/L
1.0
02/18/99
02/22/99
OX
1
Calcium
60.0
mg/L
1.0
02/18/99
02/22/99
OX
1
Magnesium
22.2
mg/L
0.010
02/18/99
02/22/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
JMO
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
EPA 418.1
TPH
3
mg/L
1
02/19/99
02/20/99
SAB
1
EPA 8270C
Benzoic acid
<50
µg/L
50
02/20/99
03/01/99
MJB
1
4-Chloro-3-methylphenol
<20
µg/L
20
02/20/99
03/01/99
MJB
1
2-Chlorophenol
< 10
µg/L
10
0220/99
03/01/99
MJB
1
2,4-Dichlorophenol
< 10
µg/L
10
0220/99
03/01/99
MJB
1
2,4-Dimethylphenol
<10
µg/L
10
0220/99
03/01/99
MJB
1
4,6-Dinitro-2-methylphenol
<50
µg/L
50
0220/99
03/01/99
MJB
1
2,4-Dinitrophenol
<50
µg/L
50
0220/99
03/01/99
MJB
1
2-Methylphenol
<50
µg/L
50
0220/99
03/01/99
MJB
1
Page 16 of 24
Cartes Environmental Laboratories
72C9 Wisconsin Street, Suite 200 Dallas. Taxas, 75229.972-620-7966.800-394-2872 - = --620.7963- Email: certes@aol.com
---iytical Chemistry Environmental Sciences :z-arch Microbiology
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-005 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C 4-Methylphenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2-Nitrophenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Nitrophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
Pentachlorophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
Phenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2,4,5-Trichlorophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
2,4,6-Trichlorophenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Acenaphthene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Acenaphthylene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Anthracene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzidine
<20
µg/L
20
02/20/99
03/01/99
MJB
1
Benzo(a)anthracene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(a)pyrene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(b)fluoranthene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(g,h,i)perylene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(k)fluoranthene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzyl alcohol
<20
µg/L
20
02/20/99
03/01/99
MJB
1
bis-(2-chloroethyl) ether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
bis-(2-chloroethoxy) methane
<10
µg/L
10
02/20/99
03/01/99
MJB
1
bis-(2-chloroisopropyl) ether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
bis-(2-ethylhexyl)phthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Bromophenyl-phenylether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Butylbenzylphthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Chloroaniline
<20
µg/L
20
02/20/99
03/01/99
MJB
1
2-Chloronaphthalene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Chlorophenyl-phenylether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Chrysene
<10
µg/L
10
0220/99
03/01/99
MJB
1
Dibenzo(a,h)anthracene
<10
µg/L
10
0220/99
03/01/99
MJB
1
Dibenzofuran
<10
µg/L
10
0220/99
03/01/99
MJB
1
1,2-Dichlorobenzene
<10
µg/L
10
0220/99
03/01/99
MJB
I
1,3-Dichlorobenzene
<10
µg/L
10
0220/99
03/01/99
MJB
1
1,4-Dichlorobenzene
<10
µg/L
10
02/20/99
03/01/99
MJB
I
3,3-Dichlorobenzidine
<20
µg/L
20
0220/99
03/01/99
MJB
1
Diethylphthalate
<10
µg/L
10
0220/99
-03/01/99
MJB
I
Dimethylphthalate
<10
µg/L
10
0220/99
03/01/99
MJB
1
Di-n-butylphthalate
<10
µg/L
10
0220/99
03/01/99
MJB
I
2,6-Dinitrotoluene (2,6-DNT)
<10
µg/L
10
02/20/99
03/01/99
MJB
I
Di-n-octylphthalate
<10
µg/L
10
0220/99
03/01/99
MJB
I
Azobenzene
<20
µg/L
20
0220/99
03/01/99
MJB
1
Page 17 of 24
Certes Environmental Laboratories
-=:9 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966 .800-394-2872 - F-'- •520-7963 • Email: certes daol.com
�-a ;;ical Chemistry Environmental Sciences Fa:==rch Microbiology
k
l
Results of Analyses CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
I
Sample: 99-0488-005 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
}
EPA 8270C Fluoranthene
<10
µg/L.
10
02/20/99
03/01/99
MJB
1
Fluorene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
r„
Hexachlorobenzene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Hexachlorobutadiene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Hexachlorocyclopentadiene
<10
µg/L.
10
02/20/99
03/01/99
MJB
1
Hexachloroethane
<10
µg/L
10
02/20/99
03/01/99
MJB
I
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Isophorone
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2-Methylnaphthalene
<10
µg/L.
10
02/20/99
03/01/99
MJB
1
1^
Naphthalene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
I
2-Nitroani.line
<50
µg/L
50
02/20/99
03/01/99
MJB
1
3-Nitroaniline
<50
µg/L
50
02/20/99
03/01/99
MJB
1
r
4-Nitroaniline
<50
µg/L
50
02/20/99
03/01/99
MJB
1
Nitrobenzene (NB)
<10
µg/L
10
02/20/99
03/01/99
MJB
1
,..
N-Nitrosodimethylamine
<20
µg/L
20
02/20/99
03/01/99
MJB
1
N-Nitrosodiphenylamine
<10
µg/L
10
02/20/99
03/01/99
MJB
1
N-Nitrosodiprepylamine
<10
µg/L.
10
02/20/99
03/01/99
MJB
1
Phenanthrene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Pyrene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
1,2,4-Trichlorobenzene
<10
µg/L
10
02/20/99
03/01/99
MJB
I
**Quality Control Surrogate
02/20/99
03/01/99
MJB
I
Nitrobenzene-d5 (SS)
69%
49-118%
02/20/99
03/01/99
MJB
I
P"
2-Fluorobiphenyl (SS)
64%
43-116%
02/20/99
03/01/99
MJB
1
Terphenyl-d14 (SS)
67%
33-144%
02/20/99
03/01/99
MJB
I
* Surrogate recovery is out of range
Client Sample ID: WELL C
Sample Number: 99-0488-006
Date Sampled: 02/16/99
Sample Matrix:
Liquid
Time Sampled: 11:50
Sampled By:
LW
r.
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/19/99 02/28/99
MGK
1
I
4,4'-DDE
<0.050
µg/L
0.050
02/19/99 02/28/99
MGK
I
4,4'-DDT
<0.050
µg/L.
0.050
02/19/99 02/28/99
MGK
1
Aldrin
<0.050
µg/L
0.050
02/19/99 02/28/99
MGK
1
alpha-BHC
<0.050
µg/L
0.050
02/19/99 02/28/99
MGK
1
beta-BHC
<0.050
µg/L.
0.050
02/19/99 02/28/99
MGK
1
ON%
t
delta-BHC
<0.050
µg/L
0.050
02/19/99 02/29/99
MGK
1
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99 02/29/99
MGK
1
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99 02/29/99
MGK
1
Page 18 of 24
Certes Environmental Laboratories
_209 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972-620-7966.800.394-2872 • FAX .--2.620-7963 • Email: certes®aol.com
.-alytical Chemistry Environmental Sciences Research Microbiology
Results of Analyses CEL File No.: 99-0488 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-006 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Dieldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan I
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan I1
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin keytone
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
gamma-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Methoxychlor
<0.10
µg/L
0.10
02/19/99
02/28/99
MGK
1
Toxaphene
< 1.0
µg/L
1.0
02/19/99
02/28/99
MGK
1
**Quality Control Surrogate
02/19/99
02/28/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (*
50%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
80%
60-140%
02/19/99
02/28/99
MGK
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
**Quality Control Surrogate
02/19/99
02/28/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (*
50%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
80%
60-140%
02/19/99
02/28/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
02/22/99
02/23/99
ARM
1
2,4-DB
<2
µg/L
2
02/22/99
02/23/99
ARM
1
2,4,5-T
<2
µg/L
2
02/22/99
02/23/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dalapon
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dicamba
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dichloroprop
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dinoseb
<2
µg/L
2
02/22/99
02/23/99
ARM
1
MCPA
<2
µg/L
2
02/22/99
02/23/99
ARM
1
MCCP
<2
µg/L
2
02/22/99
02/23/99
ARM
1
SM 4500C1.B
Chloride
150
mg/L
50
02/19/99
02/18/99
BWB
10
EPA 375.4
Sulfate
130
mg/L
25
02/19/99
02/19/99
DJD
5
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 3533
Nitrate
6.80
mg/L
1.00
02/18/99
02/18/99
BWB
10
Page 19 of 24
` Certes Environmental Laboratories
---49 Wisconsin Street. Suite 200 Dallas. Texas. 75229 . 972.620-7966. 800-394-2872 • F ;-=-620-7963 • Email: Certes®aol.com
Anaiytical Chemistry Environmental Sciences s arch Microbiology
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-006 Continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
Sh14500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
1
SN12320B
Alkalinity as Carbonate
<5
mg/L
5
02/22/99
02/22/99
DJD
1
Alkalinity as Bicarbonate
290
mg/L
25
02/22/99
02/22/99
DJD
5
EPA 6010B
Boron
0.399
mg/L
0.010
02/18/99
02/22/99
OX
1
Potassium
16.1
mg/L
1.0
02/18/99
02/22/99
OX
1
Sodium
99.2
mg/L
1.0
02/18/99
02/22/99
OX
I
Calcium
67.9
mg/L
1.0
02/18/99
02/22/99
OX
1
Magnesium
22.4
mg/L
0.010
02/18/99
02/22/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
JMO
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
I
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
I
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
* Surrogate recovery Is out of range
Client Sample ID: WELL E
Sample Number: 99-0488-007
Date Sampled: 02/16/99
Sample Matrix:
Liquid
Time Sampled: 14:30
Sampled By:
LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Aldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
alpha-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
beta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
delta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
Dieldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan 1
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan 11
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Page 20 of 24
r-
t . Certes Environmental Laboratories
7TC9 Wisconsin Street. Suite 200 Dallas, Texas, 75229.972-620-7966.800.394-2872 - F,!'c.:----=20-7963 • Email: certesdaol.com
-=;ytical Chemistry Environmental Sciences F - s - arch Microbiology
t,
y�q
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
t:
Reporting
Date
Date
Analyzed
p,
Sample: 99-0488-007 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Endrin keytone
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
1
gamma-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
I
�.,
Methoxychlor
<0.10
µg/L
0.10
02/19/99
02/29/99
MGK
1
Toxaphene
<1.0
µg/L
1.0
02/19/99
02/29/99
MGK
1
**Quality Control Surrogate
02/19/99
02/29/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (
* 58%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
84%
60-140%
02/19/99
02R8/99
MGK
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/19/99
02/29/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
02/29/99
MGK
1
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
I
P"
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
02/29/99
MGK
1
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
02/29/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
02/29/99
MGK
1
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
I
**Quality Control Surrogate
02/19/99
02/28/99
MGK
1
`.
2,4,5,6-Tetrachloro-m-xylene (*
58%
60-140%
02/19/99
02/29/99
MGK
1
Decachlorobiphenyl (SS)
84%
60-140%
02/19/99
02/29/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
02/22/99
02/23/99
ARM
I
2,4-DB
<2
µg/L
2
02/22/99
02/23/99
ARM
1
2,4,5-T
<2
µg/L
2
02/22/99
02/23/99
ARM
1
,1
2,4,5-TP (Silvex)
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dalapon
<2
µg/L
2
02/22/99
02/23/99
ARM
I
Dicamba
<2
µg/L
2
02/22/99
02/23/99
ARM
1
Dichloroprop
<2
µg/L
2
02/22/99
02/23/99
ARM
I
Dinoseb
<2
µg/L
2
02/22/99
02/23/99
ARM
1
MCPA
<2
µg/L
2
02/22/99
02/23/99
ARM
1
MCCP
<2
µg/L
2
02/22/99
02/23/99
ARM
1
SM 4500CLB
Chloride
190
mg/L
50
02/18/99
02/19/99
BWB
10
0-
EPA 375.4
Sulfate
266
mg/L
50
02/19/99
02/19/99
DJD
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 353.3
Nitrate
5.52
mg/L
1.00
02/18/99
02/18/99
BWB
10
y�
SM4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
1
€
Shi 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/22/99
02/22/99
DJD
1
EPA 6010B
Alkalinity as Bicarbonate
Boron
370
0.496
mg/L
mg/L
25
0.010
02/22/99
02/18/99
02/22/99
02/22/99
DJD
OX
5
I
Potassium
17.6
mg/L
1.0
02/18/99
02/22/99
OX
1
Sodium
142
mg/L
1.0
02/19/99
02/22/99
OX
1
Page 21 of 24
LM
Certes Environmental Laboratories
Wisconsin Street. Suite 200 Dallas. Texas, 75229-972-620-7966.800.394.2872 - _ :-620-7963 • Email: certes (g�aol.com
^a,vtical Chemistry Environmental Sciences = = -arch Microbiology
i
!�
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date Analyzed
Sample: 99-0488-007 continued...
Result
Units
Limit
Prepared
Analyzed
By Dilution
r�
G
EPA 6010B Calcium
62.0
mg/L
1.0
02/18/99
02/22/99
OX
I
Magnesium
22.5
mg/L
0.010
02/18/99
02/22/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
I
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
^•
EPA 7470A Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
JMO
1
EPA 6010B Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
("
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
1
t'^
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
!^
SM 9222D Fecal Coliform
< 1
coUl00mL
1
02/17/99
02/18/99
DID
1
SM 9222B Total Coliform
16
coUl00mL
4
02/17/99
02/18/99
DJD
4
* Surrogate recovery is out of range
pw
i
Client Sample ID: WELL I
Sample Number:
99-0488-008
r
Date Sampled: 02/16/99
Sample Matrix:
Liquid
t
Time Sampled: 14:50
Sampled By:
LW
r..,
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Aldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
I
4
alpha-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
beta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
delta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
i
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
Dieldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan I
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
1
Endosulfan II
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
r„
Endrin
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
1
Endrin aldehyde
0.071
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin keytone
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
1
gamma-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
02/29/99
MGK
1
Page 22 of 24
Certes Environmental Laboratories
=rn Wisconsin Street. Suite 200 Gallas, Texas. 75229.972-620-7966.800-394-2872 • _-2-620-7963 • Email: certes@aol.com
A�a:y;ical Chemistry Environmental Sciences E_==arch Microbiology
t
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
+^
Sample: 99-0488-008 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Methoxychlor
<0.10
µg/L
0.10
02/19/99
02/28/99
MGK
1
Toxaphene
<1.0
µg/L
1.0
02/19/99
02/28/99
MGK
1
r
R
"Quality Control Surrogate
02/19/99
02/28/99
MGK
1
2,4,5,6-Tetmchloro-m-xylene (
77%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
79%
60-140%
02/19/99
02/28/99
MGK
1
!�
?_
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
[
4
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
r.
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
"Quality Control Surrogate
02/19/99
0228/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (
77%
60-140%
02/19/99
0229/99
MGK
1
Decachlorobiphenyl (SS)
79%
60-140%
02/19/99
0228/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
0222/99
0223/99
ARM
1
2,4-DS
<2
µg/L
2
0222/99
0223/99
ARM
1
2,4,5-T
<2
µg/L
2
0222/99
0223/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
0222/99
0223/99
ARM
1
Dalapon
<2
µg/L
2
0222/99
0223/99
ARM
1
Dicamba
<2
µg/L
2
0222/99
0223/99
ARM
1
Dichloroprop
<2
µg/L
2
0222/99
0223/99
ARM
1
Dinoseb
<2
µg/L
2
0222/99
0223/99
ARM
1
f
MCPA
<2
µg/L
2
0222/99
02/23/99
ARM
1
MCCP
<2
µg/L.
2
0222/99
0223/99
ARM
1
i
SM 4500CLB
Chloride
500
mg/L
50
02/18/99
02/18/99
BWB
10
t
EPA 375.4
Sulfate
262
mg/L
50
02/19/99
02/19/99
DID
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 353.3
Nitrate
1.29
mg/L
1.00
02/18/99
02/18/99
BWB
10
SM4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
l
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
0222/99
0222/99
DJD
1
E
Alkalinity as Bicarbonate
390
mg/L
25
0222/99
0222/99
DJD
5
EPA 6010B
Boron
0.387
mg/L
0.010
02/18/99
02/22/99
OX
1
Potassium
27.4
mg/L
1.0
02/18/99
0222/99
OX
1
Sodium
211
mg/L
1.0
02/18/99
0222/99
OX
1
Calcium
45.1
mg/L
1.0
02/18/99
0222/99
OX
1
Magnesium
24.6
mg/L
0.010
02/18/99
0222/99
OX
l
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Page 23 of 24
Certes nvir E onmental Laboratories
22o9 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972-620-7966. 800-394-2872 - .-=-620-7963- Email: certes@aol.com
Anaivtical Chemistry Environmental Sciences = - s = arch Microbiology
r
i
Results of Analyses
CEL File No.: 99-0488
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0488-008 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 6010B
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/19/99
02/19/99
JMO
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
I
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
EPA 418.1
TPH
1
mg/L
1
02/19/99
02/20/99
SAB
1
EPA 351.4
Total Kjeldahl Nitrogen
1.0
mg/L
0.4
02/23/99
02/23/99
ARM
1
r."
Page 24 of 24
Certes Environmental Laboratories
_=C9 Wisconsin Street. Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2672 - _= _-2-620.7963- Email: certes@aol.com
.-a.vtical Chemistry Environmental Sciences = = search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
:
As
B..
Ca
Cd
Laboratory Control Sample
Batch Number
021899A
021899A
021999A
021899A
Date Prepared
02/18/99
02/19/99
02/18/99
02/18/99
Date Analyzed
02/25/99
02/25/99
02/25/99
02/25/99
% Recovery
97
97
115
96
% Recovery Duplicate
93
94
120
93
Relative Percent Difference (RPD)
4
3
5
3
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<2.50
<10.0
<50.0
<0.50
C
Cu
K
Mg
Laboratory Control Sample
Batch Number
021899A
021899A
021899A
021899A
Date Prepared
02/18/99
02/18/99
02/18/99
02/18/99
Date Analyzed
02/25/99
02/25/99
1 02/25/99
02/25/99
% Recovery
86
95
75
106
% Recovery Duplicate
86
95
175
107
Relative Percent Difference (RPD)
0
0
1 0
1
I
Method Blank
(m ) (µ ) (m ) ( )
<0.50
<0.50
<50.0
<0.50
µg/I - micrograms per liter (ppb) mg/l = milligrams per liter (ppm)
jig/kg = micrograms per kilogram (ppb) mg/kg = milligrams per kilogram (ppm)
< = less than % = percent
MS = Matrix Spike RPD = Relative Percentage Difference
MSD = Matrix Spike Duplicate RW - Reagent Water
LCS = Laboratory Control Sample LCSD = Laboratory Control Sample Duplicate
BS = Blank Spike BSD = Blank Spike Duplicate
µmhos/cm = micromhos/centimeter
Certes Environmental Laboratories
__.9 Wisconsin Street, Suite 200 Dallas. Texas, 75229. 972-620.7966.800.394-2872 - r-i : -_•c20-7963 - Email: certes@aol.com
r-a.ytical Chemistry Environmental Sciences Ps arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Mo .
Na
Ni .
Pb
Laboratory Control Sample
Batch Number
021899A
021899A
021899A
021899A
Date Prepared
02/18/99
02/18/99
02/18/99
02/18/99
Date Analyzed
02/25/99
02/25/99
0225/99
02/25/99
% Recovery
101
116
93
95
% Recovery Duplicate
103
117
96
93
Relative Percent Difference (RPD)
2
1
3
2
Method Blank
(m ) ( ) (mg/Kg) (µ )
<1.00
<50.0
<1.00
<1.50
Se
Zn
Laboratory Control Sample
Batch Number
021899A
021899A
102/25/99
Date Prepared
02/18/99
02/18/99
Date Analyzed
02/25/99
% Recovery
70•
108
% Recovery Duplicate
90
110
Relative Percent Difference (RPD)
20•
2
Method Blank
m ) ( ) m ) ( )
<2.00
<5.00
*Outside Control Limits
µg/I = micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kiloo-am (ppm)
% = percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
:_09 Wisconsin Street. Suite 200 Dal!as. Texas. 75229.972.620-7966.800.394-2872 • _ :-2.620.7963 - Email: certes@aol.com
--_:ytical Chemistry Environmental Sciences --=search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
.. E
A3
Cd
Cr
Cu ..
Mo
Matrix S ike
Batch Number
W021899
W021899
W021899
W021899
W021899
Date Prepared
02/18/99
02/18/99
02/18/99
02/18/99
02/18/99
Date Analyzed
02/19/99
02/19/99
02/19/99
02/19/99
02/19/99
Spiked Sample ID
0492-1
0492-1
0492.1
0492-1
0492-1
Sample Measured Result
<0.050
<0.005
<0.005
<0.010
<0.010
Spike Level
(m ) ( L) (mg/Kg) (jig/Kg)
0.50
0.50
0.50
0.50
0.50
Spike Result
(mg/L) (µg/L) (mg/Kg) (µg/Kg)
0.467
0.446
0.437
0.445
0.455
% Recovery
93
89
87
89
91
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
0.462
0.445
0.437
0.438
0.458
% Recovery Duplicate
92
89
87
88
92
Relative Percent Difference (RPD)
1
0
0
1
1
Control Limits (%low %hi
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.005
<0.005
<0.010
<0.010
Laboratory Control Sample
Spike Level
(m ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.50
Spike Result
m ) ( ) (mg/Kg) ( )
0.457
0.465
0.453
0.456
0.455
% Recovery
91
93
91
91
91
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
0.457
0.476
0.459
0.463
0.467
% Recovery Duplicate
91
95
92
93
93
Relative Percent Difference (RPD)
0
2
180-120
1
2
3
Control Limits %low -%hi
80-120
80-120
80-120
80-120
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1 - milligrams per liter I ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=_'-9 Wisconsin Street, Suite 200 Dallas. Texas. 75229. 972.620-7966.800-394-2872 - c-2.620-7963- Email: certes4aol.com
Ar-=-tytical Chemistry Environmental Sciences = = s=arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Ni
Pb,
St
Zn
. Hg
Matrix S ike
Batch Number
W021899
W021899
W021899
W021899
W021899
Date Prepared
02/18/99
02/18/99
02/18/99
02/18/99
02/18/99
Date Analyzed
02/19/99
02/19/99
02/19/99
02/19/99
02/19/99
Spiked Sample 1D
0492-1
0492-1
0492-1
0492-1
0492-2
Sample Measured Result
<0.010
<0.015
<0.020
<0.050
<0.0001
Spike Level
(m ) ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ) ( (mg/Kg) (jig/Kg)
0.448
0.468
0.469
0.464
0.0039
% Recovery
90
94
94
93
78
Spike Duplicate Result
(m ( ) (mg/Kg) ( )
0.433
0.468
0.489
0.455
0.0036
% Recovery Duplicate
87
94
98
1 91
72
Relative Percent Difference (RPD)
3
0
4
2
7
Control Limits %low %hi )
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.010
<0.015
<0.020
<0.050
<0.0001
Laboratory Control Sample
Spike Level
(m ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ) ( ) (mg/Kg) ( )
0.461
0.474
0.491
0.468
0.0050
% Recovery
92
95
96
1 94
100
Spike Duplicate Result
(m ( ) (mg/Kg) ( )
0.468
0.491
0.472
0.474
0.0051
% Recovery Duplicate
94
1
98
94
95
102
Relative Percent Difference (RPD)
2
4
2
( 1
1
Control Limits %low "/ohi
80-120
80-120
80-120
80-120
80-120
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=2^9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872- FIX :-=-620-7963- Email:certesCaol.com
- =:ytical Chemistry Environmental Sciences =_ - arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.; 99-0488
iHg
Alltalinity;
Chloride
Chloride .
Sulfate: .
Matrix Spike
Batch Number
W022299
Alk-022299
CI-22299
CI-21899
S0421999
Date Prepared
0222/99
0222/99
022299
02/18/99
02/19/99
Date Analyzed
0223/99
0222/99
02/22199
02/18/99
02/19/99
Spiked Sample ID
0517-6
0488-3
0512-1
0432-1
0492-3
Sample Measured Result
0.151
720
220
440
197
Spike Level
(m )( )(m )( )
0.500
1000
500
500
100
Spike Result
(mg/L) (µg/L) (mg/Kg) (jig/Kg)
0.578
1640
740
930
107
% Recovery
85
92
104
98
107
Spike Duplicate Result
(m )( )(m )( )
0.685
1680
740
930
110
% Recovery Duplicate
107
94
104
98
110
Relative Percent Difference (RPD)
17
2
0
0
3
Control Limits (%low%hi )
75-125
80-120
75-125
75-125
0-20
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.010
<5.00
<5.00
<5.00
<5.00
Laboratory Control Sample
Spike Level
(rn ) ( ) (mg/Kg) ( )
0.500
100
50.0
50.0
100
Spike Result
(m ) (mg/Kg) ( )
0.490
102
53.0
52.0
92.8
% Recovery
98
102
106
104
93
Spike Duplicate Result
(m )( (mg/Kg) ()
0.493
N/A
N/A
N/A
N/A
% Recovery Duplicate
99
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
1
N/A
N/A
N/A
N/A
Control Limits %low "/ohi
80-120
90-110
90-110
90-110
90-110
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
__:9 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972.620-7966.600-394-2872 • FAN. c-2-620-7963 - Email: certes4aol.com
r.ra:ytical Chemistry Environmental Sciences Fs_=.arch Microbiology
F
t
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Satiate
Ammonia
Ammonia
Nitrite
Nitrite
Matrix Spike
Batch Number
S0421999
NH321699
NH321999
NO2S22299
NO221999
Date Prepared
02/19/99
02/15/99
02/19/99
0222/99
02/19/99
Date Analyzed
02/19/99
02/16/99
02/19/99
02/22/99
02/19/99
Spiked Sample ID
0488-1
0432-1
0492-1
0488-2
0492-1
Sample Measured Result
205
0.387
0.557
26.3
<0.010
Spike Level
(m ) ( ) (mg/Kg) ( )
100
1.00
1.00
10.0
0.050
Spike Result
(m ) ( ) (mg/Kg) ( )
279
1.32
1.38
35.2
0.050
% Recovery
74
93
82
89
100
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
284
1.36
1.41
35.5
0.049
% Recovery Duplicate
79
97
85
92
98
Relative Percent Difference (RPD)
5
4
4
3
2
Control Limits (%low -%hi
0-20
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<5.00
<0.010
<0.010
<1.00
<0.010
Laboratory Control Sample
Spike Level
m ( (mg/Kg) )
100
1.00
1.00
1.00
0.020
Spike Result
(m ) ( ) (mg/Kg) ( )
92.8
0.91
0.90
1.03
0.019
% Recovery
93
91
90
103
97
Spike Duplicate Result
m ( ) (mg/Kg) ()
N/A
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
N/A
Control Limits %low -%hi )
90-110
90-110
90-110
90-110
90-110
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/em = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% - percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
_=79 Wisconsin Street, Suite 200 Dallas. Texas. 75229 - 972-620.7966.800.394-2672 • e-2-620.7963 • Email: certes @aol.com
Ara -:tical Chemistry Environmental Sciences a=search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Nitrite
IKitrtte.
Nitrite
TPH 418.1
TPH 418.1E
Matrix S ike
Batch Number
N0221999
N0322299
N0321899
W99-011
S990013
Date Prepared
02/19/99
0222/99
02/18/99
02/19/99
02/22/99
Date Analyzed
02/19/99
0222/99
02/18/99
0220/99
02/22/99
S iked Sample ID
0488-2
0488-3
0432-7
RW
0486-1
Sample Measured Result
<0.010
<1.00
12.1
<1.00
<10.0
Spike Level
(m ) ( ) (mg/Kg) )
0.020
5.00
5.00
5.00
167
Spike Result
(m ) ( ) (mg/Kg) ( )
0.018
4.70
15.6
5.70
176
% Recovery
90
94
84
114
105
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
0.019
4.60
15.8
5.70
178
% Recovery Duplicate
95
93
88
114
106
Relative Percent Difference (RPD)
5
1
5
0
1
Control Limits (%low -%hi
90-120
75-125
75-125
80-120
80-120
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.010
<0.10
<0.010
<1.00
<10.0
Laboratory Control Sample
Spike Level
(m ) ( ) (mg/Kg) (jig/Kg)
0.020
0.50
0.50
5.00
167
Spike Result
(m ) ( ) m ( )
0.019
0.51
0.52
N/A
196
% Recovery
97
102
104
N/A
117
Spike Duplicate Result
m )(m ) )
N/A
N/A
N/A
N/A
182
% Recovery Duplicate
N/A
N/A
N/A
N/A
109
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
8
Control Limits %low "/ohi
90-110
90-110
90-110
80-120
80-120
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1- milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=2109 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620.7966.800-394-2872 - = :-_•620-7963 - Email: certes@aol.com
'-alytical Chemistry Environmental Sciences -- _ search Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
-
Y.
r !
Herbicides .
Total
Kjeldahl
Nitrogen
Total
Kjeldahl
Nitrogen
Laboratory Control Sample
Batch Number
99EN0611
99ENG611
99EN0611
Date Prepared
0222/99
OV221199
02/22/99
Date Analyzed
0222/99
0121 '99
0222/99
Spiked Sample ID
GA269-174
GA-169-176
GA116-154
% Recovery
99
103
98
Method Blank
(m ) ( ) (mg/Kg) ( )
<1.00
<16.0
<21.0
pg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
_::9 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972-620-7966. 800-394-2872 • F ,'2.620-7963- Email: certesaaol.com
y;ical Chemistry Environmental Sciences :=_ --- arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Fecal Total
Coliform . Coliform .
Batch Number
FecCol-021799
TotCol-021799
Date Prepared
02/18/99
02/18/99
Date Analyzed
02/ 18/99
02/ 18/99
Sample ID
0488-7
0488-7
Sample Result (umho/cm)
m ) ( (mg/Kg) ( )
<1.00
16.0
Sample Duplicate Result (umho/cm)
(m ) ( ) (mg/Kg) ( )
<1.00
16.0
Relative Percent Difference RPD
0
0
Control Limits
0-20
0-20
Method Blank
<1.00 1 <1.00
Control Sa
Spike Level
(m )( )(m )( )
N/A
N/A
Spike Result
(m )( )(m )( )
N/A
N/A
% Recovery
N/A
N/A
Control Limits (%low -%hi
N/A
90-110
µg/1= micrograms per liter (ppb)
µglkg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% — percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=i^.8 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966. 800.394-2872 - FAX ;-=-620-7963 • Email: certes®aol.ccm
--..vocal Chemistry Environmental Sciences Fe=_arch Microbiology
r
r
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Phenol
2-Chloro-
phenol
Acenaph
thene
Pyrene
1,4-
Dichloro-
benzene
n-Nitroso-
d>I n- :
propylamine
Matrix Spike
Batch Number
S990144
S990144
S990144
S990144
S990144
S990144
Date Prepared
02/22/99
02/22/99
02/22/99
02 22/99
02/22/99
02/22/99
Date Analyzed
02/23/99
02/23/99
02/23/99
0223/99
02/23/99
02/23/99
% Recovery
102
91
123
109
105
104
% Recovery Duplicate
105
95
126
109
114
107
Relative Percent Difference (RPD)
3
4
2
0
8
3
Control Limits (%low "/ohi )
10-120
23-134
47-145
52-125
20-124
10-230
Method Blank
(m )(µ )(m )(µ )
1 <20
<20
<10
<10
<10
<10
:;`
14,4
Trichloro- ;
benzene
4-Chloro- ;
".: 3-methyl= '
Ph eno
4-Nitro-
phenol ..
2,4,-Dini _
trotoluene
ni
Penta-
chloro-
phenol
Matrix Spike
Batch Number
S990144
S990144
S990144
S990144
S990144
Date Prepared
02/22/99
02/22/99
0222/99
02/22/99
02/22/99
Date Analyzed
02/23/99
0223/99
0223/99
02/23/99
02/23/99
% Recovery
124
91
111
121
125
% Recovery Duplicate
128
91
116
121
129
Relative Percent Difference (RPD)
3
1
4
0
3
Control Limits (%low -%hi
44-142
22-147
10-132
39-139
14-176
Method Blank
(m ) ( ) (mg/Kg) ( )
<10
<20
<20
<10
<20
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1 - milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=C9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966.600-394-2872 - : -2-620-7963. Email: certesoaol.com
Arawtical Chemistry Environmental Sciences -search Microbiology
f
.—
I
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Phenol
2-Chloro-
phenol
1,4
kDtchloro-,'
benzene
n-Nitroso-:
di-n
propylami :
Oe
1,2,4-_
Trichloro-
benzene
4-Chioro-
3- ethyl-.:
phenol
Matrix Spike
Batch Number
SVW-019
SVW-019
SVW-019
SVW-019
SVW-019
SVW-019
Date Prepared
03/01/99
03/01/99
03/01/99
03 01/99
03/01/99
03/01/99
Date Analyzed
03/01/99
03/01/99
03/01/99
03 '01 /99
03/01/99
03/01/99
Spiked Sample ID
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
Spike Level
(mg/L)( )(rn )( )
200
200
100
100
100
200
Spike Result
(mg/L) ( ) (mg/Kg) ( )
N/A
N/A
N/A
NA
N/A
N/A
916 Recovery
N/A
N/A
N/A
N A
N/A
N/A
Spike Duplicate Result
(mg/L)( )(m )( )
N/A
N/A
N/A
N A
N/A
N/A
%' Recovery Duplicate
N/A
N/A
N/A
N A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N A
N/A
N/A
Control Limits %low %hi )
5-112
23-134
20-124
10-230
44-142
22-147
Method Blank
(mg/L) ()(m )( )
CIO
CIO
<10
<10
<10
<20
Laboratory Control Sample
Spike Level
(mg/L) (mg/Kg) ( )
200
200
100
100
100
200
Spike Result
(mg/L) ) (mg/Kg) (jig/Kg)
79
118
52
79
59
148
%' Recovery
40
59
52
79
59
74
Spike Duplicate Result
(mg/L) ( (mg/Kg) (jig/Kg)
49
92
45
64
50
118
°.'o Recove Du licate
25
46
45
64
50
59
Relative Percent Difference (RPD)
46*
25
116
26
16
22
Control Limits %low -%hi )
5-112
23-134
20-124
1 10-230
44-142
1 22-147
*Outside Control Limits
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
"9 Wisconsin Street. Suite 200 Callas, Texas. 75229.972-620-7966.800-394-2872 - F,i;t c- 620-7963 - Email: certes daol.com
Microbiology
:;ical Chemistry Environmental Sciences Fes=arch
Results of Analyses - Laboratory Quality Control
File No.: 99-0498
Acenaph-
then
4-Nitro-
phenol'
2,4rDiini-
trotoluene
Pentachloro—
phenol
Pyrene
Matrix S ike
Batch Number
SVW-019
SVW-019
SVW-019
SVW-019
SVW-019
Date Prepared
03/01/99
03/01/99
03/01/99
03/01/99
03/01/99
Date Analyzed
03/01/99
03/01/99
03/01/99
03/01/99
03/01/99
Spiked Sample 1D
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
Spike Level
(m )( )(m )( )
100
200
100
200
100
Spike Result
(m )( (mg/Kg) ()
N/A
N/A
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
N/A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
N/A
Control Limits (%low %hi )
47-145
10-132
39-139
14-176
52-115
Method Blank
(m )( )(m )( )
<10
<20
<10
<20
<10
Laboratory Control Sample
Spike Level
(m )( )(m )( )
100
200
100
200
100
Spike Result
(m )( (mg/Kg) ()
70
133
90
202
99
% Recovery
70
67
90
101
99
Spike Duplicate. Result
(m )(pg/L) (mg/Kg) ()
59
51
71
159
79
% Recovery Duplicate
59
26
71
80
79
Relative Percent Difference (RPD)
17
89*
24*
24
22
Control Limits (%low -%hi
47-145
10-132
39-139
14-176
52-115
*Outside Control Limits
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (Fpm)
mg/kg = milligrams per kilogram (ppm)
% - percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicare
Certes Environmental Laboratories
=_09 Wisconsin Street. Suite 200 Dallas, Texas, 75229.972-620.7966.800-394-2872 - Fr;, :-2-=20-7963 - Email: certes@aol.com
.:;ical Chemistry Environmental Sciences search Microbiology
pip
I
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
-
-Gamma-
(Llndane)
Heptachlor.
Aldrin
Matrix S ike
Batch Number
PST99014
PST99014
PST99014
Date Prepared
02/18/99
0218/99
02/18/99
Date Analyzed
02/27/99
02:27/99
02/27/99
S iked Sample 1D
N/A
N!A
N/A
Spike Level
(m ( ) (mg/Kg) ( )
0.40
0.40
0.40
Spike Result
(m )( )(mg/Kg) (
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
Control Limits (%low %hi
50-119
46-117
44-104
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
(m ) ( ) (m ) ( )
0.40
0.40
0.40
Spike Result
(m ) ( (mg/Kg) ( )
0.227
0.292
0.239
% Recovery
57
73
60
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
0.249
0.314
0.262
% Recovery Duplicate
62
78
66
Relative Percent Difference (RPD)
9
7
9
Control Limits %low %hi
50-119
46-117
44-104
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
::,"9 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972.620-7966. 600-394-2872 • FAX c'2-620-7263- Email: certes@aol.com
A ;;;ical Chemistry Environmental Sciences Fe:earch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0488
Dieldrin:;
Endrin
-:
4,4-DDT; ,
Arachlor
1260
Matrix Spike
Batch Number
PST99014
PST99014
PST99014
PCB99014
Date Prepared
02/19/99
02/19/99
02/18/99
02/18/99
Date Analyzed
02/27/99
02/27/99
02/27/99
02/27/99
Spiked Sample ID
N/A
N/A
N/A
N/A
Spike Level
(m ( (mg/Kg) ( )
1.00
1.00
1.00
5.00
Spike Result
(m ( )(m )( )
N/A
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
Control Limits (%low'/ohi )
48-119
62-133
59-148
48-139
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
<5.00
Laboratory Control Sample
Spike Level
m ) (mg/Kg) ( )
1.00
1.00
1.00
5.00
Spike Result
(m ) ) (mg/Kg) ( )
0.823
0.919
0.990
4.03
% Recovery
82
92
99
81
Spike Duplicate Result
m ( ) (mg/Kg) (jig/Kg)
0.817
0.903
1.00
4.22
% Recovery Duplicate
82
90
100
84
Relative Percent Difference (RPD)
1
2
1
5
Control Limits %low -%hi
48-119
62-133
59-148
48-139
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
_:09 Wisconsin Street, Suite 200 Dallas. Texas, 75229.972.620.7966.800-394-2872 - FAX e-2.620-7963 • Email: certes@aol.com
r-3 :,tical Chemistry Environmental Sciences Re arch Microbiology
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Dallas, Texas 75229
972-620-7966 972-620-7963 Fax
Analysis(es) Requested
Client Name
�NPaaTEct-Ta.0
Phone No.
-7 9 4-1 L60
V
X
<
V)
Client Address
C310 (-rz"ok SV OE
Fax No.
A.M.) -7 9 4 -
Billing Address city state Zip
LUV380,-K -5( 79qZ'/
Purchase Order No.
E
To ensure proper billing, please reference quotation number.
Project Manager
MAP -I( C,:i c-4 PiCibElL
Site Location
I- A. I3 A PP 5 tTE
No.Ip
pate'
TIM
lwfttkl`
-SType
V
0.1
J-
o
P3
ozit999 IZI�
SL
was r Foiji)
Sampled By
a I MA 13
1 Matrix:. a A - Air Bag; C - Charcoal. Tube; . L, - Liquid; OL-00- S-Soili:SD,�SofidL-;� ,:,-SSludge;:.WP-wipe.;
2 Conllain&.Ty06.'.: V, 40ml VOA Vi ai k`- G:..A'mber or Glass. I , Liter_ J - 260ml Wide'-.rrwu Glass. , 4AW AtW.; WatedWastewater
"'
Preservative::: C -Hydrochloric A*W-::;,: HNO2-. - : 9Add ;... 1-1,40, - SulfuricAcId,*,-...,, C046"... ... Nitd
'rt
TAT
Standard: Date Required
RUSH: Date Required
Client Project ID
Special Instructions (including specific detection limits)
SEA AMA"iFbIr
c- iffT
Cerles Job Number
c>98 s
Relinquished by Sampler
Date
72 Qfi
Time
7, 1
Received By
A
Relinquished by
Date
Time
—
Received By
Relinquished by
Date
Time
Received By Laboratory t �4 Wv <,
NOTE: By submitting these samples you agreeto the term; and conditions iwntained.in,Certes,Schedulalo[,Foet�-.Ceftes cannoticcek*rto Changes �w ench es
than. ...,.Te.ase,;FAX ritt .(972)�620-7,9
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Analysis(es) Requested
-- - Dallas, Texas 75229
- - - _-
972-620-7966 972-620-7963 Fax
Client Name
Phon No.
C ry
ry
Client Address
Fax
X
rZ
Billing Address City tftle Zip
-�
l'O eV kCA CL
Purchase Order No.
To ensure proper billing, please reference quotation number.
Eto 1
S - 11�
-Y
N
Project Manager
Site Location
'�
j✓1
4-
— -. -
--
CedesNo.
No.Sample
ID
Date
Time
MaIdX'
& ype of Container'
�V
G
J
O
P'
oz. \ ��WKY—
---
---
t02\to \07�0
x
X
Lj� �
aTd
x
x
0-2.1 cotyq 1\50
XiC
7
b-Lt to9y I43.0
-14310
c rx. to C1g WsSU
1 V5�Y,Y`
Sampled By
1 Matrix: A - Air Bag; C - Charcoal Tube; . L - Liquid; . OL - Oil; S - Sal, , SD - Solid; SL - Sludge, WP - Wipe W Watermastewater
2 Container Type: V - 40ml VOA Vial; G Amber or Glass 1 Liter, J - 250ml Wide -mouth Glass Jar. O - Other
3 Preservative: HC1- Hydrochloric Acid-. HNOq - Nitric Acid;:: H,SO• - Sulfuric Acid;:: O =.Other.
TAT
Client Project ID
Special Instructions (including specific detection limits)
Certes Job Number
Standard: Date Required
F= r'k 1-7 tp
\
RUSH: Dale Required
Relinquished by Sampler
Date !
Time
Received �,2
Relinquished by
Date
Time
Received By
Relinquished by
Date (� nC�
Time h 0O
Received By Laboratory
`changes.
NOTE: By submitting these samples. you agree to the terms and conditions contained In Certes' Schedule of Fees: Certes cannot accept verbal changes. Please FAX written to (972) 620-7963...: .
L---C-L L-.. L _ � i - _r Lr". L 4—
2209 Wisconsin Stree: wire 2CO
Gallas. Texas 75229
? 72-o2C^- 7 966
800-394-2872 FAX
972-6210-%9VJ FA/� 6 Email: cartes _ _ .: oni
CERTES ENVIRONMENTAL LABORATORIES
ANALYTICAL REPORT
Certes File Number: 99-0492
t;
Client Project I.D.:
EN1761
Prepared for:
ENPROTEC INC.
6310 Genoa Avenue, Suite E
Lubbock, TX 79424
Attention:
Mark Schneider
Report Date:
03/02/99
Included are the results of chemical analyses for the samples submitted to Certes Environmental
Laboratories, L.L.C., on 02/17/99. All analytical results met Quality Control requirements as set by the
industry accepted criteria. Please refer to the Laboratory Quality Control Results section of this report.
This report must be reproduced in its entirety.
Sincerely,
Certes Environmental Laboratories, L.L.C.
4
v
Amy LaSalle
President
- .. ...a: ��, .R=stry crt:'i...., , . .- '.-.t— C0S -. --. Cis
Results of Analyses CEL File No.: 99-0492
Report Date: 03/02/99
Reporting
Date
Date Analyzed
,...
Result
Units
Limit
Prepared Analyzed
By Dilution
Client Sample ID: WELL O
Sample Number:
99-0492-001
Date Sampled:
02/12/99
Sample Matrix:
Liquid
Time Sampled:
11:30
Sampled By:
LW
EPA 8081A
4,4'-DDD
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
"~
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
I
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Aldrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
f
alpha-BHC
<0.050
µg/L,
0.050
02/19/99
02/28/99
MGK
1
beta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
delta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
0228/99
MGK
1
Dieldrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Endosulfan 1
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Endosulfan 11
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
F
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Endrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Endrin keytone
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
gamma-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Heptachlor
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
I
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
0228/99
MGK
1
Methoxychlor
<0.10
µg/L
0.10
02/19/99
0228/99
MGK
1
Toxaphene
< 1.0
µg/L
1.0
02/19/99
0228/99
MGK
1
**Quality Control Surrogate
02/19/99
0228/99
MGK
1
s
2,4,5,6-Tetrachloro-m-xylene (*
56%
60-140%
02/19/99
0228/99
MGK
1
Decachlorobiphenyl (SS)
80%
60-140%
02/19/99
0228/99
MGK
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
{
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Auk
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
0228199
MGK
1
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
0228199
MGK
1
**Quality Control Surrogate
02/19/99
0228/99
MGK
1
�*
2,4,5,6-Tetrachloro-m-xylene (*
56%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
80%
60-140%
02/19/99
0228/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4-DB
<2
µg/L
2
0222/99
0222/99
ARM
1
i
Page 2 of 11
r-
r:
Certes Environmental Laboratories
-09 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620-7966. 800-394-2872 • FAX -2.620-7963 • Email: certes@aol.com
Ara.ytical Chemistry Environmental Sciences c_Search Microbiology
Results of Analyses
CEL File No.: 99-0492
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0492-001 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8151A
2,4,5-T
<2
µg/L
2
02/22/99
02/22/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dalapon
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dicamba
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dichloroprop
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dinoseb
<2
µg/L
2
0222/99
02/22/99
ARM
1
MCPA
<2
µg/L
2
02/22/99
02/22/99
ARM
1
MCCP
<2
µg/L
2
02/22/99
02/22/99
ARM
I
SM 4500CLB
Chloride
2500
mg/L
2500
02/18/99
02/18/99
BWB
500
EPA 375.4
Sulfate
264
mg/L
50
02/19/99
02/19/99
DID
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 353.3
Nitrate
8.25
mg/L
1.00
02/18/99
02/18/99
BWB
10
SM4500NH3.D
Ammonia
0.56
mg/L
0.10
02/19/99
02/19/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/22/99
02/22/99
DJD
1
Alkalinity as Bicarbonate
290
mg/L
25
02/22/99
02/22/99
DJD
5
EPA 6010B
Boron
0.454
mg/L
0.010
02/18/99
02/22/99
OX
1
Potassium
21.9
mg/L
1.0
02/18/99
02/22/99
OX
1
Sodium
101
mg/L
1.0
02/18/99
02/22/99
OX
1
Calcium
76.5
mg/L
1.0
02/18/99
02/22/99
OX
1
Magnesium
23.6
mg/L
0.010
02/18/99
02/22/99
OX
I
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
I
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
JMO
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
I
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
* Surrogate recovery Is out of range
Client Sample ID: WELL R Sample Number. 99-0492-002
Date Sampled: 02/12/99 Sample Matrix: Liquid
Time Sampled: 13:30 Sampled By: LW
EPA 8081A 4,4'-DDD
<0.050 µg/L 0.050
02/19/99 02/28/99
MGK I
t '
4,4'-DDE
<0.050 µg/L 0.050
02/19/99 02/28/99
MGK 1
p,..,
4,4'-DDT
<0.050 µg/L 0.050
02/19/99 02/28/99
MGK 1
f"
Page 3 of 11
Certes Environmental Laboratories
:709 Wisconsin Street. Suite 200
Dallas, Texas, 75229.972.620-7966. 800.394.2872 • FAX
:'=-620-7963• Email: certes@aol.com
i
r.!-=.vtical Chemistry
-
Environmental Sciences
F;search
Microbiology
4
Results of Analyses CEL File No.: 99-0492
Report Date: 03/02/99
i
Reporting
Date
Date
Analyzed
,.,
Sample: 99-0492-002 Continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 8081A Aldrin
<0.050
µg/L
0.050
02/19/.99
02/28/99
MGK
1
alpha-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
F
i
beta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
delta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
1
Dieldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan 1
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan II
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Endrin keytone
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
gamma-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
I
Methoxychlor
<0.10
µg/L
0.10
02/19/99
02128/99
MGK
1
r•
Toxaphene
< 1.0
µg/L
1.0
02/19/99
02/28/99
MGK
1
**Quality Control Surrogate
02/19/99
02/28/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (
* 59%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
89%
60-140%
02/19/99
02/28/99
MGK
1
I
EPA 8082 Aroclor-1016
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
r„
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
02128/99
MGK
1
**Quality Control Surrogate
02/19/99
02/28/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (*
59%
60-140%
02/19/99
02/28/99
MGK
1
Decachlorobiphenyl (SS)
89%
60-140016
02/19/99
02/28/99
MGK
1
EPA 8151A 2,4-D
<2
µg/L
2
02/22/99
02/22/99
ARM
1
2,4-DB
<2
µg/L
2
02/22/99
02/22/99
ARM
1
2,4,5-T
<2
µg/L
2
02/22/99
02/22/99
ARM
1
i
2,4,5-TP (Silvex)
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dalapon
<2
µg/L
2
02/22/99
02/22/99
ARM
1
-
Dicamba
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dichloroprop
<2
µg/L
2
02/22/99
02/22/99
ARM
1
Dinoseb
<2
µg/L
2
02122/99
02/22/99
ARM
1
'
Page 4of11
Certes Environmental Laboratories
_7:3 Wisconsin Street. Suite 200 Dallas. texas. 75229 - 972-6207,966.800.394-2872
• F4'8
:-:-320.7_2; 0"3 •Email: cerlesaaol.c0m
i
- =_ • 6cal Chemistry Environmental Sciences
sarch
Microbiology
Results of Analyses
CEL File No.: 99-0492
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0492-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8151A
MCPA
<2
µg/L
2
02/22/99
02/22/99
ARM
1
MCCP
<2
µg/L
2
02/22/99
02/22/99
ARM
I
SM 4500CLB
Chloride
500
mg/L
250
02/18/99
02/18/99
BWB
50
EPA 375.4
Sulfate
270
mg/L
50
02/19/99
02/19/99
DJD
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 3533
Nitrate
9.25
mg/L
5.00
02/18/99
02/18/99
BWB
50
SM4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02122/99
02/22/99
DJD
1
Alkalinity as Bicarbonate
1060
mg/L
25
02/22/99
02/22/99
DJD
5
EPA 6010B
Boron
0.361
mg/L
0.010
02/18/99
02/22/99
OX
1
Potassium
27.2
mg/L
1.0
02/18/99
02/22/99
OX
1
Sodium
162
mg/L
1.0
02/18/99
02/22/99
OX
1
Calcium
100
mg/L
1.0
02/18/99
02/22/99
OX
1
Magnesium
24.5
mg/L
0.010
02/18/99
02/22/99
OX
l
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
JMO
1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
1
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC
1
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC
I
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
EPA 8270C
Benzoic acid
<50
µg/L
50
02/20/99
03/01/99
MJB
1
4-Chloro-3-methylphenol
<20
µg/L
20
02/20/99
03/01/99
MJB
1
2-Chlorophenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2,4-Dichlorophenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2,4-Dimethylphenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4,6-Dinitro-2-methylphenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
2,4-Dinitrophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
2-Methylphenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
4-Methylphenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2-Nitrophenol
< 10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Nitrophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
Pentachlorophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
Phenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
2,4,5-Trichlorophenol
<50
µg/L
50
02/20/99
03/01/99
MJB
1
2,4,6-Trichlorophenol
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Page 5 ofll
FCertes Environmental Laboratories
Wisconsin Street. Suite 200 Dallas. Texas, 75229.972.620-7966.800-394.2872 - FAX : -_-620-7963 - Email: certescgaol.ccrn
r.�� :,ical Chemistry Environmental Sciences R==-=arch Microbioioov
FResults of Analyses CEL File No.: 99-0492 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
..,
Sample: 99-0492-002 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8270C Acenaphthene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Acenaphthylene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Anthracene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzidine
<20
µg/L
20
02/20/99
03/01/99
MJB
1
Benzo(a)anthracene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(a)pyrene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(b)fluoranthene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
k
Benzo(g,h,i)perylene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Benzo(k)fluoranthene
<10
µg/L
10
0220/99
03/01/99
MJB
1
Benzyl alcohol
<20
µg/L
20
02/20/99
03/01/99
MJB
1
4
bis-(2-chloroethyl) ether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
bis-(2-chloroethoxy)methane
<10
µg/L
10
02/20/99
03/01/99
MJB
1
bis-(2-chloroisopropyl) ether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
bis-(2-ethylhexyl) phthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Bromophenyl-phenylether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
r
Burylbenzylphthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Chloroaniline
<20
µg/L
20
02/20/99
03/01/99
MJB
1
2-Chloronaphthalene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
4-Chlorophenyl-phenylether
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Chrysene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Dibenzo(a,h)anthracene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Dibenzofuran
<10
µg/L
10
02/20/99
03/01/99
MJB
1
y
f
1,2-Dichlorobenzene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
1,3-Dichlorobenzene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
i.
1,4-Dichlorobenzene
<10
µg/L
10
0220/99
03/01/99
MJB
1
3,3-Dichlorobenzidine
<20
µg/L
20
0220/99
03/01/99
MJB
1
C
Diethylphthalate
<10
µg/L
10
0220/99
03/01/99
MJB
1
Dimethylphthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Di-n-butylphthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
I
2,6-Dinitrotoluene (2,6-DN7)
<10
µg/L
10
02/20/99
03/01/99
MJB
1
DI-n-octylphthalate
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Azobenzene
<20
µg/L
20
02/20/99
03/01/99
MJB
1
Fluoranthene
<10
µg/L
10
0220/99
03/01/99
MJB
1
j
Fluorene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Hexachlorobenzene
<10
µg/L
10
0220/99
03/01/99
MJB
1
7
Hexachlorobutadiene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Hexachlorocyclopentadiene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
i
Hexachloroethane
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Indeno(1,2,3-cd)pyrene
<10
µg/L
10
02/20/99
03/01/99
MJB
1
Page 6 of 11
7
t. Cerles Environmental Laboratories
2209 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620.7966.800-394-2872 - FAt ;-2-620-7963 - Email: ceries@aol.com
r r--.vticai Chemistry Environmental Sciences R=:=arch Microbiology
l Results of Analyses CEL File No.: 99-0492 Report Date: 03/02/99
Reporting
Date
Date
Analyzed
7
Sample: 99-0492-002 continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
10
EPA 8270C Isophorone
<10
µg/L
02/20/99
03/01/99
MJB 1
2-Methylnaphthalene
<10
µg/L
10
02/20/99
03/01/99
MJB 1
Naphthalene
<10
µg/L
10
02/20/99
03/01/99
MJB I
2-Nitroaniline
<50
µg/L
50
02/20/99
03/01/99
MJB I
3-Nitroaniline
4-Nitroaniline
<50
<50
µg/L
µg/L
50
50
02/20/99
02/20/99
03/01/99
03/01/99
MJB I
MJB 1
Nitrobenzene (NB)
<10
µg/L
10
02/20/99
03/01/99
MJB 1
r"
N-Nitrosodimethylamine
<20
µg/L
20
02/20/99
03/01/99
MJB 1
N-Nitrosodiphenylamine
<10
µg/L
10
02/20/99
03/01/99
MJB 1
N-Nitrosodipropylamine
<10
µg/L
10
02/20/99
03/01/99
MJB 1
Phenanthrene
<10
µg/L
10
02/20/99
03/01/99
MJB 1
Pyrene
<10
µg/L
10
02/20/99
03/01/99
MJB 1
I,2,4-Trichlorobenzene
<10
µg/L
10
02/20/99
03/01/99
MJB 1
**Quality Control Surrogate
02/20/99
03/01/99
MJB 1
Nitrobenzene-d5 (SS)
65%
49-118%
02/20/99
03/01/99
MJB 1
2-Fluorobiphenyl (SS)
61%
43-116%
02/20/99
03/01/99
MJB 1
Terphenyl-d14 (SS)
67%
33-144%
02/20/99
03/01/99
MJB 1
r
I
* Surrogate recovery is out of range
Client Sample ID: WELL H Sample Number: 99-0492-003
Date Sampled: 02/12/99 Sample Matrix: Liquid
Time Sampled: 14:40 Sampled By: LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Aldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
alpha-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
beta-BHC
<0.050
µg/L
0.050
02/I9/99
02/28/99
MGK
delta-BHC
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
02/28/99
MGK
Dieldrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Endosulfan I
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Endosulfan 11
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Endrin
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Endrin keytone
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
Page 7 of 11
Certes Environmental Laboratories
_=09 Wisconsin Street, Suite 200 Dallas, Texas. 75229. 972.620-7966 - 600-394-2872 • F= -620.7963- Email: certes@aol.com
$ A:-a,ytical Chemistry Environmental Sciences = _ : =arch Microbiology
i
Results of Analyses
CEL File No.: 99-0492
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0492-003 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
gamma-BHC
<0.050
µg/L,
0.050
02/19/99
02/28/99
MGK
1
Heptachlor
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
02/28/99
MGK
1
Methoxychlor
<0.10
µg/L
0.10
02/19/99
02/28/99
MGK
1
Toxaphene
< 1.0
µg/L
1.0
02/19/99
0228/99
MGK
1
1
**Quality Control Surrogate
02/19/99
0228/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (*
58%
60-140%
02/19/99
0228199
MGK
1
Decachlorobiphenyl (SS)
86%
60-140%
02/19/99
0228/99
MGK
1
EPA 8082
Aroclor-1016
<5.0
µg/L,
5.0
02/19/99
0228/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1132
<5.0
µg/L
5.0
02/19/99
0228199
MGK
I
Aroclor-1242
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
I
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
t.,
Aroclor-1260
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
**Quality Control Surrogate
02/19/99
0228/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (
* 58%
60-140%
02/19/99
0228/99
MGK
1
Decachlorobiphenyl (SS)
86%
60-140%
02/19/99
0228/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4-DB
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4,5-T
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
0222/99
0222/99
ARM
1
Dalapon
<2
µg/L,
2
0222/99
0222/99
ARM
l
I
Dicamba
<2
µg/L
2
0222/99
0222/99
ARM
1
Dichloroprop
<2
µg/L
2
0222/99
0222/99
ARM
1
Dinoseb
<2
µg/L
2
0222/99
0222/99
ARM
1
I
MCPA
<2
µg/L
2
0222/99
0222/99
ARM
1
MCCP
<2
µg/L
2
0222/99
0222/99
ARM
1
SN14500CLB
Chloride
500
mg/L
50
02/19/99
02/18/99
BWB
10
EPA 375.4
Sulfate
197
mg/L
50
02/19/99
02/19/99
DJD
10
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 3533
Nitrate
2.88
mg/L
1.00
02/18/99
02/18/99
BWB
10
Slii4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
1
Sht 2320B
Alkalinity as Carbonate
<5
mg/L
5
0222/99
0222N9
DJD
1
Alkalinity as Bicarbonate
480
mg/L
25
0222/99
0222/99
DJD
5
EPA 6010B
Boron
0396
mg/L
0.010
02/19/99
0222/99
OX
1
i
Potassium
293
mg/L
1.0
02/19/99
0222/99
OX
I
Sodium
185
mg/L
1.0
02/18/99
0222/99
OX
1
r
Calcium
105
mg/L
1.0
02/19/99
0222/99
OX
1
Page 8 of 11
F
Certes Environmental Laboratories
:209 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.600-394-2872 - FAX ',-_-620-7963 - Email: certes @aol.ccm
-a ytical Chemistry Environmental Sciences E__earch Microbiology
Results of Analyses
CEL File No.: 99-0492
Report Date: 03/02/99
r
I
F
Samnle: 99-0492-003 continued...
EPA 6010B
Magnesium
Arsenic
Cadmium
Chromium
EPA 7470A
Mercury
EPA 6010B
Zinc
Copper
Nickel
Lead
Selenium
Molybdenum
EPA 418.1
TPH
EPA 351.4
Total Kjeldahl Nitrogen
* Surrogate recovery is out of range
Reporting
Date
Date
Analyzed
Result
Units
Limit
Prepared Analyzed
By Dilution
24.7
mg/L
0.010
02/18/99
02/22/99
OX 1
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC 1
<0.005
mg/L
0.005
02/19/99
02/19/99
KJC 1
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC 1
<0.0001
mg/L
0.0001
02/19/99
02/19/99
JMO 1
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC 1
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC 1
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC 1
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC 1
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC 1
<0.050
mg/L
0.050
02/19/99
02/19/99
KJC 1
2
mg/L
1
02/19/99
0220/99
SAB 1
0.90
mg/L
0.40
0222/99
0222/99
ARM
Client Sample ID: WELL K
Sample Number:
99-0492-004
Date Sampled: 02/12/99
Sample
Matrix:
Liquid
Time Sampled: 15:50
Sampled By:
LW
EPA 8081A 4,4'-DDD
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
4,4'-DDE
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
4,4'-DDT
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Aldrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
alpha-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
beta-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
delta-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
alpha -Chlordane
<0.05
µg/L
0.05
02/19/99
0228/99
MGK I
gamma -Chlordane
<0.05
µg/L
0.05
02/19/99
0228/99
MGK I
Dieldrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
Endosulfan I
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endosulfan II
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endosulfan sulfate
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endrin
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endrin aldehyde
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Endrin keytone
<0.050
µg/L
0.050
02/19/99
0228/99
MGK I
gamma-BHC
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Heptachlor
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Heptachlor epoxide
<0.050
µg/L
0.050
02/19/99
0228/99
MGK 1
Methoxychlor
<0.10
µg/L
0.10
02/19199
0228/99
MGK 1
Page 9 of 11
Certes Environmental Laboratories
=_:3 Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394.2872- F 620-7963- Email: certes@aol.com
,=-� .:;!cal Chemistry Environmental Sciences = -Z arch Microbiology
Results of Analyses
CEL File No.: 99-0492
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0492-004 continued...
Result
Units
Limit
Prepared Analyzed
By
Dilution
EPA 8081A
Toxaphene
<1.0
µg/L
1.0
02/19/99
02/28/99
MGK
1
**Quality Control Surrogate
02/19/99
02/28/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene (*
51%
60-140%
02/19/99
0228/99
MGK
1
Decachlorobiphenyl (SS)
84%
60-140%
02/19/99
0228/99
MGK
1
EPA 8082
Aroclor-1016
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1221
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1232
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1242
<5.0
µg/L
5.0
02/19/99.
02/28/99
MGK
1
Aroclor-1248
<5.0
µg/L
5.0
02/19/99
02/28/99
MGK
1
Aroclor-1254
<5.0
µg/L
5.0
02/19/99
0228/99
MGK
1
Aroclor-1260
<5.0
µg/L.
5.0
02/19/99
0228/99
MGK
1
**Quality Control Surrogate
02/19/99
0228/99
MGK
1
2,4,5,6-Tetrachloro-m-xylene(
*51%
60-140%
02/19/99
0228/99
MGK
1
Decachlorobiphenyl (SS)
84%
60-140%
02/19/99
0228/99
MGK
1
EPA 8151A
2,4-D
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4-DB
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4,5-T
<2
µg/L
2
0222/99
0222/99
ARM
1
2,4,5-TP (Silvex)
<2
µg/L
2
0222/99
0222/99
ARM
1
Dalapon
<2
µg/L
2
0222/99
0222/99
ARM
1
Dicamba
<2
µg/L
2
0222/99
0222/99
ARM
1
Dichloroprop
<2
µg/L
2
0222/99
0222/99
ARM
1
Dinoseb
<2
µg/L
2
0222/99
0222/99
ARM
1
MCPA
<2
µg/L
2
0222/99
0222/99
ARM
1
MCCP
<2
µg/L
2
0222/99
0222/99
ARM
1
SM 4500CI.B
Chloride
350
mg/L
50
02/18/99
02/18/99
BWB
10
EPA 375.4
Sulfate
406
mg/L
75
02/19/99
02/19/99
DJD
15
EPA 354.1
Nitrite
<0.01
mg/L
0.01
02/19/99
02/19/99
BWB
1
EPA 353.3
Nitrate
4.58
mg/L
1.00
02/18/99
02/18/99
BWB
10
SM4500NH3.D
Ammonia
<0.10
mg/L
0.10
02/19/99
02/19/99
BWB
1
SM 2320B
Alkalinity as Carbonate
<5
mg/L
5
02/22/99
0222/99
DJD
1
Alkalinity as Bicarbonate
260
mg/L
25
0222/99
0222/99
DJD
5
EPA 6010B
Boron
0.620
mg/L
0.010
02/18/99
02/22/99
OX
1
Potassium
26.5
mg/L
1.0
02/18/99
02/22/99
OX
1
Sodium
187
mg/L
1.0
02/18/99
0222/99
OX
1
Calcium
93.2
mg/L
1.0
02/18/99
0222/99
OX
1
Magnesium
23.9
mg/L
0.010
02/18/99
0222/99
OX
1
Arsenic
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC
1
Cadmium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Chromium
<0.005
mg/L
0.005
02/18/99
02/19/99
KJC
1
Page 10 of 11
7 Certes Environmental Laboratories
:709 Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620.7966.600-394-2872 • Gs + 2-520-7963 - Email: certes@aol.com
Ara.ytical Chemistry Environmental Sciences res=arch Microbiology
P
Results of Analyses
CEL File No.: 99-0492
Report Date: 03/02/99
Reporting
Date
Date
Analyzed
Sample: 99-0492-004 Continued...
Result
Units
Limit
Prepared Analyzed
By Dilution
EPA 7470A
Mercury
<0.0001
mg/L
0.0001
02/18/99
02/19/99
.IMO 1
EPA 6010B
Zinc
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC 1
Copper
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC I
Nickel
<0.010
mg/L
0.010
02/18/99
02/19/99
KJC
Lead
<0.015
mg/L
0.015
02/18/99
02/19/99
KJC 1
Selenium
<0.040
mg/L
0.040
02/18/99
02/19/99
KJC 1
Molybdenum
<0.050
mg/L
0.050
02/18/99
02/19/99
KJC 1
EPA 418.1
TPH
l
mg/L
1
02/19/99
02/20/99
SAB I
* Surrogate recovery is out ojrange
Page 11 of 11
Certes Environmental Laboratories
:209 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972-620.7966.800.394-2872 - Fes'- ;'=-620.7963 • Email: certesdaol.com
Ana;ytical Chemistry Environmental Sciences Fe;=arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
Ca
Cd
K
Mg
Na
Laboratory Control Sample
Batch Number
021999
ICVS
021899
021999
021899
Date Prepared
02/19/99
02/19/99
02/18; 99
02/19/99
02/18/99
Date Analyzed
02/22/99
02/22/99
02/21'99
02/22/99
02/22/99
% Recovery
84
104
88
104
89
% Recovery Duplicate
80
105
86
105
89
Relative Percent Difference (RPD)
4
1
2
1
0
Method Blank
<0.010 1 <0.005 1 <1.00 1 <0.010 I <1.00
µwl = micrograms per liter (ppb) mg/I = milligrams per liter I ppm)
µkg = micrograms per kilogram (ppb) mg/kg = milligrams per kilogram (ppm)
< = less than % = percent
MS = Matrix Spike RPD = Relative Percentage Difference
.MSD = Matrix Spike Duplicate RW - Reagent Water
LCS = Laboratory Control Sample LCSD = Laboratory Control Sample Duplicate
BS = Blank Spike BSD = Blank Spike Duplicate
µmhos/cm = micromhos/centimeter
Mertes Environmental Laboratories
__:3 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972.620-7966. 800-394-2872- 2-620-7963 • Email: certes4�aol.com
:,cal Chemistry Environmental Sciences = _ : earch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
As
Cd
Cr
Cu :
Mo
Matrix S ike
Batch Number
W021999
W021899
W021899
W021899
W021899
Date Prepared
02/18/99
02/18/99
02/18/99
02/18/99
02/19/99
Date Analyzed
02/19/99
02/19/99
02/19/99
02/19/99
02/19/99
Spiked Sample ID
0492-1
0492-1
0492-1
0492-1
0492-1
Sample Measured Result
<0.050
<0.005
<0.005
<0.010
<0.010
Spike Level
(m ) ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.50
Spike Result
(mg/L) (µg/L) (mg/Kg) (µg/Kg)
0.467
0.446
0.437
0.445
0.455
% Recovery
93
89
87
89
91
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
0.462
0.445
0.437
0.438
0.458
% Recovery Duplicate
92
89
87
88
92
Relative Percent Difference (RPD)
1
0
0
1
1
Control Limits (%low -%hi )
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.005
<0.005
<0.010
<0.010
Laboratory Control Sample
Spike Level
(m ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.50
Spike Result
(m ) ( ) (m ) ( )
0.457
0.465
0.453
0.456
0.455
% Recovery
91
93
91
91
91
Spike Duplicate Result
m ( ) (mg/Kg) ( )
0.457
0.476
0.459
0.463
0.467
% Recovery Duplicate
91
95
92
93
93
Relative Percent Difference (RPD)
0
2
1
2
3
180-120
Control Limits %low "/ohi )
80-120
80-120
k80-120
80-120
µg/l = micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS — Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD - Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=C9 Wisconsin Street. Suite 200 Dallas. Texas. 75229.972.620-7966.800.394.2872 • FAX : 620-7963- Email: certes®aol.com
Ana.ytical Chemistry Environmental Sciences F:==arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
Ni
Pb
Se
7.n
Hg
Matrix Spike
Batch Number
W021899
W021899
W021899
W021899
W021899
Date Prepared
02/18/99
02/18/99
02/18/99
02/18/99
02/18/99
Date Analyzed
02/19/99
02/19/99
02/19/99
02/19/99
02/19/99
Spiked Sample ID
0492-1
0492-1
0492-1
0492-1
0492-2
Sample Measured Result
<0.010
<0.015
<0.020
<0.050
<0.0001
Spike Level
(m ) ( ) (mg/Kg) ( )
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ) ( ) (mg/Kg) (jig/Kg)
0.448
0.468
0.469
0.464
0.0039
% Recovery
90
94
94
93
78
Spike Duplicate Result
m ) ( ) (mg/Kg) ( )
0.433
0.468
0.489
0.455
0.0036
% Recovery Duplicate
87
94
98
91
72
Relative Percent Difference (RPD)
3
0
4
2
7
Control Limits (%low%hi )
75-125
75-125
75-125
75-125
75-125
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.010
<0.015
<0.020
<0.050
<0.000I
Laboratory Control Sample
Spike Level
m ) ) (m ) (jig/Kg)
0.50
0.50
0.50
0.50
0.0050
Spike Result
(m ) ( (mg/Kg) ( )
0.461
0.474
0.481
0.468
0.0050
% Recovery
92
95
96
94
100
Spike Duplicate Result
(m ( (mg/Kg) (
0.468
0.491
0.472
0.474
0.0051
% Recovery Duplicate
94
98
94
95
102
Relative Percent Difference (RPD)
2
4
2
1
1
Control Limits %low -%hi
80-120
80-120
80-120
80-120
80-120
µg/I = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=_09 Wisconsin Street, Suite 200 Dallas, Texas. 75229.972.620.7966.800-394-2872 - F.:.t : -_-620-7963 • Email: certes@aol.com
rn:ytical Chemistry Environmental Sciences Fe==arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
r
Alkalinity
Chloride
x jY
Sulfate
Ammonia :.
Matrix Spike
Batch Number
Alk-022299
CI-21899 1 SO421999
NH321999
Date Prepared
02/22/99
02/18/99 i 02/19/99
02/19/99
Date Analyzed
02/22/99
02/18/99 i 02/19/99
02/19/99
Spiked Sample ID
0492-1
0432-1 10492-3
0492-1
Sample Measured Result
290
440 197
0.557
Spike Level
(m ) ( ) (mg/Kg) ( )
540
500 100
1.00
Spike Result
(mg/L) (µg/L) (mg/Kg) (µg/Kg)
250
930 1304
1.38
% Recovery
100
98 107
82
Spike Duplicate Result
(m ) ( ) (mg/Kg) ( )
550
i
930 1 307
1.41
% Recovery Duplicate
104
98 110
85
Relative Percent Difference (RPD)
4
0 3
4
Control Limits (%low -%hi )
80-120
75-125 0-20
75-125
Method Blank
(m ) ( ) (mg/Kg) ( )
<5.00
44
<5.00 i <5.00
<0.010
I
Laboratory Control Sample
i
I
Spike Level
(m ( ) (m ) ( )
100
50.0 100
1.00
Spike Result
(mQ/L) ( ) (mg/Kg) ( )
102
52.0 92.8
0.90
% Recovery
102
104 °: 93
90
Spike Duplicate Result
(m ( )(m ) )
N/A
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A I N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A I N/A
N/A
190-110
Control Limits %low -%hi
90-110
90-110 1 90-110
µgA = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
NIS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (Fpm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplic=
Certes Environmental Laboratories
__:? Wisconsin Street. Suite 200 Dallas, Texas. 75229.972-620-7966.800-394-2872 - ==._ :-2.520-7963 - Email: certesc-aot.com
:k?-__ .-:cal Chemistry Environmental Sciences = --- :=arch Microbiology
F
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
:.
Nifnte
oNUmte
TPH 418.1
Arochlor
1260
Matrix Spike
Batch Number
NO221999
NO321899
W99-011
PCB99014
Date Prepared
02/19/99
02/18/99
02/19/99
02/18/99
Date Analyzed
02/19/99
02/18/99
02/20/99
02/27/99
Spiked Sample ID
0492-1
0432-7
RW
N/A
Sample Measured Result
<0.010
12.1
<1.00
N/A
Spike Level
(m ( ) m ) ( )
0.050
5.00
5.00
5.00
Spike Result
(m ) ( ) (mg/Kg) ( )
0.050
15.6
5.70
N/A
% Recovery
100
84
114
N/A
Spike Duplicate Result
(m ) ( (mg/Kg) ( )
0.049
15.8
5.70
N/A
% Recovery Duplicate
98
88
114
N/A
Relative Percent Difference (RPD)
2
5
0
N/A
Control Limits (%low%hi
75-125
75-125
80-120
48-139
Method Blank
(m ) ( ) (mg/Kg) (jig/Kg)
<0.010
<0.010
<1.00
<5.00
Laboratory Control Sample
Spike Level
(m ( (mg/Kg) (jig/Kg)
0.020
0.50
5.00
5.00
Spike Result
(m ( (mg/Kg) ( )
0.019
0.52
N/A
4.03
% Recovery
97
104
N/A
81
Spike Duplicate Result
(m ( ) (mg/Kg) ( )
N/A
N/A
N/A
4.22
% Recovery Duplicate
N/A
N/A
N/A
84
Relative Percent Difference (RPD)
N/A
N/A
N/A
5
Control Limits %low %hi )
90-110
90-110
80-120
48-139
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=_=3 Wisconsin Street, Suite 200 Dallas, Texas, 75229.972.620.7966 •800-394.2B72 - FAX :-=-620-7963 • Email: certes lc�'aol.com
Aga ;ical Chemistry Environmental Sciences Re-z arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
Gamma-BHC .
(Lindane) =:
Heptachlor.
Aldrin
Matrix S ike
Batch Number
PST99014
PST99014
PST99014
Date Prepared
02/18/99
02.18/99
02/18/99
Date Analyzed
02/27/99
02, 27/99
02/27/99
Spiked Sample ID
N/A
N/A
N/A
Spike Level
(m ) ( ) (mg/Kg) ( )
0.40
0.40
0.40
Spike Result
(m ( (mg/Kg) ()
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N/A
N/A
% Recovery Duplicate
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
Control Limits (%low -%hi )
50-119
46-117
44-104
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sample
Spike Level
m ) ( (m ) )
0.40
0.40
0.40
Spike Result
(m ) ( (mg/Kg) )
0.227
0.292
0.239
% Recovery
57
73
60
Spike Duplicate Result
(m ( ) (mg/Kg) ( )
0.249
0.314
0.262
% Recovery Duplicate
62
78
66
Relative Percent Difference (RPD)
9
7
9
Control Limits %low -%hi
50-119
46-117
44-104
µg/1= micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
77:9 Wisconsin Street. Suite 200 Dallas. Texas, 75229. 972.620-7966. 800-394.2872- FAX ;'2.620-7963 • Email: certes(daol.com
Ar.aA,'Zical Chemistry Environmental Sciences Re search Microbiology
Results of Analyses - Laboratory Quality Control File No.: 99-0492
pi Idrin
E ndrin
4,4-DDT
Matrix Spike
Batch Number
PST99014
PST99014
PST99014
Date Prepared
02/18/99
02 18/99
02/18/99
Date Analyzed
02/27/99
0227/99
02/27/99
Spiked Sample ID
N/A
NrA
N/A
Spike Level
(m ) ( (mg/Kg) ( )
1.00
1.00
1.00
Spike Result
(m )( )(m )( )
N/A
N..A
N/A
% Recovery
N/A
N'A
N/A
Spike Duplicate Result
(m )( )(m )( )
N/A
N A
N/A
% Recovery Duplicate
N/A
N A
N/A
Relative Percent Difference (RPD)
N/A
N A
N/A
Control Limits (%low -%hi
48-119
62-133
59-149
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.050
<0.050
<0.050
Laboratory Control Sam le
Spike Level
(m (mg/Kg) ( )
1.00
1.00
1.00
Spike Result
(m ( (mg/Kg) (jig/Kg)
0.823
0.919
0.990
% Recovery
82
92
99
Spike Duplicate Result
(m (m )(gg/Kg)
0.817
0.903
1.00
% Recovery Duplicate
82
90
100
Relative Percent Difference (RPD)
1
2
1
Control Limits %low -%hi
48-119
62-133
59-148
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
=_99 Wisconsin Street, Suite 200 Dallas, Texas. 75229-972-620.7966.800.394-2872 - FIX c-2-620.7963 • Email: certes@aol.com
Aram ical Chemistry Environmental Sciences F::=arch Microbiology
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
Phenol ;
2-Chlora
phenol
;14
Dichloro-
benzene
n-Nitroso- ;
di-n
propylami
ne.
1,2,4-
Trichloro-
benzene
4-Chloro-
3-methyl
phenol
Matrix Spike
Batch Number
SVW-019
SVW-019
SVW-019
SN-W-019
SVW-019
SVW-019
Date Prepared
03/01/99
03/01/99
03/01/99
03 01/99
03/01/99
03/01/99
Date Analyzed
03/01/99
03/01/99
03/01/99
03 01/99
03/01/99
03/01/99
Spiked Sample ID
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
Spike Level
(m )( ) (mg/Kg) ()
200
200
100
100
100
200
Spike Result
(m )( )(m )( )
N/A
N/A
N/A
N A
N/A
N/A
% Recovery
N/A
N/A
N/A
N A
N/A
N/A
Spike Duplicate Result
(mg" ()(m )( )
N/A
N/A
N/A
N A
N/A
N/A
°.'o Recovery Duplicate
N/A
N/A
N/A
N A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N A
N/A
N/A
Control Limits (%low -%hi )
5-112
23-134
20-124
10-230
44-142
22-147
Method Blank
(m )( )(m )( )
<20
<20
<10
<10
<10
<20
Laboratory Control Sample
Spike Level
(m )( )(m )( )
200
200
100
100
100
200
Spike Result
(m )( ) m )
79
118
52
79
59
148
% Recovery
40
59
52
79
59
74
Spike Duplicate Result
(m ) mg/Kg) ()
49
92
45
64
50
118
% Recovery Duplicate
25
46
45
64
50
59
Relative Percent Difference (RPD)
46•
25
16
26
16
22
Control Limits (%low -%hi
5-112
23-134
20-124
10-230
44-142
22-147
*Outside Control Limits
µg/l = micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/l = milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
Wisconsin Street, Suite 200 Dallas. Texas. 75229.972-620-7966.800-394-2872 • :-2-620-7963 - Email: certes @gaol.com
--.-.a.,: tical Chemistry Environmental Sciences == s e arch Microbiology
t
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
Acenaph-
these
4-Nitro- .. ;:
phenol
,.2,4,-Dini-
trotoluene
Pentachloro-
phenol
Pyrene
Matrix Spike
Batch Number
SVW-019
SVW-019
SVW-019
SVW-019
SVW-019
Date Prepared
03/01/99
03/01/99
03/01/99
03/01/99
03/01/99
Date Analyzed
03/01/99
03/01/99
03/01/99
03/01/99
03/01/99
Spiked Sample ID
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
LCS/LCSD
Spike Level
(m )( )(m )( )
100
200
100
200
100
Spike Result
(m )( )(m )( )
N/A
N/A
N/A
N/A
N/A
% Recovery
N/A
N/A
N/A
N/A
N/A
Spike Duplicate Result
(m )( (mg/Kg) ()
N/A
N/A
N/A
N/A
N/A
4'6 Recovery Duplicate
N/A
N/A
N/A
N/A
N/A
Relative Percent Difference (RPD)
N/A
N/A
N/A
N/A
N/A
Control Limits (%low -%hi
47-145
10-132
39-139
14-176
52-115
Method Blank
(m )( )(m )(µ )
<10
<20
<10
<20
<10
Laboratory Control Sample
'
Spike Level
(m )(pgIL) (mg/Kg) ()
100
200
100
200
100
Spike Result
(m ( ) (mg/Kg) ()
70
133
90
202
99
% Recovery
70
67
90
101
99
Spike Duplicate Result
(m (jig/L) (mg/Kg) ()
59
51
71
159
79
% Recovery Duplicate
59
26
71
80
79
Relative Percent Difference (RPD)
17
89•
24*
24
22
Control Limits %low -%hi
47-145
10-132
39-139
14-176
52-115
*Outside Control Limits
µejl =micrograms per liter (ppb)
µg/kg = micrograms per kilogram (ppb)
< = less than
MS = Matrix Spike
MSD — Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/1= milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD — Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
'-:--Wisconsin Street. Suite 200 Dallas. Texas, 75229.972-620-7966.800-394-2872 - FAX c_ 7963 • Email: tortes@aol.com
__ .-cal Chemistry Environmental Sciences Re:==rch Microbioiogy
Results of Analyses - Laboratory Quality Control
File No.: 99-0492
Total °
Kjeldahl
Nitrogen
Herbicides
Laboratory Control Sample
Batch Number
99EN0610
99EN0610
Date Prepared
02/ 19/99
02/22/99
Date Analyzed
02/19/99
02/22/99
Spiked Sample ID
GA116-154
GA269-174
% Recovery
98
99
Method Blank
(m ) ( ) (mg/Kg) ( )
<0.40
<1.00
µg/I = micrograms per liter (ppb)
jig/kg = micrograms per kilogram (ppb)
< — less than
MS = Matrix Spike
MSD = Matrix Spike Duplicate
LCS = Laboratory Control Sample
BS = Blank Spike
µmhos/cm = micromhos/centimeter
mg/I - milligrams per liter (ppm)
mg/kg = milligrams per kilogram (ppm)
% = percent
RPD = Relative Percentage Difference
RW - Reagent Water
LCSD = Laboratory Control Sample Duplicate
BSD = Blank Spike Duplicate
Certes Environmental Laboratories
_;09 V/isconsin Street, Suite 200 Dallas, Texas, 75229. 972-620-7966. 800-394-2872 • FAX _•320.7963 • Email: certesre'aol.com
r.-a:yvcal Chemistry Environmental Sciences Research Microbiology
Environmental Laboratories, L.L.C.
Certes 2209 Wisconsin Street, Suite 200
Dallas, Texas 75229
972-620-7966 972-620-7963 Fax
An ysis(es) Requested
Client Nam
Phone No.
Z
0
r
ON
VII
Client Address
Fax No.
'b c) -1 :o "t
Billing Address City State Zip
er-A 0 A
Purchase Order No.
E
To ensure p oper billing, please ref quotation nurnbe
T•t 11, C', Ik tr
Project Manager
Site Location
Cedes
NO.
Sample ID
Date
Time
Matrix'
No. & Type of Container2
V
G
J
0
P3
GF L t-
o 1-\,LI9
W FF L-,, Z
offl%,Lo%
F kj— \A
JI
YM
\k
Sampled By
I Matrix: A - Air Bag; C - Charcoal Tube;.. L - Liquid; OL - Oil; S - Soil, SD - Solid. SL - Sludge; WP. Wipe;. W - -Water/Wastewater
2 Container Type.-V - 40ml VOA Vial; G Amber or Glass 1 Liter, J - 250ml Wide-.nwuth Glass Jar, 0
3 Preservative : HCI - Hydrochloric Acid: HNO= = Nitric Add; H.,SO, - Sulfuric Add;,: 0 - Other
TAT
Standard: Date Required
RUSH: Date Required
Client Project ID
Special Instructions (including specific detection limits)
Cedes Job Number
Relinquished by Sampler
Dat� 4
1
Time
Received By 0 _
Relinquished by
Date
Time
Received By
Relinquished by
Date
Time
Received By Laboratory
KIlQ
NOTE: By submitting these samples, you agree to the terms and conditions contained In Cedes' Schedule of Fees. Cedes cannot accept verbal changes. Please FAX written changes to (972) 620-7963.
t- L U- t-- L Lt--
t, --' --;* t 1
ij-AILWLTRACEANALYSIS,1I1.�
6701 Aberdeen Avenue, Suite 9 Lubbock, Texas 79424 800.378.1296 806.7:-*9' 296 FAX 806.794.1298
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ANALYTICAL RESULTS FOR
EmDrotec,Inc.
Attention Mark Schneider
Daze: Feb 26, 1999 6310 Genoa, Ste E
Da_= ?ec: 2/24/99 Lubbock TX 79424 La^ =eceivin # 9902000389
Pr^==__. EN 1761
Prc: =ame. N/A
Pr^ oc: N/A
Sa-,_ing Date: 2/24/99
Sa-c_e,Condition: Intact and Cool
Sa--,:e Received By: VW
TA= Field Code
MATRIX
=RPHC
mg/L)
11:_=_ Tank l 0224991530
Water
<..500
Tank 2 0224991550
Water
<=.500
Tank 3 0224991610
Water
<:.500
Me=:=t Blank
<:.500
Re-=_=_ng Limit
0.5
QC
95
RPC 0
% Ex=:action Accuracy :07
% =__s=_ument Accuracy 95
CE_= PREP
METHOD
PREP
DATE
ANALYSIS
METHOD
ANALYSIS
COMPLETED
ZHEMIST QC:
(mg/L)
SPIKE:
(mg/L)
CR_- N/A
2/24/99
EPA 418.1
2/25/99
MF 100
8.5
Director, Dr. Blair Leftwich
Date
I
' ) A .�
Page of
! 6701 Aberdeen Avenue, Ste. 9 4725 Ripley Dr., Ste A
j NhWck, Toxas 79424 • El Paso, Toxns 79922.1028
! 794- Trace.Analysis Inc. Tai(95)5i15-44
CHAIN -OF -CUSTODY AND ANALYSIS REQUEST
Fax (806) %94-1298
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1 (888) 508.3443
Company Name:
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�• �•.•.» .� ... tee.. l .• netin,epQ onrraamanr rn Torms and Conditions listed on reverse side of C.O.C.7
ca..;Pr x / l ter
99 03/09 TlE 10:59 FAX 972 241 4776 CERIES
uu.: uuo
CERTES ENVIRONMENTAL LABORATORIES
ANALYTICAL REPORT
Certes File Number: 99.0704
Client Project I.D.:
N/A
Prepared for:
ENPROTEC INC.
6310 Genoa Avenue, Suite E
Lubbock, TX 79424
Attention:
Jerry Oldham
Report Date:
03/09/99
Included are the results of chemical analyses for the samples submitted to Certes Environmental
Laboratories, L.L.C., on. All analytical results met Quality Control requirements as set by the industry
accepted criteria. Please refer to the Laboratory Quality Control Results section of this report.
This report must be reproduced in its entirety.
Sincerely,
Certes Environmental Laboratories, L.L.C.
r
Amy LaSalle
President
'99 03/09 TCE 11:00 FAX 972 241 4776 CERIES
VVJ, VUJ
Results of Analyses
CEL File No.:
99.0704
Report Date: 03/09/99
,.,
Reporting
Date Date Analyzed
t
Result Units
Limit
Prepared Analyzed
By
Dilution
Client Sample M: Pl'%'OT *4-SHALLOW
Sample Number:
99.0704.001
Date Sampled:
S=pTe Matrix:
Solid
-
Time Sampled:
Sampled By:
EPA 3270C
Benzoic acid
< 1650
µg/Kg
1650
03/07/99
MJB
1
�..
4-Chloro-3-methylphenol
<660
jig/KS
660
03/07/99
MJB
1
2-Chlorophenol
<330
µg/Kg
330
03107/99
MJB
I
2,4-Dichlorophenol
<330
µg/Kg
330
03/07/99
MJB
1
2,4-Dimethylphenol
<330
µg/Kg
330
03107/99
MJB
1
4,6-Dinitro-2-methylphenol
<1650
VS/Kg
1650
03/07/99
MJB
1
j
2,4-Diaitrophezol
< 1650
µg/Kg
1650
03107/99
MJB
1
2-Methylphenol
<330
µg/Kg
330
03107/99
MJB
1
4-Methylphenol
<330
µg/Kg
330
03/07/99
MJB
1
2-Nitrophenol
<330
µg/Kg
330
03/07/99
MJB
1
-
4-Nitropheool
< 1650
µg/Kg
1650
03/07/99
MJB
1
.�
Pentachloropbenol
< 1650
ug/Kg
1650
03/07/99
MJB
1
E
Phenol
<330
µg1Kg
330
03/07/99
MJB
1
2,4,5-Tricblorophenol
< 1650
pg/Kg
1650
03/07/99
MJB
1
2,4,6-Trichlorophenol
<330
pg/Kg
330
03/07/99
MJB
1
Acenaphthene
<330
µg/Kg
330
03/07/99
MJB
1
Acenaphthylene
<330
µg/Rg
330
03/07/99
MJB
1
Anthracene
<330
jig/Kg
330
03/07/99
MJB
1
Benzidine
<660
µg/Kg
660
03/07/99
MJB
1
,»
t
Benzo(a)anthracenc
<330
µg/Kg
330
03/07/99
MJB
1
Beazo(a)pyrene
<330
µg/Kg
330
03/07/99
MJB
1
Benzo(b)fluorantheae
<330
µg/Kg
330
03/07/99
MJB
1
Benzo(g,h,i)perylene
<330
µg/Kg
330
03/07/99
MJB
1
f
Benzo(k)fiuoranthene
<330
µg/Kg
330
03/07/99
MJB
1
Benzyl alcohol
<660
µg/KE
660
03/07/99
MJB
I
bis-(2-chloroethyl) ether
<330
µg/Kg
330
03/07/99
MJB
1
bis-(2-ehloroethoxy) methane
<330
µg/Kg
330
03/07/99
MJB
1
bis-(2-chloroisopropyl) ether
<330
µg/Kg
330
03/07/99
MJB
1
bis-(2-ethylhexyl) phthalate
<330
µg/Kg
330
03/07/99
MTB
1
4-Bromophenyl-phenylether
<330
µg/KS
330
03/07/99
MJB
1
!'
ButylbeazylpbdWate
<330
µg/Kg
330
03/07/99
MJB
1
4-Chloroaailine
<660
µg/Kg
660
03/07/99
MJB
1
2-Chloronaphthalene
<330
µg/Kg
330
03/07/99
MJB
1
y�
4-Chlorophenyl-phenylether
030
µg/Kg
330
03/07/99
MJB
1
1
Chrysene
<330
µg/Kg
330
03/07/99
MJB
1
r.,
Dibeazo(a,h)anthracene
<330
µF/Kg
330
03/07/99
MJB
I
Page 2 of
I
PA
I 1
99 03%09 TGE 11: 00 FAX 972 241 4776 CERIES
UU4%UUJ
f,.
Results of Analyses CEL File No.: 99-0704
Report Date. 03/09/99
Reporting
Date Date
Analyzed
,SarnPlc- 99.0794-001 continued...
Result
Units
Limit
Prepared Analyzed
By
Dllution
EPA 8270C Dibenzofuran
<330
µg/Kg
330
03/07/99
MJB
1
1,2-Dichlorobeazece
<330
pg/Kg
330
03/07/99
M1B
1
1,3-Dichlorobenzene
<330
µg/Kg
330
03/07/99
MJB
1
1,4-Dichlorobenzene
<330
PS/Kg
330
03/07/99
MJB
I
3,3-Dichlorobenzidine
<660
pg/Kg
660
03/07/99
MJB
1
Diethylphthalate
<330
µg/Kg
330
03/07/99
MJB
1
D'imethylphthalate
<330
pg/Kg
330
03/07/99
MJB
I
Di-n-butylphthalatc
<330
pg/Kg
330
03/07/99
MJB
1
2,6-Diaitrotoluene (2,6-DNT)
<330
µg/Kg
330
03/07/99
MJB
I
Dl-n-octylphtbalate
<330
µg/Kg
330
03/07/99
MJB
1
Azobenzeae
<660
pg/Kg
660
03/07/99
MJB
1
Fluoranthene
<330
µg/Kg
330
03/07/99
MJB
I
Fluorene
<330
pg/Kg
330
03/07/99
MJB
1
Hexachlorobenzene
<330
µg/Kg
330
03/07/99
MJB
1
Hexachlorobutadiene
<330
µg1Kg
330
03/07/99
MJB
I
Henchlorocyclopentadiene
<330
µg/Kg
330
03/07/99
MJB
1
HexachIcroethane
<330
pg/Kg
330
03/07/99
MJB
1
Indeno(1,2,3-cd)pyrene
<330
µg/Kg
330
03/07/99
MJB
1
Isophorone
<330
µg/Kg
330
03/07/99
MJB
1
2-Methylnaphthalene
<330
pg/Kg
330
03/07/99
MTB
I
Naphthalene
<330
µg/Kg
330
03/07/99
MJB
1
2-Nitroaailine
<1650
µg/Kg
1650
03/07/99
MJB
1
3-Nitroaniline
<1650
µg/KS
1650
03/07/99
MJB
1
4-Nitroaailine
< 1650
pg/Kg
1650
03/07/99
MJB
1
Nitrobenzene (NB)
<330
µg/Kg
330
03/07/99
MJB
1
N-Nitrosodimethylamine
<660
pg/Kg
660
03/07/99
MJB
1
N-Nitrosodiphenylamine
<330
pg/Kg
330
03/07/99
MJB
1
N-Nitrosodipropylamine
<330
pg/Kg
330
03/07/99
MJB
1
Phenanthrene
<330
vs/Kg
330
03/07/99
MJB
1
Pyrene
<330
µg/Kg
330
03/07/99
MJB
I
1,2,4-Trichlorobenzene
<330
pg1Kg
330
03107/99
MJB
1
"Quality Control Surrogate
03/07/99
MJB
1
Nitrobenzene-5 (SS)
68%
43-138%
03/07/99
MJB
I
2-Fluorobiphenyl (SS)
62%
50-124%
03/07/99
MJB
1
Terpheny1-d14 (SS)
71 %
62.145%
03/07/99
MJB
I
2-Fluorophenol (SS)
S4elo
25-121%
03/07/99
MJB
I
Phenol-d5 (SS)
579a
24-11317v
03/07/99
MJB
I
•2,4,6-Tribromophenol (SS)
92%
19-122rya
03/07/99
MJB
I
Page 3 of 4
199 03/09 TCE 11:01 FAX 97Z 941 477G k-tKua � wo -vva
Results of Analyses CEL File No.: 99.0704 Report Date: 03/09/99
r Reporting Date Date Analyzed
Result Units Limit Prepared Analyzed By Dilution
Client Sample ID: PIVOT #7-SHALLOW
Sample Number:
99.0704.002
Date Sampled:
Sample Matrix:
Solid
Time Sampled:
Sampled By:
TX1005 C6-C10 - Carbon Range <50
mg/Kg 50 03/05/99 03/06/99
KSM 1
>C10-C28 - Carbon Range <50
mg/Kg 50 03/05/99 03/06/99
KSM 1
C6-C2& - Carbon Range <50
mg/Kg 50 03105/99 03106/99
KSM 1
Client Sample ID: PIVOT #8-SHALLOW
Sample Number.
99-0704-003
Date Sampled:
Sample Matrix:
Solid
Time Sampled:
Sampled By:
TX1005 C6-C 10 - Carbon Range <50
mg/KS 50 03/05/99 03/06/99
KSM 1
>C10-C28 - Carbon Range <50
mg/Kg 50 03/05/99 03/06/99
KSM 1
C6-C2& - Carbon Range <50
mg/Kg 50 03/05/99 03/06/99
KSM 1
Client Sample ID: PIVOT #16-SHALLOW
Sample Number:
99.0704.004
Date Sampled:
Sample Matrix:
Solid
Time Sampled:
Sampled By:
TX1005 C6-C10 - Carbon Range <50
mg/Kg 50 03/05/99 03/06/99
KSM 1
>C10-C28 - Carboa Range <50
mg/Kg SO 03/05/99 03/06/99
KSM 1
C6-C28 - Carbon Range <50
mg/Kg 50 03/05/99 03/06/99
KSM 1
Page 4 of 4
Exhibit "G" To Amendment and
Modification of Contract of Sale and
Contract of Sale, as Amended —
Deed Without Warranty
+� EXHIBIT "G"
To Amendment and Modification of Contract of Sale
I' and Contract of Sale, as Amended
L PEED
THE STATE OF TEXAS {
{ KNOW ALL MEN BY THESE PRESENTS:
COUNTY OF LYNN {
THAT Lubbock Christian University and J.E_ Hancock, dealing in
his sole and separate estate and in property which constitutes no
part of his homestead, herein collectively called "Grantor", for
and in consideration of the sum of TEN AND NO/100 DOLLARS ($10.00),
and other good and valuable consideration to Grantor in hand paid
by the CITY OF LUBBOCK, a Texas Home Rule Municipal Corporation
(herein called "Grantee"), P.O. Box 2000, Lubbock, Texas 79457, the
receipt and sufficiency of which are hereby acknowledged and
confessed, subject to the reservations set forth below, have
GRANTED, SOLD and CONVEYED, and by these presents do hereby GRANT,
SELL and CONVEY, without Warranty, unto Grantee all of the real
property located in Lynn County, Texas, described in Exhibit "A"
attached hereto, together with all fixtures and improvements
attached thereto (the "Lands').
PROVIDED HOWEVER, the Lands are hereby conveyed subject to all
valid, existing mineral reservations and conveyances, and easements
and rights -of -way, if any affecting said premises and of record in
the Office of the County Clerk of Lynn County, Texas.
Grantor, subject to the restrictions set forth below,
expressly reserves to themselves in the proportions Grantor now own
same, and unto their respective successors, assigns, heirs,
executors and administrators, all oil, gas and other minerals lying
in, on, under and that may be produced from the Lands. As used
herein, the term "minerals" shall exclude (i) all substances
(except oil, and gas) that any reasonable extraction, mining or
j" other exploration and/or production method, operation, process or
procedure Would consume, deplete or destroy the surface of the
f' Lands; and (ii) all substances (except oil and gas) which are at or
near the surface of the Lands. The intent of the parties hereto is
that the meaning of the term "mineral" as utilized herein, shall be
in accordance with that set forth in Reed v. Wylie, 597 S.W.2d 743
(Tex.1980).
For the protection of the surface estate of the Lands, and as
a covenant running with said lands and binding upon the Grantor
herein and Grantor's respective successors, assigns, heirs,
executors and administrators, it is agreed that any person, company
or other entity conducting operations in connection with the
interest in the oil, gas and other minerals in, on, under and that
may be produced from said Lands which is now owned by Grantor,
under the authority of the Grantor, and Grantor's respective
successors, assigns, heirs, executors and administrators, granted
after the date hereof, shall comply with the following provisions
and requirements for the protection of the surface estate of said
Lands, and any oil, gas and mineral lease hereafter executed by the
Grantor, and Grantor's respective successors, assigns, heirs,
executors and administrators, shall contain such provisions, it
being understood and agreed, however, that such provisions will be
binding upon the person, company or other entity conducting such
mineral operations (in such provisions referred to as Lessee) as
covenants running with the land and whether or not such provisions
are included in such lease or leases hereafter executed, said
r
provisions being as follows:
(a) Lessee, its successors and assigns, (as used in
paragraphs (a) through (k), the term "Lessee" shall
include Grantor if Grantor is the party conducting the
oil, gas and other mineral exploration and/or production
activities) shall pay to the owner of the surface estate
of the Lands (the "surface Owner") a reasonable amount
for all damages of any type or kind caused or related to
mineral exploration and/or production activities upon the
Lands.
(b) Lessee shall conduct all of its mineral exploration
and/or production activities upon the Lands in such a
manner so as to interfere as little as reasonably
possible with the use and operation of the Lands of the
Surface Owner. No surface drilling location, storage
facility, roadway or facility of any kind located on or
above the surface shall be located within or under a
pivot irrigation system without the prior consent of the
Surface Owner, which consent shall not be unreasonably
withheld.
(c) It is further understood and agree that any and all roads
established by the Lessee hereunder shall be located as
nearly as practical as agreed upon by and between Lessee
and the Surface Owner.
(d) All pipeline, flowlines, electric transmission lines,
telephone lines or other lines necessary or related to
mineral exploration and/or production activities on the
Lands shall be buried no less than thirty-six (36) inches
below the surface of the ground, except at the actual
drilling or storage facility site.
(e) upon completion of any mineral exploration and/or
production activities, including exploration activities
that result in the completion of an oil or gas well (s) or
abandonment of any drill site(s), pit area(s), well
location(s), tank battery locations(s), roadway(s) or
other surface disturbance(s), Lessee shall as soon as
reasonably practicable (i) remove all rock, gravel,
caliche, or other materials foreign to the natural
condition of the Lands; (ii) level and fill with topsoil
all pits, ruts, or other surface disturbances in such a
manner as to restore same to the natural contour of the
Lands; (iii) clean the area to the and that all objects,
materials and structures not reasonably necessary to the
production of oil and/or gas are removed and eliminated;
(iv) reseed the affected area with native grass; and (v)
otherwise restore the surface of the Lands to its
original condition as nearly as reasonably possible.
7,
a
(f) Any saltwater produced from Wells drilled on the Lands
shall be disposed of off the Lands, or shall be
jreinjected into a subsurface strata at a depth sufficient
to protect all sources and supplies of fresh and potable
water. No saltwater shall be disposed on the Lands, as
�•• set forth herein, except that produced from the Lands.
(g) Lessee agrees to protect the potable water, in, on and
under the Lands, from contamination from mineral
exploration and/or production activities, and upon the
abandonment of any oil or gas well. Lessee shall plug
the same in compliance with the applicable laws, rules
and regulations of the Railroad Commission of Texas,
and/or any other governmental authority having
jurisdiction over such matters.
(h) Lessee, if requested by Surface Owner, shall construct
and maintain fences around each site of surface
facilities related to mineral pumping units, tank
batteries and pits sufficient to keep all livestock out
of such sites.
(i) Lessee shall not, and shall not permit any of its
employees, contractors, agents, or other third parties
acting on behalf of such parties entering upon the Lands,
to bring upon the Lands any alcoholic beverages or
illegal drugs, to hunt on any portion of the Lands or to
take or carry any firearms thereon for any purpose
whatsoever.
(j) All mineral exploration and/or production operations on
the Lands shall be conducted in a reasonably prudent
wanner and in compliance with the laws, rules and
regulations pertaining to oil, gas and mineral operations
within the State of Texas.
(k) No potable water, or water suitable for livestock
consumption, irrigation or land application purposes, may
be taken or used, in any way, manner or form, from the
Lands for or related to any mineral exploration and/or
production activities of any kind or type.
Notwithstanding any of the above language to the contrary,
Grantor shall have no personal liability to the owner of the
surface estate in connection with the mineral operations
conducted thereon by other parties.
TO HAVE AND TO HOLD the Lands, together with, all and
singular, the rights and appurtenances thereto in anywise belonging
unto Grantee and Grantee's successors and assigns, forever.
EXECUTED this Sth day of April, 1999.
GRANTOR:
LUBBOCK CHRISTIAN UNIVERSITY
By:
Jerry D. Harris
Chairman of the Board
J.E. Hancock
STATE OF TEXAS
COUNTY OF LUBBOCK
This instrument was acknowledged before me on the day
of April, 1999, by Jerry D. Harris, Chairman of the Board of
Lubbock Christian University, on its behalf.
Notary Public, State of Texas
STATE OF TEXAS
COUNTY OF LUBBOCK
This instrument was acknowledged before me on the day
of April, 1999, by J.E. Hancock.
Notary Public, State of Texas
EXHIBIT "A"
To Deed Without Warranty
TRACT 1
Three (3) tracts of land, being: (a) 31.39 acre tract, more or less, in the
form of a triangle, said triangle being bounded on the N by the S line of
Tracts 3 and 4, League 4, Wilson County School Land; on the SE by the
Panhandle and South Plains Railroad right-of-way; and on the SW by Kerr
Avenue of the Town of Wilson, Texas; (b) 31.50 acres, more or less, said
tract being bounded on the N by the S line of Tracts 3 and 4, League 4,
Wilson County School Land; on the NE by Culpepper Avenue of the
Town of Wilson, Texas; on the SE by 16`h Street of the Town of Wilson,
Texas; on the SW by Green Avenue of the Town of Wilson, Texas; and on
the W by the W line of League 4, Wilson County School Land, SAVE &
EXCEPT Lots 1, 2, 3, 10, 11 and 12, Block 171, Lots 1, 2, 3, 7, 8, 9, 10,
11 & 12, Block 172, all of Block 178, 160' x 175' tract sold to Dan Cook
(being all of Lots 11 and 12, Block 182 and all of the Street lying South of
said lots); (c) a 14.25 acre tract, more or less, being all of Blocks 173, 175,
176, 177, 183, 185, 186, 187, 188 and 189, as shown of record in Volume
15, Page 102-103, Deed Records of Lynn County, Texas, SAVE &
EXCEPT those portions of the aforementioned blocks deeded to Henry
Dreyer, Jr., by deed recorded in Volume 62, Page 418-419, Deed Records
of Lynn County, Texas, and EXCEPTING all of Block 174 dedicated as a
public park.
TRACT 2
All of Block 169, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-
12 of Block 170, Old Town Wilson, Wilson, Lynn County, Texas; Lots 4-
9 of Block 171, Old Town Wilson, Wilson, Lynn County, Texas; Lots 4-6
of Block 172, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-12
of Block 179, Old Town Wilson, Wilson, Lynn County, Texas; All of
Block 180, Old Town Wilson, Wilson, Lynn County, Texas; All of Block
181, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-6 of Block
182, Old Town Wilson, Wilson, Lynn County, Texas; Lots 5-12 of Block
184, Old Town Wilson, Wilson, Lynn County, Texas.
cityattlrichar&ExhA-DeedwoWarr.doc
?Ow`
i
Exhibit "H" To Amendment and
Modification of Contract of Sale and
Contract of Sale as Amended —
�'. Description of Lands
l
EXHIBIT "H"
To Amendment and Modification of Contract of Sale
and Contract of Sale, as Amended
TRACT 1
Three (3) tracts of land, being: (a) 31.39 acre tract, more or less, in the
form of a triangle, said triangle being bounded on the N by the S line of
{
Tracts 3 and 4, League 4, Wilson County School Land; on the SE by the
Panhandle and South Plains Railroad right-of-way; and on the SW by Kerr
►�
Avenue of the Town of Wilson, Texas; (b) 31.50 acres, more or less, said
tract being bounded on the N by the S line of Tracts 3 and 4, League 4,
Wilson County School Land; on the NE by Culpepper Avenue of the
Town of Wilson, Texas; on the SE by 16`h Street of the Town of Wilson,
Texas; on the SW by Green Avenue of the Town of Wilson, Texas; and on
the W by the W line of League 4, Wilson County School Land, SAVE &
EXCEPT Lots 1, 2, 3, 10, 11 and 12, Block 171, Lots 1, 2, 3, 7, 8, 9, 10,
u ;
11 & 12, Block 172, all of Block 178, 160' x 175' tract sold to Dan Cook
(being all of Lots 11 and 12, Block 182 and all of the Street lying South of
said lots); (c) a 14.25 acre tract, more or less, being all of Blocks 173, 175,
176, 177, 183, 185, 186, 187, 188 and 189, as shown of record in Volume
15, Page 102-103, Deed Records of Lynn County, Texas, SAVE &
'
EXCEPT those portions of the aforementioned blocks deeded to Henry
h
Dreyer, Jr., by deed recorded in Volume 62, Page 418-419, Deed Records
of Lynn County, Texas, and EXCEPTING all of Block 174 dedicated as a
public park.
TRACT 2
All of Block 169, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-
12 of Block 170, Old Town Wilson, Wilson, Lynn County, Texas; Lots 4-
9 of Block 171, Old Town Wilson, Wilson, Lynn County, Texas; Lots 4-6
of Block 172, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-12
of Block 179, Old Town Wilson, Wilson, Lynn County, Texas; All of
Block 180, Old Town Wilson, Wilson, Lynn County, Texas; All of Block
181, Old Town Wilson, Wilson, Lynn County, Texas; Lots 1-6 of Block
182, Old Town Wilson, Wilson, Lynn County, Texas; Lots 5-12 of Block
184, Old Town Wilson, Wilson, Lynn County, Texas.